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1.
以锐钛矿TiO2(P25)为载体采用原位生长法负载锰氧化物制备了Mn/TiO2催化剂,再以等体积浸渍-煅烧法对该催化剂掺杂氧化铈制备Ce(x)Mn/TiO2-y催化剂用以烟气低温SCR脱硝.在固定锰负载量(质量分数为8%)的基础上,考察了铈掺杂量(铈锰摩尔比)、煅烧温度对催化剂SCR脱硝性能的影响.采用TEM、BET、XRD和XPS等手段表征了催化剂的理化结构特性.结果发现,当Ce/Mn的摩尔比例为1.0,煅烧温度为300℃时,Ce(1.0)Mn/TiO2-300催化剂在150—300℃温度范围内、10500—27000 h-1的空速范围内,能够保持90%以上的NO转化率.理化性能分析结果表明,煅烧温度对催化剂的微观形貌影响显著,随着煅烧温度的升高,Ce(1.0)Mn/TiO2-500催化剂活性物种颗粒集聚明显、比表面积降低,且锰氧化物价态分布偏向于低价态;铈的掺杂有助于Ce(1.0)Mn/TiO2-300催化剂活性物种在载体表面的均匀分散,可以促进产生更多的Mn4+物种和更多的吸附氧,有利于催化剂低温SCR脱硝性能的提升. 相似文献
2.
Jessica A. Ericson Miles D. Lamare Simon A. Morley Mike F. Barker 《Marine Biology》2010,157(12):2689-2702
Ocean acidification, or the lowering of seawater pH, is caused by sequestration of atmospheric CO2 into the oceans. This study investigated the effects of present-day pH 8.0, predicted ocean surface pH for the years 2100
and 2300 (pH 7.7 and pH 7.3, respectively) and an extreme pH (pH 7.0) on fertilisation and embryogenesis in the Antarctic
nemertean worm Parborlasia corrugatus and sea urchin Sterechinus neumayeri. Fertilisation success was not affected by pH in P. corrugatus across a range of sperm concentrations. Fertilisation success in S. neumayeri declined significantly in pH 7.0 and 7.3 seawater, but only at a low sperm concentration. Seawater pH had no effect on the
rate of egg cleavage in S. neumayeri, or the proportion of abnormal embryos 1-day post-fertilisation. P. corrugatus embryogenesis was also relatively robust to pH changes, with a significant effect detected only when the seawater pH was
decreased to 7.0. While fertilisation and early cell division were relatively robust, later development through to the gastrula
was sensitive to pH. In S. neumayeri, an effect of pH on development was evident by the gastrula stage, while there were significantly more abnormal P. corrugatus embryos in pH 7.0 up to the blastula stage, and in pH 7.0 and pH 7.3 at the coeloblastula stage. Our results are similar
to the observations on other marine invertebrate species where fertilisation and early embryonic development are generally
robust to lowered seawater pH, while the older coeloblastula and gastrula stages are more responsive. We also found no evidence
to suggest that Antarctic species are more adversely affected by lower seawater pH compared with the findings for non-Antarctic
counterparts. We conclude that in the two species we examined, near-future decreases in pH (decreases of ≈0.3–0.5 pH units)
may not have a significant effect on fertilisation and early embryogenesis, while predicted longer term decreases (decreases
of ≈0.7–0.77 pH units) could reduce fertilisation success in S. neumayeri if sperm concentrations are low and may increase abnormalities in P. corrugatus during later embryogenesis. 相似文献
3.
Juvenile red sea urchins, Strongylocentrotus franciscanus, aggregate under adult conspecifics, whereas sympatric juvenile green sea urchins, Strongylocentrotus droebachiensis, are typically more solitary and dispersed. Neither the potential advantage of juvenile sheltering nor the differences in
post-settlement behavior between the two species has been demonstrated experimentally, but may be related to protection from
predators and/or hydrodynamics. In predation experiments, juvenile vulnerability differed in the two species as the seastar
Pycnopodia helianthoides consistently chose juvenile S. franciscanus over S. droebachiensis (100% vs. 0%). When associated with adults, juvenile mortality decreased dramatically in S. franciscanus (90% alone vs. 5% with adults), but very little in S. droebachiensis (85% vs. 75%). Not surprisingly, juvenile behavioral responses in the two species reflect this difference in vulnerability.
Juvenile S. franciscanus sheltered under adults when predation risk was high, but not when risk was low (44% vs. 13%), whereas sheltering in S. droebachiensis was infrequent and not related to predation risk (7% for high risk versus 5% for low risk). From a hydrodynamic perspective,
the presence of an adult led to the creation of a hydrodynamic refuge for juveniles, where average water velocities were reduced
by > 60% around the adult urchin. Again, striking differences in sheltering rate were apparent in S. franciscanus (52% vs. 13% for high flow and low flow, respectively), but not S. droebachiensis (5% for high flow versus 4% for low flow). Sheltering behavior was also species-specific as juveniles did not shelter at
high rates under adults of the opposite species (≤ 16%). A field survey confirmed these finding in that juvenile S. franciscanus abundance was associated with both adults and water motion (R
2 = 0.80, P = 0.008, best-subsets regression). These results suggest that sheltering confers juvenile S. franciscanus with a degree of protection from predators and water motion, and that species-specific differences in this post-settlement
behavior may be related to the differences in the protection afforded by adults. 相似文献
4.
The determination of reproductive status and the reconstruction of individual reproductive histories are central to many ecological
studies. In cetaceans, it has been assumed that ovarian scars accumulate with age and provide a lifetime record of female
reproductive history. If ovarian scars persist, the number of scars should increase with age after puberty. To test this,
we examined age, reproductive status and ovarian scars from 187 short-beaked common dolphins (Delphinus delphis) from the eastern North Atlantic. The number of Corpus Albicans (CA) present in ovaries did not increase with age after age
at sexual maturity (ASM), suggesting that ovarian scars are not persistent and that their number at any one time would be
a function of rates of ovulation and healing, the latter being defined here as the resorption or disintegration of CA tissue.
Since female mammals stop ovulating when pregnant, inferences about healing rates could be made by using pregnant females.
Pregnant females had ca. 40% fewer scars than non-pregnant females. This suggests that most CAs would heal quickly, with a
half-life of less than 1 year, although larger scars may persist longer. Therefore, counting CAs would have limited potential
for reconstructing individual reproductive lifetime histories in the common dolphin. A reassessment of the use of ovarian
scars to reconstruct individual life reproductive histories in cetaceans is suggested. 相似文献
5.
Sclerocrangon boreas is uncommon among marine coastal carideans in having a non-dispersing, abbreviated (2-stage) larval phase. We investigated
the implications of this strategy in terms of fecundity, offspring provisioning and brood care in S. boreas from the St. Lawrence Gulf and Estuary in 2009–2010. Fecundity scaled positively to female body size but was low due to the
production of large, lipid-rich eggs. Offspring size at all stages of development was positively related to female size. Larval
traits and lipid dynamics indicate obligatory lecithotrophic development from hatching to juvenile. The larva becomes a juvenile
on the mother and remains associated with her for sometime after. The co-occurrence of early egg stages among many juveniles
in some clutches raises the possibility that maternal care of juveniles includes the provisioning of trophic eggs or eggs
reclaimed from other females. 相似文献
6.
通过2010—2011年的监测建立了桂林盘龙洞坡地和洼地不同深度土壤CO2体积分数的季节性变化。监测土壤CO2体积分数空间上变化为:坡地80 cm>50 cm>30 cm;洼地80 cm>100 cm>50 cm>30 cm。监测土壤CO2体积分数时间上变化为2010年7月和2011年6月未CO2体积分数达到最高值,2010到2011年冬季为土壤CO2达到最低值。由于受到大气降水量急剧减少的影响2011年土壤CO2体积分数整体比2010年低。显示大气降水量也是影响土壤CO2体积分数的重要环境因素。为我国固碳减排科学的选择时间和空间提供有力的依据。 相似文献
7.
American black bears frequently abandon their home ranges in late summer and move to feeding areas to fatten themselves for
hibernation. We examined seasonal movements of 206 radio-collared bears in north-central Minnesota during 1981–1990. We exploited
the variability in this long-term data set to test tradeoffs for animals leaving their home range. Late summer movements were
common for both sexes and all ages (39% of females, 44% of males), but were variable from year-to-year in prevalence, timing,
and destination. Bears typically left their summer home ranges in August and returned ~6 weeks later in September or October.
Most traveled southward, where acorns were more plentiful (median = 10 km for females, 26 km for males; maximum = 168 km).
These facultative migrations were most common when rich resources were available outside home ranges. Bears were least apt
to leave when foods were scarce in their home range, possibly sensing a risk of migrating during a widespread food failure.
Among females, those whose body mass was close to a reproductive threshold were most prone to migrate. Migrating bears were
less likely to be killed by hunters, suggesting that they were especially vigilant. 相似文献
8.
Autumn-spawned North Sea herring larvae (Clupea harengus L.) were released in two outdoor mesocosms of 2500 m3 (A) and 4000 m3 (B). The mesocosms were monitored for temperature, salinity, oxygen, chlorophyll a, zooplankton and herring larvae abundance. The density of suitable prey for first feeding larvae (mainly copepod nauplii) was initially low in Mesocosm A (<0.11-1) compared to in Mesocosm B (>11-1). Half-way through the experiment the situation was reversed, with higher densities of prey in Mesocosm A (>31-1) as compared to Mesocosm B (11-1). The average temperature declined steadily in both mesocosms from 18°C at release to 11–12°C by the end of the experiment 60 d later. The RNA:DNA values of individual herring larvae were related to protein growth rates and temperature adjusted according to Buckley (1984). A corresponding DNA growth index (Gdi) was given as: Gdi=0.68 TEMP+3.05 RNA:DNA-9.92. The RNA:DNA based growth indices were significantly correlated with other somatic growth estimates. The average estimated protein growth rate in the two mesocosms followed the same temporal pattern as the somatic growth rate, but with a lag of 2 d or more. Residual analysis of the regression of ln RNA versus ln DNA also showed the same temporal pattern as the RNA:DNA ratios, but the shift in condition as estimated by this method occurred more in synchrony with the other somatic growth measures. Larvae in Mesocosm A had RNA:DNA values similar to the starvation control kept in the laboratory the first days after release, confirming that larvae in Mesocosm A initially were in poor nutritional condition. On the other hand, the majority of the herring from Mesocosm B were characterised as starving or in poor nutritional condition towards the end of the experiment. The assessment of growth and nutritional condition were in accordance with independent survival estimates which suggested that the majority of the total mortality occurred during the first 15 d in Mesocosm A and there-after in Mesocosm B. 相似文献
9.
Adults of the sea urchin Arachnoides placenta (L.) were induced to spawn, and eggs were fertilized at 28°C in September 1989. After 5 min, eggs were transferred to 28, 31, 34, or 37°C and reared to metamorphosis. Embryos were observed at 20-min intervals during the first 2 h; larvae were observed daily. The cleavage was higher at higher temperatures. Embryos reared at 28°C were still at the 4th cleavage (16-cell stage) after 100 min, while those at 34°C had reached the 5th cleavage (32-cell stage). All embryos reared at 37°C died on the second day. Incidence of abnormality was 20 to 30% at 28 and 31°C, 48% at 34°C, and 77% at 37°C. The 8-arm stage was reached after 4 d at 28°C, 3 d at 31°C and 2 d at 34°C. Larvae displayed decreasing body length and arm length with increasing temperature. Larvae at 31°C have relatively long arms, as a result of a decrease in body length, not because of increased arm length. Incidence of metamorphosis was 43.9±1.7% (mean/plusmn;SD) at 28°C, 24.5±1.9% at 31°C, and 5.3% at 34°C. The size of metamorphosed juveniles was significantly larger at 28°C than at 31 and 34°C. Temperatures of 31°C negatively affect larvae and juveniles of the sand dollar. 相似文献
10.
This study was designed to assess the contribution of moulting and eggs to production of the euphausiid Nyctiphanes australis G. O. Sars. For this purpose, live specimens were collected from Storm Bay, south-eastern Tasmania, between August and December 1981, while preserved samples, collected between February 1980 and February 1981, were also examined. The intermoult period of N. australis increased exponentially with increase in body length and weight. Larvae moulted approximately every 2.5 to 3 d and adults every 4 to 5 d at 15°C. A decrease in temperature from 15° to 10°C resulted in the intermoult period almost doubling. The mean weight of exuviae produced represented nearly 6% of the body dry weight of the individual. Continuous maturation of ova was observed, with an individual female capable of releasing a total of 1 100 eggs in a lifetime. These are deposited as a series of batches into a pair of external ovisacs every 30 d. The size of the batch of eggs was dependent on the size of the female. Moulting of euphausiids forms a significant contribution of organic matter to detrital food webs. A value of 42.01 mg m-3 yr-1 was obtained for the production of exuviae. Egg production was calculated to be between 1.41 and 4.22 mg m-3 yr-1. Production and mean annual biomass of N. australis was previously calculated as 78.29 mg m-3 yr-1 and 5.39 mg m-3, respectively. Thus, the total production integrated for the whole of Storm Bay was 125 mg m-3 yr-1 or 2 309 tonnes dry wt yr-1, representing an overall P:B ratio of 23.1. 相似文献
11.
Summary. Chemical structures of 27 ellagitannins were systemically compared in respect of their in vitro oxidative activity at high pH found e.g. in lepidopteran insects. The analysis revealed over six-fold differences in the
oxidative activities of individual ellagitannins which could be explained by the chemical divergences of the ellagitannins.
These findings allowed the formulation of a simple equation that can be used to estimate the oxidative activities of other
ellagitannins with known structures. The results suggest that, in future studies of plant-herbivore interactions, ellagitannins
should be (1) taken into account as possible oxidative stress -based defences of plants against herbivores, (2) chemically
characterized from the study plants, and (3) quantified individually, not as chemically ill-defined group. These actions together
with the utilization of the created equation would allow the clarification of the role of ellagitannins in plant-herbivore
interactions as natural pro-oxidants. 相似文献
12.
Fuji Jian Digvir S. Jayas Noel D.G. White Paul G. Fields 《Ecological modelling》2007,200(3-4):412-420
A time-varying distributed-delay model simulating effects of multifactors was developed. Prediction of the ageing rate and survival distribution of adults of the rusty grain beetle, Cryptolestes ferrugineus (Stephens) (Coleoptera: Laemophloeidae) in various environments found in wheat-filled granaries was conducted as an example to illustrate the application of this developed model. Published adult mortalities, determined at different temperatures, relative humidities, and food sources, were directly used to find the average ageing rate and family of cumulative function of adult mortality. The developed model could predict the adult survival rate at constant or transient temperatures with different relative humidities. This model could also simulate the effect of adult acclimation to their environment when they experience temperature and moisture fluctuations inside granaries. To validate the developed model, the simulation results were compared with available experimental data from the literature. There was no difference between predicted and measured mortalities in two granaries in which the mortalities were determined in a 4-month experiment. 相似文献
13.
二氧化硫(Sulfur dioxide,SO2)和多环芳烃(Polycyclic aromatic hydrocarbons,PAHs)是山西工矿区同时发现的两种典型环境污染物,对区域土壤环境的影响极大.本文以山西工矿区生黄土为供试土壤,以玉米种子为供试作物,采用室内培养皿育苗试验,研究了不同浓度的SO2(0、10、100、500、1 000 mg kg-1)与PAHs(0、1、10、50、100 mgkg-1)单一及复合污染对玉米种子的萌发率、苗期株高、根长和总生物量的影响,以表征SO2与PAHs复合污染的生态毒性.结果表明,与对照相比,SO2单一污染对玉米种子萌发起到促进作用,对玉米苗期株高、根伸长及早期总生物量则是低浓度(10-100 mg kg-1)促进生长,高浓度(500-1 000 mg kg-1)抑制生长;PAHs单一污染对玉米种子的萌发没有明显的影响,对玉米苗期株高、根伸长及总生物量也是低浓度(1-10 mg kg-1)促进生长,高浓度(50-100 mg kg-1)抑制生长;SO2-PAHs复合污染条件下,只有高浓度的复合污染处理对玉米种子萌发起抑制作用,但与对照相比没有显著性差异;低浓度的SO2与低浓度的PAHs处理对玉米株高、根伸长及总生物量有一定的刺激作用,而高浓度的SO2与高浓度的PAHs处理则抑制了玉米的生长,即随着SO2和PAHs浓度的升高,复合污染的毒性逐渐增强.多元回归分析进一步表明,玉米株高和根伸长主要受SO2和PAHs的共同影响,而玉米苗期总生物量主要受PAHs的影响. 相似文献
14.
The effect of salinity on embryonic development ofSepia officinalis (cuttlefish) in the Delta Area (South Western part of The Netherlands) was investigated in 1988/1989, and compared with data concerning the distribution ofS. officinalis in the three main parts of this area: Oosterschelde, Westerschelde and Grevelingen. Embryos hatched in water collected at Yerseke (Oosterschelde), Vlissingen (Western part of the Westerschelde) and Bommenede (Grevelingen), i.e., at salinity values above 28.1, but not in water sampled at Hoedekenskerke and Hansweert (Middle and Eastern part of the Westerschelde; salinities below 22.0). Under laboratory conditions, using diluted Oosterschelde water, the highest hatching percentages ofS. officinalis were found at salinities above 29.8. Some embryos hatched at a salinity value of 26.5 but no hatching occurred at salinities below 23.9. In embryos exposed to salinity changes during late embryonic development, the developmental rate decreased at salinity values of 28.7 or less. Below 22.4 embryos with morphological malformations were found. It can be concluded that salinity is an important factor limiting the distribution ofS. officinalis in most parts of the Delta Area, with the exception of the Western part of the Westerschelde and the Grevelingen.Contribution no. 489 of the Library of the Delta Institute for Hydrobiological Research 相似文献
15.
C. A. Lewis 《Marine Biology》1975,32(2):127-139
Observations on the effects of several environmental conditions in embryonic and larval cultures are reported for the gooseneck barnacle Pollicipes polymerus (Sowerby, 1833). When the growth rates of control embryos kept in finger bowls at ambient-temperature sea water (ca. 12°–15°C) were compared to those of embryos grown under variously modified circumstances, it was found that growth rates were faster under conditions closely simulating the adult barnacle mantle-cavity (e.g. darkness and aeration). Addition of antimicrobial drugs and reduction of egg-mass size also promoted fast growth and development. Nauplii were fed several species of algae; only three species promoted growth to Stage V or older. Naupliar growth was fastest in larvae fed the combination of Prorocentrum micans/Platymonas sp. Larvae fed Prococentrum micans/pennate diatom grew slowest, and most larvae died at Naupliar Stage III. Interactions between algal species may have affected their nutritional value for Pollicipes polymerus nauplii. Less larval activity, slower growth rates, and higher mortality rates were observed in individuals given small amounts of food. The development of embryos and larvae in culture depends greatly on the culture conditions. These conditions should be described if comparison of timetables and envents are to be made between studies. 相似文献
16.
17.
Changes in digestive pH and protease activity have been determined throughout the transition from larvae to the juvenile stage in Sparus aurata in rearing conditions (from 0.04 to 100 g wet weight). Measurements of pH have been taken in the stomach and different segments along the length of the intestine using a pH microelectrode. In starved fish, the gastric pH ranged between 6.0 and 8.0 approximately, except in juveniles of intermediate size (between 1.0 and 7.0 g wet weight), which exhibited a wider pH range of 2.0–8.0. Fed fish with digestive content showed, in general, lower pH values in the stomach. A progressive decrease was observed from a pH range of 5.5–8.0 in the youngest animals (0.04 g) to a pH range of 2.0–6.2 when juveniles were approaching 1.0 g wet weight. Above this weight, the gastric pH remained constant (between 2.0 and 6.0 approximately). The pH values in the intestine ranged between 6.7 and 8.4. They were similar in the different segments and weight classes examined, and there were no significant differences between fed and starved animals. Specific acid protease activity (units per milligram soluble protein) in fed animals increased from small (0.04–1.0 g) to intermediate juveniles (1.0 and 7.0 g), but then remained similar in larger juveniles. On the contrary, specific alkaline protease activity in fed animals decreased from small to intermediate juveniles, and then remained at a similar level in larger juveniles. The results reflect a progressive transition during several months from alkaline digestion in larvae with undeveloped stomachs to the acid digestion in juveniles with fully developed stomachs. Full gastric capacity is developed in seabream juveniles of 1 g wet weight, which represents approximately 100 days post-hatching in cultured populations. Nevertheless, in the following 2.5 months, during which the intestine reaches the appropriate length, juveniles still show a transitional period in the regulatory mechanism of digestion, probably linked to the adaptation to a different feeding habit.Communicated by S.A. Poulet, RoscoffThis revised version was published in December 2003 with corrections to the legend of Fig. 3. 相似文献
18.
Larval development in Amphiglena mediterranea is direct in the parental tube, and larvae crawl away as young juveniles with a radiolar crown capable of feeding. The non-feeding
larvae of A. nathae are initially brooded in the parental tube, and then have a swimming phase before settling and developing a radiolar crown.
Developmental data and reproductive features such as sperm structure are combined with other morphological data for an assessment
of the cladistic relationships of the species in the genus Amphiglena. Two species of Laonome are included as part of the ingroup. Six genera, representing a sister group to the Laonome/Amphiglena clade, are used as an outgroup. Two most-parsimonious cladograms were found, and the evolution of reproductive features are
discussed. The monophyly of Amphiglena is indicated by features previously identified, as well as two features based on sperm morphology. At present a plesiomorphic
larval form cannot be identified for the genus Amphiglena.
Received: 16 June 1997 / Accepted: 29 January 1998 相似文献
19.
During early development in fish, phospholipase A2 (EC 3.1.1.4) regulates membrane lipid modifications, which relates to changes in environmental conditions and provision of
fatty acids required for metabolic energy substrates and prostaglandin biosynthesis. A method to analyze phospholipase A2 in rat tissues has been modified to measure its activity in embryonic Atlantic halibut (Hippoglossus hippoglossus L.). Egg and embryo samples were collected during the 1994 spawning season. Enzyme activity was undetectable at fertilization
but in 10-d embryos was 230 pmol mg−1 h−1 (at 20 °C) and increased by ∼120% at hatch (17-d). Significant alterations in the fatty acid composition of important phospholipids,
phosphatidylcholine (PC) and phosphatidylethanolamine (PE), were also observed. The content of some critical polyunsaturated
fatty acids, and the ratio of unsaturated/saturated fatty acids, declined significantly over development. Acyl-chain restructuring
mediated through the activity of phospholipase A2, coupled with other observed lipid changes (significant increases in the PC/PE ratio and cholesterol content), would produce
a decreased fluidity of membranes during embryonic development, coinciding with the predicted upward movement of larvae in
the water column. Arachidonic acid (20:4n-6) removed from PE could serve as a precursor for biosynthesis of 2-series prostaglandins, and eicosapentaenoic acid (20:5n-3) from PC is a likely source for other prostaglandin types. Despite removal of polyunsaturated fatty acids, there was an
overall increase in lipid and fatty acid concentration, which can be attributed to amino acid catabolism during early developmental
stages.
Received: 9 September 1996 / Accepted: 8 September 1997 相似文献
20.
Photocatalytic degradation of indole in UV/TiO2: optimization and modelling using the response surface methodology (RSM) 总被引:1,自引:0,他引:1
Smail Merabet Didier Robert Jean-Victor Weber Mohammed Bouhelassa Smail Benkhanouche 《Environmental Chemistry Letters》2009,7(1):45-49
The aim of our research is to apply experimental design methodology to the optimization of photocatalytic degradation of indole present in wastewater. Heterogeneous photocatalysis for the oxidation of organic biorecalcitrant pollutants in water is an environmental promising method. We used the response surface methodology (RSM) for the modelization and optimization of the photodegradation of indole in the presence of titanium dioxide. The effect of indole concentration, UV intensity and stirring speed on the yield of indole degradation was determined. According to the mathematic optimization of the process, the optimum point when 100% of degradation is achieved is given by the following values: UV intensity = 250 W/m2, stirring speed = 536.36 tr/min and initial indole concentration = 10.10 mg/l. 相似文献