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1.
This study assessed the effectiveness of three novel control technologies for particulate matter (PM) and volatile organic compound (VOC) removal from commercial meat cooking operations. All experiments were conducted using standardized procedures at University of California, Riverside''s commercial test cooking facility. PM mass emissions collected using South Coast Air Quality Management District (SCAQMD) Method 5.1, as well as a dilution tunnel-based PM method showed statistically significantly reductions for each control technology when compared to baseline testing (i.e., without a catalyst). Overall, particle number emissions decreased with the use of control technologies, with the exception of control technology 2 (CT2), which is a grease removal technology based on boundary layer momentum transfer (BLMT) theory. Particle size distributions were unimodal with CT2 resulting in higher particle number populations at lower particle diameters. Organic carbon was the dominant PM component (> 99%) for all experiments. Formaldehyde and acetaldehyde were the most abundant carbonyl compounds and showed reductions with the application of the control technologies. Some reductions in mono-aromatic VOCs were also observed with CT2 and the electrostatic precipitator (ESP) CT3 compared to the baseline testing.  相似文献   

2.
In this study, the particle size-resolved distribution from a China-3 certificated light-duty diesel vehicle was measured by using a portable emission measurement system (PEMS). In order to examine the influences of vehicle specific power (VSP) and high-altitude operation, measurements were conducted at 8 constant speeds, which ranged from 10 to 80 km/hr at 10 km/hr intervals, and two different high altitudes, namely 2200 and 3200 m. The results demonstrated that the numbers of particles in all size ranges decreased significantly as VSP increased when the test vehicle was running at lower speeds (< 20 km/hr), while at a moderate speed (between 30 and 60 km/hr), the particle number was statistically insensitive to increase VSP. Under high-speed cruising conditions, the numbers of ultrafine particles and PM2.5 were insensitive to changes in VSP, but the numbers of nanoparticles and PM10 surged considerably. An increase in the operational altitude of the test vehicle resulted in increased particle number emissions at low and high driving speeds; however, particle numbers obtained at moderate speeds decreased as altitude rose. When the test vehicle was running at moderate speeds, particle numbers measured at the two altitudes were very close, except for comparatively higher number concentrations of nanoparticles measured at 2200 m.  相似文献   

3.
以一辆国V排放缸内直喷汽油车为研究对象,试验研究了NEDC、FTP-75和WLTC对该车颗粒物质量、23nm~2.5μm固态颗粒物数量、5.6~560nm超细颗粒数量及粒径分布、颗粒物有机组分的影响.结果表明:NEDC、FTP-75、WLTC颗粒粒径分布基本相同,均呈对数双峰分布,在9nm和60nm两个粒径处出现峰值;5.6~23nm颗粒物数量排放占5.6~560nm颗粒物数量的43.1%~57.7%;与NEDC比较,加减速比例高、瞬态性强的FTP-75、WLTC循环的颗粒物质量、23nm~2.5μm固态颗粒数量、5.6~560nm颗粒数量排放增大;缸内直喷汽油车的颗粒物可溶性有机物组分占颗粒物的20.5%~27.9%,可溶性有机物主要为C16和C18的脂肪酸、C20~C29烷径和5环以上的高分子量多环芳烃,测试循环对颗粒SOF排放及组分产生影响,瞬态性强的FTP-75、WLTC的PAHs比例增加.  相似文献   

4.
柴油轿车颗粒多环芳烃的排放特性   总被引:1,自引:3,他引:1  
谭丕强  周舟  胡志远  楼狄明 《环境科学》2013,34(3):1150-1155
以一辆柴油轿车为研究样车,分别使用纯柴油、生物柴油掺混比例为10%的B10燃油,进行了NEDC整车循环工况试验,测取了该车HC、CO、NOx、颗粒等法规限制的排放,利用气相色谱-质谱法对采集的排气颗粒样品进行了分析,重点研究了颗粒中多环芳烃的排放特性.结果表明,与柴油相比,燃用B10燃油的HC、CO、NOx和颗粒等常规排放均有所降低;两种燃料产生的颗粒多环芳烃排放中均以荧蒽和芘最多,与纯柴油相比,燃用B10燃油产生的低环数PAHs排放略有增加,中高环数的PAHs排放降幅明显.苯并[a]芘等效毒性分析结果显示燃用B10燃油的BEQs值比纯柴油降低了21.6%,表明柴油轿车燃用生物柴油后,排气颗粒的多环芳烃毒性有所下降.  相似文献   

5.
Two continuously regenerating diesel particulate filter (CRDPF) with different configurations and one particles oxidation catalyst (POC) were employed to perform experiments in a controlled laboratory setting to evaluate their effects on NO2, smoke and particle number emissions. The results showed that the application of the after-treatments increased the emission ratios of NO2/NOx significantly. The results of smoke emissions and particle number (PN) emissions indicated that both CRDPFs had sufficient capacity to remove more than 90% of total particulate matter (PM) and more than 97% of solid particles. However, the POC was able to remove the organic components of total PM, and only partially to remove the carbonaceous particles with size less than 30 nm. The negligible effects of POC on larger particles were observed due to its honeycomb structure leads to an inadequate residence time to oxidize the solid particles or trap them. The particles removal efficiencies of CRDPFs had high degree of correlations with the emission ratio of NO2/NOx. The PN emission results from two CRDPFs indicated that more NO2 generating in diesel oxidation catalyst section could obtain the higher removal efficiency of solid particles. However this also increased the risk of NO2 exposure in atmosphere.  相似文献   

6.
In this study, the effects of a diesel oxidation catalyst (DOC) coupled with a catalyzed diesel particulate filter (CDPF) with different catalyst loadings on the power, fuel consumption, gaseous and particulate emissions from a non-road diesel engine were investigated. Results showed that the after-treatment had a negligible effect on the power and fuel consumption. The reduction effect of the DOC on the CO and hydrocarbon (HC) increased with the engine load. Further reductions occurred coupling with the CDPF. Increasing the catalyst loading resulted in a more significant reduction in the HC emissions than CO emissions. The DOC could increase the NO2 proportion to 37.9%, and more NO2 was produced when coupled with the CDPF below 250°C; above 250°C, more NO2 was consumed. The after-treatment could reduce more than 99% of the particle number (PN) and 98% of the particle mass (PM). Further reductions in the PN and PM occurred with a higher CDPF catalyst loading. The DOC had a better reduction effect on the nucleation particles than the accumulation ones, but the trend reversed with the CDPF. The DOC shifted the particle size distribution (PSD) to larger particles with an accumulation particle proportion increasing from 13% to 20%, and the geometric mean diameter (GMD) increased from 18.2 to 26.0 nm. The trend reversed with the CDPF and the accumulation particle proportion declined to less than 10%. A lower catalyst loading on the CDPF led to a higher proportion of nucleation particles and a smaller GMD.  相似文献   

7.
乌鲁木齐市城区机动车大气污染物排放特征   总被引:4,自引:1,他引:3  
对乌鲁木齐市城区车辆信息(包括车流量和车辆构成、车辆控制技术水平、车辆行驶工况、车辆启动分布等)进行调研和测试,并根据IVE模型计算得到机动车污染物排放清单,获得分车型、燃料类型及启动/运行方式的机动车污染物排放分担率.结果表明:2011年乌鲁木齐市机动车CO、NO_x、HC和PM的排放量分别为20.22×104、2.60×104、1.84×104和0.44×10~4t·a~(-1),机动车污染物排放分担率差别显著,乘用车、公交车和重型货车是CO和HC主要排放源;重型货车和乘用车是NO_x的主要排放源;重型货车是PM的主要排放源.汽油车是CO和HC排放的主要来源,柴油车是NO_x和PM排放的主要来源,天然气车各类污染物排放量均较低.控制柴油重型货车是消减机动车污染物排放的重要方式.  相似文献   

8.
Mineral particles or particulate matters(PMs) emitted during agricultural activities are major recurring sources of atmospheric aerosol loading.However,precise PM inventory from agricultural tillage and harvest in agricultural regions is challenged by infrequent local emission factor(EF) measurements.To understand PM emissions from these practices in northeastern China,we measured EFs of PM_(10) and PM_(2.5) from three field operations(i.e.,tilling,planting and harvesting) in major crop production(i.e.,corn and soybean),using portable real-time PM analyzers and weather station data.County-level PM_(10) and PM_(2.5) emissions from agricultural tillage and harvest were estimated,based on local EFs,crop areas and crop calendars.The EFs averaged(107 ± 27),(17 ± 5) and 26 mg/m~2 for field tilling,planting and harvesting under relatively dry conditions(i.e.,soil moisture 15%),respectively.The EFs of PM from field tillage and planting operations were negatively affected by topsoil moisture.The magnitude of PM_(10) and PM_(2.5) emissions from these three activities were estimated to be 35.1 and 9.8 kilotons/yr in northeastern China,respectively,of which Heilongjiang Province accounted for approximately45%.Spatiotemporal distribution showed that most PM_(10) emission occurred in April,May and October and were concentrated in the central regions of the northeastern plain,which is dominated by dryland crops.Further work is needed to estimate the contribution of agricultural dust emissions to regional air quality in northeastern China.  相似文献   

9.
This study presents the emission factor of gaseous pollutants(CO, CO_2, and NO X) from on-road tailpipe measurement of 14 passenger cars of different types of fuel and vintage. The trolley equipped with stainless steel duct, vane probe velocity meter, flue gas analyzer, Nondispersive infra red(NDIR) CO_2 analyzer, temperature, and relative humidity(RH) sensors was connected to the vehicle using a towing system. Lower CO and higher NO X emissions were observed from new diesel cars(post 2010) compared to old cars(post 2005), which implied that new technological advancement in diesel fueled passenger cars to reduce CO emission is a successful venture,however, the use of turbo charger in diesel cars to achieve high temperature combustion might have resulted in increased NO X emissions. Based on the measured emission factors(g/kg), and fuel consumption(kg), the average and 95% confidence interval(CI) bound estimates of CO, CO_2,and NO X from four wheeler(4W) in Delhi for the year 2012 were 15.7(1.4–37.1), 6234(386–12,252),and 30.4(0.0–103) Gg/year, respectively. The contribution of diesel, gasoline and compressed natural gas(CNG) to total CO, CO_2 and NO X emissions were 7:84:9, 50:48:2 and 58:41:1respectively. The present work indicated that the age and the maintenance of vehicle both are important factors in emission assessment therefore, more systematic repetitive measurements covering wide range of vehicles of different age groups, engine capacity, and maintenance level is needed for refining the emission factors with CI.  相似文献   

10.
Diesel vehicles have caused serious environmental problems in China. Hence, the Chinese government has launched serious actions against air pollution and imposed more stringent regulations on diesel vehicle emissions in the latest China VI standard. To fulfill this stringent legislation, two major technical routes, including the exhaust gas recirculation (EGR) and high-efficiency selective catalytic reduction (SCR) routes, have been developed for diesel engines. Moreover, complicated aftertreatment technologies have also been developed, including use of a diesel oxidation catalyst (DOC) for controlling carbon monoxide (CO) and hydrocarbon (HC) emissions, diesel particulate filter (DPF) for particle mass (PM) emission control, SCR for the control of NOx emission, and an ammonia slip catalyst (ASC) for the control of unreacted NH3. Due to the stringent requirements of the China VI standard, the aftertreatment system needs to be more deeply integrated with the engine system. In the future, aftertreatment technologies will need further upgrades to fulfill the requirements of the near-zero emission target for diesel vehicles.  相似文献   

11.
采用COPERTⅣ模型计算佛山市公交车、摩托车和小型客车排放因子,结合保有量、年平均行驶里程计算其排放量,对佛山市公交车出行环境效果及尾气削减潜力进行情景分析。结果表明:2011年佛山市公交车CO、VOC、NOx和PM的排放量为804.57、283.85、3 365.32和73.00 t。单人单次公交车出行CO和VOC的排放量较摩托车和小型客车低,但NOx则较高。公交车载客人数从17人上升至25、35、45人,单人单次出行每公里排放量分别下降32.00%、51.43%和57.50%。佛山市低排放标准的柴油公交车全部更换成国Ⅳ排放标准柴油车,CO、VOC、NOx和PM的年排放量分别削减611.66、151.6、1 231.18和58.39 t。EEV标准天然气公交车替代柴油公交车可减少NOx和PM的排放,但对VOC的削减并无优势。佛山市现有柴油公交车更换成EEV标准天然气公交车,CO、NOx和PM的年排放量分别削减293.71 t、2 086.87 t和70.34 t,但VOC的年排放量升高228.01 t。  相似文献   

12.
重型柴油公交车实际道路颗粒物排放的理化特征   总被引:1,自引:0,他引:1       下载免费PDF全文
为研究重型柴油公交车实际道路颗粒物排放的理化特征,采用车载排放测试方法,选取了2辆国Ⅲ和4辆国Ⅳ柴油公交车,对气态污染物和颗粒物排放因子、粒径分布及颗粒物中的组分(包括碳组分、离子、元素和有机组分)排放特征进行了实测分析.结果表明:测试车辆的颗粒数量主要集中在100 nm以下粒径段,颗粒质量排放总体呈倒U型分布,粒径峰值位于300 nm左右.OC和EC分别占尾气颗粒物总质量的36.10%±8.94%和27.97%±10.00%,离子和元素组分分别占7.75%±1.01%和22.71%±3.09%.柴油质量对柴油车尾气颗粒物成分具有较大影响,燃用国Ⅲ柴油的车辆尾气中富含S、Ca、Mg、Na等元素组分,其主要来自燃油中的硫分和杂质.在可检出的弱极性可溶有机物中,正构烷烃和脂肪酸的含量较为丰富,分别占颗粒物总质量的1.95%和5.13%,此外还有一定量的藿烷和PAHs(多环芳烃).其中,正构烷烃组分主要分布于C19~C29,正构烷酸主要集中在C12、C14、C16和C18等偶数碳组分.国Ⅲ和国Ⅳ柴油公交车的PAHs排放因子分别为198.2、62.5 μg/km,以3环和4环PAHs为主,菲、荧蒽、芘、惹烯、苯并荧蒽、、苯并[123-cd]芘和苯并苝是较为主要的PAHs组分.需要指出的是,由于采用定比例稀释方法,颗粒物中组分的测试结果可能与其实际排放存在一定偏差.   相似文献   

13.
南京市夏季大气气溶胶新粒子生成事件分析   总被引:5,自引:5,他引:5  
研究了南京市夏季大气气溶胶数浓度的基本特征和气溶胶新粒子生成事件的形成条件及其影响因子.应用宽范围颗粒粒径谱仪(WPS)和双光路差分吸收光谱仪(DOAS)对南京市2010年7月大气气溶胶数浓度谱分布和污染气体(O3、SO2和NO2)进行了观测,并结合气象要素观测数据和后向轨迹模式模拟,探讨了南京市夏季大气气溶胶新粒子生成的条件及其影响因子.结果表明,南京市夏季10~500nm气溶胶平均数浓度为1.7×104cm-3,与北美和欧洲的一些典型城市观测值相近;10~25 nm气溶胶粒子数浓度占总数浓度的比例为25%.观测期间共出现6次新粒子生成事件,通过分析发现比较稳定的风速风向、较强的太阳辐射有利于南京夏季新粒子的形成.南京夏季新粒子生成事件的相对湿度条件在50%~70%,通过后向轨迹模式模拟的结果发现偏东风或偏南风带来的海洋性洁净气团有利于新粒子的生成.南京夏季新粒子生成事件发生时,10~25 nm气溶胶数浓度与SO2的浓度呈正相关,与O3的浓度呈负相关,而与NO2的浓度相关性较差.  相似文献   

14.
为了获取机动车源尾气和主要民用燃料源燃烧过程排放的颗粒物中含碳气溶胶的排放特征,使用多功能便携式稀释通道采样器和Model 5L-NDIR型OC/EC分析仪,采集分析了典型机动车源(汽油车、轻柴油车、重柴油车)、民用煤(块煤和型煤)和生物质燃料(麦秆、木板、葡萄树树枝)的PM10和PM2.5样品中的有机碳(OC)和元素碳(EC).结果表明,不同排放源释放的PM10和PM2.5中含碳气溶胶的质量分数存在显著差异.总碳(TC)在不同源PM10和PM2.5中的质量分数范围分别为40.8%~68.5%和30.5%~70.9%,OC/EC范围分别为1.49~31.56和1.90~87.57.不同源产生的含碳气溶胶均以OC为主,OC在PM10和PM2.5中的质量分数范围分别为56.3%~97.0%和65.0%~98.7%.在PM10和PM2.5的含碳气溶胶中OC质量分数按照从高到低...  相似文献   

15.
在一台电控增压中冷四缸柴油机的进气道上加装一套电控喷射装置,使其运行柴油/甲醇双燃料(DMDF)模式.研究了甲醇中Ti O_2添加剂的添加量及同一添加剂添加量在不同甲醇分散系喷射量时对发动机大负荷工况的燃烧和颗粒物(PM)排放的影响.结果表明,在甲醇中添加适量(30和100 mg·kg~(-1))的纳米Ti O_2能够使爆发压力升高,对燃烧有一定的促进作用,但添加过量(100 mg·kg~(-1))会对燃烧产生不利影响.加入纳米Ti O_2后,干炭烟烟度排放和积聚态颗粒数明显降低,在添加剂添加量为1000 mg·kg~(-1)时,最大降幅分别达到26.8%和29.4%,而核态颗粒物排放变化不大.在相同添加剂添加量下,增加甲醇分散系替代率R_m会使放热始点后移,放热更加集中,爆发压力增大,干炭烟烟度和颗粒物排放均大幅度降低.在添加剂添加量为100 mg·kg~(-1)时,与R_m=10%相比,R_m=40%时爆发压力增加0.94 MPa,放热率峰值增加53.5%,烟度、核态颗粒数、积聚态颗粒数和颗粒物总数的降幅分别达66.9%、42.3%、67.0%和58.0%.  相似文献   

16.
生物源一次气溶胶(PBAP),是大气颗粒物的重要组成部分,不论微生物死活,对空气质量和人类健康均会产生影响,同时对大气化学以及气候变化都有重要影响.基于流式细胞仪分析技术,结合碘化丙啶(PI)和SYBR (SYBR Green I)双荧光探针,对北京城区大气环境中死的和活的PBAP进行了识别和定量分析,并探究气象因子和空气污染因子对其影响.结果发现,北京城区死的和活的PBAP数浓度中值夏季(1.03×106个·m-3和7.43×105个·m-3)高于冬季(7.34×105个·m-3和6.18×105个·m-3),且两者呈现明显的同步变化趋势.统计学结果分析发现,PBAP数浓度与气象条件和空气质量等环境影响因子相关性并不显著,与温度和湿度呈现弱正相关关系,与O3、最大风速和日照时数呈现弱负相关关系.PBAP数浓度与细颗粒物PM2.5浓度相关性较弱,与粗颗粒物(PM2.5-10)浓度呈现明显的正相关关系.静稳天气和沙尘长距离传输都可以提升北京城区PBAP的数浓度水平.  相似文献   

17.
The aerosol number concentration and size distribution as well as size-resolved particle chemical composition were measured during haze and photochemical smog episodes in Shanghai in 2009. The number of haze days accounted for 43%, of which 30% was severe (visibility 〈 2 km) and moderate (2 km 〈 visibility 〈 3 km) haze, mainly distributed in winter and spring. The mean particle number concentration was about 17,000/cm3 in haze, more than 2 times that in clean days. The greatest increase of particle number concentration was in 0.5-1μm and 1-10 μm size fractions during haze events, about 17.78 times and 8.78 times those of clean days. The largest increase of particle number concentration was within 50-100 nm and 100-200 nm fractions during photochemical smog episodes, about 5.89 times and 4.29 times those of clean days. The particle volume concentration and surface concentration in haze, photochemical smog and clean days were 102, 49, 15 μm3/cm3 and 949, 649, 206 μm2/cm3, respectively. As haze events got more severe, the number concentration of particles smaller than 50 nm decreased, but the particles of 50-200 nm and 0.5-1μm increased. The diurnal variation of particle number concentration showed a bimodal pattern in haze days. All soluble ions were increased during haze events, of which NH4, SO24- and NO3 increased great/y, followed by Na+, IC, Ca2+ and CI-. These ions were very different in size-resolved particles during haze and photochemical smog episodes.  相似文献   

18.
Size-resolved aerosol samples were collected by MOUDI in four seasons in 2007 in Beijing. The PM10 and PM1.8 mass concentrations were 166.0 ± 120.5 and 91.6 ± 69.7 μg/m3, respectively, throughout the measurement, with seasonal variation: nearly two times higher in autumn than in summer and spring. Serious fine particle pollution occurred in winter with the PM1.8/PM10 ratio of 0.63, which was higher than other seasons. The size distribution of PM showed obvious seasonal and diurnal variation, with a smaller fine mode peak in spring and in the daytime. OM (organic matter = 1.6 × OC (organic carbon)) and SIA (secondary inorganic aerosol) were major components of fine particles, while OM, SIA and Ca2 + were major components in coarse particles. Moreover, secondary components, mainly SOA (secondary organic aerosol) and SIA, accounted for 46%–96% of each size bin in fine particles, which meant that secondary pollution existed all year. Sulfates and nitrates, primarily in the form of (NH4)2SO4, NH4NO3, CaSO4, Na2SO4 and K2SO4, calculated by the model ISORROPIA II, were major components of the solid phase in fine particles. The PM concentration and size distribution were similar in the four seasons on non-haze days, while large differences occurred on haze days, which indicated seasonal variation of PM concentration and size distribution were dominated by haze days. The SIA concentrations and fractions of nearly all size bins were higher on haze days than on non-haze days, which was attributed to heterogeneous aqueous reactions on haze days in the four seasons.  相似文献   

19.
为了进一步减少甲醇掺烧后的柴油机颗粒物排放,在一台由增压中冷的高压共轨柴油机改造成的柴油甲醇组合燃烧(DMCC—diesel/methanol compound combustion)发动机上详细研究了柴油喷射时刻对两种燃料共燃时的颗粒物生成及其排放的影响.试验工况选择重型柴油机常用的A50工况.试验结果表明,当柴油在上止点后喷射时,颗粒物排放的数量浓度随着甲醇替代率的增加而减少,当上止点前喷射时,颗粒物的数量浓度先减少后增加.随着喷射时刻的提前,颗粒中超细颗粒所占比例增大.随着喷射时刻的推迟,甲醇替代率降低颗粒物质量浓度的作用增强,同时甲醇替代率降低颗粒物几何平均直径的作用减弱.  相似文献   

20.
《Journal of Cleaner Production》2007,15(11-12):1122-1134
As a consequence of the introduction of limits on exhaust gas emissions and a target agreement between the Swiss association of car importers (auto-schweiz) and the Swiss government calling for a reduction in the specific fuel consumption, a considerable reduction of exhaust emissions of newly registered Swiss passenger cars occurred in the last 10 years. Also, for the near future an ongoing reduction of exhaust emissions of newly registered vehicles is expected. However, applying the concept of life cycle thinking, exhaust emission reductions may be outbalanced with an increase in specific car manufacturing expenditures and/or a longer use of the car. Thus, from the point of view of an individual car owner, a prolonged car use may be the environmentally preferable option. In order to investigate this question, a comprehensive analysis of the environmental performance of newly registered diesel and petrol passenger cars in the time period from 2000 to 2010 has been performed. Life Cycle Assessment (LCA) has been employed focusing on three transport components: ‘vehicle travel’ (exhaust and abrasion emissions), ‘fuel chain’ (supply of fuels) and ‘car infrastructure’ (manufacturing, maintenance and disposal of cars). The presented model aims to gain insight into the issue of longevity and prolonged car use for the Swiss case, rather than giving ultimate recommendations. The analysis focuses on classical road pollutants (NOx and PM2.5) as well as on fuel consumption reduction and CO2. Moreover, impact assessment has been applied, employing a common approach: Eco-Indicator (EI) 99. The ranking of different car replacement options revealed prolonged car use as the environmentally better option. As a consequence of the continuous use of the car representing 2000 average technology, the components ‘vehicle travel’ and ‘fuel chain’ show a 10% and 9% higher performance, respectively. This effect is compensated by savings in ‘car infrastructure’ (26%). Uncertainty analysis has been performed by additional model runs with different parameter settings. Despite the fact that a considerably prolonged car use scores best for all additional model runs, the resulting differences between options further decrease. This holds particularly true, if a higher yearly average fuel reduction rate of 3% is assumed. Furthermore, applying an avoided burden concept for infrastructure modeling (Value Corrected Substitution (VCS)) shows the same effect. In both cases the resulting scores differ merely marginally between the considered options and would not allow for discrimination.As a consequence of these outcomes, it is not possible to give any general recommendation to Swiss car owners to extend the use of their cars, in the short term.  相似文献   

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