Chemical and microbiological examination of well and Nile water

The chemical composition and microbiological contamination of well water and Nile River water used for drinking were investigated in localities around Khartoum, Sudan, to present baseline data. The chemical analyses results obtained indicated that public health hazards due to pH, Ca⁺⁺, CO₃^??, HCO₃^?, and NO₃^? are unlikely in all the samples studied, while Na⁺ and Cl^? ions concentrations in well water warrant some attention. Contamination from organic matter and suspended material is also negligible. Microbial contamination with coliform and fecal coliform is high in surface wells and in the Nile River, but negligible in deep bores, tap water, and mineral water. The logarithm of the colony count ranges from zero for mineral water to 6.8 for water from the White Nile. In addition to drawing further attention to the well water and Nile water used for drinking by a wide sector of the population, the microbial count data for water from the Nile disagreed with the generally held belief that the Nile, being one of the largest rivers of the world, carries no detectable fecal contamination. Our data also did not support the belief that the White Nile is more contaminated than the Blue Nile.     

Microbial degradation of hydrocarbons in Ismailia canal water

The biodegradation of hydrocarbons was performed in refinery wastewater obtained by natural microbial flora in Ismailia canal water. About 87% of hydrocarbons were degraded after 9 days under simulated natural conditions. It was found that the addition of fuel oil to the canal water, which already contained significant amounts of refinery wastewater, retarded biological degradation. Percentage of degradation was found to be 67%. This increase in the hydrocarbons concentration affects dramatically on the generation rate of microorganisms present naturally in canal water.     

Oil pollution studies in the Nile River. I. Survey of oil and grease in Nile water

A survey of oil and grease along the Nile River indicated the presence of variable concentrations of these pollutants. It was found that some stations along the Nile are more polluted than others. These are located mostly at lake Nasser port (Aswan segment); oil distribution centers and ship waiting areas (Assiut segment); boat docks, a ship yard, and an electric power station (Cairo segment); and at factory areas (Rossetta segment). The level of oil and grease decreased significantly when moving downstream. In addition, the level of oil and grease along the river was lower in summer than in winter and spring. This may be attributed to the decrease of activities and increase of vaporization processes.     

Removal of copper from water using limestone filtration technique. Determination of mechanism of removal

This paper discusses heavy metal removal from wastewater by batch study and filtration technique through low-cost coarse media. Batch study has indicated that more than 90% copper (Cu) with concentration up to 50 mg/l could be removed from the solution with limestone quantity above 20 ml (equivalent to 56 g), which indicates the importance of limestone media in the removal process. This indicates that the removal of Cu is influenced by the media and not solely by the pH. Batch experiments using limestone and activated carbon indicate that both limestone and activated carbon had similar metal-removal efficiency (about 95%). Results of the laboratory-scale filtration technique using limestone particles indicated that above 90% removal of Cu was achieved at retention time of 2.31 h, surface-loading rate of 4.07 m3/m2 per day and Cu loading of 0.02 kg/m3 per day. Analyses of the limestone media after filtration indicated that adsorption and absorption processes were among the mechanisms involved in the removal processes. This study indicated that limestone can be used as an alternative to replace activated carbon.     

Effect of Nile River water quality on algal distribution at Cairo,Egypt

Changes of phytoplankton density and their relation to physicochemical characteristics along the Nile River have been noted in the Cairo district between 1976 and 1982. Three major phytoplankton groups were found to dominate the river Nile: green algae, blue-green algae, and diatoms. Diatoms represent the most dominant group and comprised from 42% to 96% of the phytoplankton community during the investigated period. Blue-green algae comprised from 0.7% to 48% of total cell number. Green algae represent the low percentage group, which ranges from 0.2% to 41% of Nile water algae. High species diversity (H′) was detected in green algae (1.22) followed by diatoms (0.84); the lowest diversity was in blue-green algae (0.45). The density of total phytoplankton count fluctuated between 10⁶ and 10⁷ organism/L. The concentration of chlorophyll-a ranged from 5 to 37 mg/m³. Primary production rates in the Nile River ranged from 8.5 to 52 mg O₂/m³h. Statistical analysis revealed significant positive correlations between chlorophyll-a content, and concentrations of phosphoruss and nitrate. Phytoplankton diversity, primary production, ammonia, and nitrite content revealed that there is no indication of pollution in the Nile.     

A review of occurrences and treatment of polynuclear aromatic hydrocarbons in water

The scope of PAH contamination of raw, finished, and distributed waters is reviewed. The concentrations of PAHs in drinking water sources range from nanogram to microgram-per-liter quantities. Conventional treatment (flocculation, sedimentation, chlorination, and filtration) appears to substantially reduce total PAH concentrations present at higher concentrations in source waters. A major factor in this reduction is the removal of PAHs adsorbed onto particulate matter. The role of chlorination is not clear and reactions of PAHs with chlorine may in fact produce products which themselves are deleterious. Activated carbon can further assist in PAH removal. However, it may be inappropriate for treatment of PAHs present at low concentrations. Water entering the distribution system can become recontaminated via contact with reservoirs and pipes coated with coal-tar or asphalt based products.     

Removal of NOM in the different stages of the water treatment process

Natural organic matter (NOM) is abundant in natural waters in Finland and in many ways affects the unit operations in water purification. In this study, the organic matter content in water in different stages of a full-scale treatment process over 1 year was measured. The full-scale treatment sequence, studied at the Rusko water treatment plant in Tampere, Finland, consisted of coagulation, flocculation, clarification by sedimentation or flotation, activated carbon (AC) filtration, and disinfection. High-performance size exclusion chromatography (HPSEC) was used for separation to determine changes in the humic substances content during the purification process. In addition, total organic carbon (TOC), KMnO4-number, and UV-absorbance at wavelength 254 nm (UV254) were measured. High molecular weight (HMW) matter was clearly easier to remove in coagulation and clarification than low molecular weight (LMW) matter. Furthermore, depending on the regeneration of the activated carbon filters, activated carbon filtration was effective to a degree but did not remove most of the lowest molecular weight compounds. Significant correlation was established among HPSEC, KMnO4, UV254 absorbance, and TOC. HPSEC proved to be a fast and relatively easy method to estimate NOM content in water and, in fact, gave more information than traditional methods on the type of NOM in a water sample. It also helped the process performance follow-up.     

Biodegradability of hydrocarbons in the refinery wastewater from moustorod oil refinery

The present investigation deals with the study of hydrocarbon degradation present in refinery wastewater by natural microbial flora in addition to that obtained using Ps. aeruginosa under laboratory conditions. Results indicated that Ps. aeruginosa may have a significant role in the degradation of hydrocarbons. After seven days, several of the compounds in the original wastewater were completely degraded and four compounds (n-paraffins) were partially degraded. Without Ps. aerruginosa, the same picture had been obtained after 23 days.     

Removal of synthetic dyes from wastewaters: a review

The more recent methods for the removal of synthetic dyes from waters and wastewater are complied. The various methods of removal such as adsorption on various sorbents, chemical decomposition by oxidation, photodegradation, and microbiological decoloration, employing activated sludge, pure cultures and microbe consortiums are described. The advantages and disadvantages of the various methods are discussed and their efficacies are compared.     

Land use changes and its impacts on water resources in Nile Delta region using remote sensing techniques

Sustainable water resources management plans depend on reliable monitoring of land use –land cover (LULC) changes. The use of the remote sensing techniques in LULC changes detection brings consistency and reliability to the decision maker at regional scale. Three temporal data sets of images were used to obtain the land cover changes in this study: Landsat-5 Thematic Mapper (TM) acquired in 1984, and Landsat-7 enhanced Thematic Mapper acquired in 2000 and 2005 consequently. Each temporal data set consists of four Landsat scenes, which were mosaicked to cover the whole Nile Delta. Two different supervised classification algorithms were implemented to produce classification maps in thematic form. Support vector machine showed higher classification accuracies in comparison with maximum likelihood classification. The results indicated that the rapid imbalance changes occurred among three land cover classes (urban, desert, and agricultural land). These changes powered the land degradation and land fragmentation processes over the agricultural land exclusively due to urban encroachment. Slight land cover changes were detected between fish farms and surface water land cover classes.     

Utilization of petroleum hydrocarbons by Pseudomonas fluorescens isolated from a petroleum-contaminated soil

A strain of Pseudomonas fluorescens, isolated from petroleum hydrocarbon-contaminated soil was examined for its ability to utilize a variety of hydrocarbon substrates. Surface tension measurements indicated the production of biosurfactant during the microbial degradation of hydrocarbon. The organism utilized both short and long chain n-alkanes. It emulsified a number of aliphatic and aromatic hydrocarbons.     

Evaporation of solutes from water

A model is developed to define the evaporation rates of solutes from water. The rate equation, similar in form to the Knudsen equation, takes into consideration the effect of air and subwater turbulences on the evaporation loss. At given system conditions, the factor accounting for the air turbulence appears to be essentially constant and independent of temperature (3.5–25°C) for various organic chemicals and water. These characteristics allow one to study the rate of evaporation from water and the relative enhancement by subwater mixing for different solutes. This report shows that the volatilization loss of pure substances and solutes with low Henry's law constants is enhanced by air turbulence, not by subwater mixing. However, the loss of volatile solutes (high Henry's law constants) may be promoted both by air turbulence and by subwater mixing, in which the extent of enhancement by liquid mixing is determined primarily by the Henry's law constant. The present model provides a theoretical basis to explain these effects and others, which appear to be important for assessment of pollutant evaporative transport in the environment.     

Analyzing the hydrologic effects of region-wide land and water development interventions: a case study of the Upper Blue Nile basin

In the drylands of the Upper Blue Nile basin, high climate variability and land degradation are rampant. To enhance adaptive capacity in the region, various soil and water conservation interventions have been implemented. Moreover, water resources development schemes such as the Grand Ethiopian Renaissance Dam should be implemented by 2025. We modeled the effects of these interventions on surface runoff in the basin for both current and future (2025) basin conditions, using the runoff coefficient method in a spatially explicit approach. Under current conditions, we observed high spatial variability of mean annual runoff. The northeastern Blue Nile-1 sub-basin produces the highest mean annual runoff (391 mm or 10 × 10⁹ m³), whereas the northwestern Blue Nile-2 sub-basin produces the lowest mean annual runoff (178 mm or 0.2 × 10⁹ m³). The basin generates a total annual runoff volume of 47.7 × 10⁹ m³, of which about 54 % comes from cultivated land. The strong association between land use and topography masked the direct effect of rainfall on runoff. By 2025, total annual runoff yield could decrease by up to 38 % if appropriate basin-wide soil and water conservation interventions and the Grand Ethiopian Renaissance Dam are implemented. However, the full effects of most physical structures will only last for 1 or 2 years without regular maintenance. The improved understanding of the dynamics of the Upper Blue Nile basin’s hydrology provided by the present study will help planners to design appropriate management scenarios. Developing the basin’s database remains important for a holistic understanding of the impacts of future development interventions.     

Degradation of polycyclic aromatic hydrocarbons by a bacterial consortium enriched from mangrove sediments

The biodegradability of a polycyclic aromatic hydrocarbons (PAHs) mixture consisted of fluorene (Fl), phenanthrene (Phe) and pyrene (Pyr) by a bacterial consortium enriched from mangrove sediments under sediment-free and sediment slurry conditions was investigated. The enriched consortium made up of three bacterial strains, namely Rhodococcus sp., Acinetobacter sp. and Pseudomonas sp., had a good PAH degradation capability with 100% degradation of Fl and Phe in sediment-free liquid medium after 4 weeks of growth. The Fl and Phe degradation percentages in sediment slurry were higher than that in liquid medium. Autochthonous microorganisms in sediments also possessed satisfactory PAH degradation capability and all three PAHs were almost completely degraded after 4 weeks of growth. Bioaugumentation (inoculation of the enriched consortium to sediments) showed a positive effect on PAH biodegradation after 1 week of growth. Complete biodegradation of pyrene took longer time than that for Fl and Phe, indicating the enriched bacterial consortium had preference to utilize low-molecular weight PAHs.     

Understanding the fate and transport of petroleum hydrocarbons from coal tar within gasholders

Coal tars have been identified as posing a threat to human health due to their toxic, mutagenic and carcinogenic characteristics. Workers involved in former gasholders decommissioning are potentially exposed to relevant concentrations of volatile and semi-volatile hydrocarbons upon opening up derelict tanks and during tar excavation/removal. While information on contaminated sites air-quality and its implications on medium-long term exposure is available, acute exposure issues associated with the execution of critical tasks are less understood. Calculations indicated that the concentration of a given contaminant in the gasholder vapour phase only depends on the coal tar composition, being only barely affected by the presence of water in the gasholder and the tar volume/void space ratio. Fugacity modelling suggested that risk-critical compounds such as benzene, naphthalene and other monocyclic and polycyclic aromatic hydrocarbons may gather in the gasholder air phase at significant concentrations. Gasholder emissions were measured on-site and compared with the workplace exposure limits (WELs) currently in use in UK. While levels for most of the toxic compounds were far lower than WELs, benzene air-concentrations where found to be above the accepted threshold. In addition due to the long exposure periods involved in gasholder decommissioning and the significant contribution given by naphthalene to the total coal tar vapour concentration, the adoption of a WEL for naphthalene may need to be considered to support operators in preventing human health risk at the workplace. The Level I fugacity approach used in this study demonstrated its suitability for applications to sealed environments such as gasholders and its further refining could provide a useful tool for land remediation risk assessors.     

Partitioning coefficients of polycyclic aromatic hydrocarbons in stack gas from a municipal incinerator

In this study, solid-gas partitioning coefficients of PAHs on fly ash in stack gas from a municipal incinerator were determined according to elution analysis with gas-solid chromatography. The fly ash from the electrostatic precipitator was sieved and packed into a 1/4 inch (6.3 mm) pyrex column. Elution analysis with gas-solid chromatography was conducted for three PAHs, Napthalene, Anthracene, and Pyrene. The temperature for elution analysis was in the range of 100°C to 300°C. V_g, specific retention volume obtained from elution analysis, and S, specific surface area of fly ash measured by a surface area measurement instrument, were used to estimate the solid-gas partitioning coefficient, K_R. In addition, the relationships between K_R and temperature and K_R and PAH concentrations were investigated.     

Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes

Over the past few years, pharmaceuticals are considered as an emerging environmental problem due to their continuous input and persistence to the aquatic ecosystem even at low concentrations. Advanced oxidation processes (AOPs) are technologies based on the intermediacy of hydroxyl and other radicals to oxidize recalcitrant, toxic and non-biodegradable compounds to various by-products and eventually to inert end-products. The environmental applications of AOPs are numerous, including water and wastewater treatment (i.e. removal of organic and inorganic pollutants and pathogens), air pollution abatement and soil remediation. AOPs are applied for the abatement of pollution caused by the presence of residual pharmaceuticals in waters for the last decade. In this light, this paper reviews and assesses the effectiveness of various AOPs for pharmaceutical removal from aqueous systems.     

Removal of nutrients and heavy metals from anaerobic waste by aerobiological treatment

This study was conducted to investigate the effectiveness of aerobic biological treatment in removal of nitrogen, phosphorous, and heavy metals from a unique anaerobic liquid waste, produced at a solid waste-to-methane anaerobic digestion facility. Laboratory scale continuous flow activated sludge reactors were employed in this study. The liquid waste has moderate BOD/COD ratio with BOD concentration of 1300 mg/L and high concentration of essential nutrients, making the liquid waste biologically treatable. Results showed that aerobic biological treatment can remove nitrogen and phosphorous on the order of 85%. Metal removal efficiencies vary widely for 11 metals studied in this investigation.     

Removal of uranium (VI) from aqueous solution by adsorption of hematite

Hematite, a type of inorganic-sorptive medium, was used for the removal of U (VI) from aqueous solutions. Variables of the batch experiments including solution pH, contact time, initial concentration, temperature, calcium and magnesium ions were studied. The results indicated that the adsorption capacities are strongly affected by the solution pH, contact time and initial concentration. A higher pH favors higher U (VI) removal. The adsorption was also affected by temperature and calcium and magnesium ions, but the effect is very weak. The maximum adsorption capacity (q_m) only increased from 3.36 mg g⁻¹ to 3.54 mg g⁻¹ when the temperature was increased from 293 K to 318 K. A two-stage kinetic behavior was observed in the adsorption of uranium (VI): very rapid initial adsorption in a few minutes, followed by a long period of slower uptake. It was found that an increase in temperature resulted in a higher uranium (VI) loading per unit weight of the sorbent. The adsorption of uranium by hematite had good efficiency, and the equilibrium time of adsorbing uranium (VI) was about 6 h. The isothermal data were fitted with both Langmuir and Freundlich equations, but the data fitted the former better than the latter. The pseudo-first-order kinetic model, pseudo-second-order kinetic model and intraparticle diffusion model were used to describe the kinetic data, but the pseudo-second-order kinetic model was the best. The thermodynamic parameter ΔG⁰ were calculated, the negative ΔG⁰ values of uranium (VI) at different temperatures confirmed the adsorption processes were spontaneous.     

Biologically induced Po emission from fresh water

Behavior of Po in fresh waters was examined in laboratory culture experiments using fresh water collected from a small pool, Xi river and Xiqing lake, showing formation of volatile Po compounds followed by emission to air. Addition of tryptone to the fresh water cultures increased the emission of Po considerably along with a growth of microorganisms, suggesting a connection of chemoheterotrophs to Po emission. Participation of photoautotrophs was also considered because Po emission was increased when NaHCO3 was added to the fresh water cultures. The emission behavior of Po and S in these experiments appeared in different ways. The quantity of Po emitted was comparable to the previous culture experiments (Momoshima, Song, Osaki & Maeda, Environ. Sci. Technol., 35, 2956-2960, 2001) in which artificial culture medium containing 3% NaCl was used and inoculated with sea sediment extract. The biological support for Po emission, thus, would be a general phenomenon in fresh water as well as a seawater environment and is possibly a source for atmospheric Po.