Regional and Temporal Differences in Nitrate Trends Discerned from Long‐Term Water Quality Monitoring Data

Riverine nitrate (NO₃) is a well‐documented driver of eutrophication and hypoxia in coastal areas. The development of the elevated river NO₃ concentration is linked to anthropogenic inputs from municipal, agricultural, and atmospheric sources. The intensity of these sources has varied regionally, through time, and in response to multiple causes such as economic drivers and policy responses. This study uses long‐term water quality, land use, and other ancillary data to further describe the evolution of river NO₃ concentrations at 22 monitoring stations in the United States (U.S.). The stations were selected for long‐term data availability and to represent a range of climate and land‐use conditions. We examined NO₃ at the monitoring stations, using a flow‐weighting scheme meant to account for interannual flow variability allowing greater focus on river chemical conditions. River NO₃ concentration increased strongly during 1945‐1980 at most of the stations and have remained elevated, but stopped increasing during 1981‐2008. NO₃ increased to a greater extent at monitoring stations in the Midwest U.S. and less so at those in the Eastern and Western U.S. We discuss 20th Century agricultural development in the U.S. and demonstrate that regional differences in NO₃ concentration patterns were strongly related to an agricultural index developed using principal components analysis. This unique century‐scale dataset adds to our understanding of long‐term NO₃ patterns in the U.S.     

VARIABLES INDICATING NITRATE CONTAMINATION IN BEDROCK AQUIFERS,NEWARK BASIN,NEW JERSEY1

ABSTRACT: Variables that describe well construction, hydrogeology, and land use were evaluated for use as possible indicators of the susceptibility of ground water in bedrock aquifers in the Newark Basin, New Jersey, to contamination by nitrate from the land surface. Statistical analyses were performed on data for 132 wells located throughout the Newark Basin. Concentrations of nitrate (as nitrogen) did not exceed the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter (mg/L) in any of the water samples (U.S. Environmental Protection Agency, 1991). Variables that describe hydrogeology and well construction were found not to be statistically significant in relation to concentrations of nitrate. This finding can be attributed to the complex nature of flow in bedrock aquifers and mixing of water from shallow and deep water-bearing zones that occurs within these wells, which are constructed with long open intervals. Distributions of nitrate concentrations were significantly different among land-use groups on the basis of land use within both a 400 and an 800-m radius zone of the well. The median concentrations of nitrate (as N) in water from wells in predominantly urban-residential (2.5 mg/L) and agricultural areas (1.8 mg/L) were greater than the median concentration of nitrate in water from wells in predominantly undeveloped areas (0.5 mg/L).     

Estimation of Nonpoint Source Nitrate Concentrations in Indiana Rivers Based on Agricultural Drainage in the Watershed

Subsurface tile‐drained agricultural fields are known to be important contributors to nitrate in surface water in the Midwest, but the effect of these fields on nitrate at the watershed scale is difficult to quantify. Data for 25 watersheds monitored by the Indiana Department of Environmental Management and located near a U.S. Geological Survey stream gage were used to investigate the relationship between flow‐weighted mean concentration (FWMC) of nitrate‐N and the subsurface tile‐drained area (DA) of the watershed. The tile DA was estimated from soil drainage class, land use, and slope. Nitrate loads from point sources were estimated based on reported flows of major permitted facilities with mean nitrate‐N concentrations from published sources. Linear regression models exhibited a statistically significant relationship between annual/monthly nonpoint source (NPS) nitrate‐N and DA percentage. The annual model explained 71% of the variation in FWMC of nitrate‐N. The annual and monthly models were tested in 10 additional watersheds, most with absolute errors within 1 mg/l in the predicted FWMC. These models can be used to estimate NPS nitrate for unmonitored watersheds in similar areas, especially for drained agricultural areas where model performance was strongest, and to predict the nitrate reduction when various tile drainage management techniques are employed.     

NITRATE CONTAMINATION IN OREGON WELL WATER: GEOLOGIC VARIABILITY AND THE PUBLIC'S PERCEPTION1

ABSTRACT: Approximately 4.5 million people in the United States who rely on well water are exposed to nitrate‐N concentrations exceeding the 10 mg/l standard. In this study in the Southern Willamette Valley in Oregon we reassessed nitrate‐N in rural wells sampled in 2000–2001, compared nitrate‐N concentrations among geological units, and surveyed residents about their perceptions of well water quality. Nitrate‐N concentrations were again sampled in 2002 and found to have increased significantly from the previous period. With rapid population growth in the area, the potential health risk in drinking well water that exceeds 10 mg/l nitrate‐N warrants continued public education. Nitrate‐N concentrations were found to be higher in the Holocene alluvium of the Willamette River and the Pleistocene sand and gravel post‐Missoula Flood deposits. Researchers conducting future studies may choose to stratify and monitor wells by geologic unit and by other parameters that estimate input of nutrients to the environment. Opinions differed between agricultural landowners and nonagricultural landowners with regard to the impact that agricultural fertilizers may have on water quality. Participants were supportive of a range of regulatory actions that might be used by homeowners or landowners to address ground water contamination. Given that the area is now designated a Groundwater Management Area, understanding local stakeholders’perceptions is critical and strategic and has the potential to help public agencies manage potential conflicts of opinion among stakeholders, build consensus, and help guide the approach to restoring ground water quality.     

Effects of watershed-scale land use change on stream nitrate concentrations

The Walnut Creek Watershed Monitoring Project was conducted from 1995 through 2005 to evaluate the response of stream nitrate concentrations to changing land use patterns in paired 5000-ha Iowa watersheds. A large portion of the Walnut Creek watershed is being converted from row crop agriculture to native prairie and savanna by the U.S. Fish and Wildlife Service at the Neal Smith National Wildlife Refuge (NSNWR). Before restoration, land use in both Walnut Creek (treatment) and Squaw Creek (control) watersheds consisted of 70% row crops. Between 1990 and 2005, row crop area decreased 25.4% in Walnut Creek due to prairie restoration but increased 9.2% in Squaw Creek due to Conservation Reserve Program (CRP) grassland conversion back to row crop. Nitrate concentrations ranged between <0.5 to 14 mg L(-1) at the Walnut Creek outlet and 2.1 to 15 mg L(-1) at the downstream Squaw Creek outlet. Nitrate concentrations decreased 1.2 mg L(-1) over 10 yr in the Walnut Creek watershed but increased 1.9 mg L(-1) over 10 yr in Squaw Creek. Changes in nitrate were easier to detect and more pronounced in monitored subbasins, decreasing 1.2 to 3.4 mg L(-1) in three Walnut Creek subbasins, but increasing up to 8.0 and 11.6 mg L(-1) in 10 yr in two Squaw Creek subbasins. Converting row crop lands to grass reduced stream nitrate levels over time in Walnut Creek, but stream nitrate rapidly increased in Squaw Creek when CRP grasslands were converted back to row crop. Study results highlight the close association of stream nitrate to land use change and emphasize that grasslands or other perennial vegetation placed in agricultural settings should be part of a long-term solution to water quality problems.     

MODELING NITROGEN TRANSPORT IN THE IPSWICH RIVER BASIN,MASSACHUSETTS, USING A HYDROLOGICAL SIMULATION PROGRAM IN FORTRAN (HSPF)1

ABSTRACT: Increased riverine nitrogen (N) fluxes have been strongly correlated with land use changes and are now one of the largest pollution problems in the coastal region of the United States. In the present study, the Hydrological Simulation Program‐FORTRAN (HSPF) is used to simulate transport of N in the Ipswich River basin in Massachusetts and to evaluate the effect of future land use scenarios on the water quality of the river. Model results show that under a land use change scenario constructed with restrictions from environmental protection laws, where 44 percent of the forest in the basin was converted to urban land, stream nitrate concentrations increased by about 30 percent of the present values. When an extreme land use scenario was used, and 100 percent of the forest was converted to urban land, concentrations doubled in comparison to present values. Model simulations also showed that present stream nitrate concentrations might be four times greater than they were prior to urbanization. While pervious lands with high density residential land use generated runoff with the highest N concentrations in HSPF simulations, the results suggested that denitrification in the riparian zone and wetlands coupled with the hydrology of the basin are likely to control the magnitude of nitrate loads to the aquatic system. The simulation results showed that HSPF can predict the general patterns of inorganic N concentrations in the Ipswich River and tributaries. Nevertheless, HSPF has some difficulty simulating the extreme variability of the observed data throughout the main stem and tributaries, probably because of limitations in the representation of wetlands and riparian zones in the model, where N processes such as denitrification seem to play a major role in controlling the transport of N from the terrestrial system to the river reaches.     

NUTRIENT CONCENTRATIONS AND YIELDS IN UNDEVELOPED STREAM BASINS OF THE UNITED STATES1

ABSTRACT: Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow‐weighted concentrations during 1990–1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow‐weighted concentration of nitrate exceeded 0.6 mg/L in only three basins. Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid‐Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states.     

ALGAL PRODUCTIVITY AND NITRATE ASSIMILATION IN AN EFFLUENT DOMINATED CONCRETE LINED STREAM1

This study examined algal productivity and nitrate assimilation in a 2.85 km reach of Cucamonga Creek, California, a concrete lined channel receiving treated municipal wastewater. Stream nitrate concentrations observed at two stations indicated nearly continuous loss throughout the diel study. Nitrate loss in the reach was approximately 11 mg/L/d or 1.0 g/m²/d as N, most of which occurred during daylight. The peak rate of nitrate loss (1.13 mg/l/hr) occurred just prior to an afternoon total CO₂ depletion. Gross primary productivity, as estimated by a model using the observed differences in dissolved oxygen between the two stations, was 228 mg/L/d, or 21 g/m²/d as O₂. The observed diel variations in productivity, nitrate loss, pH, dissolved oxygen, and CO₂ indicate that nitrate loss was primarily due to algal assimilation. The observed levels of productivity and nitrate assimilation were exceptionally high on a mass per volume basis compared to studies on other streams; these rates occurred because of the shallow stream depth. This study suggests that concrete‐lined channels can provide an important environmental service: lowering of nitrate concentrations similar to rates observed in biological treatment systems.     

Field Testing the Riparian Ecosystem Management Model on a Riparian Buffer in the North Carolina Upper Coastal Plain

The riparian ecosystem management model (REMM) was field tested using five years (2005‐2009) of measured hydrologic and water quality data on a riparian buffer located in the Tar‐Pamlico River Basin, North Carolina. The buffer site received NO₃‐N loading from an agricultural field that was fertilized with inorganic fertilizer. Field results showed the buffer reduced groundwater NO₃‐N concentration moving to the stream over a five‐year period. REMM was calibrated hydrologically using daily field‐measured water table depths (WTDs), and with monthly NO₃‐N concentrations in groundwater wells. Results showed simulated WTDs and NO₃‐N concentrations in good agreement with measured values. The mean absolute error and Willmott's index of agreement for WTDs varied from 13‐45 cm and 0.72‐0.92, respectively, while the root mean square error and Willmott's index of agreement for NO₃‐N concentrations ranged from 1.04‐5.92 mg/l and 0.1‐0.86, respectively, over the five‐year period. REMM predicted plant nitrogen (N) uptake and denitrification were within ranges reported in other riparian buffer field studies. The calibrated and validated REMM was used to simulate 33 years of buffer performance at the site. Results showed that on average the buffer reduced NO₃‐N concentrations from 12 mg/l at the field edge to 0.7 mg/l at the stream edge over the simulation period, while the total N and NO₃‐N load reductions from the field edge to the stream were 77 and 82%, respectively.     

Atmospheric nitrogen deposition and its long-term dynamics in a southeast China coastal area

Measurements were conducted during 2004-2005 and 2009-2010 to characterize atmospheric nitrogen (N) deposition to the Jiulong River Estuary - Xiamen Bay area in southeast China. Isotopic analysis and long-term data (1990-2009) for inorganic N extracted from the national acid deposition dataset were used to determine the dominant source of atmospheric nitrate and N component dynamics. The results showed that the mean dissolved total N concentration in rain water for the three coastal area sites was 2.71 ± 1.58 mg N L(-1) (n = 141) in 2004. The mean dissolved inorganic N at the Xiamen site was 1.62 ± 1.19 mg N L(-1) (n = 46) in 2004-2005 and 1.56 ± 1.39 mg N L(-1) (n = 36) in 2009-2010, although the difference is not significant, nitrate turnover dominates the N component in the latter period. Total deposition flux over Xiamen was 30 kg N ha(-1) yr(-1), of which dry and wet deposition contributed 16% and 84%, respectively. Nitrate in wet deposition with low isotopic value (between -3.05 and -7.48‰) was likely to have mostly originated from combustion NO(x) from vehicle exhausts. The inorganic N in acid deposition exhibited a significant increase (mainly for nitrate) since the mid-1990s, which is consistent with the increased gaseous concentrations of NO(x) and expanding number of automobiles in the coastal city (Xiamen). The time series of nitrate anions and ammonium cations as well as pH values during the period 1990-2009 reflected an increasing trend of N emission with potential implication for N-induced acidification.     

EVALUATING THE INFLUENCE OF SOURCE BASINS ON DOWNSTREAM WATER QUALITY IN THE MISSISSIPPI RIVER1

ABSTRACT: Chemical variability in the Mississippi River during water years 1989 to 1998 was evaluated using stream discharge and water‐quality data in conjunction with the DAFLOW/BLTM hydraulic model. Model simulations were used to identify subbasin contributions of water and chemical constituents to the Mississippi River upstream from its confluence with the Ohio and the Mississippi River and at the Atchafalaya Diversion in Louisiana. Concentrations of dissolved solids, sodium, and sulfate at the Thebes site showed a general decreasing trend, and concentrations of silica and nitrate showed a general increasing trend as the percentage of discharge from the Mississippi River upstream from Grafton increased. Concentrations of most chemical constituents in the Mississippi River at the Atchafalaya Diversion exhibited a decreasing trend as the percentage of water from the Ohio River increased. Regression models were used to evaluate the importance of the source of water to the water chemistry in the Mississippi River at Thebes and the Atchafalaya Diversion. The addition of terms in regression equations to account for the percent of water from sub‐basins improved coefficients of determination for predicting chemical concentrations by as much as nine percent at the Thebes site and by as much as 48 percent at the Atchafalaya Diversion site. The addition of source‐water terms to regression equations increased the estimated annual loads of nitrate and silica delivered from the Mississippi River Basin to the Gulf of Mexico by as much as 14 and 13 percent, respectively.     

NUTRIENT CONCENTRATIONS IN WASTEWATER TREATMENT PLANT EFFLUENTS,SOUTH PLATTE RWER BASIN1

ABSTRACT: Accurate data about nutrient concentrations in wastewater treatment plant effluents are needed for river basin water-quality studies. As part of the U.S. Geological Survey's National Water-Quality Assessment Program in the South Platte River Basin, nutrient data were requested from 31 wastewater-treatment plants located in the basin. This article describes the types of nutrient data available from the plants, examines the variability of effluent nutrient concentrations, and discusses methods for estimation of nutrient concentrations where data are lacking. Ammonia was monitored at 88 percent of the plants, nitrite plus nitrate was monitored at 40 percent of the plants, and organic nitrogen and phosphorus were monitored at less than 25 percent of the plants. Median total nitrogen concentrations and median total phosphorus concentrations were small compared to typical literature estimates for wastewater-treatment plants with secondary treatment. Nutrient concentrations in effluent from wastewater-treatment plants varied widely between and within plants. For example, ammonia concentrations varied as much as 5 mg/L during a day, as much as 10 mg/L from day to day, and as much as 30 mg/L from summer to winter within a plant. In the South Platte River Basin, estimates of median annual ammonia and nitrite plus nitrate concentrations can be improved based on plant processes; and nitrite plus nitrate and organic nitrogen concentrations can be estimated based on ammonia concentrations. However, to avoid large estimation errors, more complete nutrient data from wastewater-treatment plants are needed for integration into river basin water quality studies. The paucity of data hinders attempts to evaluate the relative importance of point source and nonpoint source nutrient loadings to rivers.     

DIN Retention‐Transport Through Four Hydrologically Connected Zones in a Headwater Catchment of the Upper Mississippi River1

Abstract: Dissolved inorganic nitrogen (DIN) retention‐transport through a headwater catchment was synthesized from studies encompassing four distinct hydrologic zones of the Shingobee River Headwaters near the origin of the Mississippi River. The hydrologic zones included: (1) hillslope ground water (ridge to bankside riparian); (2) alluvial riparian ground water; (3) ground water discharged through subchannel sediments (hyporheic zone); and (4) channel surface water. During subsurface hillslope transport through Zone 1, DIN, primarily nitrate, decreased from ～3 mg‐N/l to <0.1 mg‐N/l. Ambient seasonal nitrate:chloride ratios in hillslope flow paths indicated both dilution and biotic processing caused nitrate loss. Biologically available organic carbon controlled biotic nitrate retention during hillslope transport. In the alluvial riparian zone (Zone 2) biologically available organic carbon controlled nitrate depletion although processing of both ambient and amended nitrate was faster during the summer than winter. In the hyporheic zone (Zone 3) and stream surface water (Zone 4) DIN retention was primarily controlled by temperature. Perfusion core studies using hyporheic sediment indicated sufficient organic carbon in bed sediments to retain ground water DIN via coupled nitrification‐denitrification. Numerical simulations of seasonal hyporheic sediment nitrification‐denitrification rates from perfusion cores adequately predicted surface water ammonium but not nitrate when compared to 5 years of monthly field data (1989‐93). Mass balance studies in stream surface water indicated proportionally higher summer than winter N retention. Watershed DIN retention was effective during summer under the current land use of intermittently grazed pasture. However, more intensive land use such as row crop agriculture would decrease nitrate retention efficiency and increase loads to surface water. Understanding DIN retention capacity throughout the system, including special channel features such as sloughs, wetlands and floodplains that provide surface water‐ground water connectivity, will be required to develop effective nitrate management strategies.     

Development of environmental thresholds for nitrogen and phosphorus in streams

Inputs of nutrients (P and N) to freshwaters can cause excessive aquatic plant growth, depletion of oxygen, and deleterious changes in diversity of aquatic fauna. As part of a "National Agri-Environmental Standards Initiative," the Government of Canada committed to developing environmental thresholds for nutrients to protect ecological condition of agricultural streams. Analysis of data from >200 long-term monitoring stations across Canada and detailed ecological study at ~70 sites showed that agricultural land cover was associated with increased nutrient concentrations in streams and this, in turn, was associated with increased sestonic and benthic algal abundance, loss of sensitive benthic macroinvertebrate taxa, and an increase in benthic diatom taxa indicative of eutrophication. Chemical thresholds for N and P were defined by applying five approaches, employing either a predetermined percentile to a water chemistry data set or a relationship between water chemistry and land cover, to identify boundaries between minimally disturbed and impaired conditions. Comparison of these chemical thresholds with biological thresholds (derived from stressor-response relationships) produced an approach for rationalizing these two types of thresholds and deriving nutrient criteria. The resulting criteria were 0.01 to 0.03 mg L(-1) total P and 0.87-1.2 mg L(-1) total N for the Atlantic Maritime, 0.02 mg L(-1) total P and 0.21 mg L(-1) total N for the Montane Cordillera, ~0.03 mg L(-1) total P and ~1.1 mg L(-1) total N for the Mixedwood Plains, and ~0.10 mg L(-1) total P and 0.39-0.98 mg L(-1) total N for the interior prairies of Canada. Adoption of these criteria should result in greater likelihood of good ecological condition with respect to benthic algal abundance, diatom composition, and macroinvertebrate composition.     

Sources of nitrate yields in the Mississippi River Basin

Riverine nitrate N in the Mississippi River leads to hypoxia in the Gulf of Mexico. Several recent modeling studies estimated major N inputs and suggested source areas that could be targeted for conservation programs. We conducted a similar analysis with more recent and extensive data that demonstrates the importance of hydrology in controlling the percentage of net N inputs (NNI) exported by rivers. The average fraction of annual riverine nitrate N export/NNI ranged from 0.05 for the lower Mississippi subbasin to 0.3 for the upper Mississippi River basin and as high as 1.4 (4.2 in a wet year) for the Embarras River watershed, a mostly tile-drained basin. Intensive corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] watersheds on Mollisols had low NNI values and when combined with riverine N losses suggest a net depletion of soil organic N. We used county-level data to develop a nonlinear model ofN inputs and landscape factors that were related to winter-spring riverine nitrate yields for 153 watersheds within the basin. We found that river runoff times fertilizer N input was the major predictive term, explaining 76% of the variation in the model. Fertilizer inputs were highly correlated with fraction of land area in row crops. Tile drainage explained 17% of the spatial variation in winter-spring nitrate yield, whereas human consumption of N (i.e., sewage effluent) accounted for 7%. Net N inputs were not a good predictor of riverine nitrate N yields, nor were other N balances. We used this model to predict the expected nitrate N yield from each county in the Mississippi River basin; the greatest nitrate N yields corresponded to the highly productive, tile-drained cornbelt from southwest Minnesota across Iowa, Illinois, Indiana, and Ohio. This analysis can be used to guide decisions about where efforts to reduce nitrate N losses can be most effectively targeted to improve local water quality and reduce export to the Gulf of Mexico.     

WALNUT CREEK WATERSHED MONITORING PROJECT,IOWA MONITORING WATER QUALITY IN RESPONSE TO PRAIRIE RESTORATION1

ABSTRACT: Land use and surface water data for nitrogen and pesticides (1995 to 1997) are reported for the Walnut Creek Watershed Monitoring Project, Jasper County Iowa. The Walnut Creek project was established in 1995 as a nonpoint source monitoring program in relation to watershed habitat restoration and agricultural management changes implemented at the Neal Smith National Wildlife Refuge by the U.S. Fish and Wildlife Service. The monitoring project utilizes a paired‐watershed approach (Walnut and Squaw creeks) as well as upstream/downstream comparisons on Walnut for analysis and tracking of trends. From 1992 to 1997, 13.4 percent of the watershed was converted from row crop to native prairie in the Walnut Creek watershed. Including another 6 percent of watershed farmed on a cash‐rent basis, land use changes have been implemented on 19.4 percent of the watershed by the USFWS. Nitrogen and pesticide applications were reduced an estimated 18 percent and 28 percent in the watershed from land use changes. Atrazine was detected most often in surface water with frequencies of detection ranging from 76–86 percent. No significant differences were noted in atrazine concentrations between Walnut and Squaw Creek. Nitrate‐N concentrations measured in both watersheds were similar; both basins showed a similar pattern of detection and an overall reduction in nitrate‐N concentrations from upstream to downstream monitoring sites. Water quality improvements are suggested by nitrate‐N and chloride ratios less than one in the Walnut Creek watershed and low nitrate‐N concentrations measured in the subbasin of Walnut Creek containing the greatest amount of land use changes. Atrazine and nitrate‐N concentrations from the lower portion of the Walnut Creek watershed (including the prairie restoration area) may be decreasing in relation to the upstream untreated component of the watershed. The frequencies of pesticide detections and mean nitrate‐N concentrations appear related to the percentage of row crop in the basins and subbasins. Although some results are encouraging, definitive water quality improvements have not been observed during the first three years of monitoring. Possible reasons include: (1) more time is needed to adequately detect changes; (2) the size of the watershed is too large to detect improvements; (3) land use changes are not located in the area of the watershed where they would have greatest effect; or (4) water quality improvements have occurred but have been missed by the project monitoring design. Longer‐term monitoring will allow better evaluation of the impact of restoration activities on water quality.     

Simulation of Nitrogen Transport in Soil Under Municipal Wastewater Application Using LEACHN1

Abstract: To reduce the risk of surface and ground water pollution from nitrate, and in so doing improve the quality of receiving waters, better management options for land application of wastewater must be explored. In order to determine proper and environmentally safe wastewater land application methods, different application scenarios were simulated in this study to determine the fate and transport of nitrogen in sand‐filled field lysimeters. The Leaching Estimation and CHemistry Model for Nutrients (LEACHN) model was used to assess alternative wastewater land application scenarios: applications of low‐, medium‐, or high‐N concentration wastewaters, at different rates (0.06, 0.19, 0.31, or 0.6 m³/m²/day), under continuous or intermittent application. In the simulations, the NO₃^?‐N levels decreased in the leachate with an increase in wastewater application rates, due to enhanced denitrification in the upper anoxic zone of the soil generated under high flow rates. With low‐N concentrated wastewater, under all tested flow rates, the NO₃^?‐N levels in the leachate were below the permissible limit. When medium‐N wastewater was applied, the NO₃^?‐N level in leachate from the highest flow rate was below the permissible limit. Therefore, wastewater with low‐N concentrations, about 10 and 0.5 mg/l NO₃^?‐N and NH₄⁺‐N, may be continuously applied to soil at all tested flow rates, with minimal nitrate pollution problems. Medium and high‐N concentrated wastewaters increased nitrate levels in the leachate, as compared to their levels in the low‐N concentrated wastewater. It appears that while low‐N wastewater can be safely applied to land without much nitrate leaching problems, the application of medium and high‐N wastewater could pose nitrate pollution problems. The simulation with intermittent application of low‐, medium‐, and high‐N concentrated wastewater at different rates showed a 51‐89% greater reduction in NO₃^?‐N levels in the leachate, than for continuous application under all tested wastewater N‐levels and flow rates. Also, the levels of NO₃^?‐N in their leachates were below the permissible limit. Therefore, wastewater with high levels of nitrogenous compounds (up to 54 NO₃‐N mg/l) could be treated through an intermittent application to land.     

Nitrate distributions and source identification in the Abbotsford-Sumas Aquifer,northwestern Washington State

The Abbotsford-Sumas Aquifer is a shallow, predominantly unconfined aquifer that spans regions in southwestern British Columbia, Canada and northwestern Washington, USA. The aquifer is prone to nitrate contamination because of extensive regional agricultural practices. A 22-month ground water nitrate assessment was performed in a 10-km2 study area adjacent to the international boundary in northwestern Washington to examine nitrate concentrations and nitrogen isotope ratios to characterize local source contributions from up-gradient sources in Canada. Nitrate concentrations in excess of 10 mg nitrate as nitrogen per liter (mg N L(-1)) were observed in ground water from most of the 26 domestic wells sampled in the study area, and in a creek that dissects the study area. The nitrate distribution was characteristic of nonpoint agricultural sources and consistent with the historical documentation of agriculturally related nitrate contamination in many parts of the aquifer. Hydrogeologic information, nitrogen isotope values, and statistical analyses indicated a nitrate concentration stratification in the study area. The highest concentrations (> 20 mg N L(-1)) occurred in shallow regions of the aquifer and were linked to local agricultural practices in northwestern Washington. Nitrate concentrations in excess of 10 mg N L(-1) deeper in the aquifer (> 10 m) were related to agricultural sources in Canada. The identification of two possible sources of ground water nitrate in northwestern Washington adds to the difficulty in assessing and implementing local nutrient management plans for protecting drinking water in the region.     

Using the late spring nitrate test to reduce nitrate loss within a watershed

Excessive nitrate leaching from the U.S. Corn Belt has created serious water quality problems and contributed to the expansion of the hypoxic zone in the Gulf of Mexico. We evaluated the effect of implementing the late spring nitrate test (LSNT) for corn (Zea mays L.) grown within a 400-ha, tile-drained subbasin in central Iowa. Surface water discharge and NO3 concentrations from the treated subbasin and two adjacent subbasins receiving primarily fall-applied, anhydrous ammonia were compared. In two of four years, the LSNT method significantly reduced N fertilizer applications compared with the farmers' standard practices. Average corn yield from LSNT fields and nonlimiting N fertilizer check strips was not significantly different. Autoregressive (AR) models using weekly time series in surface water NO3 concentration differences between the LSNT and control subbasins indicated no consistent significant differences during the pre-LSNT (1992-1996) period. However, by the second year (1998) of the treatment period (1997-2000), NO3 concentrations in surface water from the treated subbasin were significantly lower than the concentrations coming from both control basins. Annual average flow-weighted NO3 concentrations for the last two years (1999-2000) were 11.3 mg N L(-1) for the LSNT and subbasin and 16.0 mg N L(-1) for the control subbasins. Based on these values and the AR models, widespread adoption of the LSNT program for managing N fertilizer where fall N application is typically practiced could result in a > or = 30% decrease for NO3 concentrations in surface water.     

GROUND WATER AS A SOURCE OF NUTRIENTS AND ATRAZINE TO STREAMS IN THE SOUTH PLATTE RIVER BASIN1

ABSTRACT: Concentrations of nitrite plus nitrate, ammonia, orthophosphate, and atrazine were measured in streams and ground water beneath the streams at 23 sites in the South Platte River basin of Colorado, Nebraska, and Wyoming to assess: (1) the role of ground water as a source of nutrients and atrazine to streams in the basin, and (2) the effect of land-use setting on this process. Concentrations of nitrite plus nitrate, ammonia, orthophosphate, and atrazine were higher in ground water than in the overlying streams at 2, 12, 12, and 3 of 19 sites, respectively, where there was not a measurable hydraulic gradient directed from the stream to the ground water. Orthophosphate was the only constituent that had a significantly higher (p ≤ 0.05) concentration in ground water than in surface water for a given land-use setting (range land). Redox conditions in ground water were more important than land-use setting in influencing whether ground water was a source of elevated nitrite plus nitrate concentrations to streams in the basin. The ratios of nitrite plus nitrate in ground water/surface were were significantly lower (p ≤ 0.05) at sites having concentrations of dissolved oxygen in ground water ≤ 0.5 mg/L than at sites having dissolved oxygen concentrations ≥ 0.5 mg/L. Elevated concentrations of ammonia or atrazine in ground water occurred at sites in close proximity to likely sources of ammonia or atrazine, regardless of land-use setting. These results indicate that land-use setting is not the only factor that influences whether ground water is a source of elevated nutrient and atrazine concentrations to streams in the South Platte River Basin.