Modelling flow to leachate wells in landfills

Vertical wells are frequently used as a means of controlling leachate levels in landfills. They are often the only available dewatering option for both old landfills without any basal leachate collection layer and for newer sites where the installed drainage infrastructure has failed. When the well is pumped, a seepage face develops at the entry into the well so that the drawdown in the surrounding waste will not be as great as might be expected. The numerical groundwater flow model MODFLOW-SURFACT, which contains the functionality to model seepage surfaces, has been used to investigate the transient dewatering of a landfill. The study concludes that the position of the seepage face and information about the characteristics of the induced seepage flow field are important and should not be neglected when designing wells in landfills.     

Practice review of five bioreactor/recirculation landfills

Five landfills were analyzed to provide a perspective of current practice and technical issues that differentiate bioreactor and recirculation landfills in North America from conventional landfills. The bioreactor and recirculation landfills were found to function in much the same manner as conventional landfills, with designs similar to established standards for waste containment facilities. Leachate generation rates, leachate depths and temperatures, and liner temperatures were similar for landfills operated in a bioreactor/recirculation or conventional mode. Gas production data indicate accelerated waste decomposition from leachate recirculation at one landfill. Ambiguities in gas production data precluded a definitive conclusion that leachate recirculation accelerated waste decomposition at the four other landfills. Analysis of leachate quality data showed that bioreactor and recirculation landfills generally produce stronger leachate than conventional landfills during the first two to three years of recirculation. Thereafter, leachate from conventional and bioreactor landfills is similar, at least in terms of conventional indicator variables (BOD, COD, pH). While the BOD and COD decreased, the pH remained around neutral and ammonia concentrations remained elevated. Settlement data collected from two of the landfills indicate that settlements are larger and occur much faster in landfills operated as bioreactors or with leachate recirculation. The analysis also indicated that more detailed data collection over longer time periods is needed to draw definitive conclusions regarding the effects of bioreactor and recirculation operations. For each of the sites in this study, some of the analyses were limited by sparseness or ambiguity in the data sets.     

FULL-SCALE EXPERIENCES WITH LEACHATE RECIRCULATING LANDFILLS: CASE STUDIES

Leachate recirculation has been shown in lysimeter, pilot-scale and full-scale investigations to reduce the time required for waste stabilization, improve leachate quality, provide the opportunity for leachate volume reduction, and to enhance the rate of gas production. New generation full-scale landfills are implementing recirculation as a leachate management tool with increasing frequency. Leachate recirculation techniques used at full-scale landfills include pre-wetting of waste, leachate spraying, surface ponds, vertical injection wells and horizontal introduction systems. From observations of operating full-scale recirculating landfills, it appears to be important to provide flexibility in design, minimize low permeability daily and intermediate cover, include adequateex situstorage volume, control infiltration into the landfill, and utilize waste moisture holding capacity efficiently.     

Leachate injection using vertical wells in bioreactor landfills

Leachate recirculation or liquid injection in municipal solid waste landfills offers economic and environmental benefits. The key objective of this study was to carry out numerical evaluation of key design variables for leachate recirculation system consisting of vertical wells. In order to achieve the objective, numerical modeling was carried out using the finite-element model HYDRUS-2D. The following design parameters were evaluated by simulating liquid pressure head on the liner and the wetted width of the waste under steady-state flow conditions: (1) hydraulic conductivities of the waste and vertical well backfill; (2) liquid injection rate and dosing frequency; (3) well diameter, screen height and screen depth; and (4) hydraulic conductivity of the leachate collection system, slope of the leachate collection system and spacing of the leachate collection pipes. The key findings of this study are as follows. The well diameter, hydraulic conductivity of the well drainage pack, and screen height and screen depth of the well have very little effect on the wetted width for a given liquid flux. The wetted width and the injection pressure for a given liquid flux decrease with the increase in the hydraulic conductivity of the waste. The pressure head on the liner increases with the decrease in the vertical distance between the bottom of the well screen and the top of leachate collection system. The liquid injection flux increases with the decrease in hydraulic conductivity of the leachate collection system. Unlike sand (k approximately 10(-4)m/s), pea gravel (k approximately 0.01 m/s) resulted in less than 0.3m pressure head on the liner for all simulations carried out in this study.     

Indirect measurements of field-scale hydraulic conductivity of waste from two landfill sites

Management and prediction of the movement and distribution of fluids in large landfills is important for various reasons. Bioreactor landfill technology shows promise, but in arid or semi-arid regions, the natural content of landfilled waste may be low, thus requiring addition of significant volumes of water. In more humid locations, landfills can become saturated, flooding gas collection systems and causing sideslope leachate seeps or other undesirable occurrences. This paper compares results from two different approaches to monitoring water in waste. At the Brock West Landfill in eastern Canada, positive pore pressures were measured at various depths in saturated waste. The downward seepage flux through the waste is known, thus the vertical saturated hydraulic conductivity of the waste at this landfill was determined to be 3 × 10(-7)cm/s. By comparison, the Spadina Landfill in western Canada is predominantly unsaturated. The infiltration of moisture into the waste was measured using moisture sensors installed in boreholes which determined arrival time for moisture fronts resulting from major precipitation events as well as longer-term change in moisture content resulting from unsaturated drainage during winter when frozen ground prevented infiltration. The unsaturated hydraulic conductivity calculated from these data ranged from approximately 10(-6)cm/s for the slow winter drainage in the absence of significant recharge to 10(-2)cm/s or higher for shallow waste subject to high infiltration through apparent preferential pathways. These two very different approaches to field-scale measurements of vertical hydraulic conductivity provide insight into the nature of fluid movement in saturated and unsaturated waste masses. It is suggested that the principles of unsaturated seepage apply reasonably well for landfilled waste and that the hydraulic behavior of waste is profoundly influenced by the nature and size of voids and by the degree of saturation prevailing in the landfill.     

Probabilistic approach for estimating the release of contaminants under field management scenarios

A probabilistic approach is presented for estimating the release of contaminants by leaching, when wastes are being considered for disposal in a class of landfills but the specific landfill disposal site is uncertain. A simple percolation and equilibrium-based release model is used in conjunction with laboratory testing results and observations of field leachate characteristics for municipal solid waste landfills, hazardous waste landfills and industrial co-disposal landfills. The approach is applied for assessing the efficacy of potential treatment processes for mercury contaminated soils. For each landfill scenario, historical values of leachate pH and annual leachate generation quantities were used to derive the probability distribution functions of the field pH and LS ratio that may be expected to contact the disposed material over an estimated time period of 100 years. For each potential treatment process, laboratory testing was used to establish the treated material's leaching characteristics as a function of pH LS ratio. This approach allowed determination of distribution frequencies and limit values for release estimates instead of single point estimates. The probability of the mass of a constituent of interest released exceeding a hypothetical threshold was examined for each treatment process and landfill system. Results of the probabilistic analysis allowed for integration of a range of data and provided a good basis for assessing the efficacy of the examined treatment processes over the three assumed disposal scenarios.     

Wet landfill decomposition rate determination using methane yield results for excavated waste samples

An increasing number of landfills are operated to accelerate waste decomposition through liquids addition (e.g., leachate recirculation) as a wet landfill. Landfill design and regulation often depend on utilizing landfill gas production models that require an estimate of a first-order gas generation rate constant, k. Consequently, several studies have estimated k using collected gas volumes from operating wet landfills. Research was conducted to examine an alternative approach in which k is estimated not from collected landfill gas but from solid waste samples collected over time and analyzed for remaining gas yield. To achieve this goal, waste samples were collected from 1990 through 2007 at two full-scale landfills in Florida that practiced liquids addition. Methane yields were measured from waste samples collected over time, including periods before and after leachate recirculation, and the results were applied to a first-order decay model to estimate rate constants for each of the sites. An initial, intensive processing step was conducted to exclude non-biodegradable components from the methane yield testing procedure. The resulting rate constants for the two landfills examined were 0.47 yr(-1) and 0.21 yr(-1). These results expectedly exceeded the United States Environmental Protection Agency's rate constants for dry and conventional landfills (0.02-0.05 yr(-1)), but they are comparable to wet landfill rate constants derived using landfill gas data (0.1-0.3 yr(-1)).     

Hydrologic evaluation of landfill performance (HELP) modeling in bioreactor landfill design and permitting

The practice of operating municipal solid waste landfills as bioreactor landfills has become more common over the past decade. Because simulating moisture balance and flow is more critical in such landfills than in dry landfills, researchers have developed methods to address this problem using the hydrologic evaluation of landfill performance (HELP) model. This paper discusses three methods of applying the HELP model to simulate the percolation of liquids added to landfill waste: the leachate recirculation feature (LRF), the subsurface inflow (SSI) feature, and additional rainfall to mimic liquids addition. The LRF is simple to use but may not be able to bring the landfill to bioreactor conditions. The SSI feature provides a convenient user interface for modeling liquids addition to each layer. The additional rainfall feature provides flexibility to the model, allowing users to estimate the leachate generation rate and the leachate head on bottom liner associated with daily variation in the liquids addition rate. Additionally, this paper discusses several issues that may affect the HELP model, such as the time of model simulation, layers of liquids addition, and the limitations of the HELP model itself. Based on the simulation results, it is suggested that the HELP model should be run over an extended period of time after the cessation of liquids addition in order to capture the peak leachate generation rate and the head on the liner (HOL). From the perspectives of leachate generation and the HOL, there are few differences between single-layer injection and multiple-layer injection. This paper also discusses the limitations of using the HELP model for designing and permitting bioreactor landfills.     

Pollutant release and pollutant reduction--impact of the aeration of landfills

The in situ stabilization of old deposits aims for a lasting and controlled reduction of pollutant emissions from the deposited waste in order to diminish expenditure and the duration of landfill aftercare measures. The stabilization operation so far, observed over a period of 1-2 years at three landfills in Germany, shows that leachate contamination is permanently reduced, biodegradation processes are significantly accelerated and main settlements take place within a short period of time.     

LCA and economic evaluation of landfill leachate and gas technologies

Landfills receiving a mix of waste, including organics, have developed dramatically over the last 3-4 decades; from open dumps to engineered facilities with extensive controls on leachate and gas. The conventional municipal landfill will in most climates produce a highly contaminated leachate and a significant amount of landfill gas. Leachate controls may include bottom liners and leachate collection systems as well as leachate treatment prior to discharge to surface water. Gas controls may include oxidizing top covers, gas collection systems with flares or gas utilization systems for production of electricity and heat.The importance of leachate and gas control measures in reducing the overall environmental impact from a conventional landfill was assessed by life-cycle-assessment (LCA). The direct cost for the measures were also estimated providing a basis for assessing which measures are the most cost-effective in reducing the impact from a conventional landfill. This was done by modeling landfills ranging from a simple open dump to highly engineered conventional landfills with energy recovery in form of heat or electricity. The modeling was done in the waste LCA model EASEWASTE. The results showed drastic improvements for most impact categories. Global warming went from an impact of 0.1 person equivalent (PE) for the dump to −0.05 PE for the best design. Similar improvements were found for photochemical ozone formation (0.02 PE to 0.002 PE) and stratospheric ozone formation (0.04 PE to 0.001 PE).For the toxic and spoiled groundwater impact categories the trend is not as clear. The reason for this was that the load to the environment shifted as more technologies were used. For the dump landfill the main impacts were impacts for spoiled groundwater due to lack of leachate collection, 2.3 PE down to 0.4 PE when leachate is collected. However, at the same time, leachate collection causes a slight increase in eco-toxicity and human toxicity via water (0.007E to 0.013PE and 0.002 to 0.003 PE respectively). The reason for this is that even if the leachate is treated, slight amounts of contaminants are released through emissions of treated wastewater to surface waters.The largest environmental improvement with regard to the direct cost of the landfill was the capping and leachate treatment system. The capping, though very cheap to establish, gave a huge benefit in lowered impacts, the leachate collection system though expensive gave large benefits as well. The other gas measures were found to give further improvements, for a minor increase in cost.     

Changes in carbon and nitrogen pool during in-situ aeration of old landfills under varying conditions

Emissions from old landfills via leachate and the gas phase are influenced by state and stability of the organic matter in the solid waste and by environmental conditions within the landfill. Remediation of landfills by means of in-situ aeration is one possibility to reduce these emissions. By establishing aerobic conditions, biological processes in the landfill are accelerated. To investigate the effects of this remediation technology, lab-scale experiments with column tests have been carried out. The main goal of the present work is to characterize the changes of the carbon and nitrogen compounds in the aerated solid waste, the leachate and the gas phase under varying conditions. The results demonstrate a clear reduction of emissions and a stabilization of the organic matter. Furthermore, it is shown that both the intensity of aeration and the amount of water affect biological processes to a certain extent. Even when columns were operated under anaerobic conditions after a long running period of aeration, the emissions remained low.     

Sustainable disposal of municipal solid waste: Post bioreactor landfill polishing

Sustainable disposal of municipal solid waste (MSW) requires assurance that contaminant release will be minimized or prevented within a reasonable time frame before the landfill is abandoned so that the risk of contamination release is not passed to future generations. This could be accomplished through waste acceptance criteria such as those established by the European Union (EU) that prohibit land disposal of untreated organic matter. In the EU, mechanical, biological and/or thermal pretreatment of MSW is therefore necessary prior to landfilling which is complicated and costly. In other parts of the world, treatment within highly engineered landfills is under development, known as bioreactor landfills. However, the completed bioreactor landfill still contains material, largely nonbiodegradable carbon and ammonia that may be released to the environment over the long-term. This paper provides a conceptual analysis of an approach to ensure landfill sustainability by the rapid removal of these remaining materials, leachate treatment and recirculation combined with aeration. The analysis in this paper includes a preliminary experimental evaluation using real mature leachate and waste samples, a modeling effort using a simplified mass balance approach and input parameters from real typical bioreactor cases, and a cost estimate for the suggested treatment method.     

Aerobic in situ stabilization of Landfill Konstanz Dorfweiher: Leachate quality after 1 year of operation

Modern landfill understanding points out controlled operation of landfills. Emissions from landfills are caused mainly by anaerobic biodegradation processes which continue for very long time periods after landfill closure. In situ landfill stabilization aims controlled reduction of emissions towards reduced expenditures as well as aftercare measures. Since April 2010, a new in situ stabilization technique is being applied at a pilot scale landfill (BAIV) within Landfill Konstanz Dorfweiher. This new method utilizes intermittent aeration and leachate recirculation for waste stabilization. In this study, influence of this technique on leachate quality is investigated. Among many other parameters, leachate analyses were conducted for COD, BOD₅, NH₄–N, NO₂–N, NO₃–N, TKN and chloride besides continuously on site recorded pH, electrical conductivity and oxidation–reduction potential (ORP). Results from leachate quality analyses showed that biological activity in the landfill was accelerated resulting in initial higher leachate strength and reduced emission potential of landfill. During full scale in situ aeration, ambient conditions differ from optimized laboratory scale conditions which mainly concern temperature increase and deficient aeration of some landfill parts (Ritzkowski and Stegmann, 2005). Thus, as a field application results of this study have major importance on further process optimization and application.     

Numerical modelling of multiphase flow and transport processes in landfills.

Waste material in municipal landfills can be described as heterogeneous porous media, where flow and transport processes of gases and liquids are combined with local material degradation. This paper deals with the basic formulation of a multiphase flow and transport model applicable to the numerical analysis of coupled transport and reaction processes inside landfills. The transport model treats landfills within the framework of continuum mechanics, where flow and transport processes are described on a macroscopic level. The composition of organic and inorganic matter in the solid phase and its degradation are modelled on a microscopic scale. The degradation model captures the different reaction schemes of various microbial activities. Subsequently, transport and reaction processes have to be coupled, since emissions at the surface and from the drainage layer depend on the flow of leachate and gas, the transport of various substances and heat, and the biodegradation of organic matter. The theoretical considerations presented here are fundamental to the development of numerical models for the simulation of multiphase flow and transport processes inside landfills coupled with biochemical reactions and heat generation. The implicit modelling of leachate and gas flows including growth and decay of micro-organisms are innovative contributions to landfill modelling     

Influence of tropical seasonal variations on landfill leachate characteristics--results from lysimeter studies

Considering the quality of design and construction of landfills in developing countries, little information can be derived from randomly taken leachate samples. Leachate generation and composition under monsoon conditions have been studied using lysimeters to simulate sanitary landfills and open cell settings. In this study, lysimeters were filled with domestic waste, highly organic market waste and pre-treated waste. Results over two subsequent dry and rainy seasons indicate that the open cell lysimeter simulation showed the highest leachate generation throughout the rainy season, with leachate flow in all lysimeters coming to a halt during the dry periods. More than 60% of the precipitation was found in the form of leachate. The specific COD and TKN load discharged from the open cell was 20% and 180% more than that of the sanitary landfill lysimeters. Types of waste material and kind of pre-treatment prior to landfilling strongly influenced the pollutant load. Compared to the sanitary landfill lysimeter filled with domestic waste, the specific COD and TKN load discharged from the pre-treated waste lysimeter accounted for only 4% and 16%, respectively. Considering the local settings of tropical landfills, these results suggest that landfill design and operation has to be adjusted. Leachate can be collected and stored during the rainy season, and recirculation of leachate is recommended to maintain a steady and even accelerated degradation during the prolonged dry season. The open cell approach in combination with leachate recirculation is suggested as an option for interim landfill operations.     

Batch tests on mineral deposit formation due to co-mingling of leachates derived from municipal solid wastes and waste-to-energy combustion residues

Deposit formation in leachate collection systems can be problematic for landfill operations. Deposits from municipal solid waste (MSW) derived leachates are impacted by microbial activity and biofilm development, whereas leachates generated from co-disposal of MSW with combustion residues (CR) from waste-to-energy (WTE) facilities and other mineral-rich waste materials are more prone to forming dense mineral deposits dominated by calcium carbonate. In this study, leachates from laboratory lysimeters containing either WTE-CR or shredded MSW were mixed at different volumetric ratios. The mixed leachates were incubated for 5 weeks in batch tests to evaluate the potential for formation of precipitates. Although mineral precipitates have been reported to form in landfills with no co-disposal practices, in this study mineral precipitates did not form in either the WTE-CR derived leachate or the MSW derived leachate, but formed in all leachate mixtures. Mineral precipitates consisted of calcium carbonate particles, with the highest yield from a 1:1 combination of the WTE-CR derived leachate mixed with the MSW derived leachate. The introduction of gaseous carbon dioxide or air into WTE-CR derived leachate resulted in the production of particles of similar chemical composition but different morphology. Operation of landfills to prevent co-mingling of mineral-rich leachates with microbially active leachates and/or to control leachate exposure to sources of carbon dioxide may help to prevent this type of precipitate formation in leachate collection systems.     

Single-walled carbon nanotube behavior in representative mature leachate

Escalating production and subsequent incorporation of engineered nanomaterials in consumer products increases the likelihood of nanomaterials being discarded in landfills. Although direct measurement of particle disposal has not yet occurred, life cycle assessments suggest that over 50% of nanomaterials produced will eventually reside in landfills. Laboratory-scale experiments were conducted to evaluate how organics (humic acid: 20-800 mg/L), ionic strength (100-400 mM NaCl), and pH (6-8) typical of mature leachates influence carbon nanotube surface charge, relative stability, and mobility through representative solid waste environments. Results from the batch experiments suggest that the presence of high molecular weight organics, such as humic acid, acts to stabilize carbon nanotubes present in leachate, even at high ionic strengths (>100 mM NaCl). These results also suggest that in mature landfill leachate, as long as humic acid is present, ionic strength (when represented as NaCl) will be a dominant factor influencing nanomaterial stability. Column experiment results indicate the carbon nanotubes may be mobile through solid waste, suggesting particle placement within landfills needs to be examined more closely.     

CCA-treated wood disposed in landfills and life-cycle trade-offs with waste-to-energy and MSW landfill disposal

Chromated copper arsenate (CCA)-treated wood is a preservative treated wood construction product that grew in use in the 1970s for both residential and industrial applications. Although some countries have banned the use of the product for some applications, others have not, and the product continues to enter the waste stream from construction, demolition and remodeling projects. CCA-treated wood as a solid waste is managed in various ways throughout the world. In the US, CCA-treated wood is disposed primarily within landfills; however some of the wood is combusted in waste-to-energy (WTE) facilities. In other countries, the predominant disposal option for wood, sometimes including CCA-treated wood, is combustion for the production of energy. This paper presents an estimate of the quantity of CCA-treated wood entering the disposal stream in the US, as well as an examination of the trade-offs between landfilling and WTE combustion of CCA-treated wood through a life-cycle assessment and decision support tool (MSW DST). Based upon production statistics, the estimated life span and the phaseout of CCA-treated wood, recent disposal projections estimate the peak US disposal rate to occur in 2008, at 9.7 million m(3). CCA-treated wood, when disposed with construction and demolition (C&D) debris and municipal solid waste (MSW), has been found to increase arsenic and chromium concentrations in leachate. For this reason, and because MSW landfills are lined, MSW landfills have been recommended as a preferred disposal option over unlined C&D debris landfills. Between landfilling and WTE for the same mass of CCA-treated wood, WTE is more expensive (nearly twice the cost), but when operated in accordance with US Environmental Protection Agency (US EPA) regulations, it produces energy and does not emit fossil carbon emissions. If the wood is managed via WTE, less landfill area is required, which could be an influential trade-off in some countries. Although metals are concentrated in the ash in the WTE scenario, the MSW landfill scenario releases a greater amount of arsenic from leachate in a more dilute form. The WTE scenario releases more chromium from the ash on an annual basis. The WTE facility and subsequent ash disposal greatly concentrates the chromium, often oxidizing it to the more toxic and mobile Cr(VI) form. Elevated arsenic and chromium concentrations in the ash leachate may increase leachate management costs.     

Pilot project of mechanical-biological treatment of waste in Brazil

By mechanical-biological treatment (MBT) of residual municipal solid waste the behaviour of landfills can be significantly improved. After MBT the organic content (COD and BOD5), total organic carbon, and total nitrogen in the leachate, as well as the gas production rate, are reduced to values lower than 90% of the fresh untreated waste. The volume of the stabilized material to be disposed on landfills decreases enormously, by up to 70%. The monitoring effort for a landfill constructed under these conditions is reduced to a minimum and the stabilized material can be used in other ways, as material for reforestation, for cover material or for thermal utilization to produce energy. Environmental conditions are important in MBT, as well as waste characteristics. This paper describes the results of a pilot project of MBT performed in Rio de Janeiro, Brazil. The results have shown that this technology can be used successfully in developing countries, with economy for the society and important results for the environment.     

Bioreactor landfills: experimental and field results

Bioreactor landfills allow a more active landfill management that recognizes the biological, chemical and physical processes involved in a landfill environment. This paper presents the results of an experimental study carried out to determine the effect of solid waste size, leachate recirculation and nutrient balance on the rate of municipal solid waste (MSW) biodegradation. Higher rates of MSW biodegradation eventually cause a reduction of the contaminant life span of the landfill and decrease in the cost of long term monitoring. The study indicated that the smaller the size of the MSW the faster the biodegradation rate of the waste. In addition, the paper presents the results of leachate recirculation on solid waste biodegradation in a full-scale landfill site, which is located in Nepean, Ontario, Canada. The leachate was recirculated into the landfilled solid waste for 8 years through infiltration lagoons. Similar results to those obtained in the laboratory scale experiments were noted. The average pH of the leachate in the early stages of recirculation was on the acidic range of the pH scale, however, the pH value was in the range of 7-8 after 2 years of leachate recirculation. The concentration of chloride remained fairly constant at about 1000 mg/l during the leachate recirculation period. A decreasing trend of the organic load, measured as biological oxygen demand and chemical oxygen demand, was observed. Recovery of landfill air space was also noted because of the enhanced subsidence and decomposition of the solid waste.