VARIABLES INDICATING NITRATE CONTAMINATION IN BEDROCK AQUIFERS,NEWARK BASIN,NEW JERSEY1

ABSTRACT: Variables that describe well construction, hydrogeology, and land use were evaluated for use as possible indicators of the susceptibility of ground water in bedrock aquifers in the Newark Basin, New Jersey, to contamination by nitrate from the land surface. Statistical analyses were performed on data for 132 wells located throughout the Newark Basin. Concentrations of nitrate (as nitrogen) did not exceed the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter (mg/L) in any of the water samples (U.S. Environmental Protection Agency, 1991). Variables that describe hydrogeology and well construction were found not to be statistically significant in relation to concentrations of nitrate. This finding can be attributed to the complex nature of flow in bedrock aquifers and mixing of water from shallow and deep water-bearing zones that occurs within these wells, which are constructed with long open intervals. Distributions of nitrate concentrations were significantly different among land-use groups on the basis of land use within both a 400 and an 800-m radius zone of the well. The median concentrations of nitrate (as N) in water from wells in predominantly urban-residential (2.5 mg/L) and agricultural areas (1.8 mg/L) were greater than the median concentration of nitrate in water from wells in predominantly undeveloped areas (0.5 mg/L).     

HYDROGEOLOGY AND PATHS OF FLOW IN THE CARBONATE BEDROCK AQUIFER,NORTHWESTERN INDIANA1

ABSTRACT: The U.S. Geological Survey (USGS) is assessing the ground-water resources of the carbonate bedrock aquifers in Indiana and Ohio as part of their Regional Aquifer Systems Analysis program. Part of this assessment includes the determination of unknown aspects of the hydraulic characteristics, boundaries, and flow paths of the carbonate aquifer. To accomplish this, the USGS drilled three wells through the carbonate aquifer near the Kankakee River in northwestern Indiana. Geophysical logs were used to help determine depths and thicknesses for testing and to help describe geology at the three wells. Packer tests were used to determine direction of ground-water flow and to provide data for an analysis of the distribution of transmissivity in the carbonate aquifer. Transmissivity of the carbonates is associated with two physical characteristics of the rocks: fractures and interconnected porosity. Almost all of the transmissivity is derived from horizontal fracturing; however, only a few of the fractures present in the carbonate are transmissive. Some transmissivity is associated with a zone of fossiliferous, vuggy dolomite, which yields water from the rock matrix. Most of the transmissivity is associated with large fractures and solution crevices in the upper 30 feet of the bedrock; less transmissivity is associated with the deeper vuggy reef material, even where extensively fractured. Transmissivity of individual fractures and fossiliferous zones ranges from 300 to 27,000 feet squared per day. The aquifer bottom is defined by a lack of transmissive fractures and an increased shale content near the contact of the Silurian and Ordovician sections. Water-level data from the three wells indicate that flow is horizontal at well site 1 north of the Kankakee River, upward at well site 2 near the river, and downward at well site 3 south of the river. Most of the flow occurs in the upper part of the carbonate bedrock where fracturing and solution-enlarged crevices are most developed. Water levels indicate the the Kankakee River is a hydrologic boundary for the regional carbonate bedrock aquifer.     

CHARACTERIZING GROUND WATER FLOW IN THE MUNICIPAL WELL FIELDS OF CEDAR RAPIDS,IOWA, WITH SELECTED ENVIRONMENTAL TRACERS1

ABSTRACT: Cedar Rapids obtains its municipal water supply from a shallow alluvial aquifer along the Cedar River in east-central Iowa. Water samples were collected and analyzed for selected isotopes and chlorofluorocarbons to characterize the ground-water flow system near the municipal well fields. Analyses of deuterium and oxygen-18 indicate that water in the alluvial aquifer and in the underlying carbonate bedrock aquifer was recharged from precipitation during modern climatic conditions. Analyses of tritium indicate modern, post-1952, water in the alluvial aquifer and older, pre-1952, water in the bedrock aquifer. Mixing of the modern and older waters occurs in areas where (1) the confining layer between the two aquifers is discontinuous, (2) the bedrock aquifer is fractured, or (3) pumping of supply wells induces the flow of water between aquifers. Analyses of chlorofluorocarbons were used to determine the date of recharge of water samples. Water in the bedrock aquifer likely was recharged prior to the 1950s. Water in the alluvial aquifer likely was recharged from the 1960s to 1990s. Biodegradation or sorption probably affected some of the ground water analyzed for chlorofluorocarbons. These processes reduce the concentrations of CFCs, which results in older than actual calculated dates of recharge.     

MODELING CONCENTRATION VARIATIONS IN HIGH-CAPACITY WELLS: IMPLICATIONS FOR GROUNDWATER SAMPLING1

ABSTRACT: High-capacity wells are used as a convenient and economical means of sampling groundwater quality. Although the inherent limitations of using these wells are generally recognized, little has been done to investigate how these wells actually sample groundwater. A semi-analytical particle tracking model is used to illustrate the influence of variable vertical contaminant distributions and aquifer heterogeneity on the composition of water samples from these wells during short pumping periods. The hypothetical pumping well used in the simulations is located in an unconfined, alluvial aquifer with a shallow water table and concentration gradients of nitrate-nitrogen contamination. This is a typical setting for many irrigated areas in the United States. The main conclusions are: (1) high-capacity wells underestimate the average amount of contamination within an aquifer; (2) shapes of concentration-time curves for high-capacity wells appear to be governed by the distribution of the contaminant and travel times to the well; (3) variables such as well construction, pumping rate, and hydrogeologic properties contribute to the magnitude of the concentration-time curves at individual high-capacity wells; and (4) a sampling strategy using concentration-time curves based on the behavioral characteristics of the well rather than individual samples will provide a much better framework for interpreting spatial contaminant distributions.     

IDENTIFYING DISCHARGE ZONES OF ARSENIC IN THE GOOSE RIVER BASIN,MAINE1

ABSTRACT: Water balance modeling and the analysis of stable water isotopes in ground water were conducted to aid the location of ground water discharge areas within the Goose River basin, in mid‐coastal Maine. Previous investigations of drinking water from wells in the fractured crystalline bedrock encountered persistent elevated total arsenic. Such contamination may be related to discharging ground water from fractured zones in the basin. Modeled discharge rates greater than +10 cm/yr and ¹⁸O values lighter than‐9.5 per mil VSMOW may indicate recent recharge is mixing with deeper ground water and is focused along some fractured zones in arsenic bearing crystalline rocks.     

EVALUATING THE EFFECTIVENESS OF A FIXED WELLHEAD DELINEATION: REGIONAL CASE STUDY 1

The 1996 Safe Drinking Water Act amendments mandated that every state must determine the hydrogeologic origin of each public drinking water system and assess the degree to which each system may be adversely affected by potential sources of contamination. Wisconsin delineated and assessed one specific class of systems, transient noncommunity drinking water wells, with the least stringent standards of all governed system types. This study evaluates the effectiveness of Wisconsin's arbitrarily fixed radius approach used in determining susceptibility to potential contamination from 1,872 transient noncommunity ground water wells. Nearly 28 percent of the wells with contaminated water did not have any recorded potential sources of contamination within the delineation radii. Additionally, regression models derived from potential contaminant inventories within the delineation radii could not accurately predict actual incidences of water contamination. Differences between observed and expected frequencies of contamination further suggest that some transient noncommunity systems should probably be delineated with larger and more sophisticated methods that would account for varying geology and contaminant susceptibility. The majority of contamination cases without recorded potential sources of contamination within the delineation radii were in a karst area. Subsequently, the arbitrarily fixed radius delineation method should not be used in areas with karst aquifers.     

SURFACE WATER-ESKER RECHARGE STUDY EAST LANSING-MERIDIAN TOWNSHIP,MICHIGAN1

ABSTRACT: The East Lansing-Meridian Water and Sewer Authority studied a sand-gravel esker near the existing water treatment plant to determine its potential as an independent surface water supply. The nearby Red Cedar River was also investigated as a possible source of water for immediate treatment or for recharge of the esker. Although the bedrock aquifer (Grand River and Saginaw Formations) yields water adequate for the next 20 years, potential savings in treatment (hardness, iron) and pumping costs, estimated at $30,000 per year for present demand of 5 MGD, are attractive incentives for a surface water-esker recharge program. Operation savings would also be realized by constructing additional bedrock wells in new areas. The river-esker-recharge and new wellfield alternatives are compared for cost-effectiveness. Land costs make the recharge alternative more expensive. The land is undeveloped suburban property with potential for recreational use in conjunction with water supply. More places of outdoor retreat and aesthetics are needed in the Lansig Metropolitan area. A portion of the land costs would have to be borne by these or other interests for the river recharge scheme to be economically feasible.     

Estimating Potential E. coli Sources in a Watershed Using Spatially Explicit Modeling Techniques1

Riebschleager, K.J., R. Karthikeyan, R. Srinivasan, and K. McKee, 2012. Estimating Potential E. coli Sources in a Watershed Using Spatially Explicit Modeling Techniques. Journal of the American Water Resources Association (JAWRA) 48(4): 745‐761. DOI: 10.1111/j.1752‐1688.2012.00649.x Abstract: The Spatially Explicit Load Enrichment Calculation Tool (SELECT) was automated to characterize waste and the associated pathogens from various sources within a mixed land use watershed. Potential Escherichia coli loads in Lake Granbury watershed were estimated using spatially variable governing factors, such as land use, soil condition, and distance to streams. A new approach for characterizing E. coli loads resulting from malfunctioning on‐site wastewater treatment systems (OWTSs) was incorporated into SELECT along with the Pollutant Connectivity Factor (PCF) module. The PCF component was applied to identify areas contributing E. coli loads during runoff events by incorporating the influence of potential E. coli loading, runoff potential, and travel distance to waterbodies. Simulation results indicated livestock and wildlife are potential E. coli contributing sources in the watershed. The areas in which these sources are potentially contributing are not currently monitored for E. coli. The bacterial water quality violations seen around Lake Granbury are most likely the result of malfunctioning OWTSs and pet wastes. SELECT results demonstrate the need to evaluate each contributing source separately to effectively allocate site specific best management practices (BMPs) utilizing stakeholder inputs. It also serves as a powerful screening tool for determining areas where detailed investigation is merited.     

ANOMALOUS NATURAL SULFATE IN WATER WELLS OF THE GREENBRIER GROUP,WEST VIRGINIA1

ABSTRACT: Many water wells developed in the Middle Mississippian Greenbrier Group of central Greenbrier County, West Virginia, are very productive because of the abundant solution conduits in this karst aquifer. Water from these wells, all of which (with one exception) are clustered in a small area about eight kilometers northwest of Lewisburg, West Virginia, is typically very hard (calcium-magnesium-bicarbonate type). Of 74 wells sampled, eight showed sulfate concentrations ranging from 600 to 1700 mg/l. These wells also showed a much higher than average concentration of calcium, magnesium, chloride, sodium, and, in a few cases, iron. The water from several of these wells was not potable. Previously unpublished work has suggested that dolomite and gypsum dissolution have contributed magnesium and sulfate ions to the ground water. It is also likely that, where sodium, chloride, and iron concentrations are above background, halite dissolution and pyrite oxidation are contributing to the problem. All of these minerals are often associated with the basal waterbearing strata of the Greenbrier Group. In addition, it is possible that the wells are receiving deeply circulating ground waters, via fracture zones, which feed many other well-known sulfur and/or thermal springs in the central Appalachians.     

DEVELOPMENT OF A WATER SUPPLY PROTECTION MODEL IN A GIS1

ABSTRACT: As part of a larger model to identify lands suitable for acquisition, a water supply protection model was developed using the Southwest Florida Water Management District's GIS. Several hydrologic and hydrogeologic data layers were overlaid to develop maps showing ground-water supply suitability, protection areas for surface-water supply, protection areas for major public supply wells, susceptibility to ground-water contamination, and recharge to the Floridan aquifer. These intermediate layers were combined into a final map to prioritize protection areas for water supply.     

NEAR‐STREAM LANDUSE EFFECTS ON STREAMWATER NUTRIENT DISTRIBUTION IN AN URBANIZING WATERSHED1

ABSTRACT: We investigated spatial and temporal relationships among surface and subsurface watershed attributes and stream nutrient concentrations in urbanizing Johnson Creek watershed in northern Oregon. We sampled stream water at eight urban and five nonurban locations from March 1998 through December 1999. We sampled eight wells distributed over the two primary aquifers in the watershed. Using a Geographic Information System (GIS), percentages of landuse attributes within a radius of 30, 91, and 152 m from each sample site were quantified. We analyzed relationships between (1) nutrient concentrations and percentage cover of different landuse attributes, and (2) nutrient concentrations and underlying hydrologic units. We did not find a significant relationship between ground water chemistry and stream water chemistry. We found elevated levels of phosphorus (P) concentrations correlated with urban landuse, while higher nitrogen (N) concentrations were correlated with nonurban (primarily agricultural) landuse. We concluded that elevated levels of N in nonurban areas of Johnson Creek watershed were associated with agricultural practices. We further concluded that urban development factors such as increases in storm drains, dry wells, and impermeable surfaces may be responsible for higher input of P to the stream in urbanizing areas of the Johnson Creek watershed.     

WATER QUALITY IN SHALLOW ALLUVIAL AQUIFERS,UPPER COLORADO RIVER BASIN,COLORADO, 19971

ABSTRACT: Shallow ground water in areas of increasing urban development within the Upper Colorado River Basin was sampled for inorganic and organic constituents to characterize water‐quality conditions and to identify potential anthropogenic effects resulting from development. In 1997, 25 shallow monitoring wells were installed and sampled in five areas of urban development in Eagle, Grand, Gunnison, and Summit Counties, Colorado. The results of this study indicate that the shallow ground water in the study area is suitable for most uses. Nonparametric statistical methods showed that constituents and parameters measured in the shallow wells were often significantly different between the five developing urban areas. Radon concentrations exceeded the proposed USEPA maximum contaminant level at all sites. The presence of nutrients, pesticides, and volatile organic compounds indicate anthropogenic activities are affecting the shallow ground‐water quality in the study area. Nitrate as N concentrations greater than 2.0 mg/L were observed in ground water recharged between the 1980s and 1990s. Low concentrations of methylene blue active substances were detected at a few sites. Total coliform bacteria were detected at ten sites; however, E. coli was not detected. Continued monitoring is needed to assess the effects of increasing urban development on the shallow ground‐water quality in the study area.     

ORIGIN AND TRANSPORT OF DISSOLVED CHEMICALS IN A KARST WATERSHED,SOUTHWESTERN ILLINOIS1

ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO₄) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO₃), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent.     

OCCURRENCE OF TOTAL DISSOLVED PHOSPHORUS IN UNCONSOLIDATED AQUIFERS AND AQUITARDS IN IOWA1

ABSTRACT: Seven sets of ground water samples from 103 observation wells were analyzed for total dissolved phosphorus (TDP) in four areas and five materials including loess and loess derived alluvium in the Deep Loess Hills of western Iowa, outwash and fractured till adjacent to Clear Lake in north central Iowa, fractured till in central Iowa, and a sand and gravel aquifer in northwest Iowa. Land use in ground water recharge zones in all four areas is dominated by crop or animal production or both. Concentrations of TDP exceeding the minimum laboratory detection limit of 20 μg/l as P were found in all areas and in all materials sampled. Samples from the outwash deposits associated with Clear Lake contained significantly larger concentrations than all other areas and materials with a median of 160 μg/l. Water from fractured till in three areas produced the smallest range of concentrations with a median of 40 μg/l. The mean value of TDP in all sample sets exceeded 50 μg/l, an important ecological threshold that causes increased productivity in lakes and perennial streams and one being considered as a surface water nutrient standard by regulatory agencies. These results clearly show that ground water in essentially all near‐surface aquifers and aquitards discharging to Iowa's streams and lakes is capable of sustaining P concentrations of 50 to 100 μg/l in streams, lakes, and reservoirs. Consequently, even if point discharges and sediment sources of P are substantially reduced, ground‐water discharge to surface water may exceed critical thresholds under most conditions.     

NUTRIENTS IN STREAMS DURING BASEFLOW IN SELECTED ENVIRONMENTAL SEVFINGS OF THE POTOMAC RiVER BASIN1

ABSTRACT: A regional assessment of water quality in small streams was conducted within four areas of distinct physiography and lithology in the upper Potomac River Basin. The Potomac River is a major tributary to the Chesapeake Bay, and this study provides new insight on the relationships between nutrient concentrations in small streams and watershed characteristics within this river basin. Nutrient concentrations were compared to land-use data including categories for agriculture (cropland and pasture), urban areas, and forests. Among agricultural areas, streams draining areas of intense row cropping typically contained higher nitrate concentrations than did those draining pastures. Streams draining forested areas typically had the lowest nutrient concentrations. Streams in areas underlain by carbonate bedrock were more likely to contain elevated concentrations of inorganic nitrogen and potassium than did streams in areas underlain by fractured siliciclastic or crystalline rocks, and we suggest that this is a physical phenomenon related to high hydraulic conductivities in carbonate ground-water systems. The median nitrate concentrations were highest in the Great Valley portion of the Valley and Ridge physiographic province, particularly in watersheds that have both carbonate bedrock and intensive row cropping. Values of nitrate in these streams ranged up to 8.99 mg/L as nitrogen. The soluble phosphorus concentrations during baseflow were generally low in all sub-units, even in some settings with potential for high phosphorus inputs such as urban areas with municipal point sources or agricultural areas. The mobility of phosphorus in these environments may be hindered by adsorption and geochemical reactions.     

GROUND WATER MONITORING FOR TEMIK (ALDICARB) IN FLORIDA1

ABSTRACT: Over 700 community drinking water supplies were sampled for the pesticide Temik (aldicarb and its oxidative metabolites aldicarb sulfoxide and aldicarb sulfone) in Florida. All community supply wells sampled for Temik were located in counties where Temik was reported to have been used and approximately one-half of the wells were located in counties where ground water was determined to be highly susceptible to contamination by Temik. Susceptibility was determined using ranking criteria that incorporated ground water recharge characteristics, water use, and Temik use patterns. Temik was not detected in any of the community supply wells sampled during the study. However, Temik was detected in shallow, private wells, as was the pesticide ethylene dibromide in counties with ground water characterized as highly susceptible to contamination.     

PATTERN OF GROUND-WATER LEVEL DECLINE IN THE HIGH PLAINS AQUIFER NEBRASKA1

ABSTRACT: Ground-water level decline patterns in parts of Nebraska conform to the circular island concept of Bredehoeft et al. (1982), which indicates how water is derived by wells developed in a circular island. If elongated, the center of the island corresponds to a regional ground-water divide while the shoreline corresponds to a regional river. In both versions, ground-water table elevation is a function of recharge and transmissivity. A dynamic equilibrium exists such that the gradient of the water table will convey all recharge to discharge areas. Withdrawals of ground water result initially in mining, with a new equilibrium attained when pumping equals capture. During early development, capture is an important source of water in discharge areas, while mining is more significant in recharge areas. The pattern observed in many areas shows the greatest ground-water level decline in the vicinity of ground-water divides and the steepest gradient near regional rivers. A similar pattern has been observed adjacent to the Arkansas River in south-central Kansas. Similar decline patterns can be modeled for a hypothetical ground-water basin. This is of major importance to water-resource managers because it dictates that management programs be applied to the entire hydrologic system.     

A LAND-USE POLICY BASED ON WATER SUPPLY1

ABSTRACT: Santa Fe Country, New Mexico, has adopted a land-use policy in which zoning densities provide a balance between the water use on a parcel of land and the water supply available bencath that land. In two of four mapped hydrologic zones, ground water in storage will be allowed to be mined to exhaustion in 100 years (40 years in urban areas). Elsewhere, the policy is for a steady state with use balanced by recharge. Equations to determine storage or recharge can be solved using site specific data or regional estimates of hydrologic conditions. Substantial reductions in the lot size requirements are allowed if water conservation convenants are adopted. Public acceptance indicates that the policy successfully integrates technical and political concerns. It is simple to administer, yet reflects widely expressed public goals and values.     

APPLICATION OF GEOGRAPHIC INFORMATION SYSTEMS TO GROUNDWATER MONITORING NETWORK DESIGN1

ABSTRACT: Effective monitoring configurations for contaminant detection in groundwater can be designed by analyzing the spatial relationships between candidate sampling sites and aquifer zones susceptible to contamination. Examples of such zones are the domain underlying the contaminant source, zones of probable contaminant migration, and areas occupied by water supply wells. Geographic information systems (GIS) are well-suited to performing key groundwater monitoring network design tasks, such as calculating values for distance variables which quantify the proximity of candidate sites to zones of high pollution susceptibility, and utilizing these variables to quantify relative monitoring value throughout a model domain. Through a case study application, this paper outlines the utility of GIS for detection-based groundwater quality monitoring network design. The results suggest that GIS capabilities for analyzing spatially referenced data can enhance the field-applicability of established methodologies for groundwater monitoring network design.     

CONCENTRATED FLOW BREAKTHROUGHS MOVING THROUGH SILVICULTURAL STREAMSIDE MANAGEMENT ZONES: SOUTHEASTERN PIEDMONT,USA1

ABSTRACT: Geomorphic characteristics and spatial frequency of ephemeral concentrated flow paths entering streamside management zones (SMZs) were evaluated to determine the efficiency of best management practices (BMPs) in preventing concentrated overland flow and associated sediment from reaching stream channels. Specifically, SMZs of 30 recently clearcut and site prepared commercial forestry units in the Georgia Piedmont were surveyed to find two types of locations: those where flow and/or sediment from the adjacent silvicultural site entered and moved through SMZs into stream channels (breakthroughs), and those where either flow and/or sediment entered SMZs without reaching stream channels or where no overland flow entered SMZs (successes). A total of 187 breakthroughs were identified on 3,773 total acres. On average, sites featured one breakthrough for every 20 acres of clearcut or site prepared area. The average hydrologic contributing area to a breakthrough was 1 acre. The percentage of the total clearcut or site prepared area contributing to breakthroughs was 5 percent. Approximately 50 percent of all breakthroughs occurred in areas of convergence (swales) and gullies, while 25 percent of all breakthroughs occurred where runoff from roads or skid trails was concentrated. Breakthroughs tended to occur in areas with large contributing area, low litter cover, and steep slopes. However, individually these variables did not differentiate well between breakthroughs and successes. The variables that discriminated best between successes and failures were the product of contributing area and percent bare ground, and the same variable multiplied by average slope. Fourteen percent of the breakthroughs traveled more than 100 feet through SMZs before reaching streams. Results imply that reduction of bare ground, better dispersal of road runoff, introduction of hydraulic resistance to likely flow paths, and targeted extensions of SMZ width may be warranted in improving BMPs on Piedmont forests.