Feedstock recycling of waste polymers by thermal cracking in molten metal: thermodynamic analysis

Waste plastics contribute to serious environmental and social problems, such as the loss of natural resources, environmental pollution, and depletion of landfill space, but they also create demands on the environmentally-oriented part of the society. Feedstock recycling of scrap polymers by thermal and chemical methods is well known and environmentally accepted. The paper presents the results of thermodynamic analysis of the conversion of polyolefins in a fuel-like mixture of hydrocarbons using thermal cracking in a new type of tubular reactor with molten metal. Evaluation of the efficiency of the process was based on exergy calculations. Calculated exergy efficiency was ca. 79.5 %. It means that feedstock recycling of waste is better from an energetic and environmental point of view than other processes, particularly incineration.     

Comparative environmental analysis of waste brominated plastic thermal treatments

The aim of this research activity is to investigate the environmental impact of different thermal treatments of waste electric and electronic equipment (WEEE), applying a life cycle assessment methodology. Two scenarios were assessed, which both allow the recovery of bromine: (A) the co-combustion of WEEE and green waste in a municipal solid waste combustion plant, and (B) the staged-gasification of WEEE and combustion of produced syngas in gas turbines. Mass and energy balances on the two scenarios were set and the analysis of the life cycle inventory and the life cycle impact assessment were conducted. Two impact assessment methods (Ecoindicator 99 and Impact 2002+) were slightly modified and then used with both scenarios. The results showed that scenario B (staged-gasification) had a potentially smaller environmental impact than scenario A (co-combustion). In particular, the thermal treatment of staged-gasification was more energy efficient than co-combustion, and therefore scenario B performed better than scenario A, mainly in the impact categories of "fossil fuels" and "climate change". Moreover, the results showed that scenario B allows a higher recovery of bromine than scenario A; however, Br recovery leads to environmental benefits for both the scenarios. Finally the study demonstrates that WEEE thermal treatment for energy and matter recovery is an eco-efficient way to dispose of this kind of waste.     

Planning hazardous waste reduction and treatment strategies: An optimization approach

An industry faced with escalating off-site waste disposal costs will often consider increasing on-site waste treatment capacity or the implementation of a waste reduction program. Waste reduction program options include input and process changes that decrease waste quantity and waste toxicity. Tradeoffs between capital investment and economy-of-scale in development are required, and will depend on the industry and the current level of waste reduction. A dynamic programming model is developed that allows the investigation of waste reduction and treatment strategies for industries in a changing regulatory and economic environment. The applicability of the optimization approach to industrial waste generators is illustrated through a hypothetical but representative industrial waste management example.     

An econometric analysis of regional differences in household waste collection: the case of plastic packaging waste in Sweden

The Swedish producer responsibility ordinance mandates producers to collect and recycle packaging materials. This paper investigates the main determinants of collection rates of household plastic packaging waste in Swedish municipalities. This is done by the use of a regression analysis based on cross-sectional data for 252 Swedish municipalities. The results suggest that local policies, geographic/demographic variables, socio-economic factors and environmental preferences all help explain inter-municipality collection rates. For instance, the collection rate appears to be positively affected by increases in the unemployment rate, the share of private houses, and the presence of immigrants (unless newly arrived) in the municipality. The impacts of distance to recycling industry, urbanization rate and population density on collection outcomes turn out, though, to be both statistically and economically insignificant. A reasonable explanation for this is that the monetary compensation from the material companies to the collection entrepreneurs vary depending on region and is typically higher in high-cost regions. This implies that the plastic packaging collection in Sweden may be cost ineffective. Finally, the analysis also shows that municipalities that employ weight-based waste management fees generally experience higher collection rates than those municipalities in which flat and/or volume-based fees are used.     

Immobilization of copper ions laden kaolin waste: influence of thermal treatment on its immobilization in cement paste

This work aims to study the influence of thermal treatment of Cu²⁺ laden kaolin wastes on its immobilization efficiency in cement paste. Compressive strength and toxicity characteristic leaching procedure (TCLP) of 5–20 % kaolin waste blended cement pastes were tested. X-ray diffraction (XRD) results illustrate that adsorption of Cu²⁺ ions modify the crystal structure of kaolinite mineral. Fourier transform infrared (FTIR) results indicate that the adsorption sites on the kaolin surface that were occupied with free water molecules have been replaced with Cu²⁺ ions adsorbed from aqueous solutions. The thermal treatment of kaolin waste improves fixation ratio of Cu²⁺ in cement pastes containing up to 20 % of thermally treated waste. This is due to: pozzolanic activity of calcined kaolin, conversion of leachable adsorbed Cu²⁺ ions into encapsulated unleachable phase that does not retard the hydration of cement as well as adsorption of much of leachable Cu²⁺ ions on surfaces of hydration products and occlusion in its lattice structure as illustrated from XRD, FTIR, thermogravimetric, scanning electron microscopy and TCLP results. The fixation ratio of Cu²⁺ in cement paste blended with 20 % of thermally treated kaolin waste, reaches maximum value of about 97 % compared to 82 % for cement paste blended with 20 % of untreated kaolin waste.     

Risk evaluation with waste scenario: lead emissions in solder waste treatment

In this work, an estimate of the elevation of airborne lead concentrations via the lead solder contained in domestic electricity installations and an investigation into the effects of human exposure were conducted using a simulation method. The elevation of airborne lead concentrations due to incineration was calculated to be 0.001 µg/m³ maximum. The simulation results of the calculations indicated that blood lead concentrations could reach as high as 10⁻⁵ µg/dl. These concentrations could primarily be attributed to the inhalation of airborne lead particles. In addition, we discuss the influences of lead solder disposal on the ecosystem via soil and water.     

Cement clinker: An environmental sink for residues from hazardous waste treatment in cement kilns

About 70% of all of the liquid and solid hazardous wastes commercially incinerated in the United States is being burned in cement kilns. The process inevitably results in residues, primarily heavy metals, entering the clinker and waste dusts (cement kiln dust, CKD) produced by these kilns. The effects of this trend on the nature and chemical composition of cement, actual and future, are discussed. The wastes burned by cement kilns are expected to increasingly have higher levels of heavy metals per Btu. In general, the effects are very simple to describe but have as yet unknown consequences. The present American Society for Testing and Materials (ASTM) standard does not effectively control hazardous waste burning residues in Portland Cement.The regulatory and economic pressures on CKD disposal suggest that much of it, and its heavy metal residues, will, in time, end up in the clinker and the resultant cement. The end point to the trend is the ability to make cement that passes the performance specifications while containing high levels of heavy metals. The only other alternative is to maximize the levels of heavy metals in the CKD, minimize the amount of CKD, and dispose of its as a hazardous waste.It is recommended that an effort to correlate heavy metal levels in clinker with adverse effects be undertaken, a new standard for cement containing hazardous and other waste residuals be developed, and labeling be required.     

Kinetic vaporization of heavy metals during fluidized bed thermal treatment of municipal solid waste

Heavy metals volatilization during thermal treatment of model solid waste was theoretically and experimentally investigated in a fluidized bed reactor. Lead, cadmium, zinc and copper, the most four conventional heavy metals were investigated. Particle temperature model and metal diffusion model were established to simulate the volatilization of CdCl₂ evaporation and investigate the possible influencing factors. The diffusion coefficient, porosity and particle size had significant effects on metal volatilization. The higher diffusion coefficient and porosity resulted in the higher metal evaporation. The influence of redox conditions, HCl, water and mineral matrice were also investigated experimentally. The metal volatilization can be promoted by the injection of HCl, while oxygen played a negative role. The diffusion process of heavy metals within particles also had a significant influence on kinetics of their vaporization. The interaction between heavy metals and mineral matter can decrease metal evaporation amount by forming stable metallic species.     

An environmental analysis for comparing waste management options and strategies

The debate on different waste management practices has become an issue of utmost importance as human activities have overloaded the assimilative capacity of the biosphere. Recent Italian law on solid waste management recommends an increase in material recycling and energy recovery, and only foresees landfill disposal for inert materials and residues from recovery and recycling. A correct waste management policy should be based on the principles of sustainable development, according to which our refuse is not simply regarded as something to eliminate but rather as a potential resource. This requires the creation of an integrated waste management plan that makes full use of all available technologies. In this context, eMergy analysis is applied to evaluate three different forms of waste treatment and construct an approach capable of assessing the whole strategy of waste management. The evaluation included how much investment is needed for each type of waste management and how much "utility" is extracted from wastes, through the use of two indicators: Environmental yield ratio (EYR) and Net eMergy. Our results show that landfill is the worst system in terms of eMergy costs and eMergy benefits. Composting is the most efficient system in recovering eMergy (highest EYR) from municipal solid waste (MSW) while incineration is capable of saving the greatest quantity of eMergy per gram of MSW (highest net eMergy). This analysis has made it possible to assess the sustainability and the efficiency of individual options but could also be used to assess a greater environmental strategy for waste management, considering a system that might include landfills, incineration, composting, etc.     

Continuous in-line gasification/vitrification process for thermal waste treatment: process technology and current status of projects

The Thermoselect High Temperature Recycling process has been developed in order to make available a thermal waste treatment technology avoiding major problems as known from traditional techniques like landfills or ashes, filter dust and emission producing processes. It combines slow degassing with fixed bed oxygen blown gasification and mineral and metal residue melting in a closed loop system. Municipal, industrial and other kinds of waste are compacted to less than one fifth of their original volume by means of an armored hydraulic press, and then periodically pushed into an indirectly heated degasification channel. As the waste plugs are pushed down the channel in an oxygen-free environment, waste humidity is evaporated and the organic components in the refuse are partially degasified and to a certain extent converted into a carbon-like product as the temperature increases. This flaky product and the enclosed inorganic components such as metals and minerals are continuously fed into a high-temperature reactor (HTR). Pure oxygen is added in controlled quantities and reacts with the material following exothermic oxidisation reactions. Due to overall under-stoichiometric conditions, gasification products form a combustible synthesis gas. The heat of reaction leading to temperatures up to about 2000°C in the core of the lower HTR section acts to also smelt the metal and mineral components of the waste. Chlorinated hydrocarbons such as dioxins and furans are reliably destroyed along with other organic compounds in the gaseous and the liquid phase. Material conversion equilibria are assured due to high temperatures and sufficient residence times. The synthesis gas is purified before use as combustible or primary material. After long term operation of the industrial scale demonstration plant in northern Italy, recent orders of differently sized Thermoselect plants can be announced and are illustrated on the basis of three cases out of five [with Herten 225,000 Mg/a and Berlin 300,000 Mg/a] in Germany: (1) Karlsruhe plant, 3 lines, 225,000 Mg/a, under construction; (2) Ansbach plant, 1 line, 75,000 Mg/a, completely purchased in July 1997; (3) Hanau plant, 2 lines, 90,000 Mg/a, partially purchased in October 1997. The technical concepts of these projects are illustrated with special emphasis on the flexibility of tailor-made energy recovery solutions.     

家用厨余垃圾处理机关键零部件结构设计及有限元分析

在现有厨余垃圾粉碎直排工艺上进行改进,变为将日常餐厨垃圾粉碎、脱水、收集的处理流程,达到避免环境污染和资源二次利用的目的.基于厨余垃圾各个组分的特性分析,以模塑螺旋挤出压缩和压榨固液分离的原理为指导,对变螺距变轴径特制螺杆的结构进行设计.基于有限元方法对变径变距螺杆进行了刚度、强度、循环寿命以及模态振动分析,仿真结果表...     

Electronic waste management approaches: An overview

Electronic waste (e-waste) is one of the fastest-growing pollution problems worldwide given the presence if a variety of toxic substances which can contaminate the environment and threaten human health, if disposal protocols are not meticulously managed. This paper presents an overview of toxic substances present in e-waste, their potential environmental and human health impacts together with management strategies currently being used in certain countries. Several tools including Life Cycle Assessment (LCA), Material Flow Analysis (MFA), Multi Criteria Analysis (MCA) and Extended Producer Responsibility (EPR) have been developed to manage e-wastes especially in developed countries. The key to success in terms of e-waste management is to develop eco-design devices, properly collect e-waste, recover and recycle material by safe methods, dispose of e-waste by suitable techniques, forbid the transfer of used electronic devices to developing countries, and raise awareness of the impact of e-waste. No single tool is adequate but together they can complement each other to solve this issue. A national scheme such as EPR is a good policy in solving the growing e-waste problems.     

Work safety in waste treatment

Accident risks in waste treatment were studied at five sanitary landfills, two plants using mainly manual sorting and one incineration plant in southern Finland. Work hazards were detected by means of safety analysis. In addition, accident statistics were used. Work safety problems were found at all work stages. At the sanitary landfills, the major safety problems were posed by operation of the compactor or other machinery and by hazardous wastes. In waste sorting, common problems are odour and dust, lacerations and back injuries. Falling into the waste compactor or paper silos may cause fatal injury and its probability was also high. The highest noise level measured was 97 dB(A). In waste incineration, the most serious hazards were caused by fires, clogging of the funnels and cleaning of the grate. Most deficiencies in work safety can be remedied at a moderate price. The corrective measures involve technical solutions, working methods, supervision, training and occupational health services. The accident rates for workers in the four waste treatment plants were slightly lower than the average for industry.     

上海市生活垃圾处置计划量指标测算模型初探

对生活垃圾处置计划管理政策的意义、生活垃圾处置计划指标测算模型建立的意义和作用进行分析,对建立模型的因素、计算公式、计算流程等进行详细说明,并对3个典型区县的实际情况进行了计算和分析,总结了模型存在的问题和完善方向。     

Assessing the perception and reality of arguments against thermal waste treatment plants in terms of property prices

The thermal processing of waste materials, although considered to be an essential part of waste management, is often sharply contested in the UK. Arguments such as health, depletion of resources, cost, noise, odours, traffic movement and house prices are often cited as reasons against the development of such facilities. This study aims to review the arguments and identify any effect on property prices due to the public perception of the plant. A selection of existing energy from waste (EfW) facilities in the UK, operational for at least 7 years, was selected and property sales data, within 5 km of the sites, was acquired and analysed in detail. The locations of the properties were calculated in relation to the plant using GIS software (ArcGIS) and the distances split into 5 zones ranging from 0 to 5 km from the site. The local property sale prices, normalised against the local house price index, were compared in two time periods, before and after the facility became operational, across each of the 5 zones. In all cases analysed no significant negative effect was observed on property prices at any distance within 5 km from a modern operational incinerator. This indicated that the perceived negative effect of the thermal processing of waste on local property values is negligible.     

An analysis of UK waste minimization clubs: key requirements for future cost effective developments

The UK waste strategy is based upon use of the best practicable environmental option (BPEO), by those making waste management decisions. BPEO is supported by the use of the waste hierarchy, with its range of preferable options for dealing with waste, and the proximity principle, where waste is treated/disposed of as close to its point of origin as possible. The national waste strategy emphasizes the key role of waste minimization and encourages industry, commerce and the public to move towards sustainable waste management practice for economic and environmental reasons. Waste minimization clubs have been used, since the early 1990s, to demonstrate to industry/commerce that reducing waste production can lead to significant financial savings. There have been around 75 such clubs in the UK and they receive support from a wide range of agencies, including the Environmental Technology Best Practice Program. The early Demonstration Clubs had significant savings to cost ratios, e.g. Aire and Calder at 8.4, but had very high costs, e.g. Aire and Calder at 400,000 pounds. It is acknowledged that the number of clubs will have to be approximately doubled in the next few years so as to have an adequate coverage of the UK. There are at present, marked regional variations in club development and cognizance needs to be taken, by facilitators, of the need for extensive coverage of the UK. Future clubs will probably have to operate in a financially constrained climate and they need to be designed to deliver significant savings and waste reduction at low cost. To aid future club design, final reports of all projects should report in a standard manner so that cost benefit analysis can be used to inform facilitators about the most effective club type. rights reserved.     

火力发电厂全厂废水零排放

讨论了火电厂废水类型、排放标准及治理与回用原则，研究了全厂废水零排放的准确含义、约束条件、影响因素、主要内容以及国内外应用示例，为实施火电厂全厂废水零排放提供参考。     

Municipal solid waste management in China: a comparative analysis

This paper illustrates an overview of the past and present MSWM strategies in China. A comparison is made with MSWM in China, and other developed and developing countries to identify and analyze the problems of existing MSWM, and evaluate some effective suggestion to overcome the limitations. Rapid urbanization and economic growth are the main factors of increasing MSW generation in China. The generating MSW has 55.86 % food waste with high moisture contain due to unavailable source separation. Chinese MSWM is dominated by 60.16 % landfilling, whereas incineration, untreated discharge, and other treatments are 29.84, 8.21, and 1.79 %, respectively. In 2014, a total of 604 sanitary landfills, 188 incineration plants, and 26 other units were used for MSWM. With the magnitude of timing, the increasing rate of incineration unit and disposal capacity is higher than the landfill. In 2004–2014, the disposal capacity of landfill and incineration is increased from 68.89 to 107.44 and 4.49 to 53.3 million tons, respectively. However, the heating value in the majority of Chinese incineration plants is 3000–6700 kJ/kg and the inappropriate leachate treatment can be found in 47 % landfill sites. A proper taxation system for MSW disposal is not fully implemented in China, which has a negative impact on overall MSW recycling. From the comparative study of MSWM, it is revealed that the source separation MSW collection, high energy recovery from incineration plants, appropriate leachate treatment, effective landfill location and management, increase waste recycling and proper taxation system for MSW disposal are essential to improve MSWM in China.     

Quantifying construction and demolition waste: An analytical review

Quantifying construction and demolition (C&D) waste generation is regarded as a prerequisite for the implementation of successful waste management. In literature, various methods have been employed to quantify the C&D waste generation at both regional and project levels. However, an integrated review that systemically describes and analyses all the existing methods has yet to be conducted. To bridge this research gap, an analytical review is conducted. Fifty-seven papers are retrieved based on a set of rigorous procedures. The characteristics of the selected papers are classified according to the following criteria - waste generation activity, estimation level and quantification methodology. Six categories of existing C&D waste quantification methodologies are identified, including site visit method, waste generation rate method, lifetime analysis method, classification system accumulation method, variables modelling method and other particular methods. A critical comparison of the identified methods is given according to their characteristics and implementation constraints. Moreover, a decision tree is proposed for aiding the selection of the most appropriate quantification method in different scenarios. Based on the analytical review, limitations of previous studies and recommendations of potential future research directions are further suggested.