Preliminary Measurements of Biogenic Sulfur-Containing Gas Emissions From Soils

Emission factors for particulate matter and carbon monoxide have been measured for wood, anthracite coal, and bituminous coal burned in residential heaters operated at less than 15 kW (50,000 Btu/hr). In these studies the stove effluent is mixed with about four volumes of outside air and samples are collected about two minutes after mixing. The main purpose of using this sampling method is to simulate atmospheric conditions more closely. Particulate samples are collected on 20 × 25 cm filters after cyclone preseparation of particles larger than 4 μm. Carbon monoxide concentrations are measured with Draeger tubes.

Particulate emission factors for wood ranged from 1.6 to 6.4 g/kg (fuel) and were found to depend on the fuel load and the firing rate, as indicated by earlier studies. These values are substantially less than the values obtained previously for stoves operated under similar conditions. The average particulate emission factors for bituminous and anthracite coal are 10.4 and 0.50 g/kg, respectively. Carbon monoxide emission factors for wood, bituminous, and anthracite coal are 100,116, and 21 g/kg, respectively.     

An Analysis of Michigan and California CO Remote Sensing Measurements

Abstract

Remote sensing measurements of CO emissions from on-road vehicles were made in California in 1991 and in Michigan in 1992. It was determined that both fleets had a small linear increase in the high emitter frequency (vehicles emitting more than 4% CO) as a function of vehicle age for 1986 and newer model vehicles. Although high emitting vehicles were only a small minority of the fleet, they had a dominant impact on the mean CO and total CO emitted by the fleet. In Michigan, the highest emitting 5% of passenger cars generated 45% of the CO from cars. In California, the highest emitting 5% of passenger cars generated 38% of the CO from cars. There was a high correlation between the mean CO emitted by each model year of vehicle and the frequency of high emitting vehicles within the model year for both the Michigan and California fleets. The frequency of high emitters within any model year had no obvious relation to that model year’s certification standards. The high emitter frequencies for vehicles less than nine years old were very similar for the California and Michigan fleets. An increase in the high emitter frequency in the ten-year-old and older Michigan passenger car fleet (relative to the California passenger car fleet), suggests, but does not conclusively demonstrate, that the rate of high emitters in Michigan and California is reduced by the inspection and maintenance (I/M) programs.     

基层环境执法存在的问题及对策浅析

阐述了环境执法中存在的问题，指出了真正造就一支“来之能战，战之能胜”的高效、廉洁、文明的环境执法队伍，必须加快立法步伐，加大环境法制宣传教育力度，提高环境法制意识，进行行政管理体制创新，改革机构，打破地方政府“供养制”，加强环保执法队伍的建设。     

建设项目环评中的清洁生产水平分析

建设项目环境影响评价中开展清洁生产分析，可促使企业调整投资结构，实现从末端治理到全过程控制的战略转移。文中从原辅材料和能源、技术工艺与设备、产品特性、管理水平与员工意识、废物处理与利用等5个方面阐述了清洁生产水平分析的要点。     

生化制药类建设项目环评的重点分析

通过分析徐州市某一生化制药建设项目的环评实例,确定了该类项目的环评重点和难点在于工程分析和污染物的排放分析,尤其是由于废水污染物具有种类多、排放不稳定的特点。同时,结合环保“三同时”建设中的废水处理工程的调试分析,评价了该类建设项目的污水处理设施的技术经济性、可行性。     

Concentrations of methylmercury in invertebrates from wetlands of the Prairie Pothole Region of North America

Prairie wetlands may be important sites of mercury (Hg) methylation resulting in elevated methylmercury (MeHg) concentrations in water, sediments and biota. Invertebrates are an important food resource and may act as an indicator of MeHg exposure to higher organisms. In 2007-2008, invertebrates were collected from wetland ponds in central Saskatchewan, categorized into functional feeding groups (FFGs) and analyzed for total Hg (THg) and MeHg. Methylmercury and THg concentrations in four FFGs ranged from 0.2-393.5 ng · g(-1) and 9.7-507.1 ng · g(-1), respectively. Methylmercury concentrations generally increased from gastropods with significantly lower average MeHg concentrations compared to other invertebrate taxa. Surrounding land use (agricultural, grassland and organic agricultural) may influence MeHg concentrations in invertebrates, with invertebrate MeHg concentrations being higher from organic ponds (457.5 ± 156.7 ng · g(-1)) compared to those from grassland ponds (74.8 ± 14.6 ng · g(-1)) and ponds on agricultural lands (32.8 ± 6.2 ng · g(-1)).     

危废填埋项目环境水文地质勘查与分析

文中以宿迁市某危废填埋项目为例,采用水文地质调查、抽水试验、渗水试验等多种水文地质勘查方法,查明了评价区内的环境水文地质条件与特征,获得了预测评价所需的水文地质参数,为地下水环境影响评价提供了基础资料,也作为类似工程的场地环境水文地质勘查工作的参考。     

Measurements of Pollutants inside an Automobile

A series of experiments was conducted to determine the concentration of certain pollutants inside a car under typical driving conditions. The work was performed during the summer months in the Los Angeles area and measurements of O₃, CO, NO, and NO_x were taken. It was found that the O₃ concentration in the passenger compartment may be maintained at relatively low values provided that the influx of outside air is limited. The low levels were explained by decay of O₃ on surfaces within the compartment. The average concentration of the other components inside the car is about equal to that on the outside. In the current tests, however, the measured concentrations did not exceed any of the present standards.     

Measurements of Rural Sulfur Dioxide and Particle Sulfate: Analysis of CASTNet Data, 1987 through 1996

ABSTRACT

The Clean Air Status and Trends Network (CASTNet) was implemented by the U.S. Environmental Protection Agency (EPA) in 1991 in response to Title IX of the Clean Air Amendments of 1990, which mandated the deployment of a national ambient air monitoring network to track progress of the implementation of emission reduction programs in terms of deposition, air quality, and changes to affected ecosystems. CASTNet evolved from the National Dry Deposition Network (NDDN). CASTNet currently consists of 45 sites in the eastern United States and 28 sites in the West. Each site measures sulfur dioxide (SO₂), nitric acid (HNO₃), particle sulfate (SO₄ ⁼), particle nitrate (NO₃ ^- ), and ozone. Nineteen sites collect precipitation samples. NDDN/CASTNet uses a uniform set of site-selection criteria which provides the data user with consistent measures to compare each site. These criteria also ensure that, to the extent possible, CASTNet sites are located away from local emission sources.

This paper presents an analysis of SO₂ and SO₄ ⁼ concentration data collected from 1987 through 1996 at rural NDDN/CASTNet sites. Annual and seasonal variability is examined. Gradients of SO₂ and SO₄ ⁼ are discussed. The variability of the atmospheric mix of SO₂ and SO₄ ⁼ is explored spatially and seasonally. Data from CASTNet are also compared to SO₂ and SO₄ ⁼ data from concurrent monitoring studies in rural areas.     

Experimental Verification of Diffusion Battery Theory

The diffusion battery, an assembly of circular tubes or rectangular channels, is one of the best devices available for measuring the size and size distribution of submicron aerosols in the diameter range 0.002 to 0.2 µ m. The performance of these batteries is known from molecular diffusion theory, but until now has not been checked experimentally in this size range because of the lack of the necessary monodisperse aerosols. Experimental measurements on singly charged monodisperse aerosols from 0.01 µm to 0.1 µ m are described using a General Electric and a Pollak condensation nucleus counter to measure the aerosol penetration through the stages of a set of portable diffusion batteries in series. Particle sizes in the range tested could be selected at will by adjusting the voltage of an electric mobility classifier. The fraction of aerosol of a given size passing through each battery stage was found to agree closely with the penetration calculated from molecular diffusion theory for that size. This shows that the theory is correct and confirms that the aerosol produced by the electric mobility classifier was monodisperse. In addition, it was found that the difference in penetration between a charged versus a neutralized aerosol was insignificant except for the smallest aerosols used.     

印染废水集中处理工程的实例分析

针对印染企业集中园区产生的综合废水复杂多变,必要选择合式的处理工艺,因此,以某印染企业集中园区的污水处理厂为例,采用厌氧＋好氧＋物化组合工艺,并对废水的脱色和可生化性的改善进行了试验研究,通过类比调查,优化工程设计参数;经工程实践证明,综合印染废水经该工艺处理后,能达到一级排放标准.     

Measurements of ammonia emission from grazed grassland

Some of the factors influencing NH(3) emission from grazed grassland were examined. The large day-to-day variation in rates of loss were only partially explained by variation in the measured environmental factors (wind speed, soil and air temperature, soil moisture status, relative humidity, rainfall and potential evapotranspiration). Of the measured variables, wind speed had the largest effect but the best multiple linear regression model of daily NH(3) loss had an adjusted R(2) value of only 0.406. The mechanisms controlling NH(3) flux were therefore unclear. There were marked diurnal rhythms in NH(3) loss and the concentration gradients above the sward were strongest during the period which included the 3 h each side of midday. This pattern of NH(3) release has important implications in relation to atmospheric mixing processes and chemical reactions. A comparison of two means of determining NH(3) concentrations, i.e. a bubbler collection system or denuder tubes, indicated that different forms were collected which could be related to the environmental conditions. Such differences and effects should be considered when models are developed to describe the behaviour of nitrogenous and other species in the atmosphere.     

Ambient Air Measurements of Petroleum Refinery Emissions

An ambient air monitoring program to characterize airborne emissions from the Exxon petroleum refinery at Benicia, California was conducted during September 8–22, 1975. Ground level sampling facilities and an instrumented aircraft provided an integrated, three-dimensional monitoring network. Measurements made during the study included ozone, oxides of nitrogen, methane, carbon monoxide, individual C₂-C₆ hydrocarbons, halocarbons, condensation nuclei, visual distance and various meteorological parameters. The study focused on three major areas: (1) the characterization of gaseous components within the refinery effluent, especially non-methane hydrocarbons and ozone, (2) natural sunlight bag irradiation experiments to determine the ozone forming potential of refinery emissions, and (3) an investigation of changes in plume chemistry as refinery emissions were transported downwind.     

Empirical Validation of Turbine Engine Exhaust Measurements

The reliability and validity of gas turbine engine exhaust measurements are of concern to all who measure these effluents. In the past, one measure of reliability has been a carbon balance between the fuel used and the C, CO, hydrocarbons, and CO₂ emitted which requires that a F/A ratio be known accurately and that the analyzed sample be representative. In addition to this carbon balance, we have considered the relationships between the concentrations of the several component species. For example, the plot of volume percent of CO₂ versus the volume percent of O₂, both properly corrected to complete combustion, is a straight line. The intercept on the Y-axis (zero oxygen) is a function of the H to C mole ratio in the fuel. This relation has been theoretically established and also established by empirical calculations. For all valid measurements, all points corresponding to CO₂ and O₂ analyses fall on the straight line. In addition, smooth functional relationships exist between other exhaust gas constituents as well, although the form is not a simply derivable linear relationship like that for O₂-CO₂. We have found it useful to employ the following correlations: CO₂ vs. log NO_x, log CO vs. log THC, log CO vs. CO₂, and log THC vs. CO₂- These relationships serve to indicate the probability of reliable data and point out sampling problems and instrument problems such as drift. Subtle changes in engine operation such as opening of the accessory bleed ports in the compressor discharge of the engine can be detected.

The use of a combination of these curves can serve to indicate which measurement is in error. If the O₂-CO₂ relation is linear and the CO-CO₂ relation is smooth, then problems with the total hydrocarbon analyses are indicated when the CO-THC relation is erratic. This would be confirmed by a similar CO₂-THC plot. No useful smooth relationship between smoke density measurements and the other constituents has been found to date. This may indicate poor data, lack of sufficient data, or possibly no correlation.     

Real-Time Measurements of Jet Aircraft Engine Exhaust

Abstract

Particulate-phase exhaust properties from two different types of ground-based jet aircraft engines—high-thrust and turboshaft—were studied with real-time instruments on a portable pallet and additional time-integrated sampling devices. The real-time instruments successfully characterized rapidly changing particulate mass, light absorption, and polycyclic aromatic hydrocarbon (PAH) content. The integrated measurements included particulate-size distributions, PAH, and carbon concentrations for an entire test run (i.e., “run-integrated” measurements). In all cases, the particle-size distributions showed single modes peaking at 20–40nm diameter. Measurements of exhaust from high-thrust F404 engines showed relatively low-light absorption compared with exhaust from a turboshaft engine. Particulate-phase PAH measurements generally varied in phase with both net particulate mass and with light-absorbing particulate concentrations. Unexplained response behavior sometimes occurred with the real-time PAH analyzer, although on average the real-time and integrated PAH methods agreed within the same order of magnitude found in earlier investigations.     

Diffusion mechanism of lindane into wood charcoal

Abstract

The wood charcoal treated by 1N HNO₃ (WCT) was used to remove toxic chlorinated pesticide lindane (y‐HCH) residue from water by the sorption process. Using a simple first order reversible kinetics constants and half time equations, the film and pore diffusion coefficients were determined. Film diffusion was found to be rate limiting step in sorbing lindane by WCT. This was further authenticated by kinetics studies at different initial sorbate concentrations, different sorbent sizes, and different agitation speeds besides interruption test. A pore diffusion model was used to fit the data of kinetics in continuously mixed batch reactors (CMBR), and the tortuosity, external resistance, and surface diffusion effects on lindane sorption by WCT were noticed. The tortuosity values of 15 to 28 were obtained for WCT‐lindane system.