Source apportionment of fine particulate matter in the southeastern United States

Particulate matter (PM) less than 2.5 microm in size (PM2.5) source apportionment by chemical mass balance receptor modeling was performed to enhance regional characterization of source impacts in the southeastern United States. Secondary particles, such as NH4HSO4, (NH4)2SO4, NH4NO3, and secondary organic carbon (OC) (SOC), formed by atmospheric photochemical reactions, contribute the majority (>50%) of ambient PM2.5 with strong seasonality. Source apportionment results indicate that motor vehicle and biomass burning are the two main primary sources in the southeast, showing relatively more motor vehicle source impacts rather than biomass burning source impacts in populated urban areas and vice versa in less urbanized areas. Spatial distributions of primary source impacts show that each primary source has distinctively different spatial source impacts. Results also find impacts from shipping activities along the coast. Spatiotemporal correlations indicate that secondary particles are more regionally distributed, as are biomass burning and dust, whereas impacts of other primary sources are more local.     

Substituent effects on azo dye oxidation by the FeIII-EDTA-H2O2 system

Toxicity potentials are scaling factors used in life cycle assessment (LCA) indicating their relative importance in terms of potential toxic impacts. This paper presents the results of an uncertainty assessment of toxicity potentials for 181 substances that were calculated with the global nested multi-media fate, exposure and effects model USES-LCA. The variance in toxicity potentials resulting from choices in the modelling procedure was quantified by means of scenario analysis. A first scenario analysis showed to what extent potential impacts in the relatively short term are obscured by the inclusion of impacts on the very long term. Toxicity potentials representing potential impacts over time horizons of 20, 100 and 500 years were compared with toxicity potentials representing potential impacts over an infinite time horizon. Time horizon dependent differences up to 6.5 orders of magnitude were found for metal toxicity potentials, while for toxicity potentials of organic substances under study, differences remain within 0.5 orders of magnitude. The second scenario analysis addressed to what extent potential impacts on the continental scale are obscured by the inclusion of impacts on the global scale. Exclusion of potential impacts on the global scale changed the toxicity potentials of metals and volatile persistent halogenated organics up to 2.3 orders of magnitude. These scenario analyses also provide the basis for determining exports to future generations and outside the emission area.     

Avoiding Land Disposal of Hazardous Waste

In response to a growing societal mandate, land disposal of hazardous wastes is gradually being replaced by treatment technologies. This shift to "alternative technologies" is the result of the impacts of past land disposal practices on other environmental media (groundwater, surface water, and air). A prime motivation for adopting alternatives to land disposal is to eliminate these cross-media impacts. Alternative technologies, however, can themselves have cross-media environmental impacts which must be recognized and addressed before such technologies are extensively applied. This paper discusses hazardous waste constituents, common disposal practices, alternative technologies currently being applied, possible cross-media environmental impacts of the alternative technologies, and proposed methods of mitigating these environmental impacts. Case studies from uncontrolled hazardous waste sites and industrial operations are used to illustrate the application of alternative technologies. Case studies include the application of waste treatment technologies as well as the adoption of waste minimization techniques.     

What do we really know about the impacts of one of the 100 worst invaders in Europe? A reality check

Invasive species are one of the greatest threats to biodiversity worldwide, and to successfully manage their introductions is a major challenge for society. Knowledge on the impacts of an invasive species is essential for motivating decision makers and optimally allocating management resources. We use a prominent invasive fish species, the round goby (Neogobius melanostomus) to objectively quantify the state of scientific knowledge on its impacts. Focusing on how native fish species are affected by round goby invasions, we analyzed 113 peer-reviewed papers and found that impacts are highly ecosystem and time scale dependent. We discovered round goby impacts to be profound, but surprisingly complex. Even if identical native species were affected, the impacts remained less comparable across ecosystems than expected. Acknowledging the breadth but also limitations in scientific knowledge on round goby impacts would greatly improve scientists’ ability to conduct further research and inform management measures.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-015-0718-9) contains supplementary material, which is available to authorized users.     

Central power generation versus distributed generation – An air quality assessment in the South Coast Air Basin of California

This study assesses the air quality impacts of central power generation and compares them with the impacts of distributed generation (DG). The central power plant emissions factors used are from a newly installed combined cycle gas turbine system. Because location of power plants is a key parameter affecting air quality impacts, this study considers three potential locations for the installation of central power plants. Air quality impacts are evaluated for the South Coast Air Basin of California, in the year 2010, using a three-dimensional air quality model. Results are compared to air quality impacts from two potential DG scenarios to meet the same power demand as that of the central power plant case.Even though emissions from central generation are lower than emissions from the DG technology mix considered herein, central generation concentrates emissions in a small area, whereas DG spreads emissions throughout a larger cross-section of the air basin. As a result, air quality impacts from central generation are more significant than those from DG. The study also shows that assessment of air quality impacts from distributed and central generation should not only consider emissions levels, but also the spatial and temporal distribution of emissions and the air quality that results from atmospheric chemistry and transport – highly non-linear processes.Finally, analysis of population exposure to ozone and PM_2.5 shows that central generation located in coastal areas upwind from populated areas would cause the highest population exposure and even though emissions from central generation are considerably lower than DG emissions spread throughout the basin, results show that central generation causes a higher pollutant exposure than DG.     

Source Apportionment of Fine Particulate Matter in the Southeastern United States

Abstract

Particulate matter (PM) less than 2.5 μm in size (PM_2.5)source apportionment by chemical mass balance receptor modeling was performed to enhance regional characterization of source impacts in the southeastern United States. Secondary particles, such as NH₄HSO₄, (NH₄)₂SO₄,NH₄NO₃, and secondary organic carbon (OC) (SOC), formed by atmospheric photochemical reactions, contribute the majority (<50%) of ambient PM_2.5 with strong seasonality. Source apportionment results indicate that motor vehicle and biomass burning are the two main primary sources in the southeast, showing relatively more motor vehicle source impacts rather than biomass burning source impacts in populated urban areas and vice versa in less urbanized areas. Spatial distributions of primary source impacts show that each primary source has distinctively different spatial source impacts. Results also find impacts from shipping activities along the coast. Spatiotemporal correlations indicate that secondary particles are more regionally distributed, as are biomass burning and dust, whereas impacts of other primary sources are more local.     

South-Siberian mountain mires: Perspectives on a potentially vulnerable remote source of biodiversity

Changes in climate, land-use and pollution are having disproportionate impacts on ecosystems and biodiversity of arctic and mountain ecosystems. While these impacts are well-documented for many areas of the Arctic and alpine regions, some isolated and inaccessible mountain areas are poorly studied. Furthermore, even in well-studied regions, assessments of biodiversity and species responses to environmental change are biased towards vascular plants and cryptogams, particularly bryophytes are far less represented. This paper aims to document the environments of the remote and inaccessible Altai-Sayan mountain mires and particularly their bryofloras where threatened species exist and species new to the regional flora are still being found. As these mountain mires are relatively inaccessible, changes in drivers of change and their ecosystem and biodiversity impacts have not been monitored. However, the remoteness of the mires has so far protected them and their species. In this study, we describe the mires, their bryophyte species and the expected impacts of environmental stressors to bring attention to the urgency of documenting change and conserving these pristine ecosystems.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-021-01596-w.     

Is small hydropower beautiful? Social impacts of river fragmentation in China’s Red River Basin

Small hydropower (SHP) is promoted as a pro-poor renewable energy source that does not have the negative social impacts of large dams. This article challenges these claims, using data from a household survey in China’s upper Red River Basin. We find that SHP can fragment river systems in ways that reduce irrigation water availability, provoke changes to agricultural practices, and negatively impact river health. These social impacts of river fragmentation mainly occur in villages situated between a plant’s intake and outflow. The frequency of plant water diversions due to continued generation in the dry season significantly predicts all social impacts; installed capacity of the plant and the quality of the village’s irrigation infrastructure predict some impacts. Villages with strong local governance can negotiate with the plant to temporarily halt generation when irrigation water is needed, lessening social impacts. Our findings reveal that SHP plants are not as benign as they are made out to be; they must be built and managed according to community needs.     

Spatial PM2.5 mobile source impacts using a calibrated indicator method

Motor vehicles are major sources of fine particulate matter (PM_2.5), and the PM_2.5 from mobile vehicles is associated with adverse health effects. Traditional methods for estimating source impacts that employ receptor models are limited by the availability of observational data. To better estimate temporally and spatially resolved mobile source impacts on PM_2.5, we developed an approach based on a method that uses elemental carbon (EC), carbon monoxide (CO), and nitrogen oxide (NO_x) measurements as an indicator of mobile source impacts. We extended the original integrated mobile source indicator (IMSI) method in three aspects. First, we generated spatially resolved indicators using 24-hr average concentrations of EC, CO, and NO_x estimated at 4 km resolution by applying a method developed to fuse chemical transport model (Community Multiscale Air Quality Model [CMAQ]) simulations and observations. Second, we used spatially resolved emissions instead of county-level emissions in the IMSI formulation. Third, we spatially calibrated the unitless indicators to annually-averaged mobile source impacts estimated by the receptor model Chemical Mass Balance (CMB). Daily total mobile source impacts on PM_2.5, as well as separate gasoline and diesel vehicle impacts, were estimated at 12 km resolution from 2002 to 2008 and 4 km resolution from 2008 to 2010 for Georgia. The total mobile and separate vehicle source impacts compared well with daily CMB results, with high temporal correlation (e.g., R ranges from 0.59 to 0.88 for total mobile sources with 4 km resolution at nine locations). The total mobile source impacts had higher correlation and lower error than the separate gasoline and diesel sources when compared with observation-based CMB estimates. Overall, the enhanced approach provides spatially resolved mobile source impacts that are similar to observation-based estimates and can be used to improve assessment of health effects.

Implications: An approach is developed based on an integrated mobile source indicator method to estimate spatiotemporal PM_2.5 mobile source impacts. The approach employs three air pollutant concentration fields that are readily simulated at 4 and 12 km resolutions, and is calibrated using PM_2.5 source apportionment modeling results to generate daily mobile source impacts in the state of Georgia. The estimated source impacts can be used in investigations of traffic pollution and health.     

环境政策对环境技术创新的影响

环境政策对技术创新具有正负两个方面的影响。本文详细分析了不同类型环境政策的技术效应 ,并阐述了环境政策的未来发展方向及其对技术创新的影响     

Big concerns with small projects: Evaluating the socio-ecological impacts of small hydropower projects in India

Although Small Hydropower Projects (SHPs) are encouraged as sources of clean and green energy, there is a paucity of research examining their socio-ecological impacts. We assessed the perceived socio-ecological impacts of 4 SHPs within the Western Ghats in India by conducting semi-structured interviews with local respondents. Primary interview data were sequentially validated with secondary data, and respondent perceptions were subsequently compared against the expected baseline of assured impacts. We evaluated the level of awareness about SHPs, their perceived socio-economic impacts, influence on resource access and impacts on human–elephant interactions. The general level of awareness about SHPs was low, and assurances of local electricity and employment generation remained largely unfulfilled. Additionally most respondents faced numerous unanticipated adverse impacts. We found a strong relationship between SHP construction and increasing levels of human–elephant conflict. Based on the disparity between assured and actual social impacts, we suggest that policies regarding SHPs be suitably revised.     

Tracking the anthropogenic drivers of ecological impacts

Despite the pivotal role human factors (anthropogenic drivers) are presumed to play in global environmental change, substantial uncertainties and contradictory conclusions about them continue. We attempt to further discipline the human factors issue by estimating the effects of two anthropogenic drivers, population and affluence, on a wide variety of global environmental impacts, including greenhouse gas emissions, emissions of ozone depleting substances, and the ecological footprint. Population proportionately increases all types of impacts examined. Affluence typically increases impacts, but the specific effect depends on the type of impact. These findings refocus attention on population and material affluence as principal threats to sustainability and challenge predictions of an ameliorating effect of rising affluence on impacts.     

Review on Fate,Toxicity, and Remediation of Perchlorate

Several issues regarding the adverse impacts of the chemical—perchlorate—have been identified recently. Perchlorate is a persistent chemical, and remains in water and soil, thereby accumulating in plants and animals. Fetuses suffer the most from perchlorate contamination. There are ongoing debates about the impacts, toxicity and health effects of perchlorate. Many studies have been conducted on its ecotoxicity and its effects, but standards do not exist for perchlorate. This study aims to review the sources, impacts, fate, transport and remediation of perchlorate.     

Eco-certification of Farmed Seafood: Will it Make a Difference?

Eco-certification is widely considered a tool for reducing environmental impacts of aquaculture, but what are the likely environmental outcomes for the world’s fastest growing animal-food production sector? This article analyzes a number of eco-certification schemes based on species choice, anticipated share of the global seafood market, size of eligible producers, and targeted environmental impacts. The potential of eco-certification to reduce the negative environmental impacts of aquaculture at scale presently appears uncertain as: (a) certification schemes currently focus on species predominantly consumed in the EU and US, with limited coverage of Asian markets; (b) the share of certified products in the market as currently projected is too low; (c) there is an inequitable and non-uniform applicability of certification across the sector; (d) mechanisms or incentives for improvement among the worst performers are lacking; and (e) there is incomplete coverage of environmental impacts, with biophysical sustainability and ecosystem perspectives generally lacking.     

Air quality and health benefits from potential coal power plant closures in Texas

As power production from renewable energy and natural gas grows, closures of some coal-fired power plants in Texas become increasingly likely. In this study, the potential effects of such closures on air quality and human health were analyzed by linking a regional photochemical model with a health impacts assessment tool. The impacts varied significantly across 13 of the state’s largest coal-fired power plants, sometimes by more than an order of magnitude, even after normalizing by generation. While some power plants had negligible impacts on concentrations at important monitors, average impacts up to 0.5 parts per billion (ppb) and 0.2 µg/m³ and maximum impacts up to 3.3 ppb and 0.9 µg/m³ were seen for ozone and fine particulate matter (PM_2.5), respectively. Individual power plants impacted average visibility by up to 0.25 deciviews in Class I Areas. Health impacts arose mostly from PM_2.5 and were an order of magnitude higher for plants that lack scrubbers for SO₂. Rankings of health impacts were largely consistent across the base model results and two reduced form models. Carbon dioxide emissions were relatively uniform, ranging from 1.00 to 1.26 short tons/MWh, and can be monetized based on a social cost of carbon. Despite all of these unpaid externalities, estimated direct costs of each power plant exceeded wholesale power prices in 2016.

Implications: While their CO₂ emission rates are fairly similar, sharply different NO_x and SO₂ emission rates and spatial factors cause coal-fired power plants to vary by an order of magnitude in their impacts on ozone, particulate matter, and associated health and visibility outcomes. On a monetized basis, the air pollution health impacts often exceed the value of the electricity generated and are of similar magnitude to climate impacts. This suggests that both air pollution and climate should be considered if externalities are used to inform decision making about power-plant dispatch and retirement.     

Questioning complacency: climate change impacts, vulnerability, and adaptation in Norway

Most European assessments of climate change impacts have been carried out on sectors and ecosystems, providing a narrow understanding of what climate change really means for society. Furthermore, the main focus has been on technological adaptations, with less attention paid to the process of climate change adaptation. In this article, we present and analyze findings from recent studies on climate change impacts, vulnerability, and adaptation in Norway, with the aim of identifying the wider social impacts of climate change. Three main lessons can be drawn. First, the potential thresholds and indirect effects may be more important than the direct, sectoral effects. Second, highly sensitive sectors, regions, and communities combine with differential social vulnerability to create both winners and losers. Third, high national levels of adaptive capacity mask the barriers and constraints to adaptation, particularly among those who are most vulnerable to climate change. Based on these results, we question complacency in Norway and other European countries regarding climate change impacts and adaptation. We argue that greater attention needs to be placed on the social context of climate change impacts and on the processes shaping vulnerability and adaptation.     

Twentieth century droughts and agriculture: Examples from impacts on soybean production in Kentucky,USA

Drought is a significant natural hazard that slowly evolves over time. Because of its character, drought is difficult to monitor and impacts are often poorly documented. Agriculture is one of the most sensitive sectors that are prone to drought. The objective of this research is to assess the impacts of drought on soybean production and revenue in Kentucky. Soybeans are one of Kentucky’s most important commodities. In this study, impacts of 1930–1931, 1940–1942, 1952–1955, 1987–1988, 1999–2000, and 2007 droughts were considered. It was found that over the recent years, up to 56 % of the revenue from soybeans was lost due to drought. During the first half of the twentieth century, revenue loss reached up to 77 %. This research is valuable to the general public as well as planners and policy makers. Proper documentation of impacts of past droughts will help identify drought vulnerabilities and results in better risk management and mitigation.     

The social implications of using drones for biodiversity conservation

Unmanned aerial vehicles, or ‘drones’, appear to offer a flexible, accurate and affordable solution to some of the technical challenges of nature conservation monitoring and law enforcement. However, little attention has been given to their possible social impacts. In this paper, I review the possible social impacts of using drones for conservation, including on safety, privacy, psychological wellbeing, data security and the wider understanding of conservation problems. I argue that negative social impacts are probable under some circumstances and should be of concern for conservation for two reasons: (1) because conservation should follow good ethical practice; and (2) because negative social impacts could undermine conservation effectiveness in the long term. The paper concludes with a call for empirical research to establish whether the identified social risks of drones occur in reality and how they could be mitigated, and for self-regulation of drone use by the conservation sector to ensure good ethical practice and minimise the risk of unintended consequences.     

Life cycle toxicity assessment of pesticides used in integrated and organic production of oranges in the Comunidad Valenciana, Spain

The relative impacts of 25 pesticides including acaricides, fungicides, herbicides, insecticides, and post-harvest fungicides, used in the production of oranges in Spain were assessed with current life cycle impact assessment (LCIA) tools. Chemical specific concentrations were combined with pesticide emission data and information on chemical toxicity to assess human toxicity and freshwater ecotoxicity impacts. As a case study, the relative impacts of two orange production systems in the region of Valencia, integrated pest management (IP) and organic production (OP), were assessed. The evaluation of active ingredients showed that on average acaricides have the highest human toxicity impact scores, while for freshwater ecotoxicity insecticides show the highest impact. In both impact categories the lowest impact scores were calculated for herbicides. In the production of 1 kg of orange fruits, where several kinds of pesticides are combined, results show that post-harvest fungicides can contribute more than 95% to the aggregate human toxicity impacts. More than 85% of aquatic ecotoxicity is generated by fungicides applied before harvest. The potential to reduce impacts on freshwater ecosystems is seven orders of magnitude, while impacts on human health can be reduced by two orders of magnitude. Hence, this stresses the importance of a careful pre-selection of active ingredients. In both impact categories, organic production represents the least toxic pest-control method.     

Pesticide Environmental Accounting: a method for assessing the external costs of individual pesticide applications

The Pesticide Environmental Accounting (PEA) tool provides a monetary estimate of environmental and health impacts per hectare-application for any pesticide. The model combines the Environmental Impact Quotient method and a methodology for absolute estimates of external pesticide costs in UK, USA and Germany. For many countries resources are not available for intensive assessments of external pesticide costs. The model converts external costs of a pesticide in the UK, USA and Germany to Mediterranean countries. Economic and policy applications include estimating impacts of pesticide reduction policies or benefits from technologies replacing pesticides, such as sterile insect technique. The system integrates disparate data and approaches into a single logical method. The assumptions in the system provide transparency and consistency but at the cost of some specificity and precision, a reasonable trade-off for a method that provides both comparative estimates of pesticide impacts and area-based assessments of absolute impacts.