Organochlorine and mercury contamination in fish tissues from the River Nestos, Greece

Polychlorinated biphenyls (PCBs), hexachlorocyclohexane (HCH) isomers, dichlorodiphenyltrichloroethane (DDT) and its metabolites, other organochlorine pesticides such as hexachlorobenzene (HCB), chlordane compounds (CHLs, including trans-chlordane and cis- and trans-nonachlor) and the heavy metal mercury were quantified in muscle and liver of the European chub (Leuciscus cephalus, Linnaeus, 1758) and in the muscle of the barbel (Barbus cyclolepis, Heckel, 1837) at two sampling sites of the River Nestos, Greece. PCBs in muscle and DDTs in the liver tissues were the predominant organochlorinated contaminants. Among the PCBs, congeners 47 (up to 9.60 ng g(-1) wet wt.), 180 (up to 1.15 ng g(-1) wet wt.) and 190 (up to 1.50 ng g(-1) wet wt.) were the most frequent and abundant. The contamination degree by the sum of PCBs on the fish tissue samples from the River Nestos is lower or similar to PCB levels found in other ecosystems. Among the organochlorine pesticides, essentially only p,p'-DDD, p,p'-DDE and alpha-, beta- and gamma-HCH were found, with the former appearing at mean levels up to 30.71 ng g(-1) wet wt. From a public health standpoint, residue organochlorine pesticide levels from our work are considerably lower than the recommended tolerance limits. Finally, mean values of Hg in chub were significant lower (up to 31.04 ng g(-1) wet wt.) compared to those detected on barbel (up to 169.27 ng g(-1) wet wt.). The concentrations of Hg in fresh water fish from the River Nestos did not exceed WHO and US EPA health guidelines, and were suitable for human consumption.     

Seasonal variation of persistent organochlorine insecticide residues in Vellar River waters in Tamil Nadu, South India

Water samples collected from Vellar river and Pichavaran mangroves at Porto Novo (11 degrees 29' N, 79 degrees 46' E), Tamil Nadu State, South India, from December 1987 to January 1989 were analyzed to determine the seasonal variation of the levels of organochlorine insecticides such as HCH (BHC) and DDT. Both these insecticides showed higher levels from October to February, although this trend was more pronounced in HCH than DDT, reflecting the application of technical HCH largely and probably small quantities of DDT during the flowering season of rice. The alpha-HCH was detected as a dominant isomer for all seasons monitored followed by beta-HCH. Among DDT compounds, p,p'-DDT was the highest in river water except in the dry season when p,p'-DDD showed a higher percentage. On the other hand, in mangroves p,p'-DDE was highest during the wet season and p,p'-DDD during the dry season. Air-water partitioning data of HCH isomers and DDT compounds in Vellar river revealed that these chemicals tend to be in the water phase. These observations may aid in understanding the role of a tropical paddy area on the behavior and fate of man-made chemicals in view of worldwide contamination.     

Occurrence and accumulation of organochlorine contaminants in swordfish from Mediterranean Sea: a case study

Polychlorinated biphenyls including coplanar congeners and DDT compounds were measured in the liver of a teleost species: namely, Xiphias gladius. PCB concentrations (median: 1121 ng/g lipid wt) were comparable with DDT levels (median: 1236 ng/g lipid wt). PCBs revealed a profile dominated by hexa-, penta- and heptachlorinated congeners. Among DDTs, the compound in the greatest concentration was p,p'-DDE, representing 70% of the total DDT burden, followed by o,p'-DDT>p,p'-DDT>p,p'-DDD=o,p'-DDD. Mean total 2,3,7,8-TCDD equivalent of five coplanar PCBs was 8.83 pg/g lipid weight. The isomers with higher TEQs values were non-ortho congeners than mono-ortho ones.     

The levels and distribution of organochlorine pesticides (OCPs) in sediments from the Haihe River, China

The levels and distribution patterns of the selected organochlorine pesticides (OCPs=p,p'-DDT, o,p'-DDT, p,p'-DDE, p,p'-DDD, alpha-, beta-, gamma- and delta-HCH) in surficial sediments from the Haihe River and Dagu Drainage River of Tianjin were investigated by means of gas chromatography coupled with micro-electronic capture detector (GC-microECD). Concentrations of OCPs in the sediments from the Haihe River ranged from 1.88 to 18.76ng g(-1) (mean 7.33ng g(-1)) for sum HCH, 0.32-80.18ng g(-1) (mean 15.94ng g(-1)) for sum DDT. Compared with the Haihe River, the Dagu Drainage River was much more contaminated by HCHs and DDTs, wherein sum HCH ranged from 33.24 to 141.03ng g(-1) (mean 87.74ng g(-1)) and sum DDT ranged from 3.60 to 83.49ng g(-1) with a mean value of 35.52ng g(-1). The concentration distribution of sum DDT and sum HCH was different indicated their different contamination sources. Composition analyses indicated that a recent usage or discharge of HCH and DDT into the Dagu Drainage River.     

Pollution sources and occurrences of selected persistent organic pollutants (POPs) in sediments of the Mekong River delta, South Vietnam

The Mekong River delta is one of the largest agricultural land in the Southeast Asia. It plays a very important role for agriculture and fisheries in South Vietnam. However, comprehensive studies on the environmental pollution of persistent organic pollutants (POPs) in Mekong River delta have not been carried out in recent years. In this study, we collected sediment samples from the Mekong River to evaluate the contamination and ecological risks caused by several POPs. The contamination pattern of POPs was DDT>PCBs>CHLs>HCHs>HCB. DDTs are the most abundant pollutants, their concentration ranging from 0.01 to 110 ng/g dry wt, followed by PCBs (0.039-9.2 ng/g dry wt). DDTs and PCBs concentrations were higher in sediment from adjacent to urban areas than those from rural and agricultural sites, suggesting urban areas as important point sources of DDTs and PCBs to the river. Ratio of p,p'-DDT/p,p'-DDE was lower compared to those previously reported. However, some samples still had the ratio higher than 0.5, indicating recent input of DDT into the aquatic environments. This result shows that although the magnitude of contamination decreased over time, recent inputs of DDTs to the river still occur. Some sediment samples had concentrations of DDT compounds higher than the standards from the Canadian Environmental Quality Guideline, suggesting continuous monitoring for POPs contamination in the Mekong River is necessary.     

Concentrations of organochlorine insecticides in edible oils from different regions of India

In this study, organochlorine insecticides (OCPs), DDT metabolites and HCH isomers were quantified in mustard, groundnut and sunflower oils collected from different regions of India. The maximum level of 222.0 ng g(-1) and minimum level of 0.2 ng g(-1) of SigmaDDT were detected in mustard oil from Deoria and Varanasi while those of SigmaHCH i.e., 1500 ng g(-1) and 8.0 ng g(-1) in mustard oil from Deoria and Kanpur, respectively. However, the maximum total concentration of alpha-, beta- and gamma-HCH was in mustard oil, whereas maximum delta-HCH was in groundnut oil. However, the maximum percentage of p,p'-DDT was in mustard oil while maximum p,p'-DDE was in groundnut oil. The study calls for periodical monitoring to ensure safe supply of edible oils to consumers.     

Polychlorinated biphenyl congeners and organochlorine insecticides in the water column and sediments of Daya Bay, China.

Samples of sub-surface water, suspended particulate matter (SPM) and surface sediments collected from Daya Bay, China have been analysed for 12 polychlorinated biphenyl (PCB) congeners and 18 organochlorine insecticides, using gas chromatography electron capture detection. Total PCB levels varied from 91.1 to 1355.3 ng l-1 in water and from 0.85 to 27.37 ng g-1 dry weight in sediments. The levels of total organochlorine insecticides were in the range 143.3-5104.8 ng l-1 in water and 2.43-86.25 ng g-1 dry weight in sediment. None of the target compounds were detected in SPM. The levels of total hexachlorocyclohexanes in water varied from 35.5 to 1228.6 ng l-1, whilst in sediments they ranged from 0.32 to 4.16 ng g-1 dry weight. For the sum of dichlorodiphenyltrichloroethanes (DDTs), their levels were in the range 26.8-975.9 ng l-1 in water, and 0.14-20.27 ng g-1 dry weight in sediments. The distribution profiles of these contaminants in water and sediments suggest that there are a number of sources contributing to total contaminant burden in the bay, including soil runoffs, wastewater discharges, sewage outfalls and shipping activites. Ratios of DDT/(DDE + DDD) in the water and sediments indicate recent inputs of such chemicals into the day. The results, therefore, provide important information on the current contamination status of a key aquacultural area in China, and point to the need for urgent actions to stop the use of persistent agrochemicals such as DDT and lindane.     

Residues of organochlorine pesticides in Hong Kong soils

It was short of research on the organochlorine pesticides (OCPs) residues in the soils of Hong Kong. Sixty-six representative soil samples were collected from the 46 sites covering five types of land uses in Hong Kong. Hexachlorohexanes (HCH) and 7 Stockholm Convention OCPs were analyzed by gas chromatograph (GC) equipped with a Nickel 63 electronic capture detector (muECD). The results presented that HCH and 5 Stockholm Convention pesticides were detected in Hong Kong soils although the detectable ratio varies to a great extent. The concentration sequence of the five detectable OCPs was HCH > dichlorodiphenyltrichloroethane (DDT) > hexachlorobenzene (HCB) approximately = Endrin > alpha-endosulfan. Among the OCPs and their homologues or isomers, beta-HCH and p,p'-DDE were the two predominant substances according to the concentrations and detectable ratios, concentrations of which in soils were averagely 6.12 microg kg(-1) and 0.41 microg kg(-1) respectively. Soil horizon samples of 0-10 cm, 10-30 cm and >30 cm depth were selected from nine soil profiles to demonstrate the depth distributions of DDT and HCH in soil profiles. Concentrations of HCH tended to increase gradually from the topsoil to bottom layer while the lowest concentration of DDT is usually found in the subsoil (10-30 cm) in most sampling sites. In addition, close correlations of pH(KCl) and total organic carbon (TOC) with HCH indicated an effect on the residues of HCH caused by these two soils properties, but such relationships were not found with DDT or other OCPs.     

Soil-air exchange of organochlorine pesticides in the Southern United States

Soil samples were collected from 30 farms in Alabama, Louisiana and Texas during 1999-2000 to determine residues of organochlorine pesticides (OCPs). One or more of the DDT compounds (p,p'-DDT, o,p'-DDT, p,p'-DDD, p,p'-DDE, o,p'-DDE) was above the quantitation limit (0.1 ng g(-1) dry weight) in every soil, and toxaphene was above the quantitation limit (3 ng g(-1)) in 26 soils. Chlordanes, dieldrin and hexachlorocyclohexane (HCH) isomers occurred less frequently (quantitation limits 0.1 ng g(-1) for dieldrin and 0.05 ng g(-1) for chlordanes and HCHs). OCPs were measured in air at 40 cm above the soil at selected farms to investigate soil-air partitioning. Concentrations of OCPs in air were positively and significantly (P<0.001-0.004) correlated to soil concentrations for toxaphene, p,p'-DDT, o,p'-DDT, p,p'-DDE, dieldrin, and trans-nonachlor. The regression was weaker (P=0.022) for cis-chlordane and not significant for trans-chlordane (P=0.43) nor gamma-HCH (P=0.80). Approach to soil-air equilibrium was assessed by calculating fugacities in the soil and air (f(s) and f(a)) for samples with quantifiable residues in both compartments. The fugacity fraction f(s)=0.5 at equilibrium and is <0.5 or >0.5 for net deposition and net volatilisation, respectively. Fugacity fractions varied greatly for different soil-air pairs, reflecting generally disequilibrium conditions. Mean fugacity fractions indicated near-equilibrium for some OCPs (p,p'-DDE, chlordanes, trans-nonachlor and dieldrin) and net volatilisation for others (p,p'-DDT, o,p'-DDT, toxaphene, gamma-HCH). Chiral analysis showed that enantioselective degradation of (+) or (-) o,p'-DDT in soil was accompanied by enrichment or depletion of the corresponding enantiomers in the overlying air, although there appeared to be some dilution by racemic o,p'-DDT from regional air transport.     

Distribution and behaviour of persistent organochlorine insecticides in paddy soil and sediments in the tropical environment: a case study in South India

Paddy soil and sediment samples collected from the Vellar River watershed, Tamil Nadu state, South India from December, 1987 to January, 1989 were analysed to understand the comprehensive behaviour of organochlorine insecticides (HCH and DDT) in the tropical environment. HCH (BHC) showed higher levels in soil during wet season, reflecting the application of technical HCH largely during the flowering season of rice. On the other hand, DDT residues were low and did not show a significant seasonal trend in soil or sediment, indicating small quantities of DDT utilized at present for agricultural purposes in India. When compared to soil, the residue levels in sediments are low and the seasonal variation is less pronounced. This indicates that in tropical watersheds, the relative flux of residues into the aquatic environment is smaller than the amount volatilized to the atmosphere.     

Pesticides and metabolites in cassava, eucalyptus, plum and cashew leaves and roots in relation to a point source in Kibaha, Tanzania

Leaves of Eucalyptus sp., Prunus domestica (plum), and Anacardium occidentale (cashew), as well as roots and leaves of Manihot esculenta (cassava) were used to study the local distribution of pesticides and metabolites from a point source, an old storage site at Vikuge farm in Tanzania. The GPC-cleaned extracts were analyzed by GC-ECD and GC/MS. Eleven organochlorine pesticide residues namely pentachloroanisole, p,p'-DDT, o,p'-DDT, p,p'-DDE, o,p'-DDE, p,p'-DDD, o,p'-DDD, alpha-HCH, beta-HCH, delta-HCH and epsilon-HCH were detected in the samples. The concentrations of total DDT were 818 ng/g fw in Eucalyptus sp., 16 ng/g fw in A. occidentale and 4 ng/g fw in P. domestica. In M. esculenta, total DDT ranged from 191 to 586 ng/g fw in roots and 7 to 425 ng/g fw in leaves. The concentrations of total HCH were up to 15 ng/g fw in Eucalyptus sp., while the concentrations of pentachloroanisole were up to 2 ng/g fw in leaves of M. esculenta. There are very strong positive correlations in the concentrations of the detected compounds, suggesting that they have a common source. The low DDE/DDT ratios (0.02-0.07) in all samples indicate input of non-degraded DDT from the source. The high alpha-HCH/gamma-HCH ratios in some samples (>3.1-10) indicate input of technical HCH. The concentrations of total DDT in cassava roots were either very close to, or greater than, the FAO/WHO limit, indicating risks and concern to public health.     

Sedimentation and seasonal variation of hexachlorocyclohexanes in sediments in a eutrophic lake, China

Hexachlorocyclohexane (HCH) concentrations in sediments and sediment trap fluxes of particulate organic carbon and HCHs were measured bi-weekly from March 31 to October 18, 2006 in an urban eutrophic lake in Tianjin, China, in order to investigate sedimentation and seasonal variation of HCHs in sediments. HCH concentrations (dry weight basis) ranged from 2.2 to 20.2 ng/g (mean 7.7 ng/g) in surface sediments and from 26.6 to 972.7 ng/g (mean 187.0 ng/g) in settling particles, respectively. A clear seasonal variation in HCH sedimentation and HCH concentrations in sediments was observed. The maximal HCH deposition occurred following a spring phytoplankton bloom. The average flux of HCHs to sediment was approximately 21-fold higher in April to mid-June as compared to late June to October. This was attributed to the high vertical fluxes at the end of the spring phytoplankton bloom. The maximum values of HCH concentrations in sediments were observed in mid-June to late July. Concentrations of HCHs in sediments from the eutrophic lake were well-correlated with organic carbon contents in sediments. The annual sediment trap flux of HCHs in the eutrophic lake, which was estimated using data obtained in the eutrophic lake, was 117 microg/m2 yr, about 72% of which was attributed to the sedimentation corresponding to spring bloom phytoplankton deposition in late May to mid-June. The high sediment trap flux of HCHs in the eutrophic lake was related to serious local contamination.     

Sedimentation and seasonal variation of hexachlorocyclohexanes in sediments in a eutrophic lake,China

Hexachlorocyclohexane (HCH) concentrations in sediments and sediment trap fluxes of particulate organic carbon and HCHs were measured bi-weekly from March 31 to October 18, 2006 in an urban eutrophic lake in Tianjin, China, in order to investigate sedimentation and seasonal variation of HCHs in sediments. HCH concentrations (dry weight basis) ranged from 2.2 to 20.2 ng/g (mean 7.7 ng/g) in surface sediments and from 26.6 to 972.7 ng/g (mean 187.0 ng/g) in settling particles, respectively. A clear seasonal variation in HCH sedimentation and HCH concentrations in sediments was observed. The maximal HCH deposition occurred following a spring phytoplankton bloom. The average flux of HCHs to sediment was approximately 21-fold higher in April to mid-June as compared to late June to October. This was attributed to the high vertical fluxes at the end of the spring phytoplankton bloom. The maximum values of HCH concentrations in sediments were observed in mid-June to late July. Concentrations of HCHs in sediments from the eutrophic lake were well-correlated with organic carbon contents in sediments. The annual sediment trap flux of HCHs in the eutrophic lake, which was estimated using data obtained in the eutrophic lake, was 117 μ g/m² yr, about 72% of which was attributed to the sedimentation corresponding to spring bloom phytoplankton deposition in late May to mid-June. The high sediment trap flux of HCHs in the eutrophic lake was related to serious local contamination.     

Levels and distribution of DDT in the Cinca River (Spain).

The evolution over time of the levels and distribution of dichlorodiphenyltrichloroethane (DDT) in water, surface sediments, and fish from the River Cinca (Spain), a tributary of the River Ebro, during the period 1999 to 2004, was investigated by means of gas chromatography coupled with mass spectrometry. The sampling site corresponded to a point downstream from Monzón, a heavily industrialized town with drainage into the river. This river has historically been a source of emissions of DDT and its metabolites. The highest levels were found in 1999 and 2000, although the concentrations of organic compounds in sediments and fish have decreased since then. The levels of DDT in water were below the quantification limit during the period of study. The average composition of DDT isomers measured in sediments and fish showed the prevalence of p,p'-DDE, the product of aerobic degradation of p,p'-DDT. Concentrations in fish were compared with sediment samples, and high quotients indicate that they are highly bioavailable.     

Monitoring of organochlorine pesticide residues in the Indian marine environment.

Organochlorine pesticide residues in sediment and fish samples collected from the east and west coasts of India are presented. HCH isomers and DDT and its metabolites are the predominantly identified compounds in most of the samples. Despite the higher quantity of consumption, HCH and DDT levels in fish in India were lower than those in temperate countries suggesting a lower accumulation in tropical fish, which could be due to rapid volatilization and degradation of these insecticides in the tropical environment. The predominance of alpha- and beta-HCH reflect the use of technical grade HCH in India. The high temperature in the tropics also enhances the elimination rate of chemicals in fish, as the biological half-lives of semivolatile compounds such as DDT are short at high temperature.     

Assessment of Organochlorine Pesticide Residues in Water,Sediment, and Fish of the Songhua River,China

This study examined residual concentrations and associated ecological risks of the organochlorine pesticides (OCPs) hexa- chlorocyclohexane (HCH) and dichloro-diphenyl-trichloroethane (DDT) in water, sediment, and fish of the Songhua River in Zhaoyuan County, China. In June 2012, 10 water, 10 sediment, and 20 fish samples were collected. Residual concentrations of ΣHCH and ΣDDT ranged from 10.0–35.59 ng L^?1 (mean 28.03 ± 11.66 ng L^?1) and 5.12–39.66 ng L^?1 (mean 32.36 ± 11.58 ng L^?1) for water. Residual concentrations of ΣHCH and ΣDDT ranged from 0.52–3.00 ng g^?1 (mean 2.04 ± 0.73 ng g^?1) and 0.34–3.41 ng g^?1 (mean 2.38 ± 0.92 ng g^?1) for sediment. The ratios of α-HCH/γ-HCH were close to 1 at the majority of sampling points, indicating considerable new pollution from the use of lindane. The ratios of p,p′-DDE + p,p′-DDD/ΣDDT were less than 0.5, indicating recent inputs from DDT impurities in dicofol. All HCH and DDT isomers except for p,p′-DDD were detected in fish tissue samples, but the associated ecological risks were estimated to be below levels of concern. The study revealed a historical usage of OCPs in the Zhaoyuan section of the Songhua River and new OCP from the use of lindane and dicofol.     

Spatial and temporal variations and possible sources of dichlorodiphenyltrichloroethane (DDT) and its metabolites in rivers in Tianjin, China

Water, suspended solid (SS) and sediment samples were collected from nine water courses in Tianjin, China and analyzed for dichlorodiphenyltrichloroethane (DDT) and its metabolites (DDXs, including o,p'-,p,p'-DDT, DDD and DDE). The average DDX concentrations in water, SS and sediment were 59+/-30 ng l(-1), 2690+/-1940 ng g(-1)dry wt. and 340+/-930 ng g(-1)dry wt., respectively. Due to the termination of the extensive agricultural application and industrial manufacture, DDXs in river sediment decreased by one order of magnitude since 1970's and low DDT fractions in these sediments were observed. Still, DDXs in the sediments near the outlets of the major manufacturers remained relatively high attributed to the historic input. DDXs in sediment were also positively correlated with organic matter content. Spatial distributions of DDXs in SS and water was different from that in sediment. For SS, a negative correlation between DDX concentration and SS content indicated a dilution effect in many rivers. Dissolved organic carbon content was the major factor affecting DDX concentrations in water phase. Wastewater discharged from dicofol manufacturers and likely illegal agricultural application were the primary reasons causing high DDT (DDE+DDD) ratios in SS and water.     

Distribution and fate of organochlorine pesticide residues in sediments from the selected rivers in Taiwan

The contamination of organochlorine pesticides (OCPs) in sediments from selected rivers in Taiwan was investigated to evaluate the pollution potentials and hazard in river sediments. Da-han River and Erh-jen River were selected as the target rivers due to their serious pollution. A total of 40 surface sediment samples were collected at five sampling stations along the rivers. Results showed that the concentrations of various pesticides in sediments were in the range of 0.57-14.1 ng/g for sigmaHCH, 0.05-0.15 ng/g for aldrin, 0.12-5.8 ng/g for dieldrin, 0.22-0.64 for endrin, 0.24-6.37 ng/g for endosulfan and 0.21-8.81 ng/g for EDDT (p,p'-DDD, p,p'-DDE, p,p'-DDT). Among the OCPs, sigmaHCH, endosulfan and sigmaDDT were the most dominant compounds in the river sediments. Endosulfan sulfate was the most frequent detected compound in the sediments from the selected rivers. Also, sigmaDDT, dieldrin and beta-HCH were in abundance. Different contamination patterns between the selected river sediments were also observed. Da-han River was mainly contaminated with endosulfan sulfate and sigmaDDT. Whereas the main pesticides in Erh-jen River were beta-HCH and sigmaDDT. Among the cyclodiene compounds, dieldrin was in abundance in most of the sediments. Moreover, the frequencies of detection of the metabolites were higher than those of parent compounds, depicting that the sediments have contaminated for a long time. The results obtained in this study showed that there still exist a variety of OCP residues in the river sediments in Taiwan.     

Organochlorine residues in water from the Mahala water reservoir, Jaipur, India

Residues of p,p'-DDE, p,p'-DDT alpha-, beta-, gamma-isomers of HCH, aldrin and heptachlor in water, from four different sites of the Mahala water reservoir were monitored periodically from September 1985 to October 1987. All the samples contained the above residues in varying concentrations. Isomers of HCH predominated and were followed in relative dominance by aldrin, total DDT and heptachlor residues, p,p'-DDE and p,p'-DDD constituted the major fraction of total p,p'-DDT. Monthly total organochlorine residue levels in water ranged between 1.07 and 81.23 microg litre-1. The variation is attributed to the run-off or subsoil water movement from the catchment area.     

Residues and chiral signatures of organochlorine pesticides in sediments from Xiangshan Bay, East China Sea

Residual levels and enantiomeric signatures of hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) in surface sediments from Xiangshan Bay, East China Sea were investigated. The concentrations of ∑HCHs (sums of α-, β-, γ-, and δ-HCH) and ∑DDTs (sums of p, p'-DDT, p, p'-DDD,p, p'-DDE, o, p'-DDT, and o, p'-DDD) ranged from 0.14 to 0.67 ng g?1 and 0.61 to 22.38 ng g?1, respectively. A slight potential health risk to the organism was then indicated for the residual levels of DDTs according to the ERL/ERM guidelines. Moreover, the predominant β-HCH implied that the technical HCH contamination was mainly due to the historical usage. But the high ratio of DDT/∑DDTs depicted a cocktail input pattern of fresh and weathered DDTs. The enantiomeric fractions (EFs) of α-HCH, o, p'-DDT, and o, p'-DDD were also determined. The degradation of α-HCH was enantioselective in all sediments samples, resulting in an enrichment of (-)-enantiomers. However, the racemic residues of o, p'-DDT and o, p'-DDD were observed in all sediments samples.