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1.
Livestock slurry storages are sources of methane (CH?), nitrous oxide (NO?), and ammonia (NH?) emissions. Total solids (TS) content is an indicator of substrate availability for CH? and N?O production and NH? emissions and is related to crust formation, which can affect these gas emissions. The effect of TS on these emissions from pilot-scale slurry storages was quantified from 20 May through 16 Nov. 2010 in Nova Scotia, Canada. Emissions from six dairy slurries with TS ranging from 0.3 to 9.5% were continuously measured using flow-through steady-state chambers. Methane emissions modeled using the USEPA methodology were compared with measured data focusing on emissions when empty storages were filled, and retention times were >30 d with undegraded volatile solids (VS) remaining in the system considered available for CH? production (VS carry-over). Surface crusts formed on all the slurries. Only the slurries with TS of 3.2 and 5.8% were covered completely for ~3 mo. Nitrous oxide contributed <5% of total greenhouse gas emissions for all TS levels. Ammonia and CH? emissions increased linearly with TS despite variable crusting, suggesting substrate availability for gas production was more important than crust formation in regulating emissions over long-term storage. Modeled CH? emissions were substantially higher than measured data in the first month, and accounting for this could improve overall model performance. Carried-over VS were a CH? source in months 2 through 6. The results of this study suggest that substrate availability regulates emissions over long-term storage and that modifying the USEPA model to better describe carbon cycling is warranted.  相似文献   

2.
Floating, organic crusts on liquid manure, stored as a result of animal production, reduce emission of ammonia (NH3) and other volatile compounds during storage. The occurrence of NO2- and NO3- in the crusts indicate the presence of actively metabolizing NH3-oxidizing bacteria (AOB) which may be partly responsible for this mitigation effect. Six manure tanks with organic covers (straw and natural) were surveyed to investigate the prevalence and potential activity ofAOB and its dependence on the O2 availability in the crust matrix as studied by electrochemical profiling. Oxygen penetration varied from <1 mm in young, poorly developed natural crusts and old straw crusts, to several centimeters in the old natural crusts. The AOB were ubiquitously present in all crusts investigated, but nitrifying activity could only be detected in old natural crusts and young straw crust with high O2 availability. In old natural crusts, total potential NH3 oxidation rates were similar to reported fluxes of NH3 from slurry without surface crust. These results indicate that old, natural surface crusts may develop into a porous matrix with high O2 availability that harbors an active population of aerobic microorganisms, including AOB. The microbial activity may thus contribute to a considerable reduction of ammonia emissions from slurry tanks with well-developed crusts.  相似文献   

3.
Anaerobic digestion of source-separated municipal organic waste is considered feasible in Denmark. The limited hydraulic retention in the biogas reactor (typically 15 d) does not allow full degradation of the organic waste. Storage of anaerobically digested municipal organic waste can therefore be a source of methane (CH4) emission that may contribute significantly to the potential global warming impact from the waste treatment system. This study provides a model for quantifying the CH4 production from stored co-digested municipal organic waste and estimates the production under typical Danish climatic conditions, thus quantifying the potential global warming impact from storage of the digested municipal organic waste before its use on agricultural land. Laboratory batch tests on CH4 production as well as temperature measurements in eight full-scale storage tanks provided data for developing a model estimating the CH4 production in storage tanks containing digested municipal organic waste. The temperatures measured in separate storage tanks on farms receiving digested slurry were linearly correlated with air temperature. In storage tanks receiving slurry directly from biogas reactors, significantly higher temperatures were measured due to the high temperatures of the effluent from the reactor. Storage tanks on Danish farms are typically emptied in April and have a constant inflow of digested material. During the warmest months the content of digested material is therefore low, which limits the yearly CH4 production from storage.  相似文献   

4.
Slurry acidification before storage is known to reduce NH(3) emissions, but recent observations have indicated that CH(4) emissions are also reduced. We investigated the evolution of CH(4) from fresh and aged cattle slurry during 3 mo of storage as influenced by pH adjustment to 5.5 with sulfuric acid. In a third storage experiment, cattle slurry acidified with commercial equipment on two farms was incubated. In the manipulation experiments, effects of acid and sulfate were distinguished by adding hydrochloric acid and potassium sulfate separately or in combination, rather than sulfuric acid. In one experiment sulfur was also added to slurry as the amino acid methionine in separate treatments. In each treatment 20-kg portions of slurry (n = 4) were stored for 95 d. All samples were subsampled nine to 10 times for determination of NH(3) and CH(4) evolution rates using a 2-L flow-through system. In all experiments, the pH of acidified cattle slurry increased gradually to between 6.5 and 7. Acidification of slurry reduced the evolution of CH(4) by 67 to 87%. The greatest reduction was observed with aged cattle slurry, which had a much higher potential for CH(4) production than fresh slurry. Sulfate and methionine amendment to cattle slurry without pH adjustment also significantly inhibited methanogenesis, probably as a result of sulfide production. The study suggests that complex microbial interactions involving sulfur transformations and pH determine the potential for CH(4) emission during storage of cattle slurry, and that slurry acidification may be a cost-effective greenhouse gas mitigation option.  相似文献   

5.
Storage of cattle slurry leads to emissions of methane (CH(4)), nitrous oxide (N(2)O), ammonia (NH(3)), and carbon dioxide (CO(2)). On dairy farms, winter is the most critical period in terms of slurry storage due to cattle housing and slurry field application prohibition. Slurry treatment by separation results in reduced slurry dry matter content and has considerable potential to reduce gaseous emissions. Therefore, the efficiency of slurry separation in reducing gaseous emissions during winter storage was investigated in a laboratory study. Four slurry fractions were obtained: a solid and a liquid fraction by screw press separation (SPS) and a supernatant and a sediment fraction by chemically enhanced settling of the liquid fraction. Untreated slurry and the separated fractions were stored in plastic barrels for 48 d under winter conditions, and gaseous emissions were measured. Screw press separation resulted in an increase of CO(2) (650%) and N(2)O (1240%) emissions due to high releases observed from the solid fraction, but this increase was tempered by using the combined separation process (CSP). The CSP resulted in a reduction of CH(4) emissions ( approximately 50%), even though high emissions of CH(4) (46% of soluble C) were observed from the solid fraction during the first 6 d of storage. Screw press separation increased NH(3) emissions by 35%, but this was reduced to 15% using the CSP. During winter storage greenhouse gas emissions from all treatments were mainly in the form of CH(4) and were reduced by 30 and 40% using SPS and CSP, respectively.  相似文献   

6.
A sink for atmospheric methane (CH4) is microbial oxidation in soils. We report CH4 oxidation rates in freely and poorly drained soils on an intensively managed dairy farm. Following cattle urine application to half the plots (650 kg of nitrogen [N] ha(-1)) 31 chamber measurements were made over 100 d during autumn and winter. In the control plots, the freely and poorly drained soils' integrated CH4 oxidation rates averaged 1.8+/-0.2 and 0.6+/-0.1 kg CH4 ha(-1) yr(-1), respectively. In the poorly drained soil, the highest CH4 oxidation rates occurred when water-filled pore space (WFPS)<56% and CH4 oxidation rate declined by ninefold to near zero as WFPS increased from 56 to 68%. Urine application induced the freely and poorly drained soils' CH4 oxidation rates to decline for up to 2 mo by 0.7+/-0.2 and 0.4+/-0.1 kg CH4 ha(-1) yr(-1), respectively. The two soils' responses were thus not significantly different. After urine application, soil pore space CH4 concentration profiles suggested a simultaneous inhibition of bacteria that were CH4 oxidizers and stimulation of CH4 producers.  相似文献   

7.
Acidification of slurry with sulfuric acid is a recent agricultural practice that may serve a double purpose: reducing ammonia emission and ensuring crop sulfur sufficiency. We investigated S transformations in untreated and acidified pig slurry stored for up to 11 mo at 2, 10, or 20 degrees C. Furthermore, the fertilizer efficiency of sulfuric acid in acidified slurry was investigated in a pot experiment with spring barley. The sulfate content from acidification with sulfuric acid was relatively stable and even after 11 mo of storage the majority was in the plant-available sulfate form. Microbial sulfate reduction during storage of acidified pig slurry was limited, presumably due to initial pH effects and a limitation in the availability of easily degradable organic matter. Sulfide accumulation was observed during storage but the sulfide levels in acidified slurry did not exceed those of the untreated slurry for several months after addition. The S fertilizer value of the acidified slurry was considerable as a result of the stable sulfate pool during storage. The high content of inorganic S in the acidified slurry may potentially lead to development of odorous volatile sulfur-containing compounds and investigations are needed into the relationship between odor development and the C and S composition of the slurry.  相似文献   

8.
The release of methane (CH4) from landfills to the atmosphere and the oxidation of CH4 in the cover soils were quantified with static chambers and a 13C-isotope technique on two landfills in Sweden. One of the landfills had been closed and covered 17 years before this investigation while the other was recently covered. On both landfills, the tops of the landfills were compared with the sloping parts in the summer and winter. Emitted CH4, captured in chambers, was significantly enriched in 13C during summer compared with winter (P < 0.0001), and was enriched relative to anaerobic-zone methane. The difference between emitted and anaerobic zone delta 13C-CH4 was used to estimate soil methane oxidation. In summer, these differences ranged from 9 to 26@1000, and CH4 oxidation was estimated to be between 41 and 50% of the produced CH4 in the new landfill, and between 60 and 94% in the old landfill. In winter, when soil temperature was below 0 degree C, no difference in delta 13C was observed between emitted and anaerobic-zone CH4, suggesting that there was no soil oxidation. The temperature effect shown in this experiment suggests that there may be both seasonal and latitudinal differences in the importance of landfill CH4 oxidation. Finally the isotopic fractionation factor (alpha) varied from 1.023 to 1.038 and was temperature dependent, increasing at colder temperatures. Methanotrophic bacteria appeared to have high growth efficiencies and the majority of the methane consumed in incubations did not result in immediate CO2 production.  相似文献   

9.
The recent growth in the size of dairy cattle farms and the concentration of farms into smaller areas in Finland may increase local water pollution due to increased manure production and slurry application to grass. Therefore, a field study was conducted to monitor losses of total phosphorus (TP), dissolved reactive phosphorus (DRP), and fecal microorganisms in surface runoff from a perennial ley. Cattle slurry was added once a year in June 1996-1997 (Study I) and biannually in June and October 1998-2000 (Study II). The slurry was surface broadcast or injected into the clay soil. The field had a slope of 0.9 to 1.7%. Mineral fertilizer was applied on control plots. Biannual slurry broadcasting increased DRP (p < 0.001) and TP losses (p < 0.001) and numbers of fecal microorganisms in surface runoff waters. The highest losses of TP (2.7 kg ha(-1) yr(-1)) and DRP (2.2 kg ha(-1) yr(-1)) and the highest numbers of fecal coliforms (880 colony-forming units [CFU] per 100 mL) and somatic coliphages (2700 plaque-forming units [PFU] per 100 mL) were measured after broadcasting slurry to wet soil followed by rainfall in fall 1998. Injection reduced the TP and DRP losses in surface runoff by 79 and 86%, respectively, compared with broadcasting (17 Oct. 1998-27 Oct. 1999). Corresponding numbers for fecal coliforms were 350 CFU (100 mL)(-1) and for somatic coliphages were 110 PFU (100 mL)(-1) in surface runoff after injection in October 1998. Slurry injection should be favored when spreading slurry amendments to grassland to avoid losses of P and fecal microorganisms in runoff to surface waters.  相似文献   

10.
Methane (CH4) oxidation is the only known biological sink process for mitigating atmospheric and terrestrial emissions of CH4, a major greenhouse gas. Methane oxidation in an alluvial soil planted to rice (Oryza sativa L.) under long-term application of organic (compost with a C/N ratio of 21.71), and mineral fertilizers was measured in a field-cum-laboratory incubation study. Oxidation rates were quantified in terms of decrease in the concentration of CH4 in the headspace of incubation vessels and expressed as half-life (t(1)2) values. Methane oxidation rates significantly differed among the treatments and growth stages of the rice crop. Methane oxidation rates were high at the maximum tillering and maturity stages, whereas they were low at grain-filling stage. Methane oxidation was low (t(1)2) = 15.76 d) when provided with low concentration of CH4. On the contrary, high concentration of CH4 resulted in faster oxidation (t(1)2) = 6.67 d), suggesting the predominance of "low affinity oxidation" in rice fields. Methane oxidation was stimulated following the application of mineral fertilizers or compost implicating nutrient limitation as one of the factors affecting the process. Combined application of compost and mineral fertilizer, however, inhibited CH4 oxidation probably due to N immobilization by the added compost. The positive effect of mineral fertilizer on CH4 oxidation rate was evident only at high CH4 concentration (t(1)2 = 4.80 d), while at low CH4 concentration their was considerable suppression (t(1) = 17.60 d). Further research may reveal that long-term application of fertilizers, organic or inorganic, may not inhibit CH4 oxidation.  相似文献   

11.
There is a need to evaluate the interference of pig slurry rate and the terrain slope in the chemical elements losses from the soil. This work aimed to quantify water and chemical element losses by surface runoff due to terrain slope and pig slurry rate (PS) in two soils with contrasting textures. Two trials were evaluated in 2018 and 2019 in Cambisol and Nitisol. Rates of 0, 22.5, 45, and 90 m3 ha−1 yr−1 of PS were applied superficially in sites with slopes ranging from 10% to 35%. Perennial forage grass Tifton 85 (Cynodon dactylon) was grown as summer crop and ryegrass (Lolium multiflorum) was sown in the cold seasons in a field environment. Were determined the runoff, the volume of water, and chemical elements (Al, Ca, P, Mg, Cd, Cr, Cu, Mn, Fe, Pb, and Zn) lost by the surface runoff after natural rainfall. Increasing land slope elevated water losses substantially, on average 23.4 times in Cambisol and 10.8 times in Nitisol. This increase resulted in average increases of 27.6 and 12.4 times in the losses of the chemical elements analyzed for Cambisol and Nitisol, respectively. There was a reduction in water losses by surface runoff due to increased PS rates applied in both sites. The increased PS rate affected the losses of Cr and Cu in Cambisol and P, Mg, Cd, and Cu in Nitisol. The clayey soil potentiated the water and chemical elements losses by surface runoff in relation to the soil with lower clay content. Regardless of the soil, water and chemical element losses are maximized at higher slopes.  相似文献   

12.
Establishing a treatment process for practical and economic disposal of laboratory wastewaters has become an urgent environmental concern of the Department of Chemical Engineering of the Universidade Estadual de Maringá (State University of Maringá), Brazil. Fenton and related reactions are potentially useful oxidation processes for destroying toxic organic compounds in water. In these reactions, hydrogen peroxide is combined with ferrous or ferric iron in the presence or absence of light to generate hydroxyl radicals (.OH). The feasibility of Fenton's reagent to treat waste chemicals from an academic research laboratory was investigated in this study. A response surface methodology was applied to optimize the Fenton oxidation process conditions using chemical oxygen demand (COD) removal as the target parameter to optimize, and the reagent concentrations, as related to the initial concentration of organic matter in the effluent, and pH as the control factors to be optimized. Maximal COD removal (92.3%) was achieved when wastewater samples were treated at pH 4 in the presence of hydrogen peroxide and iron in the ratios [COD]:[H2O2]=1:9 and [H2O2]:[Fe2+]=4.5:1. Under these conditions, it was possible to obtain simultaneously maximal COD removal and minimal chemical sludge after treatment, which is a residue that needs further processing.  相似文献   

13.
Cap rock failure assessment, either tensile fracturing or shear slip reactivation of pre-existing fault, is a key issue for preventing CO2 leakage from deep aquifer reservoirs up to the surface. For an appropriate use in risk management, the uncertainties associated with such studies should be investigated. Nevertheless, uncertainty analysis requires multiple simulations and a direct use of conventional numerical approaches might be too computer time consuming. An alternative is to use conventional analytical models, but their assumptions appear to be too conservative. An intermediate approach is then proposed based on the response surface methodology, consisting in estimating the effective stress state after CO2 injection as a linear combination of the most influential site properties based on a limited number of numerical simulations. The decision maker is provided with three levels of information: (1) the identification of the most important site properties; (2) an analytical model for a quick assessment of the maximal sustainable overpressure and (3) a simplified model to be used in a computationally intensive uncertainty analysis framework. This generic methodology is illustrated with the Paris Basin case using a large-scale hydromechanical model to assess cap rock failure in the injector zone.  相似文献   

14.
用盐酸溶解氯化镁样品,以抗坏血酸和焦磷酸钠共同作掩蔽剂,在酸性介质中用二安替比林甲烷分光光度法测定氯化镁中钛的含量,给出了合理的实验条件.  相似文献   

15.
Within the framework of an interregional project in the Emilia Romagna region of northern Italy, the coupled MACRO-SOILN model was chosen to estimate soil protective capacity against pollutants. The aim of our study was to evaluate the model to better identify key parameters and processes that influence N losses in agricultural soils. Nitrate N content was monitored in soil under corn (Zea mays L.) fertilized with urea and/or pig slurry, in two field experiments performed on four different soils: a Fienili clay, a Barco-like silt, a Sant'Omobono silt loam, and a La Boaria silty clay soil. Measurements were compared with model predictions. For all soils, nitrate content was underestimated on average by 24 to 88% at lower N rates; it was overestimated by 1 to 104% at higher N rates. The root mean square error (RMSE) was equal to 81.1%. Simulation of crop N uptake and soil water flow, estimation of the ammonia losses at pig slurry spreading, and N transformation parameter setting were considered as possible error sources. The calibration of crop N uptake gave rise to good model efficiency index values. The RMSE for the simulation of soil water content varied between 9.8 and 20.2%. A more accurate setting of the ammonia losses and of the feces transformation parameter values could allow the RMSE for the simulation of soil nitrate content to be reduced by no more than 10 to 15%. It is possible for the model not to include the simulation of processes that could have relevant effects on the soil N dynamics.  相似文献   

16.
The explosive 2,4,6-trinitrotoluene (TNT) is a contaminant of soils and ground waters worldwide. To help alleviate such environmental contamination, we investigated a coupled abiotic-biotic treatment scheme for remediating TNT-contaminated soil in slurry solutions. Two types of soil were used (sandy and silt loam) to simulate different soils that might be found at actual sites. These soils were subsequently contaminated with 5000 mg kg(-1) TNT. Mineralization of TNT was initially optimized for minimum reactant use (Fe(3+) and H(2)O(2)) and maximum soil slurry percentage (percent solids) using modified Fenton reactions conducted in the absence of light followed by the addition of an uncharacterized aerobic biomass. Greater than 97% TNT degradation was observed under optimum reaction conditions for both soils. Using two optimum reactant concentrations for each soil, coupled abiotic-biotic reactions showed an increase in TNT mineralization, from 41 to 73% and 34 to 64% in the sandy soil (10 and 20% slurry, respectively, 1470 mM H(2)O(2)), and increases from 12 to 23% and 13 to 28% in the silt loam soil (5% slurry, 294 and 1470 mM H(2)O(2), respectively). These results show promise in the use of combined abiotic-biotic treatment processes for soils contaminated with high concentrations of TNT.  相似文献   

17.
Estimating and analyzing the temporal and spatial patterns of methane emissions from agriculture (MEA) will help China formulate mitigation and adaptation strategies for the nation’s agricultural sector. Based on the Tier 2 method presented in the 2006 guidelines of the Intergovernmental Panel on Climate Change (IPCC) and on existing reports, this article presents a systematic estimation of MEA in China from 1990 to 2006, with a particular emphasis on trends and spatial distribution. Results from our study indicate that China’s MEA rose from 16.37 Tg yr−1 in 1990 to 19.31 Tg yr−1 in 2006, with an average annual increase of 1.04%. Over the study period, while emissions from field burning of crop residues remained rather low, those from rice cultivation and from livestock typically decreased and increased, respectively, showing extremely opposite trends that chiefly resulted from changes in the cultivated areas for different rice seasons and changes in the populations of different animal species. Over the study period, China’s high-MEA regions shifted generally northward, chiefly as a result of reduced emissions from rice cultivation in most of China’s southern provinces and a substantial growth in emissions from livestock enteric fermentation in most of China’s northern, northeastern, and northwestern provinces. While this article provides significant information on estimates of MEA in China, it also includes some uncertainties in terms of estimating emissions from each source category. We conclude that China’s MEA will likely continue to increase in the future and recommend a demonstration study on MEA mitigation along the middle and lower reaches of the Yellow River. We further recommend enhanced data monitoring and statistical analysis, which will be essential for preparation of the national greenhouse gas (GHG) inventory.  相似文献   

18.
Computer models help identify agricultural areas where P transport potential is high, but commonly used models do not simulate surface application of manures and P transport from manures to runoff. As part of an effort to model such P transport, we conducted manure slurry separation and soil infiltration experiments to determine how much slurry P infiltrates into soil after application but before rain, thus becoming less available to runoff. We applied dairy and swine slurry to soil columns and after both 24 and 96 h analyzed solids remaining on the soil surface for dry matter, total phosphorus (TP), and water-extractable inorganic (WEIP) and organic (WEOP) phosphorus. We analyzed underlying soils for Mehlich-3 and water-extractable P. We also conducted slurry separation experiments by sieving, centrifuging, and suction-filtering to determine which method could easily estimate slurry P infiltration into soils. About 20% of slurry solids and 40 to 65% of slurry TP and WEIP infiltrated into soil after application, rendering this P less available to transport in runoff. Slurry separation by suction-filtering through a screen with 0.75-mm-diameter openings was the best method to estimate this slurry P infiltration. Measured quantities of manure WEOP changed too much during experiments to estimate WEOP infiltration into soil or what separation method can approximate infiltration. Applying slurries to soils always increased soil P in the top 0 to 1 cm of soil, frequently in the 1- to 2-cm depth of soil, but rarely below 2 cm. Future research should use soils with coarser texture or large macropores, and slurry with low dry matter content (1-2%).  相似文献   

19.
Land application of animal manures, such as pig slurry (PS), is a common practice in intensive-farming agriculture. However, this practice has a pitfall consisting of the loss of nutrients, in particular nitrate, toward water courses. The objective of this study was to evaluate nitrate leaching for three application rates of pig slurry (50, 100, and 200 Mg ha(-1)) and a control treatment of mineral fertilizer (275 kg N ha(-1)) applied to corn grown in 10 drainage lysimeters. The effects of two irrigation regimes (low vs. high irrigation efficiency) were also analyzed. In the first two irrigation events, drainage NO(3)-N concentrations as high as 145 and 69 mg L(-1) were measured in the high and moderate PS rate treatments, respectively, in the low irrigation efficiency treatments. This indicates the fast transformation of the PS ammonium into nitrate and the subsequent leaching of the transformed nitrate. Drainage NO(3)-N concentration and load increased linearly by 0.69 mg NO(3)-N L(-1) and 4.6 kg NO(3)-N ha(-1), respectively, for each 10 kg N ha(-1) applied over the minimum of 275 kg N ha(-1). An increase in irrigation efficiency did not induce a significant increase of leachate concentration and the amount of nitrate leached decreased about 65%. Application of low PS doses before sowing complemented with sidedressing N application and a good irrigation management are the key factors to reduce nitrate contamination of water courses.  相似文献   

20.
Ammonia (NH3) volatilization commonly causes a substantial loss of crop-available N from surface-applied cattle slurry. Field studies were conducted with small wind tunnels to assess the effect of management factors on NH3 volatilization. Two studies compared NH3 volatilization from grass sward and bare soil. The average total NH3 loss was 1.5 times greater from slurry applied to grass sward. Two studies examined the effect of slurry dry matter (DM) content on NH3 loss under hot, summer conditions in Maryland, USA. Slurry DM contents were between 54 and 134 g kg(-1). Dry matter content did not affect total NH3 loss, but did influence the time course of NH3 loss. Higher DM content slurries had relatively higher rates of NH3 volatilization during the first 12 to 24 h, but lower rates thereafter. Under the hot conditions, the higher DM content slurries appeared to dry and crust more rapidly causing smaller rates of NH3 volatilization after 12 to 24 h, which offset the earlier positive effects of DM content on NH3 volatilization. Three studies compared immediate incorporation with different tillage implements. Total NH3 loss from unincorporated slurry was 45% of applied slurry NH4+-N, while losses following immediate incorporation with a moldboard plow, tandem-disk harrow, or chisel plow were, respectively, 0 to 3, 2 to 8, and 8 to 12%. These ground cover and DM content data can be used to improve predictions of NH3 loss under specific farming conditions. The immediate incorporation data demonstrate management practices that can reduce NH3 volatilization, which can improve slurry N utilization in crop-forage production.  相似文献   

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