Seasonality of selected surface water constituents in the Indian River Lagoon, Florida

Seasonality is often the major exogenous effect that must be compensated for or removed to discern trends in water quality. Our objective was to provide a methodological example of trend analysis using water quality data with seasonality. Selected water quality constituents from 1979 to 2004 at three monitoring stations in southern Florida were evaluated for seasonality. The seasonal patterns of flow-weighted and log-transformed concentrations were identified by applying side-by-side boxplots and the Wilcoxon signed-rank test (p < 0.05). Seasonal and annual trends were determined by trend analysis (Seasonal Kendall or Tobit procedure) using the U.S. Geological Survey (USGS) Estimate TREND (ESTREND) program. Major water quality indicators (specific conductivity, turbidity, color, and chloride), except for turbidity at Station C24S49, exhibited significant seasonal patterns. Almost all nutrient species (NO(2)-N, NH(4)-N, total Kjeldahl N, PO(4)-P, and total P) had an identical seasonal pattern of concentrations significantly greater in the wet than in the dry season. Some water quality constituents were observed to exhibit significant annual or seasonal trends. In some cases, the overall annual trend was insignificant while opposing trends were present in different seasons. By evaluating seasonal trends separately from all data, constituents can be assessed providing a more accurate interpretation of water quality trends.     

Vegetation dynamics in impounded marshes along the Indian River Lagoon,Florida, USA

Data are presented on the vegetation dynamics of two impounded marshes along the Indian River Lagoon, in east-central Florida, USA. Vegetation in one of the marshes (IRC 12) was totally eliminated by overflooding and by hypersaline conditions (salinities over 100 ppt) that developed there in 1979 after the culvert connecting the marsh with the lagoon was closed. Over 20% recovery of the herbaceous halophytesSalicornia virginica, S. bigelovii, andBatis maritima was observed at that site after the culvert was reopened in 1982, but total cover in the marsh remains well below the original 75%. No recovery of mangroves was observed at this site. The second site (SLC 24), while remaining isolated from the lagoon during much of the study, did not suffer the complete elimination of vegetation experienced at the first site. At this location, mangroves increased in cover and frequency with a concomitant decrease in herbaceous halophytes. Considerable damage to the vegetation was evident at IRC 12 when the impoundment was closed and flooded for mosquito control in 1986. Although the damage was temporary, its occurrence emphasizes the need of planning and constant monitoring and adjustment of management details as conditions within particular marshes change. Storms and hurricanes may be important in promoting a replacement of black mangroves by red mangroves in closed impoundments because the former cannot tolerate pneumatophore submergence for long periods of time. University of Florida-IFAS Journal Series R-00521.     

Assessing the Effects of Nutrient Management in an Estuary Experiencing Climatic Change: The Neuse River Estuary, North Carolina

Eutrophication is a serious water quality problem in estuaries receiving increasing anthropogenic nutrient loads. Managers undertaking nutrient-reduction strategies aimed at controlling estuarine eutrophication are faced with the challenge that upstream freshwater segments often are phosphorus (P)-limited, whereas more saline downstream segments are nitrogen (N)-limited. Management also must consider climatic (hydrologic) variability, which affects nutrient delivery and processing. The interactive effects of selective nutrient input reductions and climatic perturbations were examined in the Neuse River Estuary (NRE), North Carolina, a shallow estuary with more than a 30-year history of accelerated nutrient loading and water quality decline. The NRE also has experienced a recent increase in Atlantic hurricanes and record flooding, which has affected hydrology and nutrient loadings. The authors examined the water quality consequences of selective nutrient (P but not N) reductions in the 1980s, followed by N reductions in the 1990s and an increase in hurricane frequency since the mid-1990s. Selective P reductions decreased upstream phytoplankton blooms, but increased downstream phytoplankton biomass. Storms modified these trends. In particular, upstream annual N and P concentrations have decreased during the elevated hurricane period. Increased flushing and scouring from storms and flooding appear to have enhanced nutrient retention capabilities of the NRE watershed. From a management perspective, one cannot rely on largely unpredictable changes in storm frequency and intensity to negate anthropogenic nutrient enrichment and eutrophication. To control eutrophication along the hydrologically variable freshwater–marine continuum, N and P reductions should be applied adaptively to reflect point-source–dominated drought and non–point-source–dominated flood conditions.     

Toward Reversal of Eutrophic Conditions in a Subtropical Estuary: Water Quality and Seagrass Response to Nitrogen Loading Reductions in Tampa Bay, Florida, USA

Coastal waters have been significantly influenced by increased inputs of nutrients that have accompanied population growth in adjacent drainage basins. In Tampa Bay, Florida, USA, the population has quadrupled since 1950. By the late 1970s, eutrophic conditions including phytoplankton and macroalgal blooms and seagrass losses were evident. The focus of improving Tampa Bay is centered on obtaining sufficient water quality necessary for restoring seagrass habitat, estimated to have been 16,400 ha in 1950 but reduced to 8800 ha by 1982. To address these problems, targets for nutrient load reductions along with seagrass restoration goals were developed and actions were implemented to reach adopted targets. Empirical regression models were developed to determine relationships between chlorophyll a concentrations and light attenuation adequate for sustainable seagrass growth. Additional empirical relationships between nitrogen loading and chlorophyll a concentrations were developed to determine how Tampa Bay responds to changes in loads. Data show that when nitrogen load reduction and chlorophyll a targets are met, seagrass cover increases. After nitrogen load reductions and maintenance of chlorophyll a at target levels, seagrass acreage has increased 25% since 1982, although more than 5000 ha of seagrass still require recovery. The cooperation of scientists, managers, and decision makers participating in the Tampa Bay Estuary Program’s Nitrogen Management Strategy allows the Tampa Bay estuary to continue to show progress towards reversing many of the problems that once plagued its waters. These results also highlight the importance of a multi-entity watershed management process in maintaining progress towards science-based natural resource goals.     

Suspended sediment, nitrogen and phosphorus concentrations and exports during storm-events to the Tuross estuary, Australia

This paper presents a process for estimating pollutant loads from water quality data, to improve catchment-scale modelling in the region for resource management purposes. It describes a program to estimate suspended sediment, total and dissolved nitrogen and phosphorus loads to the Tuross estuary from the Tuross River catchment (1810 km(2)) of coastal southeast Australia. Event-based water quality sampling results obtained during storm events in 2005 are presented. Event 1, during July 2005 was the largest storm event in terms of peak flow for 3.5 years. Other events monitored were also in July, November and December 2005. The early July 2005 event had a flow-weighted mean suspended sediment (SS) concentration during the first 4 days of 63 mg L(-1). Of the events monitored, this was unusual as it was preceded by drought and had the largest SS concentrations (peaking at 180 mg L(-1)) during the rising-stage. In contrast, the November event had a much lower flow-weighted SS mean (28 mg L(-1)), even though peak flow magnitudes were similar. The July and November 2005 events had peak flows of 12,360 and 11,330 ML day(-1). Low-cost rising-stage siphon samplers were used to collect samples during the rapidly rising phase of these events. The use of such samplers and consideration of time-lead/lag flow adjustments, quantified using cross-correlation analysis to account for hysteresis effects, were incorporated into the load estimation techniques. The technique is a potentially useful approach for understanding relationships between water quality concentrations and flow for modelling catchment source strengths and transport processes.     

Summer total phosphorus in lakes: A map of Minnesota,Wisconsin, and Michigan,USA

A map of summer total phosphorus in lakes has been compiled for Minnesota, Wisconsin, and Michigan to clarify regional patterns in attainable lake trophic state. Total phosphorus was used as a measure of lake trophic state because: (1) phosphorus plays a central role in controlling the overall fertility of most lakes, (2) total phosphorus values are available for a great number of lakes, and (3) phosphorus is measured in a consistent manner. The maps were compiled using patterns of total phosphorus data and observed associations between these data and geographic characteristics including physiography, land use, geology, and soils. Regions depicted on the map represent areas of similarity in phosphorus concentrations in lakes, or similarity in the mosaic of values, as compared to adjacent areas. Within each region, differences in total phosphorus can be compared to natural and anthropogenic factors to determine the types of lakes representative of each region, the factors associated with differences in quality, and the realistically attainable phosphorus levels for each type of lake.     

Application of nutrient loading models to the analysis of trophic conditions in Lake Okeechobee,Florida

Lake Okeechobee (surface area = 1830 km², mean depth = 3.5 m), the largest lake in Florida, is eutrophic and has nitrogen and phosphorus loading rates in excess of nearly all established criteria. The lake is not homogeneous regarding trophic conditions, and spatial and temporal variations occur regarding nutrient limitation. Nonetheless, phosphorus loading rate and trophic state data fit reasonably well to various input-output models developed for temperate lakes. Modification of the models by regression analysis to fit data for Florida lakes resulted in improved predictions for most parameters. Analysis of nutrient management alternatives for the lake indicates that a 75% reduction of phosphorus loading from the largest source (the Taylor Creek-Nubbins Slough watershed) would reduce the average chlorophyll a concentration by less than 20%. Complete elimination of inputs from the largest nitrogen source (the Everglades Agricultural Area) would decrease the average nitrogen concentration in the lake by about 20%. Limitations of nutrient inputoutput models regarding analysis of trophic conditions and management alternatives for the lake are discussed.     

Index models to evaluate the risk of phosphorus and nitrogen loss at catchment scales

This paper investigates index models as a tool to estimate the risk of N and P source strengths and loss at the catchment scale. The index models assist managers in improving the focus of remediation actions that reduce nutrient delivery to waterbodies. N and P source risk factors (e.g. soil nutrient concentrations) and transport risk factors (e.g. distance-to-streams) are used to determine the overall risk of nutrient loss for a case study in the Tuross River catchment of coastal southeast Australia. In the development of the N index model for Tuross, particulate N was considered important based on the observed event water quality data. In contrast to previous N index models, erosion and contributing distance were therefore included in the Tuross River catchment N index. Event-based water quality monitoring, and soil information, or in data-poor catchments conceptual understanding, are essential to represent catchment-scale processes. The techniques have high applicability in other catchments, and are complementary to other modelling techniques such as process-based semi-distributed modelling. Index models generally provide much more detailed spatial resolution than fully- or semi-distributed conceptual modelling approaches. Semi-distributed models can be used to quantify nutrient loads and provide overall direction to set the broad focus of management. Index models can then be used to refine on-the-ground investigations and investment priorities. In this way semi-distributed models can be combined with index models to provide a set of powerful tools to influence management decisions and outcomes.     

Time Series Forecasting of Cyanobacteria Blooms in the Crestuma Reservoir (Douro River, Portugal) Using Artificial Neural Networks

In this work, time series neural networks were used to predict the occurrence of toxic cyanobacterial blooms in Crestuma Reservoir, which is an important potable water supply for the Porto region, located in the north of Portugal. These models can potentially be used to provide water treatment plant operators with an early warning for developing cyanobacteria blooms. Physical, chemical, and biological parameters were collected at Crestuma Reservoir from 1999 to 2002. The data set was then divided into three independent time series, each with a fortnightly periodicity. One training series was used to “teach” the neural networks to predict results. Another series was used to verify the results, and to avoid over-fitting of the data. An additional independently collected data series was then used to test the efficacy of the model for predicting the abundance of cyanobacteria. All of the models tested in this study incorporated a prediction time (look-ahead parameter) equal to the sampling interval (two weeks). Various lag periods, from 2 to 52 weeks, were also investigated. The best model produced in this study provided the following correlations between the target and forecast values in the training, verification, and validation series: 1.000 (P = 0.000), 0.802 (P = 0.000), and 0.773 (P = 0.001), respectively. By applying this model to the three-year data set, we were able to predict fluctuations in cyanobacteria abundance in the Crestuma Reservoir, with a high level of precision. By incorporating a lag-period of eight weeks, we were able to detect secondary fluctuations in cyanobacterial abundance over the annual cycle.     

Sources of water pollution and evolution of water quality in the Wuwei basin of Shiyang river, Northwest China

Based on surveys and chemical analyses, we performed a case study of the surface water and groundwater quality in the Wuwei basin, in order to understand the sources of water pollution and the evolution of water quality in Shiyang river. Concentrations of major chemical elements in the surface water were related to the distance downstream from the source of the river, with surface water in the upstream reaches of good quality, but the river from Wuwei city to the Hongya reservoir was seriously polluted, with a synthetic pollution index of 25. Groundwater quality was generally good in the piedmont with dominant bicarbonate and calcium ions, but salinity was high and nitrate pollution occurs in the northern part of the basin. Mineralization of the groundwater has changed rapidly during the past 20 years. There are 23 wastewater outlets that discharge a total of 22.4 x 10(6)m(3)y(-1) into the river from Wuwei city, which, combined with a reduction of inflow water, were found to be the major causes of water pollution. Development of fisheries in the Hongya reservoir since 2000 has also contributed to the pollution. The consumption of water must be decreased until it reaches the sustainable level permitted by the available resources in the whole basin, and discharge of wastes must also be drastically reduced.     

Water Quality and Land Use Changes in the Alafia and Hillsborough River Watersheds,Florida, USA1

Abstract: Spatial distribution of land use can have a substantial effect on surface and groundwater quality. Our objective was to test for trends in flow components and water quality related to changes in land use in the Alafia and Hillsborough River watersheds in Florida, USA, over the period 1974‐2007. In addition, water quality statistics were evaluated in the perspective of numeric water quality criteria and proposed reclassification of segments of the Alafia River. Trends in 10 water quality parameters and three discharge variables were evaluated using a nonparametric trend detection test. Results of land use analysis indicated substantial urbanization and loss of agricultural land in the study area. Discharge variables did not exhibit significant trends, whereas trends in the majority of water quality concentrations were negative or nonsignificant with total nitrogen and total Kjeldahl nitrogen as exceptions showing positive trends. Changes in nutrient pathways could not be clearly identified. Considering recently promulgated numeric nutrient criteria and standards for dissolved fluoride, much of the Alafia River was found to be out of compliance. While there were land use changes and changes in water quality over the study period, it was difficult to identify a direct cause‐effect relationship. Responses to regulatory efforts, such as the Clean Water Act and improvements in phosphate mining practices, may have had greater impacts on water quality than changes in land use.     

An online water quality monitoring and management system developed for the Liming River basin in Daqing, China

This paper describes an online water quality monitoring and management system that was developed by combining a chemical oxygen demand sensor with an artificial neural network technology and a virtual instrument technique. The system was used to model the hydrological environment of the Liming River basin in Daqing City, China, in an effort to maintain the water quality in this basin at a level compatible with the status of Daqing City as a scenic resort. Operation of the system during the past 2 years has shown that an optimal allocation of water (including water released from an environmental reservoir to mitigate pollution events) could be achieved for the basin using the information gathered by the system; using mathematic models established for this system, the quantity of water released from the reservoir is adequate to improve the overall water environment. The results demonstrate that the system provides an effective approach to water quality control for environmental protection.     

Application of sediment quality guidelines in the assessment and management of contaminated surficial sediments in Port Jackson (Sydney Harbour), Australia

Sediments in the Port Jackson estuary are polluted by a wide range of toxicants and concentrations are among the highest reported for any major harbor in the world. Sediment quality guidelines (SQGs), developed by the National Oceanographic and Atmospheric Administration (NOAA) in the United States are used to estimate possible adverse biological effects of sedimentary contaminants in Port Jackson to benthic animals. The NOAA guidelines indicate that Pb, Zn, DDD, and DDE are the most likely contaminants to cause adverse biological effects in Port Jackson. On an individual chemical basis, the detrimental effects due to these toxicants may occur over extensive areas of the harbor, i.e., about 40%, 30%, 15% and 50%, respectively. The NOAA SQGs can also be used to estimate the probability of sediment toxicity for contaminant mixtures by determining the number of contaminants exceeding an upper guideline value (effects range medium, or ERM), which predicts probable adverse biological effects. The exceedence approach is used in the current study to estimate the probability of sediment toxicity and to prioritize the harbour in terms of possible adverse effects on sediment-dwelling animals. Approximately 1% of the harbor is mantled with sediment containing more than ten contaminants exceeding their respective ERM concentrations and, based on NOAA data, these sediments have an 80% probability of being toxic. Sediment with six to ten contaminants exceeding their respective ERM guidelines extend over approximately 4% of the harbor and have a 57% probability of toxicity. These areas are located in the landward reaches of embayments in the upper and central harbor in proximity to the most industrialised and urbanized part of the catchment. Sediment in a further 17% of the harbor has between one and five exceedences and has a 32% probability of being toxic. The application of SQGs developed by NOAA has not been tested outside North America, and the validity of using them in Port Jackson has yet to be demonstrated. The screening approach adopted here is to use SQGs to identify contaminants of concern and to determine areas of environmental risk. The practical application and management implications of the results of this investigation are discussed.     

Observations of Atmospheric Nitrogen and Phosphorus Deposition During the Period of Algal Bloom Formation in Northern Lake Taihu,China

Cyanobacterial blooms in Lake Taihu occurred at the end of April 2007 and had crucial impacts on the livelihood of millions of people living there. Excessive nutrients may promote bloom formation. Atmospheric nitrogen (N) and phosphorus (P) deposition appears to play an important role in algal bloom formation. Bulk deposition and rain water samples were collected respectively from May 1 to November 30, 2007, the period of optimal algal growth, to measure the bulk atmospheric deposition rate, wet deposition rate, and dry deposition rate for total nitrogen (TN; i.e., all species of nitrogen), and total phosphorus (TP; i.e., all species of phosphorus), in northern Lake Taihu, China. The trends of the bulk atmospheric deposition rate for TN and the wet deposition rate for TN showed double peaks during the observation period and distinct influence with plum rains and typhoons. Meanwhile, monthly bulk atmospheric deposition rates for TP showed little influence of annual precipitation. However, excessive rain may lead to high atmospheric N and P deposition rates. In bulk deposition samples, the average percentage of total dissolved nitrogen accounting for TN was 91.2% and changed little with time. However, the average percentage of total dissolved phosphorus accounting for TP was 65.6% and changed substantially with time. Annual bulk atmospheric deposition rates of TN and TP during 2007 in Lake Taihu were estimated to be 2,976 and 84 kg km⁻² a⁻¹, respectively. The results showed decreases of 34.4% and 78.7%, respectively, compared to 2002–2003. Annual bulk deposition load of TN for Lake Taihu was estimated at 6,958 t a⁻¹ in 2007 including 4,642 t a⁻¹ of wet deposition, lower than the values obtained in 2002–2003. This may be due to measures taken to save energy and emission control regulations in the Yangtze River Delta. Nevertheless, high atmospheric N and P deposition loads helped support cyanobacterial blooms in northern Lake Taihu during summer and autumn, the period of favorable algal growth.     

Mass Load-Based Pollution Management of the Han River and Its Tributaries, Korea

Spatio-temporal variations of biochemical oxygen demand (BOD) and total coliform (TC) in the Han River, Korea, were investigated in terms of concentration-based and mass loading-based approaches. Considering the river water quality criteria regulated by the Ministry of Environment in Korea, the tributaries linked to the mainstream of the Han River were found to be highly contaminated with respect to both BOD and TC and, in fact, most of the tributaries exceeded the maximum water quality criteria. To evaluate the pollution impact of tributaries on the mainstream, the monthly water quality monitoring data for six years (from 1995 to 2000) were collected from the Han River basin, and statistically analyzed using Pearson’s correlation coefficient. The results revealed that mass loading-based approach was superior to the concentration-based approach for effective Han River watershed management. Overall results supported that the mass loading-based approach associated with total maximum daily loads (TMDL) management would be a useful and suitable protocol in watershed management for improving the water quality of the Han River and protecting public health. Therefore, this study supporting TMDL management can be applicable to a wide array of contaminants and watershed settings in Korea.     

The Water Fluxes of the Yellow River to the Sea in the Past 50 Years, in Response to Climate Change and Human Activities

Since the 1970s, the water fluxes to the sea of the Yellow River have declined significantly. Based on data of precipitation, air temperature, the measured and “natural” river flow, the water diversion and consumption, and the areas of erosion and sediment control measures over the drainage basin, water fluxes to the sea of the Yellow River are studied in relation with the influences of changing climate and human activities. The Yellow River basin can be divided into different water source areas; multiple regression indicates that the variation in precipitation over different water source areas has different effect on water fluxes to the sea. In the period between 1970 and 1997, averaged air temperature over the whole Yellow River increased by about 1.0°C, from 16.5°C to 17.5°C, a factor that is negatively correlated with the water yield of the Yellow River. Water diversion and consumption has sharply increased and resulted in a significant decline in the water fluxes to the sea. Since the 1960s, erosion and sediment control measures have been practiced over the drainage basin. This factor, to a lesser degree, is also responsible for the decrease in water fluxes to the sea. A multiple regression equation has been established to estimate the change in water fluxes to the sea caused by the changes in precipitation, air temperature, water diversion and consumption, erosion, and sediment control measures, indicating that the contribution of water diversion and consumption to the variation in annual water flux to the sea is 41.3%, that of precipitation is 40.8%, that of temperature is 11.4%, and that of erosion and sediment control measures is 6.5%.     

Multinational,Freshwater Biomonitoring Programs in the Developing World: Lessons Learned from African and Southeast Asian River Surveys

Biomonitoring programs are widely used in developed countries. They also offer many advantages in assessing ecological consequences of perturbations in developing countries, including reducing the equipment-operation, maintenance, and training costs associated with physicochemical monitoring. Three case histories of river biomonitoring using freshwater organisms (fish, benthic macroinvertebrates, diatoms, zooplankton) are described that involve (1) documentation of environmental effects from long-term, large-scale applications of insecticides to control insect-vectors of river blindness (onchocerciasis) in 11 West African countries; (2) water quality assessments and restoration planning in and around national parks in three East African countries; and (3) evaluation of overall ecological health of the Lower Mekong River in four Southeast Asian countries. As in developed countries, benthic macroinvertebrates are the organisms most widely used in biomonitoring in developing countries. Conflicting opinions of system resilience and whether expected changes are within natural variation may result in differences in underlying hypotheses proposed, study designs implemented, and study execution; each may lead to uncorrectable bias. Direct transfers of approaches used from developed to developing countries are often appropriate; however, techniques dependent on pollution-tolerance values are often region specific and not transferable. Typically expressed concerns about applications of biomonitoring in developing countries include poor coordination among agencies; lack of legislation, identification keys, and trained personnel; and incomplete information on how tropical rivers function. Problems are real but solvable, as evident from accomplishments in several multicountry programs in developing countries. Developed countries requiring coordinated monitoring of international rivers may benefit from examining successful programs under way in developing countries.     

Comparison of two stream temperature models and evaluation of potential management alternatives for the Speed River, Southern Ontario

Concerns over increased water temperature of the Speed River as it flows through the City of Guelph in Southern Ontario and an observed relationship between summer stream temperatures and low dissolved oxygen levels in the river prompted an investigation into potential stream temperature management practices. Two mechanistic stream temperature models, SNTEMP and CE-QUAL-W2, were applied to the Speed River in order to gauge the effectiveness of various stream temperature management options. Calibrated versions of both models performed well (0.2 degrees C相似文献   

Importance of public information and perception for managing recreational activities in the Peel-Harvey estuary, Western Australia

Surveys of water recreational activities were conducted in the Peel-Harvey estuary. Channels used by recreationists to gain information about water quality, the perception of water quality and resulting behaviour were investigated. This study showed that personal perception, local knowledge and history, absence of warnings and residency were major factors contributing to risk perception and behaviour in this recreational community. Management strategies should take this information into account to achieve maximal outcomes.     

Heavy metal content and distribution in surface sediments of the Seyhan River, Turkey

Chemical fractionation of seven heavy metals (Cd, Cr, Cu, Mn, Ni, Pb and Zn) was studied using a modified three-step sequential procedure to assess their impacts in the sediments of the Seyhan River, Turkey. Samples were collected from six representative stations in two campaigns in October 2009 and June 2010, which correspond to the wet and dry seasons, respectively. The total metal concentrations in the sediments demonstrated different distribution patterns at the various stations. Cadmium was the only metal that was below detection at all stations during both sampling periods. Metal fractionation showed that, except for Mn and Pb, the majority of metals were found in the residual fraction regardless of sampling time, indicating that these metals were strongly bound to the sediments. The potential mobility of the metals (non-residual fractions) is reflected in the following ranking: Pb > Mn > Zn > Cu > Ni > Cr in October 2009 and Mn > Pb > Zn > Cu > Ni > Cr in June 2010. The second highest proportion of metals was bound to organic matter/sulfides, originating primarily from anthropogenic activities. Non-residual metal fractions for all stations were highest in June 2010, which may be linked to higher organic matter concentrations in the sediment samples with 1.40% and 15.1% in October 2009 and June 2010, respectively. Potential sediment toxicity was evaluated using the Risk Assessment Code (RAC). Based on RAC classification, Cd and Cr pose no risk, Cu and Ni pose low risk, Pb and Zn were classified as medium risk metals, while the environmental risk from Mn was high. In addition, based on the sediment quality guidelines (SQG), the Seyhan River can be classified as a river with no, to moderate, toxicological risks, based on total metal concentrations.