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1.
Nitroaromatic compounds are known to be hazardous to ecological and human health. To assess the status of nitroaromatic compounds contamination in the main rivers in the important industrial bases of the northeastern China, we collected water, suspended particulate matter (SPM) and sediment samples from 28 sites in the Daliao River watershed and analysed them for eight nitroaromatic compounds by gas chromatography. The total concentrations of eight nitrobenzenes in the water column including aqueous and SPM phases ranged from 740 to 15,828 ng L???1, with a mean concentration of 3,460 ng L???1. The total concentrations of eight nitrobenzenes in the sediment were 7.47 to 8,185.76 ng g???1, with a mean concentration of 921.98 ng g???1, and several times higher than those found from the Yellow River in China. 4-Nitrotoluene was the predominant contaminant in the water and sediment of the three rivers of the Daliao River watershed. 2,6-Dichloro-4-nitroaniline was generally dominant in the SPM. The levels of nitroaromatic compounds were different among different sites in the Daliao River watershed, mainly caused by the distribution of pollution sources. No obvious correlation was found between the total concentrations of eight nitrobenzenes concentrations and TOC or the slit-clay content of the sediments.  相似文献   

2.
The soils at a factory for manufacturing pentachlorophenol were heavily contaminated by polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). In order to verify the contributions of dry and wet deposition of PCDD/Fs from the ambient air, the concentration of PCDD/Fs in ambient air and soil were measured, the partition of particle- and gas-phases of atmospheric PCDD/Fs was calculated, and the annual fluxes of total dry and wet PCDD/F depositions were modeled. Average atmospheric PCDD/F concentration was 1.24 ng Nm???3 (or 0.0397 ng I-TEQ Nm???3). Moreover, over 92.8% of total PCDD/Fs were in the particle phase, and the dominant species were high chlorinated congeners. The total PCDD/F fluxes of dry and wet deposition were 119.5 ng m???2 year???1 (1.34 ng I-TEQ m???2 year???1) and 82.0 ng m???2 year???1 (1.07 ng I-TEQ m???2 year???1), respectively. By scenario simulation, the total fluxes of dry and wet PCDD/F depositions were 87.1 and 68.6 ng I-TEQ, respectively. However, the estimated PCDD/F contents in the contaminated soil were 839.9 ?? g I-TEQ. Hence, the contributions of total depositions of atmospheric PCDD/F were only 0.02%. The results indicated that the major sources of PCDD/F for the contaminated soil could be attributed to the pentachlorophenol manufacturing process.  相似文献   

3.
Ships are significant air pollution sources as their high powered main engines often use heavy fuels. The major atmospheric components emitted are nitrogen oxides, particulate matter (PM), sulfur oxide gases, carbon oxides, and toxic air pollutants. Shipping emissions cause severe impacts on health and environment. These effects of emissions are emerged especially in territorial waters, inland seas, canals, straits, bays, and port regions. Candarli Gulf is one of the major industrial regions on the Aegean side of Turkey. The marine environment of the region is affected by emissions from ships calling to ten different ports. In this study, NO x , SO2, CO2, hydrocarbons (HC), and PM emissions from 7,520 ships are estimated during the year of 2007. These emissions are classified regarding operation modes and types of ships. Annual shipping emissions are estimated as 631.2 t year???1 for NO x , 573.6 t year???1 for SO2, 33,848.9 t year???1 for CO2, 32.3 t year???1 for HC, and 57.4 t year???1 for PM.  相似文献   

4.
High selenium (Se) concentrations have been found in surface waters in the Kendrick Reclamation Project, Wyoming. Precipitation and irrigation water moving over seleniferous soils are contributing causes, and drought may exacerbate this. This study surveyed Se concentrations and discharges in local surface streams, irrigation drains, and the delivery canal. Sites were sampled monthly and analyzed for Se and total suspended solids (TSS). A completely randomized design with two factors (soil parent material and location, inside or outside irrigation district) was used. Mean Se concentrations were 64 μg L???1 inside the irrigation district on shale soils, 17 μg L???1 inside the district off shale soils, 5 μg L???1 outside the district on shale soils, and 3 μg L???1 outside the district off shale soils. Correlations between discharge and Se concentrations were generally negative, while correlations between discharge and Se load were generally positive. There was little correlation between load and concentration, and little correlation between TSS and Se. A comparison of Se concentrations in streams and drains showed Se concentrations were significantly higher (p?<?0.001) in streams during the irrigation season, but not in the off-season (p?=?0.515). We conclude that higher discharges decrease Se concentration, but increase load. Conversion from flood to sprinkle irrigation may increase Se concentrations by reducing discharge, but decrease Se loads going into the N. Platte River, and will likely alter the timing and magnitude of flows. Both load and concentration should be considered when implementing Se regulations and standards.  相似文献   

5.
In this study, the variation of sewage quality was investigated and the active fraction of different microbial functional groups in biofilm was quantified in a 5.6-km trunk sewer line. The sewage quality including suspended solids, biochemical oxygen demand, total chemical oxygen demand (COD), total nitrogen, total Kjeldahl nitrogen, ammonia nitrogen, nitrite nitrogen, and nitrate nitrogen were measured and compared with the values in literatures. The results indicated that since the wastewater treatment plant was not operated at its full capacity, the concentrations of different compounds were lower compared with the values in literatures. The values of heterotrophic growth rate constant lay between 5.6 and 8.6 day???1. Its average value was 7.7 day???1. The values of heterotrophic lysis rate constant lay between 0.2 and 0.4 day???1. The active heterotrophic biomass in biofilm varied from 240 to 800 mg COD m???2 and average value was 497 mg COD m???2. The biofilm mass varied from 880 to 1,080 mg m???2. The percentage of heterotroph to biofilm mass fall within the range of 24.0–90.9% and average value was 52.9%. In the oxygen uptake rate batch tests, the biomass, growth rate constant, and lysis rate constant of autotroph could not be determined because the fraction of autotroph in biofilm was relatively few. It revealed that the degradation of organic matters, nitrification, and denitrification occurred in the trunk sewer line. But the results indicate that the condition seem favorable for nitrification.  相似文献   

6.
The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined by gas chromatography equipped with a mass spectrometry detector in 105 topsoil samples from an industrial area around Bohai Bay, Tianjin in the North of China. Results demonstrated that concentrations of PAHs in 104 soil samples from this area ranged from 68.7 to 5,590 ng g???1 dry weight with a mean of ∑16PAHs 814 ± 813 ng g???1, which suggests that there exists mid to high levels of PAH contamination. The concentration of ∑16PAHs in one soil sample from Tianjin Port was exceptionally high (48,700 ng g???1). Ninety-three of the 105 soil samples were considered to be contaminated with PAHs (>200 ng g???1), and 25 were heavily polluted (>1,000 ng g???1). The sites with high PAHs concentration are mainly distributed around chemical industry parks and near highways. Two low molecular weight PAHs, naphthalene and phenanthrene, were the dominant components in the soil samples, which accounted for 22.1% and 10.7% of the ∑16PAHs concentration, respectively. According to the observed molecular indices, house heating in winter, straw stalk combustion in open areas after harvest, and petroleum input were common sources of PAHs in this area, while factory discharge and vehicle exhaust were the major sources around chemical industrial parks and near highways. Biological processes were probably another main source of low molecular weight PAHs.  相似文献   

7.
Some wetland plant species are adapted to growing in the areas of higher metal concentrations. Use of such vegetation in remediation of soil and water contaminated with heavy metals is a promising cost-effective alternative to the more established treatment methods. Throughout the year, composite industrial effluents bringing various kinds of heavy metals contaminate our study site, the East Calcutta Wetlands, a Ramsar site at the eastern fringe of Kolkata city (formerly Calcutta), India. In the present study, possible measures for remediation of contaminated soil and water (with elements namely, Ca, Cr, Cu, Pb, Zn, Mn, and Fe) of the ecosystem had been investigated. Ten common regional wetland plant species were selected to study their efficiency and diversity in metal uptake and accumulation. Results showed that Bermuda grass (Cynodon dactylon) had the highest total Cr concentration (6,601 ± 33 mg kg???1 dw). The extent of accumulation of various elements in ten common wetland plants of the study sites was: Pb (4.4?C57 mg kg???1 dw), Cu (6.2?C39 mg kg???1 dw), Zn (59?C364 mg kg???1 dw), Mn (87?C376 mg kg???1 dw), Fe (188?C8,625 mg kg???1 dw), Ca (969?C3,756 mg kg???1 dw), and Cr (27?C660 mg kg???1 dw) indicating an uptake gradient of elements by plants as Ca>Fe>Mn>Cr>Zn>Cu>Pb. The present study indicates the importance of identification and efficiency of metal uptake and accumulation capabilities by plants in relation to their applications in remediation of a contaminated East Calcutta Wetland ecosystem.  相似文献   

8.
The distribution of fecal coliforms was investigated and determined in Izmir Bay from 1996 to 2005. Izmir Bay severely was polluted from industrial and domestic discharges during decades. In early 2000, a wastewater treatment plant began to treat domestic and industrial wastes. This plant treats the wastes about 80% capacity after 2001. The sampling periods cover before and after treatment plant. Assessment method for determining the number of fecal coliform has evolved membrane filtrations. Maximum surface fecal coliform concentration was 4.9 × 105 cfu 100 ml???1 in 1996–2000 period. Following the opening treatment system, fecal coliform density decreased 2.1 × 104 cfu 100 ml???1 during 2001–2005. A continuous improvement can be sustained in the water quality if direct inflow of untreated wastewater is prevented.  相似文献   

9.
The shipbuilding industry of Korea, ranked number one in the world in annual amount of ship orders, has contributed to national economic growth; however, this has resulted in various environmental problems. Characteristics of environmental pollution, such as particulate matters, odor, and noise, which are closely related with public complaints, were evaluated in an industrial shipbuilding complex. The concentrations of PM-10 and TSP were significantly affected by the distance between the measurement site and shipbuilding workplace, as well as the height of the measurement site. Average PM-10 concentrations in the residential area ranged from 40.10 to 44.10 ??g/m3, which were not high in comparison with the ambient air quality standard and those of major cities in Korea. Paint particles could affect a wider area than typical particulate matters due to their generation and transport properties. The properties of odor in the study area were widely affected by the work intensity in shipyards and the temperature. Twenty-five out of total 54 samples collected in the residential area exceeded the dilution factor of 10, which is the tolerable limit adopted in Korea. Noise had an influence on a limited area due to the extinction effect with distance from the shipyards, while severe noise levels higher than 90 dB(A) were frequently found inside the shipyards.  相似文献   

10.
The concentrations of seven heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, and Pb) associated with PM10 and PM2.5 at the crossroads and the background sites have been studied in Zabrze, Poland, during smog episodes. Although the background level was unusually elevated due to both high particulate emission from the industrial and municipal sources and smog favorable meteorological conditions, significant increase of the concentration of PM2.5 and PM10 as well as associated heavy metals in the roadside air compared to the urban background has been documented. The average daily difference between the roadside and corresponding urban background aerosol concentration was equal to 39.5 μg m???3 for PM10 and 41.2 μg m???3 for PM2.5. The highest levels of the studied metals in Zabrze appeared for iron carried by PM10 particles: 1,706 (background) and 28,557 ng m???3 (crossroads). The lowest concentration level (in PM10) has been found for cadmium: 7 and 77 ng m???3 in the background and crossroads site, respectively. Also the concentrations of heavy metals carried by the fine particles (PM2.5) were very high in Zabrze during the smog episodes. Concentrations of all studied metals associated with PM10 increased at the roadside compared to the background about ten times (one order) while metals contained in PM2.5 showed two to three times elevated concentrations (except Fe—five times and Cr—no increase).  相似文献   

11.
Pulp and paper mills generate varieties of pollutants depending upon type of the pulping process being used. This paper presents the characteristics of wastewater from South India Paper Mill, Karnataka, India which is using recycled waste paper as a raw material. The raw wastewater consists of 80?C90 mg L???1 suspended solid and 1,010?C1,015 mg L???1 dissolved solid. However, pH varied from 5.5?C6.8. The biochemical oxygen demand and chemical oxygen demand ranged from 200?C210 and 1,120?C1,160 mg L???1, respectively. Aerobic treatment of raw effluent attribute to significant reduction in suspended solid (range between 25 to 30 mg L???1) and total dissolved solid (range between 360 to 390 mg L???1). However, pH, temperature, and electrical conductivity were found superior after treatment. Copper, cadmium, iron, lead, nickel, and zinc were found in less quantity in raw effluent and were almost completely removed after treatment. The dendrogram of the effluent quality parameters clearly indicate that South India Paper Mill does not meet Minimal National Standard set by central Pollution Control Board to discharge in agricultural field.  相似文献   

12.
Airborne particulates (PM10) from four different areas within Agra city (a semi-arid region) were collected using respirable dust samplers during the winter season (Nov. 2005–Feb 2006) and were then extracted with methylene chloride using an automated Soxhlet Extraction System (Soxtherm®). The extracts were analyzed for 17 target polycyclic aromatic hydrocarbons (PAHs) and the heterocycle carbazole. The average concentration of total PAH (TPAH) ranged from 8.04 to 97.93 ng m???3. The industrial site had the highest TPAH concentration followed by the residential, roadside, and agricultural sites. Indeno(1,2,3-cd)pyrene, benzo(g,h,i)perylene, and benzo(b)fluoranthene were the predominant compounds found in the samples collected from all of the sites. The average B(a)P-equivalent exposure, calculated by using toxic equivalent factors derived from literature and the USEPA, was approximately 7.6 ng m???3. Source identification using factor analysis identified prominent three, four, four, and four probable factors at industrial, residential, roadside, and agricultural sites, respectively.  相似文献   

13.
Ambient air quality data, including atmospheric visibility, of Foshan city, a highly polluted city in the Pearl River Delta (PRD), and data obtained by the On-line Air Pollutant Exhaust Monitoring Network (OAPEMN), recently established by the National Emission Monitoring and Control Network for major industrial enterprises, were analyzed and are reported here for the first time, revealing the change in air pollution patterns and its impact on visibility degradation in the last decade. Reduced visibility of less than 8 km (after elimination of rainy and foggy periods) was found 22% of the time from 1998 to 2008, accompanied by elevated levels of pollutants, especially SO2 and PM10, in comparison with that of other developed cities. However, PM10 showed a steady decreasing trend (0.004 mg m???3 year???1) during 2001?C2008, in contrast to the noticeable increase in ambient NO2 concentrations from ~0.020 mg m???3 before 2005 to above 0.050 mg m???3 afterward. Multiple regression analysis revealed that the percentage of reduced visibility strongly correlated with PM10 concentration, suggesting that visibility degradation was directly proportional to the loading of particles. Moreover, the fairly significant correlation between reduced visibility and NO2 concentration also implied that the impact of primary emissions of NO2 and enhanced secondary pollutants, formed via photochemical processes in the atmosphere, could not be ignored. The decreased PM10 levels were obviously the predominant factor for the improvement in visibility (5.0% per 0.01 mg m???3) and were likely due to the implementation of stricter air pollution control measures for industrial exhaust, which also resulted in reduced SO2 pollution levels in the recent 2 years. In particular, the OAPEMN records showed an overall enhanced SO2 removal by 64% in major industrial sectors. The continuous increase in road traffic and lack of efficient NO x control strategies in the PRD region, however, caused an increase in ambient NO2 concentrations.  相似文献   

14.
Annual trends of a group of 66 volatile organic compounds (VOCs), containing 20 ozone precursors, were the aim of a sampling campaign carried out for a year in air at urban and industrial areas from Tarragona region. VOCs were determined by active collection on multisorbent tubes, followed by thermal desorption and gas chromatography–mass spectrometry. The analytical method was developed and validated, showing good levels of detection and quantification, recoveries, precision, and linearity for all the compounds in the range being studied. All the industrial and urban samples taken during the sampling campaign were similar in their qualitative composition. The most abundant compound in all urban and industrial sites was i-pentane, with concentrations between 15.2 and 202.1 μg m???3 in urban sites and between 1.3 and 98.6 μg m???3 in industrial sites. In urban sites, the following compounds in order of abundance were toluene, n-pentane, m,p-xylene, and o-xylene, with maximum levels of 150.6, 45.8, 42.3, and 31.7 μg m???3, respectively. In industrial sites, the most abundant compounds depended on the sampled site.  相似文献   

15.
This study assesses the level of background radiation for Canakkale province of northwestern Turkey. Radon concentrations in indoor air were determined using CR-39 nuclear track detectors and 222Rn activity was found to be 167 Bq m???3 (equivalent to an annual effective dose of 4.2 mSv). Measurements of outdoor gamma radiation (of terrestrial and cosmic origin) in air were performed using plastic scintillators, and the average absorbed gamma dose rate was found to be 66.4 nGy h???1 (corresponding to an annual effective dose of 81.4 μSv). The radionuclide activity concentrations in soil samples collected from the study area were measured through gamma-ray spectrometry, and the average activities were determined as 94.55, 110.4, and 1,273 Bq kg???1 for the natural radionuclides 238U, 232Th, and 40K, respectively, and 19.39 Bq kg???1 for the fission product 137Cs. The natural radioactivity sources resulted in an annual effective dose of 184 μSv. The radioactivity levels of drinking water samples were measured as 0.0599 Bq l???1 for gross-alpha activity and 0.0841 Bq l???1 for gross-beta activity using a low-background counting technique (equivalent to an annual effective dose of 12.25 μSv). The results of this study show that the activity levels of radon in air, radionuclides in soil, and alpha activities in drinking water are higher compared to the data available for other Turkish cities and the world averages. On the other hand, the outdoor gamma dose rates in air and beta activities in drinking water are within natural limits.  相似文献   

16.
Port causes environmental and health concerns in coastal cities if its operation and development are not made environmentally compatible and sustainable. An emission inventory is necessary to assess the impact of port projects or growth in marine activity as well as to plan mitigation strategies. In this study, a detailed emission inventory of total suspended particulate (TSP) matter, respirable particulate matter (PM10), sulphur dioxide (SO2) and oxides of nitrogen (NOx) for a port having operation and construction activities in parallel is compiled. The study has been done for 1 year. Results show that the maximum contribution of emission of air pollutants in the port area was from TSP (68.5%) and the minimum was from SO2 (5.3%) to the total pollutants considered in this study. Total TSP emission from all activities of the port was 4,452 tyr???1 and PM10 emission was 903 tyr???1 in the year 2006. Re-suspension of dust from paved roads was the major contributor of TSP and PM10 in the road transport sector. Construction activities of the port had contributed 3.9% of TSP and 7.4% of PM10 to total emission of particulate matter. Of the total particulate emissions from various port activities approximately 20% of TSP could be attributed to PM10. The sectoral composition indicates that major contribution of SO2 emission in the port was from maritime sector and major contribution of NOx was from road transport sector.  相似文献   

17.
A sensitive adsorptive stripping voltammetric method for the determination of simeton with universal buffer solution has been described. The method was based on the adsorption accumulation of simeton at a hanging mercury drop electrode. The overall reduction process is under controlled diffusion. The adsorptive peak was observed at ?0.8 V vs SCE in acidic solution 2 < pH < 6. The peak response was characterized with respect to pH, accumulation potential, time, and scan rate. The calibration plot was found to be linear from 1.13 × 10???5 to 3.5 × 10???8 M with a limit of detection of 2.0 × 10???8 M. Finally, the method has been applied for the determination of simeton in its formulations and vegetable samples.  相似文献   

18.
Cd, Co, Cr, Cu, Mn, Ni, Zn, and Pb were measured in feather samples of adult, subadult, and juvenile of Larus dominicanus, sampled in the Florianólis, SC, in the south of Brazil in December 2005, by flame atomic absorption spectrophotometry. The average of the distribution of Cd concentration in adult feathers (0.072 μg g???1) was significantly different than that found in juvenile feathers (0.021 μg g???1). Cu concentration averages were not significantly different between adults (13.30 μg g???1), subadults (9.67 μg g???1), and juveniles (13.76 μg g???1). For adults and juveniles there was significant difference in feather concentrations for Cd, Co, Cr, Ni, and Pb. The distribution of Mn concentration averages in feathers differs between adults (11.36 μg g???1) and juveniles (1.184 μg g???1). Ni concentration averages of adults (5.92 μg g???1) were significantly higher than those of juveniles (2.23 μg g???1). For Pb, concentration averages were significantly higher in adults (7.53 μg g???1) than in juveniles (1.47 μg g???1). The concentration of Co and Cr in juvenile and subadults are statistically different when compared with the adults. In the present study, levels of Cd, Co, Cr, Mn, Ni, Zn, and Pb increased with age. The concentrations of essential trace elements in L. dominicanus were generally comparable to values reported in other studies. With non-essential metals (Cd, Pb, and Ni), in our study, L. dominicanus had lower values than those reported for their northern Atlantic counterparts.  相似文献   

19.
A large variety of ornamental and decorative items are manufactured from bone waste by various unorganized sectors in India. An initial survey indicated that workers were exposed at various phases of final product. The subjects (12 industrial units) were tested for total suspended particulate matter (TSPM), particulate matter <10  $\upmu $ m (PM10), and particulate matter <2.5  $\upmu $ m (PM2.5). Prevalent levels of TSPM ranged between 2.90 and 5.89 mg m???3. Respirable fractions of occupational dust as PM10 and PM2.5 were found in the range of 0.30?C2.08 and 0.26?C0.50 mg m???3, respectively. Cytotoxicity study was conducted using hemolysis as a sensitive marker. In an in vitro study, rat RBCs were exposed to the concentration of 25?C1,000  $\upmu $ g/ml for 15?C120 min. A considerable variation was observed in the hemolytic activity of samples collected from different areas. At 500  $\upmu $ g/ml concentration, the hemolytic activity (12 h) was found to be in the range of 18?C25%. Due to limitation in sample mass of respirable fractions, only one concentration (100  $\upmu $ g/ml/2 h) was used for comparative study on hemolysis of RBCs caused by PM10 and PM2.5. Interestingly, the hemolytic activity was more at PM2.5 than PM10 and TSPM. These results suggest that the respirable particles are capable of reaching deep into the respiratory system. The finding is significant notably when there are no standards available in occupationally exposed populations. This is the first such study. Data could be of importance to policy makers and regulators.  相似文献   

20.
Bioaerosols are a type of suspended sediments that contribute to poor air quality in Taiwan. Bioaerosols include allergens such as: fungi, bacteria, actinomycetes, arthropods and protozoa, as well as microbial products such as mycotoxins, endotoxins and glucans. When allergens and microbial products are suspended in the air, local air quality will be influenced adversely. In addition, when the particle size is small enough to pass through the respiratory tract entering the human body, the health of the local population is also threatened. Therefore, the purpose of this study is to attempt to understand the concentration and types of bacteria and the bacteria numbers for various particle size ranges during a study period of June 2005 to February 2006 in Taichung City, Central Taiwan. The results indicate that the total average bacterial concentration by using NA medium incubated for 48 h were 8.0 × 102, 1.4 × 103, 2.4 × 103 and 1.3 × 103, 1.9 × 103, 3.5 × 103 cfu/m3 for CMES, TRIPS and RFS sampling sites during the daytime and nighttime period of June 2005 to February 2006. Moreover, the total average bacterial concentration by using R2A medium incubated for 48 h were 8.5 × 102, 1.5 × 103, 2.2 × 103 and 1.2 × 103, 1.7 × 103, 2.5 × 103 cfu/m3 for CMES, TRIPS and RFS sampling sites the daytime and nighttime during the same sampling period. The total average bacteria concentration was the same in either NA or R2A medium for the same sampling times or sites. The total average bacterial concentration was higher in daytime period than that of nighttime period for CMES, TRIPS and RFS sampling sites. The high average bacterial concentration was found in the particle size range of 0.53–0.71 mm (average bioaerosol size was in the range of 2.1–4.7 μm) for each sampling site. Also, 20 kinds of bacteria exceeded levels for each sampling site and were classified as according to shape: rod, coccus and filamentous.  相似文献   

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