Prediction of metal-adsorption behaviour in the remediation of water contamination using indigenous microorganisms

In recent years, the adsorption of heavy metal cations onto bacterial surfaces has been studied extensively. This paper reports the findings of a study conducted on the heavy metal ions found in mine effluents from a mining plant where Co²⁺ and Ni²⁺ bearing minerals are processed. Heavy metal ions are reported to be occasionally present in these mine effluents, and the proposed microbial sorption technique offers an acceptable solution for the removal of these heavy metals. The sorption affinity of microorganisms for metal ions can be used to select a suitable microbial sorbent for any particular bioremediation process. Interactions of heavy metal ions (Co²⁺ and Ni²⁺) and light metal ions (Mg²⁺ and Ca²⁺) with indigenous microbial cells (Brevundimonas spp., Bacillaceae bacteria and Pseudomonas aeruginosa) were investigated using the Langmuir adsorption isotherm, pseudo second-order reaction kinetics model and a binary-metal system. Equilibrium constants and adsorption capacities derived from these models allowed delineation of the effect of binding affinity and metal concentration ratios on the overall adsorption behaviour of microbial sorbents, as well as prediction of performance in bioremediation systems. Although microbial sorbents used in this study preferentially bind to heavy metal ions, it was observed that higher concentrations (>90 mg/?) of light metal ions in multi-metal solutions inhibit the adsorption of heavy metal ions to the bacterial cell wall. However, the microbial sorbents reduced Ni²⁺ levels in the mine-water used (93–100% Ni²⁺ removal) to below the maximum acceptable limit of 350 μg/?, established by the South African Bureau of Standards. Competition among metal ions for binding sites on the biomaterial surface can occur during the bioremediation process, but microbial sorption affinity for heavy metal ions can enhance their remediation in dilute (<5 mg/? heavy metal) wastewaters.     

The sustainability of China's major mining cities

The aim of this paper is to identify principal factors controlling the Degree of Sustainable Development of Mineral Resources (DSDMR) of mining cities and then to measure their DSDMR and reveal their developing trends. To do this, 78 Chinese mining cities are used as an example. These cities are classified on a hierarchical level of the DSDMR in order to support decision-making of sustainable development. Six principal factors controlling the DSDMR are recognized using factor analysis. They are used to measure the DSDMR of the Chinese mining cities and their developing trends. The results show that in terms of the type of mineral resources, the DSDMR decreases from petroleum to multi-resources to non-metal to coal to metal cities. It decreases also from middle to old to young aged cities and from eastern to central to western cities in geographical location. In addition, large and very large cities have higher DSDMR values than middle- and small-sized cities. These Chinese mining cities are classified into six clusters by cluster analysis, which forms the basis for policy making.     

The mining industry in the European Union: Analysis of inter-industry linkages using input–output analysis

Input–output modelling is a useful tool in policy analysis and economic planning. This methodology is used to detect the inter-industry linkages known as forward and backward linkages. Examination of these measures provides one mechanism for identifying “key” or “leading” sectors. The main objective of this paper is to measure the linkages of the mining and quarrying industry in the European Union (EU) and to determine if any of the industry subsectors can be considered key sectors. The paper shows that three subsectors can be considered key sectors: the mining of coal and lignite and extraction of peat in Germany; mining of metal ores in Sweden; and other mining and quarrying in Austria, Denmark and Spain. These sectors are more stimulated by overall industry growth than other sectors and have greater impacts in terms of investment expenditures on the national economy than other sectors. The values of the forward and backward linkages show that the mining and quarrying is an industry that would be stimulated by an increase in a regional economy's production more than other sectors, while an increase in the mining and quarrying industry's output would not stimulate this regional economy more than an increase in other sectors.     

Is mining a high-tech industry?: Investigations into innovation and productivity advance

The fundamental nature of the mining industry with respect to innovation is often questioned. Is it the conservative, stodgy industry commonly depicted by its critics or is it instead a sophisticated, high-tech industry as championed by many of proponents? Using productivity statistics, it can be shown that the innovation rate of metal mining companies directly compares with the rates associated with general manufacturing. This relationship has held true for the last 50 years. A significant difference lies in the high-tech manufacturing sector, which for the last approximately dozen years has held productivity increases of 9.5% per year, in contrast to general manufacturing and metal mining rates of 2.5% and 2.3% per year, respectively.     

Assessing the application of an additive model to estimate toxicity of a complex effluent

A number of industries monitor levels of chemicals in their effluent, but few have undertaken prolonged biological monitoring of this wastewater. The focus of the present study was to determine whether past chemical data for effluent from a lead smelter could be used to estimate its past toxicity. Since the interactive effects of metals in effluents are often assumed to be additive, it was hypothesized that an additive model, 100/[sigma(metal concentration in effluent/EC50 for individual metal)], could be used to generate an EC50 from chemical data (where EC50 is the concentration of test material that affects 50% of the test organisms). To test the approach, a larval development toxicity test with the marine polychaete, Galeolaria caespitosa, was used to test 26 separate samples of effluent from a lead smelter, generating empirical EC50 values. EC50 values for each individual metal in the effluent were also generated using the larval development toxicity test. The concentrations of trace metals in each effluent sample were determined and, using the additive model, EC50 values were calculated. For the majority of effluent samples tested, the additive model underestimated toxicity, suggesting the presence of additional unidentified contaminants in the effluent samples. Additionally, a nonlinear rather than linear regression curve was found to best describe the relationship between the model and empirically derived EC50 values. This relationship was then used to estimate past trends in toxicity of the smelter effluent. Forty-eight percent of the variability in measured toxicity was explained by the model, with the model underestimating toxicity in the majority of samples.     

The mining industry and the community: joining forces for sustainable social development

This article joins the continuing policy debate over the social responsibility of corporations, particularly in the mining industry. The author argues that the 'old school mining orthodoxy'—approaching the exploitation of mineral deposits solely from the technical and economic points of view—is long dead. Mining companies must also encompass the social dimension.
New policies for the mining industry are discussed in terms of recent worldwide trends and movements, e.g. globalization, economic interdependence and decentralization of governmental authority, and the rise of civil society as a political factor. These trends, together with the United Nations policies in quest of sustainable development and the consensus expressed at international conferences during the last decade, have deepened social awareness and set the stage for enhanced social responsiveness from the private sector. Socially responsible corporate policies include decentralization of decision-making to the field level, reaching out to stakeholders and shareholders, supporting governments which provide official development assistance for good governance and building broad partnerships to reduce social exposures.     

The metal mining industry in Eastern Europe

The mining industry has been one of the backbones of the socialist countries of Eastern Europe, not only in economic, but also in political, terms. Three years after the beginning of economic reforms, the mining industry in all the Eastern European countries is facing dramatic changes. Most mines are mining ores below acceptable cut-off grades, and there is no hope of finding new, richer deposits. Downstream metallurgical industries will need to replace their former suppliers. In addition, the social contract that had been maintained under the socialist governments is about to be undone and a new form of internal organization must be found. The success of the economic reforms in Eastern Europe depends upon the capacity to develop new industrial relations: the large mining combinates will have to be transformed into competitive capitalist enterprises and the role of the state must be redefined. Prospects for this transformation vary greatly, from metal to metal and from country to country. Finally, restructuring in Eastern Europe will also affect European and world markets, both on the supply and demand sides. The integration of the Eastern European mining industries into the international mining community should be the medium-term goal of all the participants .     

Effect of tax laws on mineral exploration in Canada

Changes since 1972 in Canadian federal and provincial tax laws have eliminated many of the prior tax incentives offered to the mining industry. These changes provide an opportunity to study the effect of tax laws on a country's mineral resource development by comparing trends in mineral exploration in various provinces with adjoining regions, and by comparing these results with firm behaviour that would be expected from microeconomic analysis. Mineral producers have sought higher, more stable returns, resulting in shifts of exploration into political regions with more favourable and less changeable tax policies. Future supplies of mineral raw materials from a political region are dependent on current exploration effort, which is in turn influenced by the region's tax laws.     

Global trends in gold mining: Towards quantifying environmental and resource sustainability

In recent years, due to public concern over perceived and actual environmental impacts, the global mining industry has been moving towards a more sustainable framework. For gold mining, there are a number of fundamental issues with regard to assessing sustainability. Commonly perceived as a finite and non-renewable resource, long-term gold production trends include declining ore grades and increasing solid wastes (tailings, waste rock) and open cut mining. Conversely, core sustainability issues include water, energy and chemical consumption and pollutant emissions—also known as ‘resource intensity’. It is important to recognise the links between gold production trends and resource intensity, as this is critical for understanding future sustainability challenges. This paper links data sets on historic gold mining production trends with emerging sustainability reporting to estimate resource intensity, demonstrating the sensitivity of ore grade for gold production and sustainability. Final judgement of the sustainability of gold mining must take account of the sensitivity of the ore grade in the resource intensity of gold production. This has implications for environmental policy and sustainability reporting in the gold mining sector.     

Limitations of applying life cycle assessment to complex co-product systems: The case of an integrated precious metals smelter-refinery

Integrated smelter-refineries play an important role in the recovery of multiple metals from complex primary and secondary materials, and hence in closing metals cycles. Processes in these facilities are strongly interconnected, dynamic, and multifunctional, which challenges a typical representation in life cycle assessment (LCA). This is especially true when LCA is applied to calculate the environmental profile of single metals products.This study examines methodological requirements for assessing complex co-product systems using attributional LCA through a static, gate-to-gate inventory model that quantifies the environmental impacts of each of the metal products of an integrated precious metals smelter-refinery. The model is based on a large number of subprocesses and is formulated using detailed industry data, which allows quantification of the sensitivity of the results with respect to allocation rationales and the data collection period.The results within one impact category vary strongly among metals (up to four orders of magnitude for copper compared to rhodium). Moving from mass- to value-based allocation changes the result for a given metal by up to two orders of magnitude. If value-based allocation is used, the selected reference year for metals prices influences the results by up to a factor of two.Allocation rationales are critically analyzed, and it is shown that none reflect the business model or other system drivers. While the model is focused on quantifying environmental impacts of metal outputs, the actual process is economically driven to efficiently treat a continuously changing feed mix. The complexity of a smelter-refinery cannot be captured by static, attributional inventory models, which is why the choice of allocation rationale remains arbitrary. Instead, marginal, parameterized models are needed; however, such models are substantially more time and data intensive and require disclosure of more detailed, process specific data.     

The Effect of Government Involvement on the Economics of the Base Metals Industry

The correctness of the statement that surplus production and depressed prices in the base metal industries are the result of state ownership in the mining industry is examined by analyzing the production figure of publicly and privately owned companies. The conclusion is that for some metals the statement is true. But it is equally true that, for some, privatelyowned mining companies have also maintained high levels of production in the face of depressed demand. The reasons why both state and privately owned mining companies have not been able to rationalize production are examined. For privately owned companies it is suggested that a shift in the method of financing mineral projects, i.e. from retained earnings to bank loans, is an important factor.     

THE ECONOMICS OF DEEP SEA NODULES: AN APPRAISAL OF RECENT ESTIMATES

The metal resources of deep sea nodules are attracting investment from many international corporations. Commercial interest in nodule mining is related to, but not governed by, existing estimates of economic profitability of the first generation ventures. Mr. Chacko reviews some of the latest published figures on costs and revenues, and these are updated and put on a comparable basis. He then argues that more attention should be paid to the long-term objectives of corporate policy in analysing the future development of the nodule mining industry.     

Dynamic metals demand model

Studies by Nutting, Jacobson and Evans and Georgentalis et al. have all concluded, using panel data sets, that a number of metals appear to share a common demand curve that is stable over time. However, these studies have a number of theoretical and econometric limitations. This paper addresses these concerns and reassesses the hypothesis that some metals share such a common demand curve with the same price elasticity of demand. This is achieved within the framework of a random coefficients model. This model was applied to a dynamic metals demand function (DLR) and various estimation techniques were used including OLS, IV, Empirical Bayes (EB) and Instrumental Variables Empirical Bayes (IV-EB). It was found that each metal had its own individual short run demand function with statistically different own price and industrial activity elasticities of demand. In the long run, each metal appeared to be equally unresponsive to price changes, but had different industrial activity elasticities. The speeds of price adjustment to periods of market disequilibrium differed substantially between metals.     

沉淀浮选法处理矿山含重金属废水技术初探

本文介绍了一种新的废水处理技术－沉淀浮选法处理矿山含重金属废水的性能，并对其净化机理作了探讨，还将其与传统的化学沉淀净化法作了比较，为矿山废水的治理及综合利用指出了一条切实可行的新途径。     

Maintaining land use agreements in Papua New Guinea Mining: ‘Business as usual’?

Most large scale resource extraction projects in Papua New Guinea (PNG) require companies to negotiate with customary landowners for access to development sites. In the discussion of process and challenges of development and operation of projects, particularly mines, the paper, basing as a case study of land use arrangements in PNG mining, has several objectives to address. First, it discusses land use arrangements in the mining industry and how they have evolved over the last few decades. Today, most of these arrangements involve pluralistic framework agreements which have been shaped by land tenure debates, civil uprisings, government initiatives and increasingly politically savvy customary landowners. This pluralistic process encourages key stakeholder involvement, particularly customary landowner participation which has been an innovative piece of sustainable mineral policy development in PNG. Second, the paper argues that ‘it is not business as usual’ for mining companies as it would generally be the case in developed and many developing countries because they are increasingly forced to be proactive in addressing landowner and community interests while managing mining projects. A brief overview of land use debates in PNG is summarised at the outset to provide background to mining and development in the country. Third, the significance of the corporate social responsibility (CSR) paradigm and its impact on business, particularly the mining industry is acknowledged intermittently in the discussion to shed light on how it is influencing development of local communities. Finally, the paper argues that the post-Bougainville period has led to a change of the old enclave model of mining development to a broad based community driven form of development around mining. However, it is difficult to predict as to how this model of mining led development in rural PNG will span out in the long run. In the meantime, genuine landowner partnerships with developers and government in the management and operation of mining projects in the country are proving to be a positive outcome for everyone despite some major challenges.     

The role of price expectations and legal uncertainties in ocean mineral,exploration activities

In this paper, a standard exploration activities model is modified and applied to time series, data from deep seabed mining of a group of minerals where the number of patents is used as a proxy, for the level of mineral exploration activities. In addition to the rational expectations model, price, expectations formation for mineral prices is decomposed into trend and cyclical components using the, HP-filter method. Estimated parameters from the supply and cost functions are used to determine the, shadow price of the minerals. The non-linear instrumental variables estimator is employed to estimate, the exploration activities function. While the rational expectations model shows the importance of, current prices on exploration efforts, the HP-filter model suggests that firms concentrate on the trend, in prices rather than the short-run cyclical fluctuations. Also, while the U.S. refusal to ratify the LOSC, has increased the legal uncertainties surrounding the management of ocean resources and reduced the, incentive to engage in exploration activities, the passage of the ISA's main legislative accomplishment, regarding regulation of the explorations for polymetallic nodules appear to have made a positive effect.     

Long memory and chaotic models of prices on the London Metal Exchange

Many financial time series exhibit irregular behaviour. Economic theory suggests that this irregular behaviour might be due to the existence of nonlinear dependence in the markets. Thus, economic time series are governed by nonlinear dynamics.The purpose of this paper is to investigate price behaviour in the London Metal Exchange market. Thus, this study will test the two most attractive nonlinear models—long memory and chaos—on six metal commodities to ascertain which model is consistent with the observed metal price nonlinear dynamics.Application of long memory and chaos analysis provides new approaches for assessing the behaviour of metal prices. We identified, in tin, a case of chaos. Our empirical results in the case of aluminium support the long memory hypothesis. A short memory model explains the underlying processes of the nickel and lead returns series, while zinc returns reflect an anti-persistent process. To our knowledge, this is one of the first attempts to apply long memory and chaos analysis in the evaluation of the behaviour of metal prices.     

水体重金属污染治理技术研究进展

随着工业的发展和人口的不断增加,重金属废水排放量增加。有毒重金属对环境的严重威胁正逐渐成为全球性问题,不仅对环境造成危害,还威胁着人类的健康。介绍了水体重金属污染现状及危害,综述了目前国内外治理水体重金属污染主要技术的研究进展,指出了微生物治理重金属污染水体的良好应用前景。     

Price and volatility transmission between primary and scrap metal markets

The relationship between primary and scrap prices has been hypothesized for the most part as unidirectional, characterized by spillovers from primary to scrap prices. The purpose of this study is to evaluate empirically the dynamic interactions between primary and scrap metal prices through multivariate time series methods. In addition, the study expands the investigation at the level of volatility transmission, which has not been previously examined. The metal prices utilized are for copper, lead, and zinc for the period 1984–2001. The paper demonstrates differing long run and short run links. Scrap prices do not improve the long run interpretation of primary prices, but information flows from the scrap to the primary markets exist in the short run. Additionally, the copper and lead markets exhibit bidirectional information flows in terms of volatility transmission. The analysis provides valuable insight into the interactions of the primary and scrap metal sectors which can be used to improve forecasting and planning.     

Changing patterns in aluminium production costs

The average cost of producing aluminium fell slightly in nominal terms between 1982 and 1992, and there has thus been a sharp fall in real terms. The average cost also shows a marked cyclical fluctuation during individual years, partly as a result of the feedback effect from final metal prices to the cost curve. Between 1985 and 1992, exchange rate fluctuations produced a sharp change in the relative position of US and European smelters. During the next eight years, costs are likely to rise gradually in real terms, reversing the historical trend, and unless the higher cost European smelters can cut costs significantly, they may face a bleak future.