Using Spatially Detailed Water‐Quality Data and Solute‐Transport Modeling to Support Total Maximum Daily Load Development1

Walton‐Day, Katherine, Robert L. Runkel, and Briant A. Kimball, 2012. Using Spatially Detailed Water‐Quality Data and Solute‐Transport Modeling to Support Total Maximum Daily Load Development. Journal of the American Water Resources Association (JAWRA) 48(5): 949‐969. DOI: 10.1111/j.1752‐1688.2012.00662.x Abstract: Spatially detailed mass‐loading studies and solute‐transport modeling using OTIS (One‐dimensional Transport with Inflow and Storage) demonstrate how natural attenuation and loading from distinct and diffuse sources control stream water quality and affect load reductions predicted in total maximum daily loads (TMDLs). Mass‐loading data collected during low‐flow from Cement Creek (a low‐pH, metal‐rich stream because of natural and mining sources, and subject to TMDL requirements) were used to calibrate OTIS and showed spatially variable effects of natural attenuation (instream reactions) and loading from diffuse (groundwater) and distinct sources. OTIS simulations of the possible effects of TMDL‐recommended remediation of mine sites showed less improvement to dissolved zinc load and concentration (14% decrease) than did the TMDL (53‐63% decrease). The TMDL (1) assumed conservative transport, (2) accounted for loads removed by remediation by subtracting them from total load at the stream mouth, and (3) did not include diffuse‐source loads. In OTIS, loads were reduced near their source; the resulting concentration was decreased by natural attenuation and increased by diffuse‐source loads during downstream transport. Thus, by not including natural attenuation and loading from diffuse sources, the TMDL overestimated remediation effects at low flow. Use of the techniques presented herein could improve TMDLs by incorporating these processes during TMDL development.     

Hydrologic and Phosphorus Export Behavior of Small Streams in Commercial Poultry‐Pasture Watersheds1

Romeis, J. Joshua, C. Rhett Jackson, L. Mark Risse, Andrew N. Sharpley, and David E. Radcliffe, 2011. Hydrologic and Phosphorus Export Behavior of Small Streams in Commercial Poultry‐Pasture Watersheds. Journal of the American Water Resources Association (JAWRA) 1‐19. DOI: 10.1111/j.1752‐1688.2011.00521.x Abstract: Few watershed‐scale studies have evaluated phosphorus export in streamflow from commercial poultry‐pasture operations. Continuous streamflow and mixed‐frequency water quality datasets were collected from nine commercial poultry‐pasture (AG) and three forested (FORS) headwater streams (2.4‐44 ha) in the upper Etowah River basin of Georgia to estimate total P (TP) loads and examine variability of hydrologic response and water quality of storm and nonstorm‐flow regimes. Data collection duration ranged from 18 to 22 months, and approximately 1,600 water quality samples were collected. Significant (p < 0.1) inverse relationships were detected between peak flow response variables and both drainage area and fraction of forest cover. Order‐of‐magnitude differences in TP and dissolved reactive P (DRP) concentration were observed between AG and FORS sites and among AG sites. TP yields of FORS sites ranged from 0.01 to 0.1 kg P/ha. Yields of AG sites ranged from 0.031 to 3.17 kg P/ha (median = 0.354 kg P/ha). With 95% confidence intervals, AG yields ranged from 0.025 to 13.1 kg P/ha. These small‐watershed‐scale yields were similar to field‐scale yields measured in other studies in other regions. TP yields were significantly related to area‐weighted Mehlich‐1 soil test P concentrations (p = 0.0073) and base‐flow water sample P concentrations (p ≤ 0.0005). Water quality sampling during base‐flow conditions may be a useful screening tool for P risk‐based management programs.     

Nitrate Removal in a Restored Spring‐Fed Wetland,Pennsylvania, USA1

ABSTRACT:  In 2001, the 1.04‐ha Hornbaker wetland in south‐central Pennsylvania was restored by blocking an artificial drainage ditch to increase water storage and hydraulic retention time (HRT). A primary goal was to diminish downstream delivery of nitrate that enters the wetland from a limestone spring, its main source of inflow. Wetland inflow and outflow were monitored weekly for two years to assess nitrate flux, water temperature, pH, and specific conductivity. In Year 2, spring discharge was measured weekly to allow calculation of nitrate loads and hydraulic retention time. Surface runoff was confirmed to be a small fraction of wetland inflows via rainfall‐runoff modeling with TR‐55. The full dataset (n = 102) was screened to remove 13 weeks in which spring discharge constituted < 85% of total inflows because of high precipitation and surface runoff. Over two years (n = 89), mean nitrate‐nitrogen concentrations were 7.89 mg/l in inflow and 3.68 mg/l in outflow, with a mean nitrate removal of 4.19 mg/l. During Year 2 (n = 47), for which nitrate load data were available, the wetland removed an average of 2.32 kg N/day, 65% of the load. Nitrate removal was significantly correlated with HRT, water temperature, and the concentration of nitrate in inflow and was significantly greater during the growing season (5.36 mg/l, 64%) than during the non‐growing season (3.23 mg/l, 43%). This study indicates that hydrologic restoration of formerly drained wetlands can provide substantial water quality benefits and that the hydrologic characteristics of spring‐fed wetlands, in particular, support effective nitrogen removal.     

Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds1

Schilling, Keith E., Thomas M. Isenhart, Jason A. Palmer, Calvin F. Wolter, and Jean Spooner, 2011. Impacts of Land‐Cover Change on Suspended Sediment Transport in Two Agricultural Watersheds. Journal of the American Water Resources Association (JAWRA) 47(4):672‐686. DOI: 10.1111/j.1752‐1688.2011.00533.x Abstract: Suspended sediment is a major water quality problem, yet few monitoring studies have been of sufficient scale and duration to assess the effectiveness of land‐use change or conservation practice implementation at a watershed scale. Daily discharge and suspended sediment export from two 5,000‐ha watersheds in central Iowa were monitored over a 10‐year period (water years 1996‐2005). In Walnut Creek watershed, a large portion of land was converted from row crop to native prairie, whereas in Squaw Creek land use remained predominantly row crop agriculture. Suspended sediment loads were similar in both watersheds, exhibiting flashy behavior typical of incised channels. Modeling suggested that expected total soil erosion in Walnut Creek should have been reduced 46% relative to Squaw Creek due to changes in land use, yet measured suspended sediment loads showed no significant differences. Stream mapping indicated that Walnut Creek had three times more eroding streambank lengths than did Squaw Creek suggesting that streambank erosion dominated sediment sources in Walnut Creek and sheet and rill sources dominated sediment sources in Squaw Creek. Our results demonstrate that an accounting of all sources of sediment erosion and delivery is needed to characterize sediment reductions in watershed projects combined with long‐term, intensive monitoring and modeling to account for possible lag times in the manifestation of the benefits of conservation practices on water quality.     

Development of the Chesapeake Bay Watershed Total Maximum Daily Load Allocation

Nutrient load allocations and subsequent reductions in total nitrogen and phosphorus have been applied in the Chesapeake watershed since 1992 to reduce hypoxia and to restore living resources. In 2010, sediment allocations were established to augment nutrient allocations supporting the submerged aquatic vegetation resource. From the initial introduction of nutrient allocations in 1992 to the present, the allocations have become more completely applied to all areas and loads in the watershed and have also become more rigorously assessed and tracked. The latest 2010 application of nutrient and sediment allocations were made as part of the Chesapeake Bay total maximum daily load and covered all six states of the Chesapeake watershed. A quantitative allocation process was developed that applied principles of equity and efficiency in the watershed, while achieving all tidal water quality standards through an assessment of equitable levels of effort in reducing nutrients and sediments. The level of effort was determined through application of two key watershed scenarios: one where no action was taken in nutrient control and one where maximum nutrient control efforts were applied. Once the level of effort was determined for different jurisdictions, the overall load reduction was set watershed‐wide to achieve dissolved oxygen water quality standards. Further adjustments were made to the allocation to achieve the James River chlorophyll‐a standard.     

Evaluation of the Temporal Transferability of a Model Describing Dissolved Solids in Streams of the Upper Colorado River Basin1

Kenney, Terry A. and Susan G. Buto, 2012. Evaluation of the Temporal Transferability of a Model Describing Dissolved Solids in Streams of the Upper Colorado River Basin. Journal of the American Water Resources Association (JAWRA) 48(5): 1041‐1053. DOI: 10.1111/j.1752‐1688.2012.00667.x Abstract: The application of a nonlinear least‐squares regression model describing the sources and transport of dissolved solids in streams of the Upper Colorado River Basin, and that was calibrated using data from water year 1991, was evaluated for use in predicting annual dissolved‐solids loads for the years 1974 through 1998. Simulations for each water year were run using annual climate data. To evaluate how well the model captures the observed annual variability across the basin, differences in predicted annual dissolved‐solids loads for each simulated year and 1991 were compared with differences in monitored annual loads. The temporal trend of the differences between predicted annual loads for the simulated years and the load for 1991 generally followed the trend of the monitored loads. The model appears to underpredict the largest annual loads and overpredict some of the smaller annual loads. An underprediction bias for wetter years was evident in the residuals as was an overprediction bias, to a lesser degree, for drier years. A regression analysis on the residuals suggests that the underprediction bias is associated with precipitation differences from 1991 and with previously defined downward trends in dissolved‐solids concentrations in the basin. In general, given the representative climatic conditions, the model adequately performs throughout the period examined. However, the model is most transferable to years with climatic conditions similar to 1991.     

Sources and Delivery of Nutrients to the Northwestern Gulf of Mexico from Streams in the South‐Central United States1

Rebich, Richard A., Natalie A. Houston, Scott V. Mize, Daniel K. Pearson, Patricia B. Ging, and C. Evan Hornig, 2011. Sources and Delivery of Nutrients to the Northwestern Gulf of Mexico From Streams in the South‐Central United States. Journal of the American Water Resources Association (JAWRA) 47(5):1061‐1086. DOI: 10.1111/j.1752‐1688.2011.00583.x Abstract: SPAtially Referenced Regressions On Watershed attributes (SPARROW) models were developed to estimate nutrient inputs [total nitrogen (TN) and total phosphorus (TP)] to the northwestern part of the Gulf of Mexico from streams in the South‐Central United States (U.S.). This area included drainages of the Lower Mississippi, Arkansas‐White‐Red, and Texas‐Gulf hydrologic regions. The models were standardized to reflect nutrient sources and stream conditions during 2002. Model predictions of nutrient loads (mass per time) and yields (mass per area per time) generally were greatest in streams in the eastern part of the region and along reaches near the Texas and Louisiana shoreline. The Mississippi River and Atchafalaya River watersheds, which drain nearly two‐thirds of the conterminous U.S., delivered the largest nutrient loads to the Gulf of Mexico, as expected. However, the three largest delivered TN yields were from the Trinity River/Galveston Bay, Calcasieu River, and Aransas River watersheds, while the three largest delivered TP yields were from the Calcasieu River, Mermentau River, and Trinity River/Galveston Bay watersheds. Model output indicated that the three largest sources of nitrogen from the region were atmospheric deposition (42%), commercial fertilizer (20%), and livestock manure (unconfined, 17%). The three largest sources of phosphorus were commercial fertilizer (28%), urban runoff (23%), and livestock manure (confined and unconfined, 23%).     

STREAM DEPTH SIGNIFICANCE DURING IN‐SITU SEDIMENT OXYGEN DEMAND MEASUREMENTS IN SHALLOW STREAMS1

ABSTRACT: Ninety‐one sediment oxygen demand (SOD) samples from six designated sites along the stretch of Lower Rapid Creek, South Dakota, were conducted using an in‐situ SOD chamber. Inside the chamber, readings of dissolved oxygen (DO), water temperature, pH, and specific conductance were recorded every minute for more than one hour using the Datasonde 3 Hydrolab. Initial readings of such parameters were recorded for the overlaying water before the deployment of the SOD chamber. Characteristics of the stream conditions, air temperature, barometric pressure, average flow velocity of the stream, depth of the stream, and the flow velocity by the chamber were recorded. Single and multiple linear regression analyses on all parameters indicated that the velocity of the stream is the least critical parameter for SOD in shallow streams.     

The Regionalization of National‐Scale SPARROW Models for Stream Nutrients1

Schwarz, Gregory E., Richard B. Alexander, Richard A. Smith, and Stephen D. Preston, 2011. The Regionalization of National‐Scale SPARROW Models for Stream Nutrients. Journal of the American Water Resources Association (JAWRA) 47(5):1151‐1172. DOI: 10.1111/j.1752‐1688.2011.00581.x Abstract: This analysis modifies the parsimonious specification of recently published total nitrogen (TN) and total phosphorus (TP) national‐scale SPAtially Referenced Regressions On Watershed attributes models to allow each model coefficient to vary geographically among three major river basins of the conterminous United States. Regionalization of the national models reduces the standard errors in the prediction of TN and TP loads, expressed as a percentage of the predicted load, by about 6 and 7%. We develop and apply a method for combining national‐scale and regional‐scale information to estimate a hybrid model that imposes cross‐region constraints that limit regional variation in model coefficients, effectively reducing the number of free model parameters as compared to a collection of independent regional models. The hybrid TN and TP regional models have improved model fit relative to the respective national models, reducing the standard error in the prediction of loads, expressed as a percentage of load, by about 5 and 4%. Only 19% of the TN hybrid model coefficients and just 2% of the TP hybrid model coefficients show evidence of substantial regional specificity (more than ±100% deviation from the national model estimate). The hybrid models have much greater precision in the estimated coefficients than do the unconstrained regional models, demonstrating the efficacy of pooling information across regions to improve regional models.     

Spatial Optimization of Six Conservation Practices Using Swat in Tile‐Drained Agricultural Watersheds

Targeting of agricultural conservation practices to the most effective locations in a watershed can promote wise use of conservation funds to protect surface waters from agricultural nonpoint source pollution. A spatial optimization procedure using the Soil and Water Assessment Tool was used to target six widely used conservation practices, namely no‐tillage, cereal rye cover crops (CC), filter strips (FS), grassed waterways (GW), created wetlands, and restored prairie habitats, in two west‐central Indiana watersheds. These watersheds were small, fairly flat, extensively agricultural, and heavily subsurface tile‐drained. The targeting approach was also used to evaluate the model's representation of conservation practices in cost and water quality improvement, defined as export of total nitrogen, total phosphorus, and sediment from cropped fields. FS, GW, and habitats were the most effective at improving water quality, while CC and wetlands made the greatest water quality improvement in lands with multiple existing conservation practices. Spatial optimization resulted in similar cost‐environmental benefit tradeoff curves for each watershed, with the greatest possible water quality improvement being a reduction in total pollutant loads by approximately 60%, with nitrogen reduced by 20‐30%, phosphorus by 70%, and sediment by 80‐90%.     

The Influence of Two‐Stage Ditches with Constructed Floodplains on Water Column Nutrients and Sediments in Agricultural Streams

The two‐stage ditch is a novel management practice originally implemented to increase bank stability through floodplain restoration in channelized agricultural streams. To determine the effects of two‐stage construction on sediment and nutrient loads, we monitored turbidity, and also measured total suspended solids (TSS), dissolved inorganic nitrogen (N) species, and phosphorus (P) after two‐stage ditch construction in reference and manipulated reaches of four streams. Turbidity decreased during floodplain inundation at all sites, but TSS and P, soluble reactive phosphorus (SRP) and total phosphorus (TP) decreased only in the two‐stage ditches with longer duration of inundation. Both TSS and TP were positively correlated within individual streams, but neither were correlated with turbidity. Phosphorus was elevated in the stream to which manure was applied adjacent to the two‐stage reach, but not the reference reach, suggesting that landscape nutrient management plans could restrict nutrient transport to the stream, ultimately determining the efficacy of instream management practices. In addition, ammonium and nitrate decreased in two‐stage reaches with lower initial N concentrations. Overall, results suggest that turbidity, TSS, and TP were reduced during floodplain inundation, but the two‐stage alone may not be effective for managing high inorganic N loads.     

Point‐Nonpoint Trading – Can It Work?1

Ribaudo, Marc O. and Jessica Gottlieb, 2011. Point‐Nonpoint Trading – Can It Work? Journal of the American Water Resources Association (JAWRA) 47(1):5‐14. DOI: 10.1111/j.1752‐1688.2010.00454.x Abstract: Water quality trading between point and nonpoint sources is of great interest as an alternative to strict command and control regulations on point sources for achieving water quality goals. The expectation is that trading will reduce the costs of water quality protection, and may speed compliance. The United States Environmental Protection Agency has issued guidance to the States on developing point‐nonpoint trading programs, and United States Department of Agriculture is encouraging farmer participation. However, existing point‐nonpoint trading programs have resulted in very few trades. Supply side and demand side impediments seem to be preventing trades from occurring in most trading programs. These include uncertainty over the number of discharge allowances different management practices can produce, high transactions costs of identifying trading partners, baseline requirements that eliminate low‐cost credits, the reluctance of point sources to trade with unfamiliar agents, and the perception of some farmers that entering contracts with regulated point sources leads to greater scrutiny and potential future regulation. Many of these problems can be addressed through research and program design.     

Life cycle assessment of hot mix asphalt and zeolite-based warm mix asphalt with reclaimed asphalt pavement

A comprehensive life cycle assessment of asphalt pavements was conducted including hot mix asphalt (HMA), warm mix asphalt (WMA) with the addition of synthetic zeolites, and asphalt mixes with reclaimed asphalt pavement (RAP). The environmental impacts associated with energy consumption and air emissions were assessed, as well as other environmental impacts resulting from the extraction and processing of minerals, binders and chemical additives; asphalt production; transportation of materials; asphalt paving; road traffic on the pavement; land use; dismantling of the pavement at the end-of-life and its landfill disposal or recycling. Monte Carlo simulations were also conducted to take into account the variability of critical input parameters. Taking into account the entire life cycle, the impacts of zeolite-based WMA pavements were almost equal to the impacts of HMA pavements with the same RAP content. The reduction in the impacts of WMA resulting from the lowering of the manufacturing temperature was offset by the greater impacts of the materials used, especially the impacts of the synthetic zeolites. Moreover, by comparing asphalt mixes with different RAP contents, it was shown that the impacts of asphalt mixes were significantly reduced when RAP was added. All endpoint impacts as well as climate change, fossil depletion and total cumulative energy demand were decreased by 13–14% by adding 15% RAP. A key advantage of WMA is the potentially greater use of RAP. Thus, the decrease in the impacts achieved by adding large amounts of RAP to WMA could turn these asphalt mixes into a good alternative to HMA in environmental terms.     

Model‐Based Nitrogen and Phosphorus (Nutrient) Criteria for Large Temperate Rivers: 2. Criteria Derivation

Nitrogen and phosphorus criteria were developed for 233 km of the Yellowstone River, one of the first cases where a mechanistic model has been used to derive large river numeric nutrient criteria. A water quality model and a companion model which simulates lateral algal biomass across transects were used to simulate effects of increasing nutrients on five variables (dissolved oxygen, total organic carbon, total dissolved gas, pH, and benthic algal biomass in depths ≤1 m). Incremental increases in nutrients were evaluated relative to their impact on predefined thresholds for each variable; the first variable to exceed a threshold set the nutrient criteria. Simulations were made at a low flow, the 14Q5 (lowest average 14 consecutive day flow, July‐September, recurring one in five years), which was derived using benthic algae growth curves and EPA guidance on excursion frequency. An extant climate dataset with an annual recurrence was used, and tributary water quality and flows were coincident with the river's 10 lowest flow years. The river had different sensitivities to nutrients longitudinally, pH being the most sensitive variable in the upstream reach and algal biomass in the lower. Model‐based criteria for the Yellowstone River are as follows: between the Bighorn and Powder river confluences, 55 μg TP/l and 655 μg TN/l; from the Powder River confluence to Montana state line, 95 μg TP/l and 815 μg TN/l. Pros and cons of using steady‐state models to derive river nutrient criteria are discussed.     

A MONTE CARLO TEST OF LOAD CALCULATION METHODS,LAKE TAHOE BASIN,CALIFORNIA‐NEVADA1

ABSTRACT: The sampling of streams and estimation of total loads of nitrogen, phosphorus, and suspended sediment play an important role in efforts to control the eutrophication of Lake Tahoe. We used a Monte Carlo procedure to test the precision and bias of four methods of calculating total constituent loads for nitrate‐nitrogen, soluble reactive phosphorus, particulate phosphorus, total phosphorus, and suspended sediment in one major tributary of the lake. The methods tested were two forms of the Beale's Ratio Estimator, the Period Weighted Sample, and the Rating Curve. Intensive sampling in 1985 (a dry year) and 1986 (a wet year) provided a basis for estimating loads by the “worked record” method for comparison with estimates based on resampling actual data at the lower intensity that characterizes the present monitoring program. The results show that: (1) the Period Weighted Sample method was superior to the other methods for all constituents for 1985; and (2) for total phosphorus, particulate phosphorus, and suspended sediment, the Rating Curve gave the best results in 1986. Modification of the present sampling program and load calculation methods may be necessary to improve the precision and reduce the bias of estimates of total phosphorus loads in basin streams.     

INPUTS OF COPPER‐BASED CROP PROTECTANTS TO COASTAL CREEKS FROM PASTICULTURE RUNOFF1

ABSTRACT: Inputs of copper‐based crop protectants from tomato fields grown under plastic mulch agriculture (plasticulture) to an estuarine creek were investigated. Copper was measured in runoff from diverse land‐uses including conventional agriculture, plasticulture, residences, and natural areas. Water column and sediment copper concentrations were measured in plasticulture and control (nonagriculture) watersheds. Copper concentrations in plasticulture‐impacted creeks exceeded background levels episodically. High concentrations occurred during or immediately after runoff‐producing rains. Concentrations of 263 μg/L total copper and 126 μg/L dissolved copper were measured in a tidal creek affected by plasticulture; concentrations exceeded the shellfish LC₅₀ values and the water quality criteria of 2.9 μg/L dissolved copper. Control watersheds indicated background water column levels of ≤ 4 μg/L dissolved copper with similar copper levels during periods with and without rain. The copper concentrations in tomato plasticulture field runoff itself contained up to 238 μg/L dissolved copper. Copper concentrations in runoff from other land‐uses were less than 5 μg/L dissolved copper. Creek sediment samples adjacent to a plasticulture field contained significantly higher copper concentrations than sediments taken from nonplasticulture watersheds.     

A Comparative Study of Stream‐Gaging Techniques for Low‐Flow Measurements in Two Virginia Tributaries1

Abstract: Nonpoint source pollution (NPS) studies, such as total maximum daily loads development, often require quantification of flow in small first‐order and second‐order streams. Frequently, stream‐gaging techniques are implemented in flows that are below the manufacturer’s recommended minimum velocity. A comparative analysis of the accuracy of current technologies used in NPS pollution stream‐gaging applications and their applicability in low‐flow conditions was conducted. Nine stream‐gaging methods were evaluated for their field and laboratory performance and control structures were used as the statistical control. Analysis of the field investigation data indicated that Marsh McBirney current meter and the One‐orange method were the most accurate in the field while the results of the laboratory experiments found that the Starflow acoustic Doppler and Valeport Braystoke current meter performed best among the 10 methods. Overall, the Marsh McBirney and Valeport Braystoke current meters exhibited the best performance for both field and laboratory situations.     

A Multi‐Agency Nutrient Dataset Used to Estimate Loads,Improve Monitoring Design,and Calibrate Regional Nutrient SPARROW Models1

Saad, David A., Gregory E. Schwarz, Dale M. Robertson, and Nathaniel L. Booth, 2011. A Multi‐Agency Nutrient Dataset Used to Estimate Loads, Improve Monitoring Design, and Calibrate Regional Nutrient SPARROW Models. Journal of the American Water Resources Association (JAWRA) 47(5):933‐949. DOI: 10.1111/j.1752‐1688. 2011.00575.x Abstract: Stream‐loading information was compiled from federal, state, and local agencies, and selected universities as part of an effort to develop regional SPAtially Referenced Regressions On Watershed attributes (SPARROW) models to help describe the distribution, sources, and transport of nutrients in streams throughout much of the United States. After screening, 2,739 sites, sampled by 73 agencies, were identified as having suitable data for calculating long‐term mean annual nutrient loads required for SPARROW model calibration. These sites had a wide range in nutrient concentrations, loads, and yields, and environmental characteristics in their basins. An analysis of the accuracy in load estimates relative to site attributes indicated that accuracy in loads improve with increases in the number of observations, the proportion of uncensored data, and the variability in flow on observation days, whereas accuracy declines with increases in the root mean square error of the water‐quality model, the flow‐bias ratio, the number of days between samples, the variability in daily streamflow for the prediction period, and if the load estimate has been detrended. Based on compiled data, all areas of the country had recent declines in the number of sites with sufficient water‐quality data to compute accurate annual loads and support regional modeling analyses. These declines were caused by decreases in the number of sites being sampled and data not being entered in readily accessible databases.     

Contaminant Retention Potential of Forested Filter Strips Established as SMZs in the Piedmont of Georgia1

Abstract: It is common practice in the United States and elsewhere to maintain vegetated filter strips adjacent to streams to retain contaminants in surface runoff. Most research has evaluated contaminant retention in managed agricultural field strips, while relatively few studies have quantified retention in forested filter strips, particularly for dissolved contaminants. Plot‐scale overland flow experiments were conducted to evaluate the efficiency of natural forested filter strips established as streamside management zones (SMZs) for retaining phosphorus (P), atrazine, and picloram transported in runoff. Retention was evaluated for five different slope classes: 1‐2, 5‐7, 10‐12, 15‐17, and 20‐22%; two cover conditions: undisturbed forest floor (O horizon intact) and forest floor removed by raking; and two periods with contrasting soil moisture conditions: summer‐dry and winter‐wet season. Surface flow was collected at 0, 2, 4, 6, and 10 m within the filter strip to evaluate changes in solution concentration as it moved through the O horizon and the surface soil horizon mixing zone. On average, a 10 m length of forested SMZ with an undisturbed forest floor reduced initial solution concentration of total dissolved P by 51%, orthophosphate P by 49%, atrazine by 28%, and picloram by 5%. Percentages of mass retention through infiltration of water plus concentration reductions in runoff were 64% for total dissolved P, 62% for orthophosphate P, 47% for atrazine, and 28% for picloram for undisturbed forest floor conditions. Lower retention occurred following forest floor removal, particularly for P. Average dissolved P retention was 16% lower following forest floor removal. For undisturbed sites, differences in retention were more closely related to forest floor depth than to slope or antecedent soil moisture. These results indicate that forested SMZ filter strips provide a significant measure of surface water protection from dissolved P and herbicide delivery to surface water.     

Vegetative Buffer Strips for Reducing Herbicide Transport in Runoff: Effects of Buffer Width,Vegetation, and Season

The effectiveness of vegetative buffer strips (VBS) for reducing herbicide transport has not been well documented for runoff prone soils. A multi‐year plot‐scale study was conducted on an eroded claypan soil with the following objectives: (1) assess the effects of buffer width, vegetation, and season on runoff transport of atrazine (ATR), metolachlor (MET), and glyphosate; (2) develop VBS design criteria for herbicides; and (3) compare differences in soil quality among vegetation treatments. Rainfall simulation was used to create uniform antecedent soil water content and to generate runoff. Vegetation treatment and buffer width impacted herbicide loads much more than season. Grass treatments reduced herbicide loads by 19‐28% and sediment loads by 67% compared to the control. Grass treatments increased retention of dissolved‐phase herbicides by both infiltration and adsorption, but adsorption accounted for the greatest proportion of retained herbicide load. This latter finding indicated VBS can be effective on poorly drained soils or when the source to buffer area ratio is high. Grass treatments modestly improved surface soil quality 8‐13 years after establishment, with significant increases in organic C, total N, and ATR and MET sorption compared to continuously tilled control. Herbicide loads as a function of buffer width were well described by first‐order decay models which indicated VBS can provide significant load reductions under anticipated field conditions.