Use of constructed wetland for the removal of heavy metals from industrial wastewater

This study was conducted to investigate the effectiveness of a continuous free surface flow wetland for removal of heavy metals from industrial wastewater, in Gadoon Amazai Industrial Estate (GAIE), Swabi, Pakistan. Industrial wastewater samples were collected from the in-let, out-let and all cells of the constructed wetland (CW) and analyzed for heavy metals such as lead (Pb), cadmium (Cd), iron (Fe), nickel (Ni), chromium (Cr) and copper (Cu) using standard methods. Similarly, samples of aquatic macrophytes and sediments were also analyzed for selected heavy metals. Results indicate that the removal efficiencies of the CW for Pb, Cd, Fe, Ni, Cr, and Cu were 50%, 91.9%, 74.1%, 40.9%, 89%, and 48.3%, respectively. Furthermore, the performance of the CW was efficient enough to remove the heavy metals, particularly Cd, Fe, and Cu, from the industrial wastewater fed to it. However, it is suggested that the metal removal efficiency of the CW can be further enhanced by using proper management of vegetation and area expansion of the present CW.     

Potential health hazard of drinking water in restaurants and tea stalls

Potable and equitable drinking water (DW) is a fundamental human right and essential for human health. This study is conducted to assess the groundwater and jar water quality of the roadside restaurants and tea stalls used for drinking by the local people around the Gazipur City area in Bangladesh. Water samples from 173 restaurants and tea stalls are collected. The physico-chemical and biological parameters are analyzed according to the guidelines and standards. The results illustrate that the color, EC, and Mn of 41%, 80%, and 62% of the samples, respectively, exceed the WHO and Environmental Conservation Rules (ECR) standards. In addition, E. coli and total coliform exceeding the threshold standards are found in 47% and 64% of the water samples, respectively. The contamination of DW by fecal coliforms is confirmed and supported by prior studies, which indicates that the DW supplied in restaurants and tea stalls are unsafe because of the possible presence of pathogens. These may cause potential health hazards to consumers from various water-borne diseases. Poor sanitation, unhygienic practices, and improper disposal of wastewater are responsible for the microbial contamination of DW. So, the authorities in charge of these places should take the right regulatory steps, such as regular sanitation inspections, DW quality monitoring, hand-washing practices, and better sanitation in these places.     

化学法处理电镀废水的自动化控制应用

采用化学法自动控制处理含铬和含镍电镀废水,选择合适的化学药剂和pH、ORP控制参数,连续式处理电镀废水.运行结果表明:该工艺简单、处理效果良好、运行稳定、可操作性好、运行成本适中、能很好的适应水质的波动,处理后的水质完全符合排放标准.     

Cost-effectiveness of two operational models at industrial wastewater treatment plants in China: A case study in Shengze town,Suzhou City

The widespread illegal discharge of industrial wastewater in China has posed significant challenges to the effective management of industrial wastewater treatment plants (IWTPs) and caused or exacerbated critical social issues such as trans-boundary environmental pollution. This study examines two operational strategies, decentralized model and an innovative integrated model, that have been used in the industrial town of Shengze (located in Suzhou City) over the past two decades at IWTPs handling wastewater from the city’s dyeing industry. Our cost-effectiveness analysis shows that, although the operational cost of IWTPs under the integrated model is higher than under the original decentralized model, the integrated model has significantly improved IWTP performance and effectively reduced illegal discharge of industrial wastewater. As a result, the number of reported incidents of unacceptable pollution in local receiving water bodies had declined from 13 in 2000–1 in 2008. Key factors contributing to the success of the innovative integrated model are strong support from municipal and provincial leaders, mandatory ownership transfer of IWTPs to a centralized management body, strong financial incentives for proper plant management, and geographically-clustered IWTPs.     

Wastewater reuse and predicted ecological risk posed by contaminant mixtures in Potomac River watershed streams

A wastewater model was applied to the Potomac River watershed to provide (i) a means to identify streams with a high likelihood of carrying elevated effluent-derived contaminants and (ii) risk assessments to aquatic life and drinking water. The model linked effluent discharges along stream networks, accumulated wastewater, and predicted contaminant loads of municipal wastewater constituents while accounting for instream dilution and attenuation. Simulations using 2016 data suggested that nearly 30% (8281 km) of streams were wastewater impacted. Low- to medium-order streams had the largest range of accumulated wastewater (ACCWW%) values. ACCWW% exceeded a 1% threshold at >39% of drinking-water intakes (varied by temporal condition). Risk assessments of municipal wastewater-contaminant mixtures indicated that 22% (1479 km) of streams impacted by municipal wastewater (5.5% of all reaches modeled) may pose high risk to aquatic organisms under mean-annual conditions, with fish more susceptible to chronic-exposure effects relative to other taxa. Risk varied temporally and by stream order, with the greatest risk occurring in the summer in small streams. These findings suggest that wastewater may be an important factor contributing to environmental degradation in the Potomac River watershed.     

Forecast optimal fluoride concentration data in drinking water according to the ambient temperature in Golestan,Iran

Controlling fluoride concentrations in drinking water at optimal levels could be effective in preventing certain negative health effects in humans. This study investigated optimal fluoride concentrations in potable water in Golestan province, according the ambient temperatures in the province. The study used data on fluoride concentrations in drinking water supplied by the Water and Wastewater Company of Golestan Province. The annual mean maximum temperatures were extracted from a website that recorded daily ambient temperature. The optimal value of fluoride in drinking water for each county of Golestan province was calculated by the Galgan and Vermillion formula. The results show that all of the counties should contain fluoride concentrations ranging from 0.73 to 0.766 milligrams per liter (mg/L) according to the calculation formula, while fluoride concentrations were instead reported to range between 0.23 and 0.53 mg/L by the Water and Wastewater company. In addition, according to World Health Organization (WHO) recommendations, the concentrations of fluoride in potable in all of the cities in Golestan province fall below the WHO standard. In conclusion, we suggest that the fluoride concentrations in Golestan province's drinking water should be taken into account by the appropriate authorities and that optimal fluoride concentrations in drinking water according to ambient temperatures be set to avoiding negative health impacts.     

西洋河流域污染的特征研究

随着卢龙县工业及畜牧业的发展及人口的增加,西洋河水域污染日益严重,水质功能已达到Ⅳ类,生态环境遭到严重的破坏。西洋河流域地表污染源主要有工业企业废水、畜禽养殖污水、甘薯淀粉加工废水和农业生产废水等。本文分析了西洋河流域地表水质污染的现状,在严格排查污染源的基础上对其水质特征进行了科学分析。     

A comparative analysis of methods to represent uncertainty in estimating the cost of constructing wastewater treatment plants

Prediction of construction cost of wastewater treatment facilities could be influential for the economic feasibility of various levels of water pollution control programs. However, construction cost estimation is difficult to precisely evaluate in an uncertain environment and measured quantities are always burdened with different types of cost structures. Therefore, an understanding of the previous development of wastewater treatment plants and of the related construction cost structures of those facilities becomes essential for dealing with an effective regional water pollution control program. But deviations between the observed values and the estimated values are supposed to be due to measurement errors only in the conventional regression models. The inherent uncertainties of the underlying cost structure, where the human estimation is influential, are rarely explored. This paper is designed to recast a well-known problem of construction cost estimation for both domestic and industrial wastewater treatment plants via a comparative framework. Comparisons were made for three technologies of regression analyses, including the conventional least squares regression method, the fuzzy linear regression method, and the newly derived fuzzy goal regression method. The case study, incorporating a complete database with 48 domestic wastewater treatment plants and 29 industrial wastewater treatment plants being collected in Taiwan, implements such a cost estimation procedure in an uncertain environment. Given that the fuzzy structure in regression estimation may account for the inherent human complexity in cost estimation, the fuzzy goal regression method does exhibit more robust results in terms of some criteria. Moderate economy of scale exists in constructing both the domestic and industrial wastewater treatment plants. Findings indicate that the optimal size of a domestic wastewater treatment plant is approximately equivalent to 15,000 m3/day (CMD) and higher in Taiwan. Yet the optimal size of an industrial wastewater treatment plant could fall in between 6000 CMD and 20,000 CMD.     

Present situation of wastewater treatment in the Iranian industrial estates: Recycle and reuse as a solution for achieving goals of eco-industrial parks

Iran is located in arid and semi-arid region, which means water resource management is a strategic issue for this country. Water scarcity is one of the most critical concerns of industrial estates in Iran. For this reason, recycling and reusing of treated wastewater is the most practical solution for compensating of water shortage in industrial estates. Currently, only 20% of total treated wastewater is used for irrigation and almost 0.81% is consumed for industrial purpose. This study presents an overview on the wastewater management at the Iranian industrial estates for the purpose of achieving the goal of eco-industrial parks by describing the present situation and discussing the experiences of wastewater reuse systems for irrigation and industrial purposes. The aims of this study was to provide an overview of the wastewater management at the industrial estates in Iran towards achieving eco-industrial parks by describing present states and the outcome of wastewater consumption for irrigation and industrial purposes.     

University of Benin water supply system: Microbiological and physico-chemical assessments

The microbiological and physico-chemical characteristics of the drinking water supplied by the Central Borehole at the University of Benin, Ugbowo Campus were investigated. The investigation entailed assessment of the pH, turbidity, total suspended solids, total dissolved solids, dissolved oxygen, temperature, salinity, conductivity, nitrate, nitrite, phosphate, sulphate, chloride, N-nitroso compounds, cadmium, chromium, nickel, lead, zinc, manganese, iron, coliform count, BOD₅ and COD of the water at the Central Borehole and at ten residential quarters. The assessment indicated that the water was fit for drinking and other domestic applications. Results were also compared with WHO, EU and Nigeria FEPA standards. The results showed that the pH values of the water (5.01–5.86) and total coliform count (1–2/100 ml) expressed as MPN were outside the limits set by the WHO, EU and FEPA. The data also showed that the other water quality parameters assessed were within WHO, EU and FEPA permissible limits. The results of ANOVA showed that significant changes occurred during distribution.     

TiO2光催化氧化的研究进展

概述了TiO2光催化氧化降解水中污染物的原理及TiO2光催化剂的制备，提出了增强其活性的途径。TiO2光催化氧化可应用于印染、农药、造纸等工业废水及饮用水处理中，研制高效的负栽型纳米TiO2光催化剂、解决太阳能利用问题、开发多功能光催化反应器是今后TiO2光催化氧化的发展趋势。     

Water quality indices appraisal and health risk assessment of nitrate,mercury and lead in water distribution network: A case study of Robat Karim in Tehran,Iran

Groundwater is a basic source of drinking water supply for urban and rural areas. This is especially the case for communities located in arid and semi-arid regions that rely on groundwater for drinking purposes. The present study set out to assess the potential health impacts of water impurities and to investigate the qualitative status of drinking water in Robat Karim rural areas, located in southwest Tehran, Iran. A total of 66 samples were collected from the water distribution network of 11 villages (33 sampling points, on two occasions) during September 2020 and were tested in terms of the most common quality parameters such as pH, mercury (Hg), lead (Pb), copper (Cu), zinc (Zn), chloride (Cl^–), chlorate (ClO₃^–), nitrite (NO₂^–), nitrate (NO₃^–), and flouride (F^–). Multiple methods and indexes including water quality index (WQI), hazard quotient (HQ), and hazard index (HI), were worked out to assess the quality of water and health risk assessment of NO₃^– Pb²⁺ and Hg²⁺. The results revealed that 33% and 90% of sampling sites have significantly high nitrate and total hardness (TH) concentrations, exceeding the maximum permissible limits set by World Health Organization (WHO; 50 and 200 mg/L, respectively). Furthermore, five sampling points exhibited poor WQIs mainly related to NO₃^– and TH. HQ values higher than 1 for nitrate were noticed in most sampling locations. Except for one sampling point, the HQ obtained for Pb²⁺ and Hg²⁺ were below 1 indicating no obvious health hazard. This study represents that children and infants are at higher risk of chronic toxicity by excess NO₃^– intake. The health hazard that is yet imposed on the community by NO₃^– necessitates regular monitoring of drinking water, the use of advanced technologies to purify water or otherwise alternative resources should be proposed.     

基于EBM模型的长江经济带工业用水效率时空差异及影响因素分析

工业化进程的加快使得工业水资源需求不断增加,工业废水排放量也越来越大,如何提高工业用水效率从而缓解水资源压力成为日益严峻的问题。本文选取工业用水量、工业就业人数、工业固定资本和工业废水治理费用作为投入指标,以工业增加值与工业废水排放量作为期望与非期望产出指标。首先利用EBM模型计算长江经济带2008—2017年工业用水效率,其次利用泰尔指数来分析工业用水效率的区域差距,最后利用面板Tobit模型来分析影响不同地区工业用水效率的驱动因素。结果显示,近年来长江经济带的工业用水效率呈波动下降趋势,不同地区效率差异明显;经济发展水平、工业化程度、技术水平、水资源禀赋和政府环境管制力度对长江经济带的工业用水效率都有一定影响,但存在地区差异。     

Public acceptance potential for reuse applications in Turkey

The water reuse applications are becoming increasingly important in Turkey due to fresh water scarcity problems. However, the success of reuse practices depends on the public's acceptance. Therefore, this study was designed to determine the public awareness, and the potential for acceptance, of reuse applications in Turkey by way of a survey carried out for this purpose. 500 questionnaires were sent to different regions of Turkey and 375 of them were returned. The study indicated that both women and men have concerns about usage of wastewater, especially regarding the use of treated wastewater as drinking water. Results also showed that the area of greatest concern among the public is the health risks associated with recycled water. Respondents of both genders felt that treated wastewater reuse for applications not involving close personal contact was acceptable, due to reduced health risk concerns. On the other hand, the cost of reclamation is another major public concern.     

Veterinary drugs in groundwater in a dairy region of central Argentina and risk assessment for human health

Veterinary drugs used in dairy production are potential contaminants of surface or groundwater sources, being able to affect human and environmental health. It is known that chronic exposure to antibiotics in low concentrations present in water can generate microbial resistance. This study aimed to evaluate the presence of veterinary drugs in 53 groundwater samples used for animal and human consumption, collected in dairy milking parlors, in an important milk-producing area of central Argentina, and to assess the risk to human health when they are used as drinking water. In 75% of the total samples analyzed, at least one veterinary drug was detected. The most frequently found drugs in water samples were the antibiotics tetracycline in 58.5% and oxytetracycline in 56.6%, and an anti-inflammatory, flunixin in 39.6%. In the water samples, the tetracycline and oxytetracycline concentrations were between 0.1 and 5.3 μg/L and flunixin concentrations were between 0.01 and 2.1 μg/L. The frequency of appearance and the concentration levels of the substances found in the water samples were evaluated according to the productivity, size, and production system (confined or pasture) of the dairy farms. Higher concentrations and proportions of water samples containing antibiotics were observed when the number of animals per dairy farm was >182 and when the productivity was high (>25 liters per animal per day). In the case of flunixin, the percentage of detection was similar in all evaluated categories. The risk assessment for children and adults, considering the intake of drinking water containing residues of these drugs, did not indicate a significant health risk. It would be advisable to evaluate other sources of drinking water, both surface and underground, in other regions of the country, to provide data to assess the impact of these substances and the other contaminants on environmental and human health.     

Relative cancer risks of chemical contaminants in the great lakes

Anyone who drinks water or eats fish from the Great Lakes consumes potentially carcinogenic chemicals. In choosing how to respond to such pollution, it is important to put the risks these contaminants pose in perspective. Based on recent measurements of carcinogens in Great Lakes fish and water, calculations of lifetime risks of cancer indicate that consumers of sport fish face cancer risks from Great Lakes contaminants that are several orders of magnitude higher than the risks posed by drinking Great Lakes water. But drinking urban groundwater and breathing urban air may be as hazardous as frequent consumption of sport fish from the Great Lakes. Making such comparisons is difficult because of variation in types and quality of information available and in the methods for estimating risk. Much uncertainty pervades the risk assessment process in such areas as estimating carcinogenic potency and human exposure to contaminants. If risk assessment is to be made more useful, it is important to quantify this uncertainty.     

高铁酸盐在水和废水处理中的应用进展

本文综述了高铁酸盐用于饮用水的消毒、杀菌、除藻，有机废水的氧化混凝，恶臭物质的氧化去除，重金属离子及放射性废水的混凝沉淀，以及色度浊度的去除等领域的最新进展。并对今后的研究进行了展望。     

Elemental contaminants in groundwater: A study of trace metals from residential area in the vicinity of an industrial area in Lagos, Nigeria

Groundwater (well water) from a residential area within the vicinity of an industrial estate in Lagos, Nigeria were sampled and analysed by Flame Atomic Absorption Spectroscopy for their heavy metals content. This was with a view of assessing the quality of the water, which was being used for domestic activities, especially, drinking usually without treatment. Total trace metal determination by mineral acid digestion of water samples was applied. This method proved to be better than an extractive concentration technique in the quality assurance protocols with the recovery range being 90.7 ± 0.006–97.6 ± 0.003%. Mean concentration of trace metals in water samples ranged from Fe: 0.05–0.47 mg l⁻¹; Al: 0.1–1.54 mg l⁻¹; Cu: 0.14–1.39 mg l⁻¹; Zn: 0.04–0.43 mg l⁻¹; Cd: trace–0.02 mg l⁻¹; Pb: trace–0.03 mg l⁻¹, Mn: 0.01–0.18 mg l⁻¹ and Ni: 0.02–0.11 mg l⁻¹. Physical parameters of water samples examined were within the drinking water safety limits except for conductivity. Results generally indicate the presence of heavy metal constituents in groundwater samples. Detection of metals such as cadmium and lead which have serious health implications above WHO and USEPA limits in drinking water gives cause for concern.     

Determination of arsenic levels in the water resources of Aksaray Province, Turkey

Arsenic levels were determined in 62 stations utilized as drinking and potable water resources by local community for Turkey's Aksaray Province (4589 km(2); 980 m above sea level). The samplings were implemented every two months for 1 year. The arsenic values were found to be ranging between 10 and 50 μg/L in 22 points and were found to be >50 μg/L in 5 stations, according to the mean value of the 6 samples. WHO and the Turkish Standards have permitted an arsenic concentration of 10 μg/L in drinking waters. The multivariate statistical technique, cluster analysis (CA), followed by principal component analysis (PCA) were applied to the data on 17 water quality parameters in 47 stations that are used for drinking and other domestic resources. Two significant sampling locations were detected based on the similarity of their water quality. The chemical correlations were observed in the two sub-sampling locations by Principal Component Analysis.