西溪湿地底泥质量现状与生态风险初步评价

为了解西溪湿地底泥质量现状,2012年9月采集保护区内不同干扰类型的底泥样本,测试了底泥中重金属和POPs中PCBs、OCPs和PAHs的含量,并对湿地底泥污染进行了生态风险初步评价。结果表明,底泥中未检出PCBs和OCPs,但检测出14种EPA优控PAHs,总PAHs的浓度范围为115.9～217.8 ng·g^-1,低于潜在生态风险的效应区间低值ERL,其中列入中国＂水中优先控制污染黑名单＂的7种PAHs均有检出并且其总量占∑PAHs 1/2左右（平均为50.08%）;底泥中8种重金属含量平均值低于《土壤环境质量标准》（GB 15618—1995）的二级标准,但Hg、Zn、Pb、Ni含量在多个位点已超过一级标准;分别采用土壤背景值和国家一级标准为参比值对湿地底泥中重金属进行单因子污染风险指数评价,发现分别有7种和4种元素的污染指数大于1;综合分析不同干扰类型的底泥质量,发现底泥疏浚能有效降低有机质含量、全氮和PAHs含量,但对全磷、重金属含量则无明显效果,封闭水体的干塘措施能显著减少污泥量和有机物含量。研究结果表明,西溪湿地底泥中高环PAHs和重金属污染水平可能对西溪湿地生物具有潜在的生物毒性作用及不利的生态影响效应,其疏浚底泥农用则无生态风险。     

Landscape metrics and estuarine sediment contamination in the mid-Atlantic and southern New England regions

In a previously published study, quantitative relationships were developed between landscape metrics and sediment contamination for 25 small estuarine systems within Chesapeake Bay. These analyses have been extended to include 75 small estuarine systems across the mid-Atlantic and southern New England regions of the USA. Because of the different characteristics and dynamics of the estuaries across these regions, adjustment for differing hydrology, sediment characteristics, and sediment origins were included in the analysis. Multiple linear regression with stepwise selection was used to develop statistical models for sediment metals, organics, and total polycyclic aromatic hydrocarbons (PAHs). The landscape metrics important for explaining the variation in sediment metals levels (R2 = 0.72) were the percent area of nonforested wetlands (negative contribution), percent area of urban land, and point source effluent volume and metals input (positive contributions). The metrics important for sediment organics levels (R2 = 0.5) and total PAHs (R2 = 0.46) were percent area of urban land (positive contribution) and percent area of nonforested wetlands (negative contribution). These models included silt-clay content (metals) or total organic C (organics, total PAHs) of sediments and grouping by estuarine hydrology, suggesting the importance of sediment characteristics and hydrology in mitigating the influence of the landscape metrics on sediment contamination levels. The overall results from this study are indicative of how statistical models can be developed relating landscape metrics to estuarine sediment contamination for distributions of land cover and point source discharges.     

Metal contamination in sediments of the western Bohai Bay and adjacent estuaries, China

Twelve sediment cores were collected in July 2007 in open waters of western Bohai Bay, the Port of Tianjin, and the adjacent estuaries of the Haihe and Yongding Rivers. While overall concentrations of trace metals at incremental depths in these cores met the Marine Sediment Quality (GB18668-2002) criteria of China, the magnitude of both metal enrichment factors (EF) and geoaccumulation indices (I(geo)) suggested that pollution with Ag, Cd, Cr, Cu and Zn was occurring in the estuaries and Port. Risk analysis also suggested that Ag and Ni concentrations were sufficiently elevated as to cause adverse biological effects in the study area. Although metal concentrations in western Bohai Bay were of less concern, a positive relationship between EF values and excess (210)Pb activity for several metals suggested that their concentrations were increasing over time.     

Metal release from bottom sediments of Ocoee Lake No. 3, a primary catchment area for the Ducktown Mining District

Ocoee Lake No. 3 is the first reservoir receiving suspended sediments contaminated with trace metals discharged by acid mine effluents from the Ducktown Mining District, Tennessee. Bottom sediments (0-5 cm) from the lake were sampled to assess the potential for future adverse environmental effects if no remediation controls or activities are implemented. The sediments were found to include a major component (173 +/- 19 g kg(-1)) that dissolved in 6 mol L(-1) HCl within 24 h. This acid-soluble and relatively labile fraction contained high concentrations of Fe (460 +/- 40 g kg(-1)), Al (99 +/- 11 g kg(-1)), Mn (10 +/- 8 g kg(-1)), Cu (2000 +/- 700 mg kg(-1)), Zn (1300 +/- 200 mg kg(-1)), and Pb (300 +/- 200 mg kg(-1)). When the pH of water in contact with the sediment was decreased experimentally from 6.4 to 2.6, the concentrations of dissolved trace metals increased by factors of 2200 for Pb, 160 for Cu, 21 for Zn, 9 for Cd, 8 for Ni, and 5 for Co. The order in which metals were released with decreasing pH was the reverse of that reported for pH-dependent sorption of these metals in upstream systems. Substantial release of trace metals from the sediment was observed even by a modest decrease of pH from 6.4 to 5.9. Therefore, the metal-rich sediment of the lake should be considered as potentially hazardous to bottom-dwelling aquatic species and other organisms in the local food chain. In addition, if the reservoir is dredged or if the dam is removed, the accumulated sediment may have to be treated for recovery of sorbed metals.     

Temporal and spatial distributions of sediment total organic carbon in an estuary river

Understanding temporal and spatial distributions of naturally occurring total organic carbon (TOC) in sediments is critical because TOC is an important feature of surface water quality. This study investigated temporal and spatial distributions of sediment TOC and its relationships to sediment contaminants in the Cedar and Ortega Rivers, Florida, USA, using three-dimensional kriging analysis and field measurement. Analysis of field data showed that large temporal changes in sediment TOC concentrations occurred in the rivers, which reflected changes in the characteristics and magnitude of inputs into the rivers during approximately the last 100 yr. The average concentration of TOC in sediments from the Cedar and Ortega Rivers was 12.7% with a maximum of 22.6% and a minimum of 2.3%. In general, more TOC accumulated at the upper 1.0 m of the sediment in the southern part of the Ortega River although the TOC sedimentation varied with locations and depths. In contrast, high concentrations of sediment contaminants, that is, total polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), were found in sediments from the Cedar River. There was no correlation between TOC and PAHs or PCBs in these river sediments. This finding is in contradiction to some other studies which reported that the sorption of hydrocarbons is highly related to the organic matter content of sediments. This discrepancy occurred because of the differences in TOC and hydrocarbon source input locations. It was found that more TOC loaded into the southern part of the Ortega River, while almost all of the hydrocarbons entered into the Cedar River. This study suggested that the locations of their input sources as well as the land use patterns should also be considered when relating hydrocarbons to sediment TOC.     

ACCUMULATION OF SELECTED TRACE METALS IN SOILS OF URBAN RUNOFF DETENTION BASINS1

ABSTRACT Field investigations were conducted at three sites in the Washington, D.C., area to detect accumulation patterns of the trace metals, cadmium, copper, lead, and zinc in the soils of urban stormwater detention basins. The research results seemed to indicate that the use of detention basins to control urban stormwater runoff had few harmful effects to fine textured soils with respect to the study trace metals. Although the trace metals, especially lead and zinc, were found to accumulate in the surface soils of the basins, little significant downward movement of metals in the soil profiles had occurred. Accumulations of metals in the surface soils appeared to be a function of microtopography and the resultant residence time of standing water. The fractions of trace metals that were present in a leachable form in surface soils and stormwater solids were small, with median values ranging from 7.7 percent of the total concentration for Cd to 0.01 percent for Pb.     

Application of sediment quality guidelines in the assessment and management of contaminated surficial sediments in Port Jackson (Sydney Harbour), Australia

Sediments in the Port Jackson estuary are polluted by a wide range of toxicants and concentrations are among the highest reported for any major harbor in the world. Sediment quality guidelines (SQGs), developed by the National Oceanographic and Atmospheric Administration (NOAA) in the United States are used to estimate possible adverse biological effects of sedimentary contaminants in Port Jackson to benthic animals. The NOAA guidelines indicate that Pb, Zn, DDD, and DDE are the most likely contaminants to cause adverse biological effects in Port Jackson. On an individual chemical basis, the detrimental effects due to these toxicants may occur over extensive areas of the harbor, i.e., about 40%, 30%, 15% and 50%, respectively. The NOAA SQGs can also be used to estimate the probability of sediment toxicity for contaminant mixtures by determining the number of contaminants exceeding an upper guideline value (effects range medium, or ERM), which predicts probable adverse biological effects. The exceedence approach is used in the current study to estimate the probability of sediment toxicity and to prioritize the harbour in terms of possible adverse effects on sediment-dwelling animals. Approximately 1% of the harbor is mantled with sediment containing more than ten contaminants exceeding their respective ERM concentrations and, based on NOAA data, these sediments have an 80% probability of being toxic. Sediment with six to ten contaminants exceeding their respective ERM guidelines extend over approximately 4% of the harbor and have a 57% probability of toxicity. These areas are located in the landward reaches of embayments in the upper and central harbor in proximity to the most industrialised and urbanized part of the catchment. Sediment in a further 17% of the harbor has between one and five exceedences and has a 32% probability of being toxic. The application of SQGs developed by NOAA has not been tested outside North America, and the validity of using them in Port Jackson has yet to be demonstrated. The screening approach adopted here is to use SQGs to identify contaminants of concern and to determine areas of environmental risk. The practical application and management implications of the results of this investigation are discussed.     

Application of Sediment Quality Guidelines in the Assessment and Management of Contaminated Surficial Sediments in Port Jackson (Sydney Harbour), Australia

Sediments in the Port Jackson estuary are polluted by a wide range of toxicants and concentrations are among the highest reported for any major harbor in the world. Sediment quality guidelines (SQGs), developed by the National Oceanographic and Atmospheric Administration (NOAA) in the United States are used to estimate possible adverse biological effects of sedimentary contaminants in Port Jackson to benthic animals. The NOAA guidelines indicate that Pb, Zn, DDD, and DDE are the most likely contaminants to cause adverse biological effects in Port Jackson. On an individual chemical basis, the detrimental effects due to these toxicants may occur over extensive areas of the harbor, i.e., about 40%, 30%, 15% and 50%, respectively. The NOAA SQGs can also be used to estimate the probability of sediment toxicity for contaminant mixtures by determining the number of contaminants exceeding an upper guideline value (effects range medium, or ERM), which predicts probable adverse biological effects. The exceedence approach is used in the current study to estimate the probability of sediment toxicity and to prioritize the harbour in terms of possible adverse effects on sediment-dwelling animals. Approximately 1% of the harbor is mantled with sediment containing more than ten contaminants exceeding their respective ERM concentrations and, based on NOAA data, these sediments have an 80% probability of being toxic. Sediment with six to ten contaminants exceeding their respective ERM guidelines extend over approximately 4% of the harbor and have a 57% probability of toxicity. These areas are located in the landward reaches of embayments in the upper and central harbor in proximity to the most industrialised and urbanized part of the catchment. Sediment in a further 17% of the harbor has between one and five exceedences and has a 32% probability of being toxic. The application of SQGs developed by NOAA has not been tested outside North America, and the validity of using them in Port Jackson has yet to be demonstrated. The screening approach adopted here is to use SQGs to identify contaminants of concern and to determine areas of environmental risk. The practical application and management implications of the results of this investigation are discussed.     

Mobilization of trace metals and inorganic compounds during resuspension of anoxic sediments from Trepangier Bayou, Louisiana

The release of trace metals (Mn, Ni, Co, Cu, Zn, Pb, and Cd) and inorganic compounds (As) from initially anoxic Trepangier Bayou sediments, Louisiana and the sources of the released metals were investigated. After 1 to 2 d aeration, significant amounts of trace metals (Mn, Zn, Cd, Ni, and Co) were released to the aqueous phase with increased acidity, primarily due to the oxidation of acid-volatile sulfide and ferrous iron and iron sulfide minerals. The addition of a bacterial inhibitor, NaN,, to the Trepangier sediment during resuspension inhibited metal release, suggesting that microbial catalysis can regulate metal mobilization during sediment resuspension. In a well buffered system, oxidation of iron sulfides alone did not appear to induce trace metal release. Moreover, when Trepangier sediment was resuspended in anoxic conditions at neutral pH, <1% of the trace metal content was released, whereas a significant release of metal was observed under acidic anoxic conditions. Although oxidation of iron sulfide minerals is an essential prerequisite for the release of Zn, Co, Cd, and Ni, carbonates and oxides also play a role. The trace metals and inorganic compounds investigated could be classified into three groups according to their release characteristics: (i) Mn, Zn, Cd, Ni, and Co; (ii) Fe, Pb, and As; and (iii) Cu. The groupings appeared to depend on the sources of compounds and their relative affinity, after oxidation, to iron oxyhydroxides or organic matter.     

Predicting estuarine sediment metal concentrations and inferred ecological conditions: an information theoretic approach

Empirically derived relationships associating sediment metal concentrations with degraded ecological conditions provide important information to assess estuarine condition. Resources limit the number, magnitude, and frequency of monitoring activities to acquire these data. Models that use available information and simple statistical relationships to predict sediment metal concentrations could provide an important tool for environmental assessment. We developed 45 predictive models for the total concentrations of copper, lead, mercury, and cadmium in estuarine sediments along the Southern New England and Mid-Atlantic regions of the United States. Using information theoretic model-averaging approaches, we found total developed land and percent silt/clay of estuarine sediment were the most important variables for predicting the presence of all four metals. Estuary area, river flow, tidal range, and total agricultural land varied in their importance. The model-averaged predictions explained 78.4, 70.5, 56.4, and 50.3% of the variation for copper, lead, mercury, and cadmium, respectively. Overall prediction accuracies of selected sediment benchmark values (i.e., effects ranges) were 83.9, 84.8, 78.6, and 92.0% for copper, lead, mercury, and cadmium, respectively. Our results further support the generally accepted conclusion that sediment metal concentrations are best described by the physical characteristics of the estuarine sediment and the total amount of urban land in the contributing watershed. We demonstrated that broad-scale predictive models built from existing monitoring data with information theoretic model-averaging approaches provide valuable predictions of estuarine sediment metal concentrations and show promise for future environmental modeling efforts in other regions.     

Assessment of the Effectiveness of Environmental Dredging in South Lake,China

Environmental dredging is a primary remedial option for removal of the contaminated material from aquatic environment. Of primary concern in environmental dredging is the effectiveness of the intended sediment removal. A 5-year field monitoring study was conducted to assess the effectiveness of the environmental dredging in South Lake, China. The concentrations of total nitrogen (TN), total phosphors, and heavy metals (Zn, Pb, Cd, Cu, Cr, Ni, Hg, and As) before and after dredging in sediment were determined and compared. Multiple ecological risk indices were employed to assess the contamination of heavy metals before and after dredging. Our results showed that the total phosphorus levels reduced 42% after dredging. Similar changes for Hg, Zn, As Pb, Cd, Cu, Cr, and Ni were observed, with reduction percentages of 97.0, 93.1, 82.6, 63.9, 52.7, 50.1, 32.0, and 23.6, respectively, and the quality of sediment improved based on the criterion of Sediment Quality Guidelines by USEPA and contamination degree values (C_d) decreased significantly (paired t-test, p < 0.05). Unexpectedly, the TN increased 49% after dredging compared to before dredging. Findings from the study demonstrated that the environmental dredging was an effective mechanism for removal of total phosphorus and heavy metals from South Lake. Nevertheless, the dredging was ineffective to remove total nitrogen from sediment. We conclude that the reason for the observed increase in TN after dredging was likely ammonia release from the sediment impairing the dredging effectiveness.     

Water and Sediment Quality in the Clinch River,Virginia and Tennessee,USA, over Nearly Five Decades

The Clinch River, in eastern United States, supports a diverse freshwater fauna including endangered mussels. Although mussel populations are stable in the Clinch's northeastern Tennessee segment, long‐term declines have been documented upstream in Virginia. We analyzed water and sediment quality data collected by government agencies from the 1960s through 2013 in an effort to inform current management. The river was divided into sections considering data availability and major tributaries. We tested for spatial differences among river sections and for temporal trends, and compared measured values to potentially protective levels if available. Ammonia concentrations approaching and exceeding protective levels were recorded, most often during the 1970s and 1980s in upstream sections. Sediment metals occurred at levels potentially causing biological effects, mainly during the 1980s and 1990s. In the 2000s, water‐column metals have been well below protective levels for general aquatic life. Dissolved solids (DS) increased in most river sections over the study period but mussel‐specific protective levels are not known. Analysis of water pH, total N, and total P did not generate conservation concern. Enhanced monitoring for sediment metals, water‐column metals, and ionic composition of DS; closer alignment of agency water monitoring practices in the two states; and research to determine biological effects of DS at current and anticipated levels can aid future conservation management.     

Use of Sediment Risk and Ecological/Conservation Value for Strategic Management of Estuarine Environments: Sydney Estuary,Australia

Sediment mantling the floor of Sydney estuary contains a wide range of chemicals at highly elevated concentrations over extensive areas. Appropriate sediment management decisions are urgently required to prevent further degradation of sediment quality and to minimize resulting adverse ecological effects. The objective of the present work was to provide a systematic, estuary-wide assessment of sediment risk and ecological/conservation value throughout the harbor to guide sediment management decisions. Sediment risk is the likelihood of sediment chemistry causing adverse biological effects to bottom-dwelling animals and was conducted using national sediment quality guidelines (SQGs) for single contaminants and the mean SQG quotient approach to assess chemical mixtures. Sediment risk was negligible at the mouth of the estuary, but increased strongly landwards. The ecological/conservation value assessment was conducted to identify sites that warrant different levels of protection and was conducted using the value of ecological communities and priority waterway use. Consideration of these two parameters combined enabled the estuary to be prioritized for management attention. The prioritization and identification of appropriate management strategies were determined through the use of management matrices also based on sediment risk and ecological/conservation value. A computer package is being developed to provide managers with information on sediment risk, ecological/conservation value, the urgency and the type of management intervention required for any location in Sydney estuary, in real-time. This approach to estuarine management is unique and will greatly improve effective management of Sydney estuary, and other harbors in urgent need of management action and protection.     

Heavy metal content and distribution in surface sediments of the Seyhan River, Turkey

Chemical fractionation of seven heavy metals (Cd, Cr, Cu, Mn, Ni, Pb and Zn) was studied using a modified three-step sequential procedure to assess their impacts in the sediments of the Seyhan River, Turkey. Samples were collected from six representative stations in two campaigns in October 2009 and June 2010, which correspond to the wet and dry seasons, respectively. The total metal concentrations in the sediments demonstrated different distribution patterns at the various stations. Cadmium was the only metal that was below detection at all stations during both sampling periods. Metal fractionation showed that, except for Mn and Pb, the majority of metals were found in the residual fraction regardless of sampling time, indicating that these metals were strongly bound to the sediments. The potential mobility of the metals (non-residual fractions) is reflected in the following ranking: Pb > Mn > Zn > Cu > Ni > Cr in October 2009 and Mn > Pb > Zn > Cu > Ni > Cr in June 2010. The second highest proportion of metals was bound to organic matter/sulfides, originating primarily from anthropogenic activities. Non-residual metal fractions for all stations were highest in June 2010, which may be linked to higher organic matter concentrations in the sediment samples with 1.40% and 15.1% in October 2009 and June 2010, respectively. Potential sediment toxicity was evaluated using the Risk Assessment Code (RAC). Based on RAC classification, Cd and Cr pose no risk, Cu and Ni pose low risk, Pb and Zn were classified as medium risk metals, while the environmental risk from Mn was high. In addition, based on the sediment quality guidelines (SQG), the Seyhan River can be classified as a river with no, to moderate, toxicological risks, based on total metal concentrations.     

The impact of urbanization on tropical mangroves (Fortaleza,Brazil): Evidence from PAH distribution in sediments

This investigation represents the first environmental diagnosis of the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments from a tropical mangrove in Fortaleza, northeastern Brazil. Sediment cores from six sampling stations in the Cocó and Ceará Rivers were retrieved in June-July 2006 to determine 17 priority PAHs. The total PAH concentrations (Σ_PAHs) ranged from 3.04 to 2234.76 μg kg^?1(Cocó River) and from 3.34 to 1859.21 μg kg^?1 (Ceará River). These levels are higher than those of other cities with more industrial development. PAH concentrations did not reach probable effect levels (PELs). However, from 4.5 to 87.5% of individual PAH concentrations can occasionally cause adverse biological effects for aquatic organisms. The PAH molecular ratios indicate that the PAHs in the sediment core were derived mainly from petroleum, wood, and charcoal combustion (pyrogenic source), and that atmospheric deposition and urban runoff may serve as important pathways for PAH input to the sediment. Clearly, the Σ_PAHs in sediments collected in the Cocó and Ceará Rivers indicate that ongoing pollution is more severe than past pollution.     

大连城市大气中多环芳烃的污染特征和毒性评价

通过对大连市工业区、居民区和城市背景区3种类型区域连续7个月大气样品的采集,分析PAHs在大气中的污染特征,并对其毒性进行评价。结果显示,城市工业区大气中PAHs含量最高,其次是居民区,城市背景区最低。3种类型采样点大气中PAHs的组成相似,菲是含量最多的物质,其次是荧蒽、芴和芘。16种PAHs基于苯并[a]芘的总毒性当量浓度为:工业区5.1 ng/m^3;居民区3.6 ng/m^3;城市背景区4.6 ng/m^3。3种类型功能区大气中PAHs的TEQ值都高于我国的《空气质量标准》(GB 3095-2012)中规定的大气中苯并[a]芘的年平均浓度(1 ng/m^3)或24 h平均浓度(2.5 ng/m^3)。     

WATER QUALITY CHARACTERISTICS OF STORM WATER FROM MAJOR LAND USES IN SOUTH FLORIDA1

ABSTRACT: Starting in 1998, a study was conducted to characterize storm water quality from predominant land use types in a coastal watershed along the south central coast of Florida, namely citrus, pasture, urban, natural wetland, row crop, dairy, and golf courses. Sixty‐three sampling sites were located at strategic points on drainage conveyances for each of seven specific land use areas. Runoff samples were collected following storm events that met defined rainfall criteria for a period of 30 months. Nitrogen (N), phosphorus (P), heavy metals, pesticides, and other water quality parameters were determined, and the results were analyzed to compare and characterize land uses as relative sources for these constituents in runoff. Results showed that runoff from most land use types had low dissolved oxygen concentration and that sediment and nutrient concentrations were closely related to land use, particularly to the amount of fertilizer applied in each land use. Among the eight heavy metals tested, copper was the most frequently detected and was mostly associated with runoff from citrus and golf course land uses. High levels of arsenic were also detected in golf course runoff. The most frequently detected pesticide was simazine from citrus. The information and methodologies presented may facilitate pollution source characterization and ecological restoration efforts.     

RIDGE REGRESSION TECHNIQUES APPLIED TO LANDSAT INVESTIGATION OF WATER QUALITY IN LAKE OKEECHOBEE1

ABSTRACT: Landsat radiance values were processed at two different (single and double) levels of accuracy to estimate chlorophyll a, turbidity, and suspended sediment in Lake Okeechobee, Florida. Both ordinary least square and ridge regression analyses were used to establish a relationship between water quality parameters and Landsat radiance. Radiance measurements made at greater precision (double level) gave a better solution in this application. The ridge regression analysis for double level not only can reduce the total mean square error about 13–20 percent and confidence interval about 6–28 percent as compared to ordinary least square analysis, but it can also change the interpretation of analysis results.     

Biodegradation of polycyclic aromatic hydrocarbons in oil-contaminated beach sediments treated with nutrient amendments

Microbial biodegradation of polycyclic aromatic hydrocarbons (PAHs) during the process of bioremediation can be constrained by lack of nutrients, low bioavailability of the contaminants, or scarcity of PAH-biodegrading microorganisms. This study focused on addressing the limitation of nutrient availability for PAH biodegradation in oil-contaminated beach sediments. In our previous study, three nutrient sources including inorganic soluble nutrients, the slow-release fertilizer Osmocote (Os; Scotts, Marysville, OH) and Inipol EAP-22 (Ip; ATOFINA Chemicals, Philadelphia, PA), as well as their combinations, were applied to beach sediments contaminated with an Arabian light crude oil. Osmocote was the most effective nutrient source for aliphatic biodegradation. This study presents data on PAH biodegradation in the oil-spiked beach sediments amended with the three nutrients. Biodegradation of total target PAHs (two- to six-ring) in all treatments followed a first-order biodegradation model. The biodegradation rates of total target PAHs in the sediments treated with Os were significantly higher than those without. On Day 45, approximately 9.3% of total target PAHs remained in the sediments amended with Os alone, significantly lower than the 54.2 to 58.0% remaining in sediment treatments without Os. Amendment with Inipol or soluble nutrients alone, or in combination, did not stimulate biodegradation rates of PAHs with a ring number higher than 2. The slow-release fertilizer (Os) is therefore recommended as an effective nutrient amendment for intrinsic biodegradation of PAHs in oil-contaminated beach sediments.     

DRAINAGE QUALITY AT DEEP COAL MINE SITES1

ABSTRACT: Samples were collected from the drainages of inactive deep coal mine sites located in eight states. Drainage quality was found to be highly variable, with a majority of sites exceeding federal effluent quality guidelines. Concentrations of trace metals including cadmium, mercury, zinc, and nickel were low. The presence of overburden calcareous material was shown to affect drainage quality. A consistent pattern of pH-acidity response was found to exist for the mine sites monitored. An empirical formula was developed to characterize this response.