芬顿臭氧联合应用于陈年垃圾渗滤液浓液处理的研究

对Fenton和O3联合作用于垃圾渗滤液膜系统之后的浓缩液进行试验和探讨,在氧化效果方面得到了较好的处理结果。在对处理垃圾渗滤液浓液等高浓度有机废水方面具有重要现实意义和实用价值。     

烟气脱硫废水处理技术前沿研究进展

综述了烟气脱硫废水的产生原因与危害、分析了脱硫废水资源回用的可行性与困难,比较与评述了国内外烟气脱硫废水处理方法的工艺、原理及效果,指出了脱硫废水处理技术的发展新方向。当前各项技术都能使脱硫废水达标排放,但各工艺侧重点不同,经济投入相差较大,且后续环境问题各有不同。通过综合经济技术对比分析发现,电驱动膜法在当前最具潜力,能真正实现脱硫废水的资源化利用,达到近"零"排放,且具有运行成本低的优点,工业应用虽未形成规模,但前景广阔。     

铁路站车生活垃圾热解烟气治理技术分析

基于铁路生活垃圾产生和处置特点,对相应的烟气处理技术进行分析.从铁路站车生活垃圾成分和热解气化炉产生的烟气污染物出发,探讨烟气净化系统工艺中的脱酸、颗粒物、二(噁)英、重金属处理技术.综合考虑治理效率、治理成本、工艺实施的难易程度等,推荐铁路站车生活垃圾热解烟气净化工艺流程,即烟气经二燃室充分燃烧后先经急冷装置降温避开...     

CANON工艺处理赖氨酸废水

<正>引言赖氨酸废水是含有大量固体悬浮物、硫酸根、氨氮,COD和BOD含量严重超标的废水,其中分为浓液、稀液以及淀粉废水。介绍了某生物工程厂废水采用MQIC厌氧工艺、CANON工艺和絮凝沉淀池处理厂区赖氨酸生产废水,处理量为2000m3/d,该工艺系统对原水中COD、NH4+-N、TN的去除率分别可达97%、98%和95%,实践证明该工艺系统对处理高氨氮有机废水方面值得推广,前景广阔。某生物科技股份有限公司以玉米为原料生产赖氨酸,其生     

应用旋流塔治理焙烧炉烟气

应用旋流板塔处理焙烧炉含硫烟气 ,达到较高的除尘脱硫效率 ,并实现废水封闭循环。     

应用施流塔治理焙烧炉烟气

应用旋流板塔处理焙烧炉含硫烟气，达到较高的除尘脱硫效率，并实现废水封闭循环。     

超效浅层气浮-接触氧化法处理造纸废水设计及运行

采用超效浅层气浮+接触氧化法污水处理工艺处理某造纸厂的废水,介绍了各处理构筑物、运行参数及经济技术指标。运行结果表明,用该工艺处理造纸废水,其出水水质达到《造纸工业水污染物排放标准》(GB3544—2001)中的要求。     

600t／d生活垃圾焚烧锅炉整套启动调试

福州红庙岭垃圾焚烧发电厂,是采用德国马丁公司SITY2000垃圾焚烧发电技术和半干式烟气净化处理技术,日处理城市生活垃圾1200t,配置2台600t／d的垃圾焚烧炉,利用余热发电,发电机装机容量为2台12MW机组．在生活垃圾焚烧锅炉整套启动调试中,由于采取了调试条件控制和调试过程控制,优化了整套启动调试方案,确保两台机组顺利通过连续72h＋24h满负荷并网发电。     

脉冲电晕自由基簇射技术用于垃圾渗滤液预处理研究

低温等离子体技术是一种全新、高效、低能耗处理难降解有机废水的技术。采用自由基簇射与等离子体液面放电相结合的方式用于垃圾渗滤液预处理,能较好地提高活性自由基的利用率,降低能耗,增强垃圾渗滤液的可生化性,达到了预期的水质适应性强、处理效果稳定的高级氧化预处理效果,为渗滤液的后续处理奠定了良好的基础。     

渣土消纳场再利用工程中生活垃圾的稳定状态评价

采用钻孔取样的方法,利用垃圾气体甲烷浓度、垃圾生化产甲烷能力等两项参数,通过综合指数计算评价方法对大型渣土消纳场内不同深度生活垃圾的稳定状态进行了评价。结果表明,该渣土消纳场内大部分区域生活垃圾处于稳定状态,不会对场地复用造成影响。少数区域生活垃圾含量较高,处于中度不稳定状态,地基处理应适当考虑其影响。     

Process analysis of an industrial waste-to-energy plant: Theory and experiments

Thermal conversion is fundamental in an integrated waste management system due to the capability of reducing mass and volume of waste and recovering energy content from unrecyclable materials. Indeed, power generation from industrial solid wastes (ISW) is a topic of great interest for its appeal in the field of renewable energy production as well as for an increasing public concern related to its emissions. This paper is based on the process engineering and optimization analysis, commissioned to the University Campus-Biomedico of Rome by the MIDA Tecnologie Ambientali S.r.l. enterprise, ended up in the construction of an ISW thermo-conversion plant in Crotone (Southern Italy), where it is nowadays operating. The scientific approach to the process analysis is founded on a novel cascade numerical simulation of each plant section and it has been used initially in the process design step and after to simulate the performances of the industrial plant. In this paper, the plant process scheme is described together with the values of main operating parameters monitored during the experimental test runs. The thermodynamic and kinetic basics of the mathematical model for the simulation of the energy recovery and flue gas treatment sections are presented. Moreover, the simulation results, together with the implemented parameters, are given and compared to the experimental data for 10 specific plant test runs. It was found that the model is capable to predict the process performances in the energy production as well as in the gas treatment sections with high accuracy by knowing a set of measurable input variables. In the paper fundamental plant variables have been considered such as steam temperature, steam flow rate, power generated as well as temperature, flow rate and composition of the resulting flue gas; therefore, the mathematical model can be simply implemented as a reliable and efficient tool for management optimization of this kind of plants.     

新型吸收剂的制备及其对甲苯废气的吸收性能研究

针对工业排放的大量有机废气,制备了一种新型吸收剂.首次以水和生物柴油为原料,经乳化形成稳定的乳液,可提高生物柴油的吸收性能.考察了油水比、乳化剂HLB值、乳化剂添加量、乳化时间和乳化温度对乳液稳定性的影响.将乳液作为甲苯废气的吸收剂,通过实验室模拟废气,考察了其对甲苯废气的去除率.结果表明,在油水比(质量比)为7:3,乳化剂HLB(亲水亲油平衡值)值为10,乳化剂质量分数为5%,乳化时间为0.5 h,乳化温度为室温时,乳液的稳定性最好,且对甲苯废气的去除率可达到90.3%.     

废水废气污染源在线监测系统日常维护及故障处理

伴随着我国社会现代化程度和城市化进程的不断加深,社会得到了非常好的发展,但同时也产生了大量的废气和废水,对生态环境造成了严重破坏。因此,为了将这个问题良好的解决,应建立一套具有较高科学性和合理性的废水废气污染源在线监测系统,并加大日常维护及故障处理的力度,从根源减少人们在工作生活中对生态环境造成的影响。因此,本文针对废水废气污染源在线监测系统日常维护及故障处理的有效措施,展开详细的分析,以期能够为我国生态环境可持续发展目标的实现贡献应有的力量。     

球团竖炉烟气脱硫工程应用研究

论述了文氏栅洗涤器及其配套系统在球团竖炉烟气脱硫工程应用方面的研究,介绍了双碱法在文氏栅洗涤器及其配套系统中的脱硫机理和工艺过程。同时对设备的防腐和废水、废渣的处理,系统的常规检测和自动监测都作了相应的研究。对文氏栅洗涤器的脱硫除尘效率、设备及工程投资、工业运行成本作了适当的介绍。文氏栅洗涤器具有良好的组合特性,适用的烟气量范围广,是用于炉窑烟气脱硫除尘的理想设备,具有广阔的开发应用前景。     

广铜酸性废水处理工艺改进研究

探讨了对广钢集团广铜公司的污水处理系统的一些改进方案。通过加强对废水排放的管理,加建天棚临时存放污泥,改进风机加强曝气过程的搅拌作用等措施,使得该系统更适应日益扩大的生产规模,废水处理能力提高了70％,并且污水处理质量提高,运行更为稳定,能源消耗减少,年可节电费10万元,污水处理费用降低,处理后废水的回用率达40％以上。     

中小型燃煤锅炉烟气湿法除尘废水中和处理技术评述

介绍了当前应用于中小型燃煤锅炉湿法除尘废水的各种中和处理技术,提出将除尘废水与中和处理与烟气脱硫结合进行的新工艺,为中小型锅炉烟气湿法脱硫除尘和废水循环回用处理提供了依据。     

New method for acrylic acid recovery from industrial waste water via esterification with 2-ethyl hexanol

Acrylic acid (AA) is an important component for the production of acrylate polymer. In a typical acrylic manufacturing unit, waste water contains AA in a range of 4–15 wt.% contributes to the high values of chemical oxygen demand. Due to the toxicity of AA to the aquatic organism, this wastewater should be treated before it is discharged to the environment. The waste water could be evaporated before sending to the incineration which was neither economic feasible nor environmental friendly. Esterification of wastewater containing carboxylic acid with alcohol could be a promising method to recover the acid by converting it to ester while purifying the wastewater. In the present study, recovery of AA via esterification with 2-ethyl hexanol (2EH) was investigated. The model industrial wastewater with various concentration of AA (10–100% w/w) was reacted with 2EH to produce 2-ethyl hexyl acrylate (2EHA) in the setups with total reflux and continuously water removal. These Amberlyst-15 (ion exchange resin) catalyzed reactions were carried out under the mass transfer resistance free region. The performance of both systems was compared. The yield for the reactions of the AA solutions with the AA concentrations of 30–80% was enhanced significantly when the reactions were carried out using the second setup. The kinetic data of the esterification of dilute AA was well described by the Eley–Rideal (ER) kinetic model incorporated with a correction factor to consider the catalyst fouling effect and pseudo-homogeneous (PH) kinetic model for the AA polymerization. The findings have shown the potential of recovering AA from the waste water stream via esterification. The concentrated AA solutions or larger amount of inhibitor should be adopted to prevent the catalyst fouling by the deposition of poly-acrylic acid on the catalyst surface.     

特种膜分离在废乳化液处理上的应用

目前国内乳化液处理普遍采用化学加药破乳,再后续生化处理的工艺,该方法投加大量化学药剂,产生二次固体危废,综合处置成本高。采用荷兰B&C特种超滤膜技术对乳化液浓缩破乳回收基础油,超滤产水后续生化处理的新工艺路线具有很好的工艺先进性。通过工艺运行数据显示,含油率1%~3%的乳化液,经过特种超滤浓缩破乳后浓缩液含油率可达15%~20%,超滤产水含油率小于50mg/L,COD为15000~20000mg/L,后续经厌氧和A/O生化+Fenton氧化后出水小于500mg/L,达到处理标准。     

硫化矿活性矿浆烟气脱硫技术适用性探析

重点进行SO_2浓度、液气比、浆液浓度、pH值对脱硫效率影响的试验研究,验证硫化矿活性矿浆脱硫技术的适用性。结果表明,该技术适用于低浓度烟气脱硫工艺,pH值在6.0~6.5,液气比在8~10 L/m3范围内,实现了高脱硫效率、低能耗、安全稳定运行,为行业内低浓度SO_2烟气脱硫开辟了新的途径。     

纵向通风条件下对隧道内烟气运动影响因素的实验研究

通过在中国科学技术大学火灾科学国家重点实验室进行的小尺寸隧道火灾实验,研究了不同坡度、火源功率以及纵向烟控风速对隧道内烟气运动的影响。结果表明:隧道坡度、火源功率与纵向烟控风速的大小对烟气层沉降都有着重要的影响。坡度越大烟气所受到的浮升力越大,冷空气的卷吸能力越强,因此烟气降温越快,烟气沉降速度也越快。纵向烟控风速越大,烟气层冷却越快,从而越易沉降。火源功率越小,供给烟气层的对流热量越少,烟气层温度越低,浮力越小,则烟气层越易沉降。