互花米草厌氧发酵产沼气研究进展

互花米草是国家环保总局首批公布的十大外来生物入侵物种之一,也是唯一的海岸盐沼植物。由于生长速度快、繁殖能力强、生物量大以及不占用耕地等特点,是发展生物质能源的优良物种。通过厌氧发酵将其转化为沼气,不但可以控制互花米草过度生长繁殖,解决其资源化问题,每年还可获得数量不菲的沼气,符合可持续发展的要求。将近年来互花米草厌氧发酵产沼气方面的研究进行了归纳和总结,主要包括互花米草特性、厌氧发酵产沼气的优劣势、可行性及相关研究进展以及今后的研究重点和展望,厌氧发酵产沼气研究进展包括直接发酵、过程控制、预处理、混合发酵和深度气化利用。互花米草中钠抑制的消除、机械收割、厌氧发酵工艺、相关工程技术设备以及能源化利用长效运行管理机制等将是今后互花米草能源化利用研究的重点     

Bacterial removal by anaerobic digestion

The impact of anaerobic digestion and post composting of the digested slurry on total bacterial counts, total coliform, fecal coliform, and fecal streptococci was investigated. Anaerobic digestion removed up to 99% of the bacterial parameters; however, the residual numbers present in the digested slurry were still high. The residuals ranged from 10⁵/g to 10¹³/g for total bacterial counts, 10²/g to 10⁸/g for total coliform, 10⁴/g to 10⁸/g for fecal coliform, and 10²/g to 10⁸/g for fecal streptococci. The digested slurry was mixed with soil for one week and then for two months, but the density of bacterial parameters was not reduced. There was an increase in numbers during the two composting steps.     

Removal of nutrients and heavy metals from anaerobic waste by aerobiological treatment

This study was conducted to investigate the effectiveness of aerobic biological treatment in removal of nitrogen, phosphorous, and heavy metals from a unique anaerobic liquid waste, produced at a solid waste-to-methane anaerobic digestion facility. Laboratory scale continuous flow activated sludge reactors were employed in this study. The liquid waste has moderate BOD/COD ratio with BOD concentration of 1300 mg/L and high concentration of essential nutrients, making the liquid waste biologically treatable. Results showed that aerobic biological treatment can remove nitrogen and phosphorous on the order of 85%. Metal removal efficiencies vary widely for 11 metals studied in this investigation.     

Life cycle assessment of municipal solid waste management methods: Ankara case study

Different solid waste management system scenarios were developed and compared for the Municipal Solid Waste Management System of Ankara by using the life cycle assessment (LCA) methodology. The solid waste management methods considered in the scenarios were collection and transportation of wastes, source reduction, Material Recovery Facility (MRF)/Transfer Stations (TS), incineration, anaerobic digestion and landfilling. The goal of the study was to determine the most environmentally friendly option of MSWM system for Ankara. The functional unit of the study was the amount of solid waste generated in the system area of concern, which are the districts of Ankara. The life cycle inventory analysis was carried out by IWM Model-1. The inputs and outputs of each management stage were defined and the inventory emissions calculated by the model were classified in to impact categories; non-renewable energy sources exhausting potential, final solid waste as hazardous and non-hazardous, global warming, acidification, eutrophication and human toxicity. The impacts were quantified with the weighing factors of each category to develop the environmental profiles of each scenario. In most of the categories, Source Reduction Scenario was found to be the most feasible management method, except the global warming category. The lowest contribution to GWP was calculated for the anaerobic digestion process. In the interpretation and improvement assessment stage, the results were further evaluated and recommendations were made to improve the current solid waste management system of Ankara.     

Harmonising conflicts between science,regulation, perception and environmental impact: The case of soil conditioners from bioenergy

As the global population is expected to reach 9 billion by 2050, humanity needs to balance an ever increasing demand for food, energy and natural resources, with sustainable management of ecosystems and the vital services that they provide. The intensification of agriculture, including the use of fertilisers from finite sources, has resulted in extensive soil degradation, which has increased food production costs and CO₂ emissions, threatening food security. The Bioenergy sector has significant potential to contribute to the formation of a circular economy. This paper presents the scientific, regulatory and socioeconomic barriers to the use of the nutrient waste streams from biomass thermal conversion (ash) and anaerobic digestion (digestate) as sustainable soil amendments for use in place of traditional fertilisers. It is argued that whilst the ability of combined ash and digestate to remedy many threats to ecosystems and provide a market to incentivise the renewable bio-energy schemes is promising, a step-change is required to alter perceptions of ‘waste’, from an expensive problem, to a product with environmental and economic value. This can only be achieved by well-informed interactions between scientists, regulators and end users, to improve the spread and speed of innovation with this sector.     

Distribution pattern of cadmium in different types of shellfish species

The study of cadmium levels in shellfish from the Atlantic coast of South Carolina was undertaken. The shellfish collected and analyzed were oysters, clams, crabs, squids, scallops, and shrimps. Fish were digested by wet digestion method and cadmium levels were determined by flame atomic absorption. The distribution pattern of cadmium levels in shellfish is different in various species. It was found that cadmium levels were relatively higher in oysters, crabs, clams, and scallops than in shrimps and squids.     

Selection of an appropriate waste-to-energy conversion technology for Dhaka City,Bangladesh

Solid waste disposal poses a significant problem, as it leads to land pollution if openly dumped, water pollution if dumped in low lands and air pollution if burnt. Moreover, the scarcity of land and increase in land prices especially in Dhaka, the capital city of Bangladesh create the problems of developing new landfill sites. Realising the existing and future impacts of waste disposal issues, the analytic hierarchy process model was applied to select an appropriate Waste-to-Energy (WTE) conversion technology for household waste of Dhaka-Mirpur Cantonment area. Three alternatives, namely, anaerobic digestion, pyrolysis and plasma gasification (PG) technologies and nine criteria under three aspects (technological, environmental and financial) were chosen for comparison. The analysis revealed that PG is the most appropriate WTE conversion technology in the study area. The selected PG technology has a relatively small footprint; it can treat unsorted waste and can produce good-quality synthetic gas without generating extremely toxic by-products.     

Conditions for the development of anaerobic digestion technologies using the organic fraction of municipal solid waste: perspectives for Poland

This article outlines problems related to the location of facilities designed to treat the organic fraction of municipal solid waste (OFMSW). Anaerobic digestion (AD) facilities are investigated as a treatment option, while taking into account the aspects of renewable energy generation. This research has been spurred on by the relationship between waste management, energy generation issues and spatial planning procedures. The analysis is focused on urban and semi-urban areas of medium and large cities. One of the most difficult issues associated with siting of waste processing plants is its integration with local infrastructures, avoiding conflicts and negative environmental impacts at the same time. This research aims to analyse possible locations for AD plants fuelled by OFMSW in Poland. Based on the experience gained from other countries and lessons learnt from the analysis of existing facilities in Europe, conditions for the location of this type of waste treatment plants have been defined, with the focus on economic, environmental and social issues. Most likely, the results of the multicriteria decision analysis for siting of municipal solid waste AD plants (M-BIST tool) could be transferred to other countries, especially those with a comparable GDP level and a similar framework for a waste management system.     

Studies on process optimization of biodiesel production from waste cooking and palm oil

This work investigated the optimisation of biodiesel production from waste cooking oil (WCO) and palm oil using a two-step transesterification process for WCO and base catalysed transesterification for palm oil. Transesterification reactions were carried out to investigate the effects of prepared catalyst CaO, methanol/WCO and methanol/palm oil ratio and temperature on the yield of biodiesel. A series of experiments were conducted to determine the best conditions for biodiesel production, using methanol/oil ratio between 4:1 and 11:1 and contact time varying between 2 and 4 h. Biodiesel yield of around 90 and 70% was obtained for palm and waste cooking oil at the methanol/oil ratios of 6:1 and 8:1 at temperature of 60 °C for reaction time of 4 h using prepared CaO as catalyst. The physicochemical properties of palm and WCO biodiesel were carried out using standard methods, while the fatty acid profile was determined using gas chromatography. The investigation concludes that biodiesel obtained from palm and waste cooking oil was within the specified limit.     

Hazardous waste, impact on health and environment for development of better waste management strategies in future in India

Industry has become an essential part of modern society, and waste production is an inevitable outcome of the developmental activities. A material becomes waste when it is discarded without expecting to be compensated for its inherent value. These wastes may pose a potential hazard to the human health or the environment (soil, air, water) when improperly treated, stored, transported or disposed off or managed. Currently in India even though hazardous wastes, emanations and effluents are regulated, solid wastes often are disposed off indiscriminately posing health and environmental risk. In view of this, management of hazardous wastes including their disposal in environment friendly and economically viable way is very important and therefore suggestions are made for developing better strategies. Out of the various categories of the wastes, solid waste contributes a major share towards environmental degradation. The present paper outlines the nature of the wastes, waste generating industries, waste characterization, health and environmental implications of wastes management practices, steps towards planning, design and development of models for effective hazardous waste management, treatment, approaches and regulations for disposal of hazardous waste. Appraisal of the whole situation with reference to Indian scenario is attempted so that a better cost-effective strategies for waste management be evolved in future.     

Techno-economic feasibility of biogas generation in Attari village,Ferozepur road,Lahore

Attari Saroba is a village located on the Ferozepur road near Attari Darbar. This study assesses techno-economic feasibility for biogas production in Attari Saroba village using different tools for data collection. Since there was no waste management system in the village, the residents threw household waste in the streets and used the animal waste as the fertilizer, while the leftover waste was disposed off in heaps scattered around the village. This waste can be utilized to generate biogas that can be a renewable substitute for natural gas as natural gas is becoming scarce in our country and is suitable for home use in cooking and heating purposes. Thus, the objective of the study is to combat pollution by managing organic waste and to produce biogas by reusing waste in Attari Saroba through waste recycling process. The suggested type of digester for this area is dispersed growth, Chinese-type combined digester and gasholder. Two designs of different measurements were proposed due to varying family size. The residents were receptive to the idea of installing and maintaining digesters in their homes as they faced regular gas shortages in their area.     

Characterization of the TE-NORM waste associated with oil and natural gas production in Abu Rudeis, Egypt

The present study was conducted to characterize the Technically Enhanced Naturally Occurring Radioactive Materials (TE-NORM) waste generated from oil and gas production. The waste was characterized by means of dry screening solid fractionation, X-ray analysis (XRF and XRD) and gamma-ray spectrometry. Sediment of the TE-NORM waste was fractionated into ten fractions with particle sizes varying from less than 100 microm to more than 3 mm. The results showed that the TE-NORM waste contains mainly radionuclides of the 238U, 235U and 232Th series. The mean activity concentrations of 226Ra (of U-series), 228Ra (of Th-series) and 40K in the waste samples before fractionation (i.e. 3 mm) were found to amount to 68.9, 24 and 1.3 Bq/g (dry weight), respectively. After dry fractionation, the activity concentrations were widely distributed and enriched in certain fractions. This represented a 1.48 and 1.82-fold enrichment of 226Ra and 228Ra, respectively, in fraction F8 (2.0-2.5 mm) over those in bulk TE-NORM waste samples. The activity ratios of 238U/226Ra, 210Pb/226Ra, 223Ra/226Ra and 228Ra/224Ra were calculated and evaluated. Activity of the most hazardous radionuclide 226Ra was found to be higher than the exemption levels established by IAEA [International Atomic Energy Agency, 1994. International Basic Safety Standards for the Protection against Ionizing Radiation and for the Safety of Radiation Sources. GOV/2715/94, Vienna]. The radium equivalent activity (Ra-eq), radon (222Rn) emanation coefficient (EC) and absorbed dose rate (Dgammar) were estimated and these are further discussed.     

A simplified method for the design and sizing of anaerobic digestion systems for smaller farms

Anaerobic digestion (AD) as a waste treatment practice has existed for nearly 200 years and has become an accepted option for many farming and small-scale residential operations. Many developing countries now encourage the use of AD in order to meet new environmental regulations and/or to provide small amounts of energy resulting from methane generated during the process. This development has been met with some difficulty due to the lack of resources and knowledge of the systems in many of the rural communities in which these digesters are placed. A properly designed AD system can help prevent soil and water pollution as well as help mitigate methane emissions by capturing them for use as a potential energy source. This paper focuses on providing guidance to the proper design and sizing of an AD system for typical small farms, which account for the majority of dairy farms worldwide. A focus was on the implementation of such systems as they might be applied in Central America, although the aspects studied here can be applied for AD systems handling animal waste streams practically anywhere. We provide a method for sizing of anaerobic digester systems based on design standards from the US National Resource Conservation Service and using field sampled data of holding pen wash water runoff. An overview of the decision process for alternative designs is given, and simple-to-use nomographs are presented for use in sizing of an anaerobic digester system for smaller (non-industrial)-scale farms.     

Energy conservation and waste utilization in the cement industry serve the green technology and environment

The cement industry is one of the most energy-intensive industries consuming 4 GJ/ton of cement, i.e. 12–15% of the energy use in total industry. Energy cost accounts for 30% of the total cost of cement production. Seventy-five per cent of this energy is due to the thermal energy for clinker production. It is also found that 35% of this supplied thermal energy is lost in flue gas streams. Most modern kilns use pet coke or coal as their primary fuel. Instead, the municipal waste in landfills offer a cheap source of energy and reduce the environmental effects of dumping solid waste. The calcination and drying processes and the kiln need large quantities of thermal energy. About 40% of the total energy input is lost in the hot flue gases and cooling the stack plus the kiln shell. Hence, it is suitable to use an organic Rankine cycle (ORC) to recover the exhaust energy from the kiln. Alternatively, a 15 MW gas turbine engine combined with a steam turbine could be utilized. It was found that ORC produces 5 MW with a capital cost recovery period of 1.26 years. However, the gas turbine combined system produces 21.45 MW with a maximum recovery period of 2.66 years.     

Measuring the environmental impact of waste flow management in Brazilian apartment buildings

As biodegradable material represents approximately 70% of household waste in Brazil, any strategy to divert appreciable waste quantities from landfills of necessity has to include valorization and recycling of this material. A societal change of attitude is required to perceive this challenge. Experiments in an urban apartment building are described that produced this change of attitude with a success factor of 80%. Divided waste collection was implemented that separated at the source biodegradable from inert material. Correct collection, handling and display procedures were established. Composting of biodegradable material was carried out under the rooftop of the building as an alternative to using it as animal feed. Half of the inert material entered the reverse logistics chain and was also diverted from the landfill. Waste related material flow through the building is completely quantified, food intake and waste production are related, diversion of both biodegradable and inert waste components from the landfill is measured and the composting process is described. The landfill diversion stands at 61%, mass reduction through the composting process is 80% and matured compost is returned to residents for use in flower cages. The system has been operational for two years and stands out as a precedent in successful decentralized household waste management supported by material flow analysis. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

The STRATEGY project: decision tools to aid sustainable restoration and long-term management of contaminated agricultural ecosystems

The STRATEGY project (Sustainable Restoration and Long-Term Management of Contaminated Rural, Urban and Industrial Ecosystems) aimed to provide a holistic decision framework for the selection of optimal restoration strategies for the long-term sustainable management of contaminated areas in Western Europe. A critical evaluation was carried out of countermeasures and waste disposal options, from which compendia of state-of-the-art restoration methods were compiled. A decision support system capable of optimising spatially varying restoration strategies, that considered the level of averted dose, costs (including those of waste disposal) and environmental side effects was developed. Appropriate methods of estimating indirect costs associated with side effects and of communicating with stakeholders were identified. The importance of stakeholder consultation at a local level and of ensuring that any response is site and scenario specific were emphasised. A value matrix approach was suggested as a method of addressing social and ethical issues within the decision-making process, and was designed to be compatible with both the countermeasure compendia and the decision support system. The applicability and usefulness of STRATEGY outputs for food production systems in the medium to long term is assessed.     

Application of active disassembly to extend profitable remanufacturing in small electrical and electronic products

Alternative production approaches are required because of conventional manufacturing's adverse environmental impacts. Remanufacturing returns used products to at least original performance specification from customers' perspectives and gives the resultant products warranties at least equal to that of new equivalents. Remanufacturing is relatively novel in research terms compared to conventional manufacture and recycling but often is more profitable than both. It would help manufacturers address competitive, environmental and legislative pressures by enabling them to meet pressing waste legislation while producing high-quality, lower cost products with less environmentally damaging end-of-life (EoL) and manufacturing modes. Remanufacturing is highly profitable in large, complex mechanical and electromechanical products but with conventional manufacturing and design modes not so in smaller products; particularly fast moving ones. However, effective waste management is urgently required for such products because waste electrical and electronic equipment constitutes the fastest growing EU waste stream and a large percentage of products being produced by major developing economies such as China are of this type. Active disassembly (AD) enables product non-destructive, self-disassembly at EoL and was invented to facilitate a step-change improvement in recycling. This research investigated the use of AD to extend profitable remanufacturing into small EoL electrical and electronic products.     

Protein futures for Western Europe: potential land use and climate impacts in 2050

Multiple production and demand side measures are needed to improve food system sustainability. This study quantified the theoretical minimum agricultural land requirements to supply Western Europe with food in 2050 from its own land base, together with GHG emissions arising. Assuming that crop yield gaps in agriculture are closed, livestock production efficiencies increased and waste at all stages reduced, a range of food consumption scenarios were modelled each based on different ‘protein futures’. The scenarios were as follows: intensive and efficient livestock production using today’s species mix; intensive efficient poultry–dairy production; intensive efficient aquaculture–dairy; artificial meat and dairy; livestock on ‘ecological leftovers’ (livestock reared only on land unsuited to cropping, agricultural residues and food waste, with consumption capped at that level of availability); and a ‘plant-based eating’ scenario. For each scenario, ‘projected diet’ and ‘healthy diet’ variants were modelled. Finally, we quantified the theoretical maximum carbon sequestration potential from afforestation of spared agricultural land. Results indicate that land use could be cut by 14–86 % and GHG emissions reduced by up to approximately 90 %. The yearly carbon storage potential arising from spared agricultural land ranged from 90 to 700 Mt CO₂ in 2050. The artificial meat and plant-based scenarios achieved the greatest land use and GHG reductions and the greatest carbon sequestration potential. The ‘ecological leftover’ scenario required the least cropland as compared with the other meat-containing scenarios, but all available pasture was used, and GHG emissions were higher if meat consumption was not capped at healthy levels.     

Pollution prevention in the pharmaceutical industry

The pharmaceutical industry traditionally uses complex batch-type processes in the manufacture of medicines, although the production of specific medicines by continuous processes is currently envisaged. Due to the diversity of these processes, it is difficult to define a general set of waste prevention guidelines that would apply to all drug manufacturing. The most applicable methods of prevention can, however, be delineated for each of the five steps in the pharmaceutical manufacturing, i.e. (i) research and development, (ii) chemical synthesis, (iii) natural product extraction, (iv) fermentation and (v) product formulation. Waste streams generally arise from cleaning and sterilising equipment, chemical spills, rejected by-products and the processes themselves. Prevention mainly involves waste reduction by materials substitution, process modification/optimisation, waste stream segregation and solvent waste recycling. These measures are assessed and lead to guidelines for waste minimisation methods according to the waste streams under scrutiny.     

Lake pollution in Ibadan,Nigeria

An investigation was made of the sources and degree of pollution of Ogunpa lake, situated in Ibadan, Nigeria. It was shown that the lake receives a variety of waste effluents from domestic and industrial sources which discharge into the Ogunpa stream. These waste effluents have caused an odour nuisance in the lake, and little or no dissolved oxygen is present. The discharge of nutrients (N and P) to the lake has resulted in excessive growth of aquatic weeds. All these impacts on the lake have resulted in a reduced fish production. Some suggestions for the prevention of pollution and the recovery of the lake are presented.