Spatiotemporal variation of radon and carbon dioxide concentrations in an underground quarry: coupled processes of natural ventilation, barometric pumping and internal mixing

Radon-222 and carbon dioxide concentrations have been measured during several years at several points in the atmosphere of an underground limestone quarry located at a depth of 18 m in Vincennes, near Paris, France. Both concentrations showed a seasonal cycle. Radon concentration varied from 1200 to 2000 Bq m⁻³ in summer to about 800-1400 Bq m⁻³ in winter, indicating winter ventilation rates varying from 0.6 to 2.5 × 10⁻⁶ s⁻¹. Carbon dioxide concentration varied from 0.9 to 1.0% in summer, to about 0.1-0.3% in winter. Radon concentration can be corrected for natural ventilation using temperature measurements. The obtained model also accounts for the measured seasonal variation of carbon dioxide. After correction, radon concentrations still exhibit significant temporal variation, mostly associated with the variation of atmospheric pressure, with coupling coefficients varying from −7 to −26 Bq m⁻³ hPa⁻¹. This variation can be accounted for using a barometric pumping model, coupled with natural ventilation in winter, and including internal mixing as well. After correction, radon concentrations exhibit residual temporal variation, poorly correlated between different points, with standard deviations varying from 3 to 6%. This study shows that temporal variation of radon concentrations in underground cavities can be understood to a satisfactory level of detail using non-linear and time-dependent modelling. It is important to understand the temporal variation of radon concentrations and the limitations in their modelling to monitor the properties of natural or artificial underground settings, and to be able to assess the existence of new processes, for example associated with the preparatory phases of volcanic eruptions or earthquakes.     

Indoor radon concentrations

The indoor air of 60 residences in and around a Maryland suburb of Washington, DC, was monitored in a pilot study to determine residential radon concentrations. In each residence, a radon grab sample was acquired in the living room, and, if possible, in the basement. Infiltration rates were determined by tracer gas dilution. To help standardize sampling conditions, each home remained closed up for 8 h prior to sampling and during analysis. Over 60% of the residences sampled showed air infiltration rates below 0.6 air changes per hour. Approximately 55% of all surveyed basements and 30% of all surveyed living areas displayed radon concentrations in excess of 4.0 nCi m⁻³. Assuming an equilibrium factor of 0.5, these radon levels may lead to working levels above the annual guidelines suggested by EPA for florida homes build on land reclaimed from phosphate mining.     

The cost effectiveness of radon reduction programmes in domestic housing in England and Wales: The impact of improved radon mapping and housing trends

In the UK, excessive levels of radon gas have been detected in domestic housing. Areas where 1% of existing homes were found to be over the Action Level of 200 Bq · m^− 3 were declared to be Radon Affected Areas. Building Regulations have been introduced which require that, for areas where between 3% and 10% of existing houses are above the Action Level, new homes should be built with basic radon protection using a membrane, and that, where 10% or more of existing homes exceed this level, new homes should be built with full radon protection.Initially these affected areas followed administrative boundaries, known as Counties. However, with increasing numbers of measurements of radon levels in domestic homes recorded in the national database, these areas have been successively refined into smaller units – 5 km grid squares in 1999, down to 1 km grid squares in 2007.One result is the identification of small areas with raised radon levels within regions where previously no problem had been identified. In addition, some parts of areas that were previously considered radon affected are now considered low, or no, risk. Our analysis suggests that the net result of improved mapping is to increase the number of affected houses. Further, the process is more complex for local builders, and inspectors, who need to work out whether radon protection in new homes is appropriate.Our group has assessed the cost-effectiveness of radon remediation programmes, and has applied this analysis to consider the cost-effectiveness of providing radon protection in both new and existing homes. This includes modelling the potential failure rate of membranes, and whether testing radon levels in new homes is appropriate. The analysis concludes that it is more cost effective to provide targeted radon protection in high radon areas, although this introduces more complexity.The paper also considers the trend in housing to a greater proportion of apartments, the regional variations in types of housing and the decreasing average number of occupants in each dwelling, and concludes that data and methods are now available to respond to the health risks of radon at a local level, in keeping with a general initiative to prioritise responses to health and social welfare issues at a more local level.     

Indoor radon levels in Greek schools

Radon and gamma dose rate measurements were performed in 512 schools in 8 of the 13 regions of Greece. The distribution of radon concentration was well described by a lognormal distribution. Most (86%) of the radon concentrations were between 60 and 250 Bq m⁻³ with a most probable value of 135 Bq m⁻³. The arithmetic and geometric means of the radon concentration are 149 Bq m⁻³ and 126 Bq m⁻³ respectively. The maximum measured radon gas concentration was 958 Bq m⁻³. As expected, no correlation between radon gas concentration and indoor gamma dose rate was observed. However, if only mean values for each region are considered, a linear correlation between radon gas concentration and gamma dose rate is apparent. Despite the fact that the results of radon concentration in schools cannot be applied directly for the estimation of radon concentration in homes, the results of the present survey indicate that it is desirable to perform an extended survey of indoor radon in homes for at least one region in Northern Greece.     

Indoor radon levels and influencing factors in houses of Patras,Greece

Measurements of indoor radon concentrations were performed in 28 low-rise houses and 30 apartments in Patras area from December 1996 to November 1997, using nuclear track detectors. The investigation was focused on the effects of season and floor number, as well as on the existence of a basement in low-rise houses on indoor radon levels. It was found that the differences in mean radon concentrations between adjacent seasons, in a number of 61 selected sampling sites distributed in 28 houses, were statistically significant. As expected, a maximum was found in winter and a minimum in summer. The differences in mean radon concentration on different floors of the same houses were also statistically significant and followed a linear decrease from underground to 2nd floor. In addition, indoor radon concentrations in the ground floor were found to be influenced by the existence or not of a basement. The average annual radon concentration was found to be 41 Bq m(-3) for the houses, 28 Bq m(-3) for the apartments and 38 Bq m(-3) for all the dwellings. These values lead to an average effective dose equivalent of 1.1, 0.7 and 0.9 mSv y(-1), respectively. Residents living on the underground in low-rise houses, during winter, where the average effective dose equivalent is 2.1 mSv y(-1), attain the higher risk.     

A survey of radon level in underground buildings in China

From 2003-2004, using solid state nuclear detectors, a survey of the air radon level in 234 underground buildings in 23 cities of China was carried out during spring as well as summer and winter. The annual radon concentrations in these underground buildings range from 14.9 to 2482 Bq m(-3), with an overall mean value of 247 Bqm(-3). When radon concentrations are averaged according to cities, Fuzhou and Baotou have the relatively higher radon levels, which are 714 and 705 Bqm(-3), respectively. Guangzhou and Shanghai have the relatively lower radon levels with 71.1 and 72.6 Bqm(-3). The annual effective dose by exposure to radon received by people working in these cities is concluded to be 1.6 mSv. The geological formation, coating level, decorating materials and ventilation situation all affect the radon concentration in underground buildings. The radon level in underground buildings has the lowest value in winter and the highest value in summer.     

Domestic radon remediation of UK dwellings by Sub-Slab Depressurisation: evidence for a baseline contribution from constructional materials

To quantify the effectiveness of Sub-Slab Depressurisation, widely used in the United Kingdom (U.K.) to mitigate indoor radon gas levels in residential properties, a study was made of radon concentration data collected from a set of 170 homes situated in Radon Affected Areas in Northamptonshire and neighbouring counties, remediated using conventional sump/pump technology. A high incidence of satisfactory remediation outcomes was achieved, with 100% of the houses remediated demonstrating post-remediation radon concentrations below the U.K. domestic Action Level of 200 Bq m(-3), while more than 75% of the sample exhibited radon mitigation factors (defined as the ratio of radon concentrations following and prior to remediation) <0.2. Two systematic trends are identified. Firstly, absolute radon concentration reduction following remediation is directly proportional to initial radon concentration, with a mean reduction factor of 0.96 and a residual component of around 75 Bq m(-3). Secondly, houses with lower initial radon concentrations demonstrate poorer (higher) mitigation factors. These observations support a model in which the total indoor radon concentration within a dwelling can be represented by two principal components, one susceptible to mitigation by sub-slab depressurisation, the other remaining essentially unaffected. The first component can be identified with radon emanating from the subsoil and bedrock geologies, percolating through the foundations of the dwelling as a component of the soil-gas, and potentially capable of being attenuated by sub-slab depressurisation or radon-barrier remediation technologies. The second contribution can be identified with radon emanating from materials used in the construction of the dwelling with a further contribution from the natural background level, and is essentially unaffected by ground-level remediation strategies. Modelling of a multi-component radon dependency using ground-radon attenuation factors derived from the experimental data, in conjunction with typical background and structural-radon levels, yields behaviour in good agreement with the observed dependence of mitigation factor on initial radon concentration.     

Indoor radon concentration in geothermal areas of central Italy

The indoor radon (²²²Rn) activity concentration was measured between January and June in the schools of two geothermal areas in Tuscany, central Italy. One of these areas (the Larderello area) is characterized by a large number of geothermal power plants, covering about 9% of the world’s geothermal power production. In contrast, the other area, Monte Pisano, has not any such facilities. About 250 measurements were made using track etch detectors. Only a slight difference in the concentrations between the two major sampling areas (98 Bq m⁻³ for Larderello area and 43 Bq m⁻³ for Monte Pisano area) was found, and this was related to different geological characteristics of the ground and not the presence of the geothermal plants. The measured radon concentrations were always well below the intervention levels in both areas, and health risks for students and personnel in the examined schools were excluded.     

Some results from the demonstration of indoor radon reduction measures in block basement houses

Active soil ventilation techniques have been tested in 26 block-wall basement houses in eastern Pennsylvania with significantly elevated indoor radon concentrations, generally above 740 Bq/m³, and the results indicate that radon levels can be reduced substantially often below the U.S. Environmental Protection Agency (EPA) guideline of 148 Bq/m³, if effective suction can be drawn on the soil underneath the concrete slabs of these houses. Such effective suction appears achievable when either: 1) the house has a complete loop of drain tile around its footings for water drainage purposes, and suction is drawn on that loop; or 2) a sufficient number of suction pipes can be inserted at the proper locations into the crushed rock or the soil underneath the slab.     

External gamma-ray dose rate and radon concentration in indoor environments covered with Brazilian granites

Health hazard from natural radioactivity in Brazilian granites, covering the walls and floor in a typical dwelling room, was assessed by indirect methods to predict external gamma-ray dose rates and radon concentrations. The gamma-ray dose rate was estimated by a Monte Carlo simulation method and validated by in-situ measurements with a NaI spectrometer. Activity concentrations of ²³²Th, ²²⁶Ra, and ⁴⁰K in an extensive selection of Brazilian commercial granite samples measured by using gamma-ray spectrometry were found to be 4.5-450 Bq kg⁻¹, 4.9-160 Bq kg⁻¹ and 190-2029 Bq kg⁻¹, respectively. The maximum external gamma-ray dose rate from floor and walls covered with the Brazilian granites in the typical dwelling room (5.0 m × 4.0 m area, 2.8 m height) was found to be 120 nGy h⁻¹, which is comparable with the average worldwide exposure to external terrestrial radiation of 80 nGy h⁻¹ due to natural sources, proposed by United Nations Scientific Committee on the Effects of Atomic Radiation. Radon concentrations in the room were also estimated by a simple mass balance equation and exhalation rates calculated from the measured values of ²²⁶Ra concentrations and the material properties. The results showed that the radon concentration in the room ventilated adequately (0.5 h⁻¹) will be lower than 100 Bq m⁻³, value recommended as a reference level by the World Health Organization.     

Dose estimation and radon action level problems due to nanosize radon progeny aerosols in underground manganese ore mine

One of the essential parameters influencing of the dose conversion factor is the ratio of unattached short-lived radon progeny. This may differ from the value identified for indoor conditions when considering special workplaces such as mines. Inevitably, application of the dose conversion factors used in surface workplaces considerably reduces the reliability of dose estimation in the case of mines.This paper surveyed the concentration of radon and its short-lived radon progeny and identified the unattached fraction of short-lived radon progeny. As well equilibrium factor during the month of August was calculated simultaneously at two extraction faces in a manganese ore mine.During working hours the average radon concentrations were 220 Bq m⁻³ and 530 Bq m⁻³ at Faces 1 and 2; the average short-lived progeny concentration was 90 Bq m⁻³ and 190 Bq m⁻³, the average equilibrium factors were 0.46 and 0.36, and the average unattached fractions were 0.21 and 0.17, respectively. The calculated dose conversion factor was between 9 and 27 mSv WLM⁻¹, but higher values could also be possible.     

Indoor radon periodicities and their physical constraints: a study in the Coimbra region (Central Portugal)

Indoor radon activities were measured during a period of 6 months, as well as several physical environmental variables (temperature, pressure, humidity and rainfall). The location was a small room at an administrative building of the University of Coimbra, usually undisturbed by human activities and situated over bedrock of low-uranium Triassic red sandstones. A low average activity of radon was observed (36 Bq m⁻³), however showing a very well marked daily periodicity (10 ± 5 Bq m⁻³), with maximum values occurring more frequently between 9 and 10 a.m. Daily variations are shown to have no relation with earth tides, and their amplitudes exhibit a significant correlation with outdoor temperature; no dependence on barometric pressure was found. Rainfall disturbs the observed daily radon cycles through a strong reduction of their amplitude, but has no effect on the long-term variability of the gas concentration.     

In-field radon measurement in water: a novel approach

This paper presents a novel approach of measuring radon in-water in the field by inserting a MEDUSA gamma-ray detector into a 210 L or 1000 L container. The experimental measurements include investigating the effect of ambient background gamma-rays on in-field radon measurement, calibrating the detector efficiency using several amounts of KCl salt dissolved in tap water, and measuring radon in borehole water. The results showed that there is fairly good agreement between the field and laboratory measurements of radon in water, based on measurements with Marinelli beakers on a HPGe detector. The MDA of the method is 0.5 Bq L⁻¹ radon in-water.     

Monitoring and modelling of indoor radon concentrations in a multi-storey building at Mumbai,India

Radon (Rn(222)) levels in an indoor atmosphere of a multi-storey building at Mumbai have been measured for one year covering all the four seasons. Monitoring was carried out using the time-integrated passive detector technique, using Kodak-115 type Solid State Nuclear Track Detector (SSNTD) films of 2.5x2.5 cm size. Measured indoor radon levels showed a decreasing trend with height with concentration ranging from 41 Bq m(-3) at ground floor level to 15 Bq m(-3) at 19th floor level. Using the dose conversion factors, the inhalation dose due to breathing of radon gas is estimated to be 1.03 mSv y(-1) at the ground floor to 0.38 mSv y(-1) at the 19th floor level. Measured indoor radon concentrations on each floor were compared with the computed values using a mathematical model. The agreement between measured values and calculated values of indoor concentrations at different floors was very good within the limitations of various field parameter values.     

Inhalation dose assessment of indoor radon progeny using biokinetic and dosimetric modeling and its application to Jordanian population

High indoor radon concentrations in Jordan result in internal exposures of the residents due to the inhalation of radon and its short-lived progeny. It is therefore important to quantify the annual effective dose and further the radiation risk to the radon exposure. This study describes the methodology and the biokinetic and dosimetric models used for calculation of the inhalation doses exposed to radon progeny. The regional depositions of aerosol particles in the human respiratory tract were firstly calculated. For the attached progeny, the activity median aerodynamic diameters of 50 nm, 230 nm and 2500 nm were chosen to represent the nucleation, accumulation and coarse modes of the aerosol particles, respectively. For the unattached progeny, the activity median thermodynamic diameter of 1 nm was chosen to represent the free progeny nuclide in the room air. The biokinetic models developed by the International Commission on Radiological Protection (ICRP) were used to calculate the nuclear transformations of radon progeny in the human body, and then the dosimetric model was applied to estimate the organ equivalent doses and the effective doses with the specific effective energies derived from the mathematical anthropomorphic phantoms. The dose conversion coefficient estimated in this study was 15 mSv WLM⁻¹ which was in the range of the values of 6-20 mSv WLM⁻¹ reported by other investigators. Implementing the average indoor radon concentration in Jordan, the annual effective doses were calculated to be 4.1 mSv y⁻¹ and 0.08 mSv y⁻¹ due to the inhalation of radon progeny and radon gas, respectively. The total annual effective dose estimated for Jordanian population was 4.2 mSv y⁻¹. This high annual effective dose calculated by the dosimetric approach using ICRP biokinetic and dosimetric models resulted in an increase of a factor of two in comparison to the value by epidemiological study. This phenomenon was presented by the ICRP in its new published statement on radon.     

An overview of an indoor radon study carried out in dwellings in India and Bangladesh during the last decade using solid state nuclear track detectors

This paper reports on radon concentrations in dwellings from fifty different locations of India. The incorporated data were obtained using the passive solid state nuclear track detector technique. The estimated geometric mean value for India is 67.1 Bq m(-3). Chuadanga in Bangladesh had the lowest observed indoor radon concentration of 27.3 Bq m(-3) and Una in the northern part of India had the highest concentration of 281.5 Bq m(-3). This paper discusses the national geometrical mean value in terms of the national geometric mean values of other countries and also in terms of the geological influence. The estimated indoor radon levels are compared with the indoor radon levels as recommended by the International Commission on Radiation Protection (ICRP). It was observed that there are several locations in India where dwellings have higher indoor radon levels than the ICRP recommended value and requires some sort of intervention from regulating authorities. The mean value for indoor radon level given in the report of UNSCEAR 2000 for India needs to be revised.     

Soil radium, soil gas radon and indoor radon empirical relationships to assist in post-closure impact assessment related to near-surface radioactive waste disposal

Least squares (LS), Theil’s (TS) and weighted total least squares (WTLS) regression analysis methods are used to develop empirical relationships between radium in the ground, radon in soil and radon in dwellings to assist in the post-closure assessment of indoor radon related to near-surface radioactive waste disposal at the Low Level Waste Repository in England. The data sets used are (i) estimated ²²⁶Ra in the <2 mm fraction of topsoils (eRa226) derived from equivalent uranium (eU) from airborne gamma spectrometry data, (ii) eRa226 derived from measurements of uranium in soil geochemical samples, (iii) soil gas radon and (iv) indoor radon data. For models comparing indoor radon and (i) eRa226 derived from airborne eU data and (ii) soil gas radon data, some of the geological groupings have significant slopes. For these groupings there is reasonable agreement in slope and intercept between the three regression analysis methods (LS, TS and WTLS). Relationships between radon in dwellings and radium in the ground or radon in soil differ depending on the characteristics of the underlying geological units, with more permeable units having steeper slopes and higher indoor radon concentrations for a given radium or soil gas radon concentration in the ground. The regression models comparing indoor radon with soil gas radon have intercepts close to 5 Bq m⁻³ whilst the intercepts for those comparing indoor radon with eRa226 from airborne eU vary from about 20 Bq m⁻³ for a moderately permeable geological unit to about 40 Bq m⁻³ for highly permeable limestone, implying unrealistically high contributions to indoor radon from sources other than the ground. An intercept value of 5 Bq m⁻³ is assumed as an appropriate mean value for the UK for sources of indoor radon other than radon from the ground, based on examination of UK data. Comparison with published data used to derive an average indoor radon: soil ²²⁶Ra ratio shows that whereas the published data are generally clustered with no obvious correlation, the data from this study have substantially different relationships depending largely on the permeability of the underlying geology. Models for the relatively impermeable geological units plot parallel to the average indoor radon: soil ²²⁶Ra model but with lower indoor radon: soil ²²⁶Ra ratios, whilst the models for the permeable geological units plot parallel to the average indoor radon: soil ²²⁶Ra model but with higher than average indoor radon: soil ²²⁶Ra ratios.     

Two error components model for measurement error: application to radon in homes

In this paper, a simple model for analysing variability in radon concentrations in homes is tested. The approach used here involves two error components, representing additive and multiplicative errors, together with variation between-houses. We use a Bayesian approach for our analysis and apply this model to two datasets of repeat radon measurements in homes; one based on 3-month long measurements for which the original measurements were close to the current UK Radon Action Level (200 Bq m⁻³), and the other based on 6-month measurement data (from regional and national surveys), for which the original measurements cover a wide range of radon concentrations, down to very low levels. The model with two error components provides a better fit to these datasets than does a model based on solely multiplicative errors.     

Temporal signatures of advective versus diffusive radon transport at a geothermal zone in Central Nepal

Temporal variation of radon-222 concentration was studied at the Syabru-Bensi hot springs, located on the Main Central Thrust zone in Central Nepal. This site is characterized by several carbon dioxide discharges having maximum fluxes larger than 10 kg m⁻² d⁻¹. Radon concentration was monitored with autonomous Barasol™ probes between January 2008 and November 2009 in two small natural cavities with high CO₂ concentration and at six locations in the soil: four points having a high flux, and two background reference points. At the reference points, dominated by radon diffusion, radon concentration was stable from January to May, with mean values of 22 ± 6.9 and 37 ± 5.5 kBq m⁻³, but was affected by a large increase, of about a factor of 2 and 1.6, respectively, during the monsoon season from June to September. At the points dominated by CO₂ advection, by contrast, radon concentration showed higher mean values 39.0 ± 2.6 to 78 ± 1.4 kBq m⁻³, remarkably stable throughout the year with small long-term variation, including a possible modulation of period around 6 months. A significant difference between the diffusion dominated reference points and the advection-dominated points also emerged when studying the diurnal S₁ and semi-diurnal S₂ periodic components. At the advection-dominated points, radon concentration did not exhibit S₁ or S₂ components. At the reference points, however, the S₂ component, associated with barometric tide, could be identified during the dry season, but only when the probe was installed at shallow depth. The S₁ component, associated with thermal and possibly barometric diurnal forcing, was systematically observed, especially during monsoon season. The remarkable short-term and long-term temporal stability of the radon concentration at the advection-dominated points, which suggests a strong pressure source at depth, may be an important asset to detect possible temporal variations associated with the seismic cycle.     

An approach to the subslab depressurization remedial action in a high Rn concentration dwelling

Galicia (NW Spain) is a radon-prone area in the Iberian Peninsula. Measurements were carried out at a rural dwelling, with an annual average of radon concentration over 4000 Bq m⁻³ and a maximum of 9000 Bq m⁻³, found during a radon screening campaign held in the Autonomous Community of Galicia. We performed a detailed study to identify the main contamination source and the behaviour of the radon concentration, in which a linear dependence with temperature was verified, once corrected for relative humidity. We used different passive methods (charcoal canisters and two types of etched track detectors) as well as a radon concentration monitor that provided continuous measurement. Subsequent to this characterization, and in order to reduce the high radon concentration, a remedial action was developed using different passive and forced ventilation methods. A modified subslab depressurization technique was found to be the most effective remedy, providing a radon concentration reduction of around 96%. This method also has the advantages of being inexpensive and reliable over time.