Assessment of Ground Water Vulnerability and its Application to the Development of Protection Strategy for the Water Supply Aquifer in Owerri, Southeastern Nigeria

Pollution vulnerability of theOwerri regional water supply aquifer wasevaluated as a basis for developing appropriateprotection strategy for the groundwaterresource. The assessment was accomplished usingLegrand, GOD, Siga and DRASTIC models.Techniques of the models generally involvedparameters rating and point count systems, whichare based on the evaluation of various parameterin relation to their capacity for enhancing orattenuating contaminants in the groundwatersystem. Field and laboratory evaluations of theparameters indicate that the Owerri areagenerally occupies a nearly, flat topographywith a relatively high groundwater recharge. Thearea is underlain by predominantly sandyfacies in the Northern area which grades intogravelly sequences towards the southwest. TheSoutheastern area is distinguished by thickclayey facies that thin westwards towards theOwerri metropolis. Effective hydraulicconductivity (Kz) in the downward directionranges from 1.44 × 10^-3 to 5.6 × 10^-9 m s^-1; with the upper limits reflecting coarsesands and gravelly units. The amount of clay andclay-size particles in the sandy and gravellyunits is negligible, suggesting that thesorptive capacity of the units is low. Depth towater table decreases southwards while hydraulichead gradients vary between 0.09 and 0.22.Groundwater occurs in unconfined conditions inmost places except in the southeastern zonewhere it is semi-confined due to the presence ofa clayey unit. The groundwater vulnerabilitymap developed on the basis of the models andseveral other thematic maps shows that theOwerri metropolis and the southwest area ofOwerri have high vulnerability, indicatinggroundwater pollution. The existing wastedisposal sites in these sub-areas should beabandoned and rehabilitated to forstall furtherpollution of the groundwater system. Areas tothe North and Southeast of Owerri have moderateand low vulnerabilities, respectively,indicating the relatively lower sensitivity ofthe groundwater system in the sub-areas tocontamination. The lower sensitivity couldfurther be matched with properly engineeredsanitary landfills in the event of choice ofsites, as an additional protective strategy forthe groundwater system.     

How Probability Survey Data Can Help Integrate 305(b) and 303(d)Monitoring and Assessment of State Waters

Section 305(b) of the United States’ Clean Water Act (CWA) requires states to assess the overall quality of waters in the states, while Section 303(d) requires states to develop a list of the specific waters in their state not attaining water quality standards (a.k.at impaired waters). An integrated, efficient and cost-effective process is needed to acquire and assess the data needed to meet both these mandates. A subset of presentations at the 2002 Environmental Monitoring and Assessment Program (EMAP) Symposium provided information on how probability data, tools and methods could be used by states and other entities to aid in development of their overall assessment of condition and list of impaired waters. Discussion identified some of the technical and institutional problems that hinder the use of EMAP methods and data in the analysis to identify impaired waters as well as development needs to overcome these problems.     

First Step for an Ecological Risk Assessment to Evaluate the Impact of Diffuse Pollution in Lake Vela (Portugal)

Lake Vela, located in the Portuguese littoral-centre, is a temperate shallow lake exhibiting a high trophic status. This aquatic ecosystem has been potentially exposed to contamination generated by agricultural and livestock activities held in their drainage basin, which seriously compromise their health. This work summarizes some background information and presents the problem formulation step of the ERA. Therefore, it evaluates the characteristics of the stressor(s), describes the ecological system and receptors and suggests a conceptual model, which predicts the potential exposure pathways, relating suspected sources to the defined endpoints. This introductory step also described an analysis plan on the entire study, which includes a delineation of the assessment design, data needs, measures, and methods for conducting the analysis phase of the risk assessment process.     

Environmental Monotoring and Assessment Program: Current Status of Virginian Province (U.S.) Estuaries

Monitoring of indicators of the ecological condition of bays, tidal rivers, and estuaries within the Virginian Biogeographic Province (Cape Cod, Massachusetts to Cape Henry, Virginia) was conducted annually by the U.S. EPA's Environmental Monitoring and Assessment Program (EMAP) during the summer months of 1990 to 1993. Data were collected at 425 probability-based stations within the Province. Indicators monitored included water quality (temperature, salinity, water clarity, and dissolved oxygen concentration), sediment contamination, sediment toxicity, benthic community structure, fish community structure, and fish gross external pathology. Data were used to estimate the current status of the ecological condition of Virginian Province estuarine resources, and provide a baseline for identifying possible future changes. Estimates, with 95% confidence limits, of the areal extent of impacted resources within the Province are provided. Data are also presented by estuarine class (large estuaries, small estuarine systems, and large tidal rivers). Results show that, overall, approximately half of the estuarine waters of the Virginian Province can be classified as impacted based on multiple indicators, with hypoxia being the major stressor.     

Screening-Level Risk Assessment of Di(2-ethylhexyl)phthalate for Aquatic Organisms Using Monitoring Data in Japan

Screening-level ecological risk assessments of di(2-ethylhexyl)phthalate (DEHP) for aquatic organisms in Japan were conducted using estimated statistical values based on surface water and sediment monitoring data and effect threshold values based on a large aquatic toxicity database. An alternative method is proposed to handle monitoring data that contain nondetects including multiple detection limits and to determine the statistical values of DEHP concentrations in Japanese surface waters. The No-Observed-Effect-Concentration (NOEC_water) of DEHP for aquatic life of 77 μ g/L was determined giving equal importance to both physical effects probably caused by undissolved DEHP and to the intrinsic toxicity potentially caused by DEHP. The NOEC_sediment of 615,000 μg/kg was determined by the Equilibrium Partitioning (EqP) theory, conservatively assuming a threshold effect level in the water column as the water solubility of 3 μ g/L. The potential risks of DEHP in Japanese water environments were characterized simply by comparing the margin of exposure (MOE) with a specified uncertainty multiplier (UM). The MOE is expressed as the ratio of NOEC_water or NOEC_sediment to the expected environmental concentrations such as the 95th percentiles of the estimated DEHP concentration distributions for surface water or sediment. The results of risk characterization show that all MOE values calculated using the statistical values of DEHP concentrations in Japanese surface waters and sediments are above 10, indicating minimal risk. Although the DEHP concentrations of some surface water samples showed MOE values of less than 10, considering environmental chemistry such as bioavailable fractions and the form of existence of DEHP in a water environment, we conclude that the current levels of DEHP are of little concern to aquatic life in the majority of Japanese surface waters and sediments.     

An Integrated Approach for Impact Assessment of Water Harvesting Techniques in Dry Areas: The Case of Oued Oum Zessar Watershed (Tunisia)

In the arid regions of Tunisia, considerable investments are being made to maintain the old water harvesting techniques and introduce new ones to capture the scarce amount of rainwater (100 mm to 230 mm annually) for agricultural and domestic purposes. However, no detailed assessment of the multiple effects and the costs and benefits of these techniques have been made so far. This paper summarizes the results of an in depth investigation of the multiple impacts (runoff mobilization, ground water recharge, agro-socio-economic impacts) of the water harvesting works undertaken in the watershed of oued Oum Zessar (southeastern Tunisia). The importance of interdisciplinary and integrated approaches was revealed through this detailed impact assessment and economic evaluation. In fact, the profitability of the water harvesting works depends largely on the criteria chosen. However, further refinements are needed to better include all possible impacts (positive and negative) that occur as a result of the installation of the water harvesting structures.     

Assessment of water quality of Manchar Lake in Sindh (Pakistan)

Manchar Lake is the largest natural freshwater lake in Pakistan. The Lake has received less fresh water in past few years. In addition, drainage water is being discharged in the Lake through Main Nara Valley Drain (MNVD) since many years. Consequently, concern has grown regarding the water quality of the Lake. The aim of this study was to assess the water quality of Manchar Lake and MNVD and the objectives were to determine physiochemical properties and the concentrations of common cations and anions as well as seven trace metals i.e. Cu, Ni, Zn, Co, Fe, Pb and Cd. The concentration of the trace metals were determined by simultaneous preconcentration and solvent extraction using flame atomic absorption spectrometer. Results of physicochemical parameters of Manchar Lake water samples showed mean pH 8.4 (±0.2), conductivity 2,310.3 (±581.3) μS cm⁻¹ and hardness (as CaCO₃) 213.1 (±62.3) mg l⁻¹. Mean concentrations of cations and anions were Na 521.5 (±49.7), Cl⁻ 413.6 (±225.7), Ca 70.7 (±12.9), Mg 56.2 (±28.9), K 17.6 (±6.5), 0.34 (±0.2) and 0.02 (±0.01) mg l⁻¹. Mean concentrations of trace metals were Zn 15.7 (±1), Fe 12 (±3.5), Pb 9 (±2.7), Cu 8.9 (±7.7), Ni 4.3 (±3.4), Co 4 (±3.4) and Cd 1.1 (±1) μg l⁻¹. MNVD water samples showed mean pH 8.9 (±0.8), conductivity 1,735.7 (±567.8) μS cm⁻¹ and hardness (as CaCO₃) 184.8 (±32.4) mg l⁻¹. In MNWD, the mean concentrations of cations and anions were Na 482.7 (±11.7), Cl⁻ 395.7 (±271.5), Ca 79.1 (±23.5), Mg 54.2 (±28.1), K 26.2 (±21.3), NO⁻³ 0.5 (±0.3) and 0.1 (±0.1) mg l⁻¹. Mean concentrations of trace metals observed in MNWD water were Fe 14.9(±3.5), Cd 8.3 (±9.4), Pb 6.9 (±2.4), Cu 6.6 (±3.1), Zn 6.2 (±1.8), Co 4.5 (±2.7), and Ni 3.5 (±2.9) μg l⁻¹. The pH of both Manchar Lake and MNVD waters and concentration of Pb in Manchar Lake and concentration of Cd in MNVD water were higher than the World Health Organisation’s guideline values for the drinking water quality. The water quality of Manchar Lake was found degraded.     

An Assessment on Variation of Sulphur Dioxide and Particulate Matter in Erzurum (Turkey)

Sulphur dioxide and PM₁₀ levels are investigated in Erzurum during the periods of 1990–2000 heating season to assess air pollution level. For that reason, emissions of sulphur dioxide and particulate matter were calculated by using consumption of fuels and Turkish emission factors. These emission values were evaluated together with air pollution levels, which were measured at six stations in Erzurum atmosphere during 1990–2000 winter periods. Results reveal that in 1990–1994 heating period, there is an increasing trend in the emissions and air pollution levels over Erzurum, and the air quality limits were not met. The daily 24 h limit (short-term limit) was exceeded 127 days in 1992–1993 winter period. The reason for this increase was found to be the switching to use of low-quality fossil fuels instead of cleaner ones. Results also indicated that there was a considerable decrease in emissions of air pollutants and air pollution levels after 1995. This can be explained by the consumption of more high-quality fossil fuels. The correlation coefficient of SO₂ with PM₁₀ is obtained as r² = 0.85, which is a high value supporting the idea that both pollutants are emitted from the same source.     

Ecotoxicological Assessment of the Impact of Residual Heavy Metals on Soil Nematodes in the Guadiamar River Basin (Southern Spain)

On 25 April 1998, as a consequence of the breaking of a dam containing the tailings of a pyrite mine, a land strip of approximately 43 km in length was covered with a layer of black sludge, containing high levels of heavy metals, along the Guadiamar River Basin (southern Spain). In this investigation we carried out an ecotoxicological assessment (field and laboratory studies) of the impact of residual heavy metals (Cu, Pb, Zn, Ni) on soil nematodes in the impacted riparian zone, two years after the huge mine spillage. Concentrations of residual heavy metals were significantly (P<0.05) higher at the impacted sampling sectors (S-2, S-3, S-4, S-5) than at the unpolluted (reference) sampling sector (S-1). Nickel however exhibited the lowest increases at the impacted sectors. As a consequence, correlation coefficients between concentrations of heavy metals and values of ecological indices were not significant for Ni. In contrast, copper, lead and zinc exhibited significant (P<0.05) negative correlation coefficients with ecological indices, particularly with diversity indices (including the~number of taxa). In addition, the toxicity of Cu and Pb to nematode test species (Aphelenchus avenae and Cephalobus persegnis) during short-term toxicity bioassays was much higher than the toxicity of Zn and Ni. We conclude that residual heavy metals were still influencing adversely the community of soil nematodes in the impacted riparian zone of the Guadiamar River Basin. Cu, Pb and, to a lesser extent, Zn would be major responsible for the observed impact.     

PCB levels in European eel (Anguilla anguilla) from two coastal lagoons of the Mediterranean

Eels are exposed to pollutants due to their unusual life cycle and are vulnerable to contamination associated with sediment due to their diet, feeding habits and territoriality. Since the 1980s, a decline in American and European eel populations has been recorded. The causes of this decline still are unknown but pollution from domestic and industrial effluents is known to be involved. Since little data is available on PCB contamination in eels from Italian waters, PCBs were measured in muscle of Anguilla anguilla captured in 2001 in two brackish ecosystems of the Mediterranean: the lagoons of Orbetello and Santa Giusta (Italy). PCBs were higher in samples from Orbetello lagoon than in those detected from Santa Giusta lagoon (P < 0.05). Congener and isomer analyses indicated Aroclor 1260 as a likely source of PCBs in the Orbetello and Santa Giusta samples. Only the toxic equivalents (TEQs) of mono-ortho PCBs were calculated.     

Hazardous Air Pollutants (HAPs) and their Effects on Biodiversity: An Overview of the Atmospheric Pathways of Persistent Organic Pollutants (POPs) and Suggestions for Future Studies

Atmospheric change comprises many phenomena, namely climate change, acidic deposition, stratospheric ozone depletion, SMOG, increasing trend of suspended particulate matter, and hazardous air pollutants (HAPs). Among HAPs, a particular group of Persistent Organic Pollutants (POPs), such as some organochlorine pesticides, has shown a variety of toxic effects, altering the biodiversity of many ecosystems. Because of their persistence in the environment, and of their long range transport, the study of the global cycle of POPs is important in understanding how they can affect biodiversity. This can be accomplished by coupling different approaches: toxicity and ecological studies, emission estimates, and the use of global models.     

Organic Liquids Storage Tanks Volatile Organic Compounds (VOCS) Emissions Dispersion and Risk Assessment in Developing Countries: The Case of Dar-Es-Salaam City, Tanzania

The emission estimation of nine volatile organic compounds (VOCs) from eight organic liquids storage tanks companies in Dar-es-Salaam City Tanzania has been done by using US EPA standard regulatory storage tanks emission model (TANKS 4.9b). Total VOCs atmospheric emission has been established to be 853.20 metric tones/yr. It has been established further that petrol storage tanks contribute about 87% of total VOCs emitted, while tanks for other refined products and crude oil were emitting 10% and 3% of VOCs respectively. Of the eight sources (companies), the highest emission value from a single source was 233,222.94 kg/yr and the lowest single source emission value was 6881.87 kg/yr. The total VOCs emissions estimated for each of the eight sources were found to be higher than the standard level of 40,000 kg/yr per source for minor source according to US EPA except for two sources, which were emitting VOCs below the standard level. The annual emissions per single source for each of the VOCs were found to be below the US EPA emissions standard which is 2,000~kg/yr in all companies except the emission of hexane from company F1 which was slightly higher than the standard. The type of tanks used seems to significantly influence the emission rate. Vertical fixed roof tanks (VFRT) emit a lot more than externally floating roof tanks (EFRT) and internally floating roof tanks (IFRT). The use of IFRT and EFRT should be encouraged especially for storage of petrol which had highest atmospheric emission contribution. Model predicted atmospheric emissions are less than annual losses measured by companies in all the eight sources. It is possible that there are other routes for losses beside atmospheric emissions. It is therefore important that waste reduction efforts in these companies are directed not only to reducing atmospheric emissions, but also prevention of the spillage and leakage of stored liquid and curbing of the frequently reported illegal siphoning of stored products. Emission rates for benzene, toluene, and xylene were used as input to CALPUFF air dispersion model for the calculation of spatial downwind concentrations from area sources. By using global positioning system (GPS) and geographical information system (GIS) the spatial benzene concentration contributed by organic liquid storage tanks has been mapped for Dar-es-Salaam City. Highest concentrations for all the three toxic pollutants were observed at Kigamboni area, possibly because the area is located at the wind prevailing direction from the locations of the storage tanks. The model predicted concentrations downwind from the sources were below tolerable concentrations by WHO and US-OSHA. The highest 24 hrs averaging time benzene concentration was used for risk assessment in order to determine maximum carcinogenic risk amongst the population exposed at downwind. Established risk for adult and children at 2.9×10^-3 and 1.9×10^-3 respectively, are higher than the acceptable US-EPA risk of 1×10^-6. It is very likely that the actual VOCs concentrations in some urban areas in Tanzania including Dar-es-Salaam City are much higher than the levels reported in this study when other sources such as petrol stations and motor vehicles on the roads are considered. Tanzania Government therefore need to put in place: an air quality policy and legislation, establish air quality guidelines and acquire facilities which will enable the implementation of air quality monitoring and management programmes.