Monitoring of nitrate leaching in sandy soils: comparison of three methods

Proper N fertilizer and irrigation management can reduce nitrate leaching while maintaining crop yield, which is critical to enhance the sustainability of vegetable production on soils with poor water and nutrient-holding capacities. This study evaluated different methods to measure nitrate leaching in mulched drip-irrigated zucchini, pepper, and tomato production systems. Fertigation rates were 145 and 217 kg N ha(-1) for zucchini; 192 and 288 kg N ha(-1) for pepper; and 208 and 312 kg N ha(-1) for tomato. Irrigation was either applied at a fixed daily rate or based on threshold values of soil moisture sensors placed in production beds. Ceramic suction cup lysimeters, subsurface drainage lysimeters and soil cores were used to access the interactive effects of N rate and irrigation management on N leaching. Irrigation treatments and N rate interaction effects on N leaching were significant for all crops. Applying N rates in excess of standard recommendations increased N leaching by 64, 59, and 32%, respectively, for pepper, tomato, and zucchini crops. Independent of the irrigation treatment or nitrogen rate, N leaching values measured from the ceramic cup lysimeter-based N leaching values were lower than the values from the drainage lysimeter and soil coring methods. However, overall nitrate concentration patterns were similar for all methods when the nitrate concentration and leached volume were relatively low.     

Predicting nitrate leaching under potato crops using transfer functions

Nitrate leaching is a major issue in many cultivated soils. Models that predict the major processes involved at the field scale could be used to test and improve management practices. This study aims to evaluate a simple transfer function approach to predict nitrate leaching in sandy soils. A convective lognormal transfer (CLT) function is convoluted with functional equations simulating N mineralization, plant N uptake, N fertilizer dissolution, and nitrification at the soil surface to predict solute concentrations under potato (Solanum tuberosum L.) and barley (Hordeum vulgare L.) fields as a function of drainage water. Using this approach, nitrate flux concentrations measured in drainable lysimeters (1-m soil depth) were reasonably predicted from 29 Apr. 1996 to 3 Dec. 1996. With average application rates of 16.9 g m(-2) of N fertilizer in potato crops, mean nitrate-leaching losses measured under potato were 8.5 g N m(-2). Tuber N uptake averaged 9.7 g N m(-2) and soil mineral N at start (spring) and end (fall) of N mass balance averaged 1.7 and 4.5 g N m(-2), respectively. Soil N mineralization was estimated by difference (4.3 g N m(-2) on average) and was small compared with N fertilization. Small nitrate flux concentrations at the beginning of the cropping season (May) resulted mainly from initial soil nitrate concentrations. Measured and predicted nitrate flux concentrations significantly increased at mid-season (July-August) following important drainage events coupled with complete dissolution and nitrification of N fertilizers, and declining N uptake by potato plants. Decreases in nitrate concentrations before the end of year (November-December) underlined the predominant effect of N fertilizers applied for the most part at planting acting as a pulse input of solute.     

In situ measurements of nitrate leaching implicate poor nitrogen and irrigation management on sandy soils

Minimizing the risk of nitrate contamination along the waterways of the U.S. Great Plains is essential to continued irrigated corn production and quality water supplies. The objectives of this study were to quantify nitrate (NO(3)) leaching for irrigated sandy soils (Pratt loamy fine sand [sandy, mixed, mesic Lamellic Haplustalfs]) and to evaluate the effects of N fertilizer and irrigation management strategies on NO(3) leaching in irrigated corn. Two irrigation schedules (1.0x and 1.25x optimum) were combined with six N fertilizer treatments broadcast as NH(4)NO(3) (kg N ha(-1)): 300 and 250 applied pre-plant; 250 applied pre-plant and sidedress; 185 applied pre-plant and sidedress; 125 applied pre-plant and sidedress; and 0. Porous-cup tensiometers and solution samplers were installed in each of the four highest N treatments. Soil solution samples were collected during the 2001 and 2002 growing seasons. Maximum corn grain yield was achieved with 125 or 185 kg N ha(-1), regardless of the irrigation schedule (IS). The 1.25x IS exacerbated the amount of NO(3) leached below the 152-cm depth in the preplant N treatments, with a mean of 146 kg N ha(-1) for the 250 and 300 kg N preplant applications compared with 12 kg N ha(-1) for the same N treatments and 1.0x IS. With 185 kg N ha(-1), the 1.25x IS treatment resulted in 74 kg N ha(-1) leached compared with 10 kg N ha(-1) for the 1.0x IS. Appropriate irrigation scheduling and N fertilizer rates are essential to improving N management practices on these sandy soils.     

THE FATE OF NITRATE IN LAKE SEDIMENT COLUMNS1

ABSTRACT: To investigate the magnitude of denitrification and assimilatory nitrate reduction as these reactions relate to the fate of nitrate reaching sediments via groundwater seepage, undisturbed core samples of sediments (40 cm length) from two lakes (Mendota and Tomahawk) were leached from the bottom (at 1.4 cm/day) with a solution of ¹⁵N-nitrate (10 mg N/liter). The sediment columns were fitted with Pt electrodes to measure the oxidation-reduction (Eh) potential. While leaching removed considerable ammonium-N and soluble organic N, essentially no ¹⁵N had passed through the columns by 50 days. The Eh readings indicated that denitrification was occurring in the lower portions of the columns. The ¹⁵N distribution of the sediment N after 50 days showed that about 15 to 26% of the added nitrate-N was converted to organic N and ammonium-N. The data show that denitrification can be a significant N sink in seepage lakes.     

REGIONAL NITRATE LEACHING VARIABILITY: WHAT MAKES A DIFFERENCE IN NORTHEASTERN COLORADO

ABSTRACT: The high spatial variability of nitrate concentrations in ground water of many regions is thought to be closely related to spatially-variable leaching rates from agricultural activities. To clarify the relative roles of the different nitrate leaching controlling variables under irrigated agriculture in northeastern Colorado, we conducted an extensive series of leaching simulations with the NLEAP model using best estimates of local agricultural practices. The results of these simulations were then used with GIS to estimate the spatial variability of leachate quality for a 14,000 ha area overlying the alluvial aquifer of the South Platte River. Simulations showed that in the study area, differences in soil type might lead to 5–10 kg/ha of N variation in annual leaching rates while variability due to crop rotations was as much as 65 kg-N/ha for common rotations. Land application of manure from confined animal feeding operations may account for more than 100 kg-N/ha additional leaching. For a selected index rotation, the simulated nitrogen leaching rates across the area varied from 10 to 299 kg/ha and simulated water volumes leached ranged from 13 to 76 cm/yr depending on soil type, irrigation type, and use of manure. Resulting leachate concentrations of 3.5–140 mg/l NO₃ as N were simulated. Land application of manure was found to be the most important factor determining the mass flux of nitrate leached and the combination of sprinkler irrigation and manure application yields the highest leachate concentrations.     

Nitrate leaching beneath a containerized nursery crop receiving trickle or overhead irrigation

Container production of nursery crops is intensive and a potential source of nitrogen release to the environment. This study was conducted to determine if trickle irrigation could be used by container nursery producers as an alternative to standard overhead irrigation to reduce nitrogen release into the environment. The effect of overhead irrigation and trickle irrigation on leachate nitrate N concentration, flow-weighted nitrate N concentration, leachate volume, and plant growth was investigated using containerized rhododendron (Rhododendron catawbiense Michx. 'Album') supplied with a controlled-release fertilizer and grown outdoors on top of soil-monolith lysimeters. Leachate was collected over two growing seasons and overwinter periods, and natural precipitation was allowed as a component of the system. Precipitation accounted for 69% of the water entering the overhead-irrigated system and 80% of the water entering the trickle-irrigated system. Leachate from fertilized plants exceeded the USEPA limit of 10 mg L(-1) at several times and reached a maximum of 26 mg L(-1) with trickle irrigation. Average annual loss of nitrate N in leachate for fertilized treatments was 51.8 and 60.5 kg ha(-1) for the overhead and trickle treatments, respectively. Average annual flow-weighted concentration of nitrate N in leachate of fertilized plants was 7.2 mg L(-1) for overhead irrigation and 12.7 mg L(-1) for trickle irrigation. Trickle irrigation did not reduce the amount of nitrate N leached from nursery containers when compared with overhead irrigation because precipitation nullified the potential benefits of reduced leaching fractions and irrigation inputs provided under trickle irrigation.     

Pig slurry application and irrigation effects on nitrate leaching in Mediterranean soil lysimeters

Land application of animal manures, such as pig slurry (PS), is a common practice in intensive-farming agriculture. However, this practice has a pitfall consisting of the loss of nutrients, in particular nitrate, toward water courses. The objective of this study was to evaluate nitrate leaching for three application rates of pig slurry (50, 100, and 200 Mg ha(-1)) and a control treatment of mineral fertilizer (275 kg N ha(-1)) applied to corn grown in 10 drainage lysimeters. The effects of two irrigation regimes (low vs. high irrigation efficiency) were also analyzed. In the first two irrigation events, drainage NO(3)-N concentrations as high as 145 and 69 mg L(-1) were measured in the high and moderate PS rate treatments, respectively, in the low irrigation efficiency treatments. This indicates the fast transformation of the PS ammonium into nitrate and the subsequent leaching of the transformed nitrate. Drainage NO(3)-N concentration and load increased linearly by 0.69 mg NO(3)-N L(-1) and 4.6 kg NO(3)-N ha(-1), respectively, for each 10 kg N ha(-1) applied over the minimum of 275 kg N ha(-1). An increase in irrigation efficiency did not induce a significant increase of leachate concentration and the amount of nitrate leached decreased about 65%. Application of low PS doses before sowing complemented with sidedressing N application and a good irrigation management are the key factors to reduce nitrate contamination of water courses.     

Policy Cost-effectiveness for Reducing Non-point Agricultural Groundwater Pollution in the UK

A pilot Nitrate Sensitive Areas Scheme was established in 1990 in order to reduce nitrate pollution in heavily polluted areas of the UK through changes in land management. A regression model is derived from field observations which predicts the quantity of nitrate leaching into the groundwater as a function of land use, drainage conditions and fertilizer usage. It is used to explore the cost effectiveness of different land management options for which incentives were provided within the scheme. The most cost effective measures in terms of net exchequer cost per kilogram reduction in nitrogen leached were conversion to grassland with limited restriction on nitrogen fertilization, or conversion to woodland. A basic option involving minor changes to fertilizer practice on arable land was also cost effective but failed to achieve the target nitrate level in groundwater of 50 mg/l. Conversion to grassland with severe restrictions on fertilizer use was less cost effective because higher payments were necessary to encourage uptake by farmers.     

Monitoring nitrate leaching from submerged drains

Monitoring nitrate N (NO3-N) leaching is important in order to judge the effect that agricultural practices have on the quality of ground water and surface water. Measuring drain discharge rates and NO3-N concentrations circumvents the problem of spatial variability encountered by other methods used to quantify NO3-N leaching in the field. A new flow-proportional drainage water sampling method for submerged drains has been developed to monitor NO3-N leaching. Both low and high discharge rates can be measured accurately, and are automatically compensated for fluctuations in ditch-water levels. The total amount of NO3-N leached was 10.6 kg N ha(-1) for a tile-drained silt-loam soil during the 114-d monitoring period. The NO3-N concentrations fluctuated between 5 mg L(-1) at deep ground water levels and 15 mg L(-1) at shallow levels, due to variations in water flow. A flow-proportional drainage water sampling method is required to measure NO3-N leaching accurately under these conditions. Errors of up to 43% may occur when NO3-N concentrations in the drainage water are only measured at intervals of 30 d and when the precipitation excess is used to estimate cumulative NO3-N leaching. Measurements of NO3-N concentrations in ground water cannot be used to accurately estimate NO3-N leaching in drained soils.     

Fate of nitrate and bromide in an unsaturated zone of a sandy soil under citrus production

Understanding water and nutrient transport through the soil profile is important for efficient irrigation and nutrient management to minimize excess nutrient leaching below the rootzone. We applied four rates of N (28, 56, 84, and 112 kg N ha(-1); equivalent to one-fourth of annual N rates being evaluated in this study for bearing citrus trees), and 80 kg Br- ha(-1) to a sandy Entisol with >25-yr-old citrus trees to (i) determine the temporal changes in NO3-N and Br- distribution down the soil profile (2.4 m), and (ii) evaluate the measured concentrations of NO3-N and Br- at various depths with those predicted by the Leaching Estimation and Chemistry Model (LEACHM). Nitrate N and Br concentrations approached the background levels by 42 and 214 d, respectively. Model-predicted volumetric water content and concentrations of NO3-N and Br- at various depths within the entire soil profile were very close to measured values. The LEACHM data showed that 21 to 36% of applied fertilizer N leached below the root zone, while tree uptake accounted for 40 to 53%. Results of this study enhance our understanding of N dynamics in these sandy soils, and provide better evaluation of N and irrigation management to improve uptake efficiency, reduce N losses, and minimize the risk of ground water nitrate contamination from soils highly vulnerable to nutrient leaching.     

Nitrogen and carbon leaching in agroecosystems and their role in denitrification potential

The drainage of water and leaching of dissolved constituents represent major components of agroecosystem mass budgets that have been exceedingly difficult to measure. Equilibrium-tension lysimeters (ETLs) were used to monitor drainage, nitrogen (N), and carbon (C) leaching through Plano silt loam (fine-silty, mixed, superactive, mesic Typic Argiudoll) for a 4-yr period in a restored prairie and N-fertilized no-tillage and chisel-plowed maize (Zea mays L.) agroecosystems. Mean drainage recorded during 4 yr for the prairie, no-tillage, and chisel-plowed ecosystems totaled 461, 1,116, and 1,575 mm and represented 16, 33, and 47% of precipitation plus melting of drifted snow received, respectively. Total inorganic N leaching losses during the 4-yr period for the prairie, no-tillage, and chisel-plowed ecosystems were 0.6, 201, and 179 kg N ha(-1), respectively. Inorganic N leaching represented 26 and 24% of applied fertilizer N additions to the no-tillage and chisel-plowed agroecosystems. Total dissolved C leaching losses were 119, 435, and 502 kg C ha(-1) for the prairie, no-tillage, and chisel-plowed ecosystems, respectively. Sufficient dissolved organic carbon (DOC) and nitrate N (NO3- -N) existed in the prairie and agroecosystems to support subsoil denitrification. Potential denitrification, however, was limited by insufficient lengths of saturated soil conditions in all three ecosystems, the supply of DOC in the agroecosystems, and the supply of nitrate N in the prairie. Based on available DOC and nitrate N, the maximum contribution of denitrification below the root zone in the agroecosystems was less than 25% of the total amount of leached nitrate N and the probable contribution of denitrification was much less.     

Is colloid-facilitated phosphorus leaching triggered by phosphorus accumulation in sandy soils?

The leaching of colloidal phosphorus (P(coll)) contributes to P losses from agricultural soils. In an irrigation experiment with undisturbed soil columns, we investigated whether the accumulation of P in soils due to excess P additions enhances the leaching of colloids and P(coll) from sandy soils. Furthermore, we hypothesized that large concentrations of P(coll) occur at the onset of leaching events and that P(coll) mobilized from topsoils is retained in subsoils. Soil columns of different P saturation and depth (0-25 and 0-40 cm) were collected at a former disposal site for liquid manure and at the Thyrow fertilization experiment in northeastern Germany. Concentrations of total dissolved P, P(coll), Fe(coll), Al(coll), optical density, zeta potential, pH, and electrical conductivity of the leachates were determined. Colloidal P concentrations ranged from 0.46 to 10 micromol L(-1) and contributed between 1 and 37% to total P leaching. Large P(coll) concentrations leached from the P-rich soil of the manure disposal site were rather related to a large P-content of colloids than to the mobilization of additional colloids. Concentrations of colloids and P(coll) in leachates from P-poor and P-rich columns from Thyrow did not differ significantly. In contrast, accumulation of P in the Werbellin and the Thyrow soil consistently increased dissolved P concentrations to maximum values as high as 300 micromol L(-1). We observed no first-flush of colloids and P(coll) at the beginning of the leaching event. Concentrations of P(coll) leached from 40-cm soil columns were not smaller than those leached from 25-cm columns. Our results illustrate that an accumulation of P in sandy soils does not necessarily lead to an enhanced leaching of colloids and P(coll), because a multitude of factors independent from the P status of soils control the mobility of colloids. In contrast, P accumulation generally increases dissolved P concentrations in noncalcareous soils due to the saturation of the P sorption capacity. This indicates that leaching of dissolved P might be a more widespread environmental problem in areas with P-saturated sandy soils than leaching of P(coll).     

SOIL EROSION AND GROUND WATER POLLUTION TRADEOFFS FOR NONIRRIGATED FARMING SYSTEMS1

ABSTRACT: Traditional focus on reducing one environmental externality may cause another externality to increase. This article examines the environmental and economic costs of abating soil loss and (or) nitrate leaching through alternative optimal production systems in the nonirrigated farming systems of Northeastern Oregon. Models estimating soil loss and nitrate‐nitrogen leaching rates associated with current production processes, are linked to a Multi‐Objective Programming (MOP) model. The results show that site specific conditions influence the level of abatement expenditures and optimal production strategies to reduce soil loss and leaching rates. Moreover, while existing production strategies are effective in reducing soil loss at little cost, no strategies could be identified to reduce nitrate leaching rate on some soils.     

Nitrate leaching and turf quality in established 'Floratam' St. Augustinegrass and 'Empire' zoysiagrass

The objectives of this research were to evaluate nitrate N (NO3-N) leaching and turf response to nitrogen rate (NR) and irrigation regime (IR) in 'Floratam' St. Augustinegrass ( [Walt.] Kuntze.) and 'Empire' zoysiagrass ( Steud). The research was conducted in Citra, FL, from 2005 through 2007. Nitrogen (N) was applied at annual rates of 32, 64, 128, and 196 kg ha?1 in 2005, and at 49, 196, 343, or 490 kg ha?1 in 2006 and 2007. Irrigation treatments consisted of 1.3 cm applied twice weekly or 2.6 cm applied once weekly. In general, NO?-N leaching was greater from zoysiagrass. In 2007, annual NO?-N leached varied due to the interaction of NR, IR, and grass. There was little association between NR and increased NO?-N leaching in St. Augustinegrass in any year. While St. Augustinegrass had no differences in NO?-N leached within NR due to IR, there were some differences in NO?-N leached from zoysiagrass at some N levels, with greater NO?-N leached from the more frequent irrigation regime. Turf quality (TQ) was generally above an acceptable level in St. Augustinegrass at all but the lowest NRs and at all NRs in zoysiagrass with the exception of the spring fertilizer cycle (SFC) in 2007, when high NR treatments resulted in disease. Maintenance of a healthy turfgrass cover is an important strategy for reducing potential nutrient movement from fertilizer application. The current recommended rates for St. Augustinegrass provide good turf cover and health, and result in minimal NO?-N leaching. Zoysiagrass N rates may need to be revised downward to reduce disease, improve turf cover, and reduce NO?-N leaching.     

Floodplain Trapping and Cycling Compared to Streambank Erosion of Sediment and Nutrients in an Agricultural Watershed

Floodplains and streambanks can positively and negatively influence downstream water quality through interacting geomorphic and biogeochemical processes. Few studies have measured those processes in agricultural watersheds. We measured inputs (floodplain sedimentation and dissolved inorganic loading), cycling (floodplain soil nitrogen [N] and phosphorus [P] mineralization), and losses (bank erosion) of sediment, N, and P longitudinally in stream reaches of Smith Creek, an agricultural watershed in the Valley and Ridge physiographic province. All study reaches were net depositional (floodplain deposition > bank erosion), had high N and P sedimentation and loading rates to the floodplain, high soil concentrations of N and P, and high rates of floodplain soil N and P mineralization. High sediment, N, and P inputs to floodplains are attributed to agricultural activity in the region. Rates of P mineralization were much greater than those measured in other studies of nontidal floodplains that used the same method. Floodplain connectivity and sediment deposition decreased longitudinally, contrary to patterns in most watersheds. The net trapping function of Smith Creek floodplains indicates a benefit to water quality. Further research is needed to determine if future decreases in floodplain deposition, continued bank erosion, and the potential for nitrate leaching from nutrient‐enriched floodplain soils could pose a long‐term source of sediment and nutrients to downstream rivers.     

Nitrate leaching under grassland as affected by mineral nitrogen fertilization and cattle urine

An experiment was performed to better understand to what extent nitrogen fertilization rate and date and amount of urine deposition, when acting in combination, influence nitrate leaching under grassland. Leaching was studied during two successive winters using 2-m2 grassed lysimeters under three levels of N fertilization (0, 150, and 300 kg N ha(-1) yr(-1), referred to as 0N, 150N, and 300N, respectively), two levels of 15N-labeled urine (105 and 165 kg N ha(-1), referred to as A2 and A3, respectively), and three dates of urine application (spring, summer, and fall). During the first winter, total N leaching losses varied between 2 and 50 kg N ha(-1). When tested in combination, N applied as urine to grassland resulted in three times the total N loss by leaching that occurred following N fertilization in the first winter (4.3, 20.8, 34.9, 14.2, 17.1, and 28.7 kg NO3- -N ha(-1) for no urine, A2, A3, ON, 150N, and 300N, respectively). Leaching of 15N urine significantly depended on the date of application: 6.6, 17.3, and 29.1 kg for spring, summer, and fall, respectively. A similar pattern was observed for the contribution of 15N urine to total N leaching with 4.3, 12.9, and 21.4%. However, urine application, both in terms of amount and date, showed very little long-term effect on these N losses in Year 2. In our conditions of low winter rainfall and drainage, grazing management (through season, urinary N amounts, and urine N concentration) resulted in a higher impact on water nitrate quality than moderate N fertilization management.     

Phosphorus release from a manure-impacted spodosol: effects of a water treatment residual

Long-term depositions of animal manures affect P dynamics in soils and can pose environmental risks associated with P losses. Laboratory studies were done on P solubility characteristics in a manure-impacted Immokalee soil (sandy, siliceous, hyperthermic Arenic Alaquod) and the effectiveness of water treatment residual (WTR) in controlling P leaching. Soil samples with contrasting initial total P concentrations were prepared by mixing samples of a manure-impacted surface A horizon and a minimally P-impacted E horizon. Effects of mixing various ratios of A and E horizons, WTR rates (0, 25, 50, and 100 g kg(-1)), and depths of WTR incorporation (mixed throughout the soil column or partially incorporated) on P leaching were determined. Between 62 and 77% of total P was released from the soil mixes by successive water extractions, suggesting a considerable buffering capacity of this manure-impacted soil to resupply P into solution. Between 224 and 408 mg kg(-1) P were leached during the 36-wk leaching period in the absence of WTR. Mixing WTRs with soil reduced soluble P concentration in leachates by as much as 99.8% compared with samples without WTR. Thoroughly mixing WTR with the entire soil column (15 cm) was much more efficient than mixing WTR with only the top 7.5 cm of soil. Calcium- and Mg-P forms appear to control P release in soils without WTR, whereas sorption-desorption reactions probably determine P leaching in WTR-treated samples. Soil P distribution in various chemical forms was affected by WTR additions. Data suggest that WTR-immobilized P is stable in the long term.     

IMPLICATIONS OF ON‐GROUND NITROGEN LOADING AND SOIL TRANSFORMATIONS ON GROUND WATER QUALITY MANAGEMENT1

ABSTRACT: This paper presents a modeling approach based on a geographic information system (GIS) to estimate the variability of on‐ground nitrogen loading and the corresponding nitrate leaching to ground water. The methodology integrates all point and nonpoint sources of nitrogen, the national land cover database, soil nitrogen transformations, and the uncertainty of key soil and land use‐related parameters to predict the nitrate mass leaching to ground water. The analysis considered 21 different land use classes with information derived from nitrogen sources such as fertilizer and dairy manure applications, dairy lagoons, septic systems, and dry and wet depositions. Simulations were performed at a temporal resolution of one month to capture seasonal trends. The model was applied to a large aquifer of 376 square miles in Washington State that serves more than 100,000 residents with drinking water. The results showed that dairy manure is the main source of nitrogen in the area followed by fertilizers. It was also seen that nitrate leaching is controlled by the recharge rate, and there can be a substantial buildup of soil nitrogen over long periods of time. Uncertainty analysis showed that denitrification rate is the most influential parameter on nitrate leaching. The results showed that combining management alternatives is a successful strategy, especially with the use of nitrification inhibitors. Also, change in the land use pattern has a noticeable impact on nitrate leaching.     

Tree species for recovering nitrogen from dairy-farm effluent in New Zealand

Land treatment of dairy-farm effluent is being widely adopted as an alternative to disposal into surface waters in New Zealand. This study investigated water balances and associated N leaching from short-rotation forest (SRF) species irrigated with dairy-farm effluent. Single trees were grown in lysimeters filled with Manawatu fine sandy loam (mixed mesic Dystric Eutrochrept). Dairy-farm effluent was applied during two irrigation periods at 21.5 mm wk(-1) with a total loading equivalent to 870 kg N ha(-1) occurring over 17 mo. Following tree harvest in April 1997, measurements continued until August 1997 to monitor tree reestablishment. Cumulative N leached did not differ between lysimeters in which evergreen Sydney blue gum (Eucalyptus saligna Sm.) and shining gum [Eucalyptus nitens (H. Deane & Maiden) Maiden] and deciduous kinu-yanagi (Salix kinuyanagi Kimura) were grown. Leachate N concentrations of all treatments were on average higher than the New Zealand drinking water standard of 11.3 mg N L(-1). The E. nitens and S. kinuyanagi treatments leached 33 and 35 kg N ha(-1) yr(-1) in 1996 following application of 236 kg N ha(-1) during the first irrigation season. Leaf area was strongly correlated to evapotranspiration, drainage volume, and nitrogen leached. The majority of leaching in the tree treatments occurred after harvest. Reducing the leaching in the regrowth phase may be achieved through timing harvest in the spring when growth rates are higher and leaching potential is lower. Based on N uptake rates observed in this study and average pond discharge, a plantation of 5.4 ha would be required for N recovery on a typical dairy farm in New Zealand.     

A study of the extraction of vanadium and nickel in oil-fired fly ash

Annual production of oil-fired fly ash in Taiwan is approximately 43 000 tons, of this approximately 13 000 tons is electrostatically precipitated, the rest is cyclonically collected. Structurewise, both consist of porous unburned carbon, vanadium and nickel oxide, and water-soluble sulfate. Electrostatically precipitated fly ash contains large amounts of ammonium sulfate. If these ashes are not properly disposed of, they become environmental problems, such as dusting, leakage of acid liquids, and pollution with heavy metals. This paper discusses the experimental extraction of vanadium and nickel from oil-fired fly ash. The results indicated that leaching of oil-fired fly ash in 0.5 N of sulfuric acid led to an extraction of 65% vanadium, 60% nickel, and 42% iron, along with an increase in the concentration of sulfuric acid. When leached in 2 N sodium hydroxide solution, the extraction of vanadium was 80%, and the extraction of nickel was negligible. If leached in an ammonia water, the extraction of nickel increased, along with an increase in the concentration of ammonia in water. When leached with 4 N ammonia water, the extraction of nickel was 60%, the extraction of vanadium was less than that obtainable from leaching in sulfuric acid solution or in sodium hydroxide solution. If electrostatically precipitated fly ash was leached in a solution of 0.25 N ammonia water and 2 N ammonium sulfate, it would yield an extraction of 60% nickel and 8% vanadium—leading to a selective extraction of nickel. This study has established an extraction flowsheet in which fly ash was first leached in an ammoniacal solution containing ammonium sulfate to recover nickel. The leached residues were then leached in an alkaline solution to recover vanadium.