Polysaccharides; Classification,Chemical Properties,and Future Perspective Applications in Fields of Pharmacology and Biological Medicine (A Review of Current Applications and Upcoming Potentialities)

Journal of Polymers and the Environment - Polysaccharides are essential macromolecules which almost exist in all living forms, and have important biological functions, they are getting more...     

Enzyme-Mediated Reactions of Oligosaccharides and Polysaccharides

Two types of enzymatic reactions are given here as examples of synthetic problems encountered in industry. In the first case, commercially available -D-galactosidase from Escherichia coli was used as a catalyst to transfer galactose from -lactose to oligosaccharides. A preference for galactosyl transfer to the 3- or 4-position of the sugar moiety of the oligosaccharide was observed for the products. As expected, only the -anomer was produced. A wide variety of sugars, including disaccharides, trisaccharides, cellotetraose, and maltodextrins, has been shown to act as acceptors, yielding oligosaccharides. In the second example, -galactomannan that had been previously treated to contain cationic groups (cationic guar gum) was subjected to treatment with a series of inexpensive commercial enzymes such as lipases, protease, and cellulases. Some enzyme preparations showed significant changes in the viscosities of 1% cationic guar solution. For example, lipases from Aspergillus niger and Aspergillus saitoi and protease XIII from Rhizopus niveus produced a substantial viscosity reduction (0–20% of original viscosity). These examples demonstrate the utility of low-cost enzymes in manipulating polymer structures.     

Anaerobic Biodegradation of Polyvinyl Alcohol Modified by Extracellular Polysaccharides

This work focused on anaerobic biodegradation of blends composed of glycerol-plasticized polyvinyl alcohol (PVA) and biopolymer (starch, gellan, xanthan) in an aqueous environment, after inoculation with digested activated sludge from a municipal wastewater treatment plant. Glycerol degradability is comparable to degradability of used modifying agents. Modifying agents added in the 20–40 wt% range proportionally increased biodegradation degree (D_t) calculated from balance of transformed carbon in the system. Biodegradation degree of polysaccharides and glycerol attained 95% and over. For PVA it was only 6.5% (in breakdown times up to 500 h). Content of polysaccharides favorably affects biodegradation degree of polyvinyl alcohol blends, but at the expense of reduced mechanical properties of resultant products.     

Review on Anti-cancer and Anti-microbial Applications of Curdlan Biomaterials

Journal of Polymers and the Environment - Polysaccharides are polymers of natural origin that are formed by microorganisms, animals and plants. Polysaccharides play an important part in the...     

Oxygen Permeability and Biodegradability of Polyuronic Acids Prepared from Polysaccharides by TEMPO-Mediated Oxidation

Polyuronic acids, i.e., amylouronic acid, cellouronic acid and chitouronic acid, were prepared from starch, cellulose and chitin, respectively, by the 2,2,6,6-tetramethylpiperidine-1-oxy radical (TEMPO)-mediated oxidation, and their gas-barrier properties and biodegradability were studied in consideration to use the polyuronic acids as flexible packaging films or coating materials. Cellouronic acid and amylouronic acid had excellent oxygen-barrier properties similar to that of poly(vinyl alcohol) (PVA), while chitouronic acid did not. The regular chemical structures of the former two polyuronic acids with no bulky substituents or adducts may have brought about such high oxygen-barrier levels. An oxidized product prepared form fine microcrystalline cellulose by the TEMPO-mediated oxidation was not completely dissolved in water, but became a paste. However, this paste also formed sufficiently smooth films by coating, and had good gas-barrier property. All polyuronic acids prepared were biodegradable; cellouronic acid and chitouronic acid had high degrees of biodegradability, while amylouronic acid had quite low value. These various characteristics are significant for end use of these new polyuronic acids as gas-barrier materials for biodegradable packaging.     

Study on Biodegradable Starch/OMMT Nanocomposites for Packaging Applications

The thermoplastic starch (TPS) and nanocomposite(TPS/OMMT) was prepared with 15% carbamide, 15% ethanolamine and different contents of organic activated montmorillonite (OMMT) by twin-screw extruder with a 130 °C barrel temperature. Fourier transforms infrared spectroscopy and wide angle X-ray diffraction shown that the alkylamine in dodecyl benzyl dimethyl ammonium bromide could react with MMT via cation exchange reaction. After treated, the d(001)space distance of MMT increased from 1.5 to 1.7 nm. Scanning electron microscope revealed that the lower contents of OMMT could disperse well in the matrixes of TPS. The carbamide, ethanolamine and the OMMT could destroy the crystallization behavior of starch, but only the OMMT restrained this behavior for long-term storing. Mechanical properties investigation indicated that the tensile strength and modulus of TPS/OMMT nanocomposites were better than those of TPS, while the elongation at break was descended with the increasing of OMMT contents. When the content of OMMT was 4%, the tensile strength and modulus of TPS was improved from 4.2 and 42 MPa to 6.0 and 76 MPa, respectively.     

Perspective and trends in the environmental remediation industry

The approach to management and execution of remediation projects has changed drastically over the past decade, as remedial project managers have begun to understand and accept the numerous environmental regulations developed in the mid-1980s. For example, the adversarial relationship that once existed between regulators and owners has become more cooperative. This article documents trends over time in remediation project practices and quantifies the impact these trends have had on the cost and schedule performance of projects. Proven successful practices are highlighted, and those with the potential for improving project performance further are also discussed.     

Recent Advances in the Production, Recovery and Applications of Polyhydroxyalkanoates

Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters that can potentially replace certain plastics derived from petroleum. PHAs can be produced using a combination of renewable feedstocks and biological methods. Native and recombinant microorganisms have been generally used for making PHAs via fermentation processes. As much as 90 % of the microbial dry mass may accumulate as PHAs. A range of PHAs has been produced using fermentation methods, including copolymers and block copolymers. Alternative production schemes based on genetically modified plants are becoming established and may become the preferred route for producing certain PHAs. Production in plants is likely to be inexpensive compared to production by fermentation, but it does not appear to be as versatile as microbial synthesis in terms of the range of products that may be generated. Cell-free enzymatic production of PHAs in vitro is receiving increasing attention and may become the preferred route to some specialty products. This review discusses the recent advances in production of polyhydroxyalkanoates by the various methods. Methods of recovering the polymer from microbial biomass are reviewed. Established and emerging applications of PHAs are discussed.     

An Overview on Starch-Based Sustainable Hydrogels: Potential Applications and Aspects

Hydrogels are a kind of three dimensional polymeric network system which has a significant amount of water imbibing capacity despite being soluble in it. Because of the potential applications of hydrogels in different fields such as biomedical, pharmaceutical, personal care products, biosensors, and cosmetics, it has become a very popular area of research in recent decades. Hydrogels, prepared from synthetic polymers and petrochemicals are not ecofriendly. For preparing biodegradable hydrogels, most available plant polysaccharides like starch are utilized. In its structure, starch has a large number of hydroxyl groups that aid in hydrogel networking. For their easy availability and applications, starch-based hydrogels (SHs) have gained huge attention. Moreover, SHs are non-toxic, biocompatible, and cheap. For these reasons, SHs can be an alternative to synthetic hydrogels. The main focus of this review is to provide a comprehensive summary of the structure and characteristics of starch, preparation, and characterization of SHs. This review also addresses several potential multidimensional applications of SHs and shows some future aspects in accordance.

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电环境技术在燃煤电厂烟气治理中的应用

简要列举了电环境技术在环境污染治理方面的一些新兴技术。重点介绍了电环境技术应用于火电厂锅炉排放烟气的治理，较为详细地介绍了电催化氧化、活性炭加微波、电屏障放电加臭氧以及电子束等技术在烟气脱硫脱硝方面的应用、反应机理和研究现状等，并对电环境技术的发展前景作了展望。     

Starch-Chitosan Hydrogels for the Controlled-Release of Herbicide in Agricultural Applications: A Study on the Effect of the Concentration of Raw Materials and Crosslinkers

Journal of Polymers and the Environment - Present work aims to synthesize the herbicide-loaded bio-based hydrogels and study the release mechanism. The different ratios of starch and chitosan were...     

Understanding the Impact of Microcrystalline Cellulose Modification on Durability and Biodegradation of Highly Loaded Biocomposites for Woody Like Materials Applications

Journal of Polymers and the Environment - The transition from fossil-based to bio-based materials requires in-depth environmental durability analysis for material engineering and construction...     

Use of Coconut Oil-Based Organo-Hydrogels in Pharmaceutical Applications

Journal of Polymers and the Environment - In this study, six different organo-hydrogel containing Agar-Glycerol (AG) based Coconut Oil (CnO) were synthesized using different crosslinkers to ensure...     

Thermal,Mechanical and Physical Properties of Composite Films Developed from Seaweed Polysaccharides/Cellulose Nanofibers

Journal of Polymers and the Environment - Algae-based materials appear to be promising substitutes for plastics in many applications due to their eco-friendly belongings. However, high solubility,...     

Impact of Lime and Ash Applications on Soil Solution Chemistry of an Acidified Podzolic Soil

Soil solution samples were taken from two sites (Horröd and Hasslöv) in the south part of Sweden to evaluate how soil solution chemistry responded to different treatmentswith dolomite and wood ash. At Horröd, samples were taken four years after application of wood ash, 4.28 ton ha^-1 and dolomite, 3.25 ton ha^-1. At Hasslöv dolomite, 3.45 ton ha^-1 and 8.75 ton ha^-1 was applied and samples were taken 15 yr later. It was found that treatment with dolomite at one site (Hasslöv) resulted in higher pH values (<2 pH units) and higher nitrification. It was also found at this site that the total Al and the inorganic Al concentrations decreased with dolomite treatment. The Ca, Mg, DOC, Fe, SO₄ ^2- and Cl^- concentrations, mainly in the topsoil, were found to be higher at both sites, following dolomite treatment; Ca and Mg concentrations were 2–8 times higher (<820 M) than in controls (<70 M). Wood ash was found to have less impact. The PO₄ concentration in the O2 horizon at Hasslöv decreased due to dolomite-treatment. ANOVA (Analyse of Variance) and PLS (Partial Least Square) were used to evaluate the data from the two sites.     

Ten Year Historical Perspective of the NOAA Damage Assessment and Restoration Program

The United States Oil Pollution Act of 1990 (OPA) was enacted to reduce the probability of oil spills in U.S. waters. A key provision of the legislation enables recovery of damages for restoration of injured natural resources and lost services due to oil spills. The National Oceanic and Atmospheric Administration (NOAA) developed regulations that set out a process for determining the appropriate type and scale of restoration actions to accomplish this goal. The restoration plan developed through this process is the basis for an economic claim for natural resource damages. The regulations recognize that various methods, including environmental models, may be used in identifying and quantifying injuries to natural resources and losses of their services and in developing a restoration approach for these injuries. Rather than designating particular assessment measures, NOAA requires each trustee to decide which methodologies are appropriate for each incident, given its particular facts and circumstances. Any procedure chosen must meet the standards in the rule: it must provide information useful for determining restoration needed for an incident, the cost of the method must be commensurate with the quality and quantity of information it is expected to generate, and, of particular significance here, the method must be reliable and valid for the particular incident. This paper describes how methods are selected, how they might be used, and what legal standards would be applied should these methods be used as evidence in litigation.     

壳牌煤气化技术的应用前景分析

介绍了壳牌煤气化技术的工艺特点和发展现状,分析论述了分布式能源系统技术,将煤气化与分布式能源系统两种技术完美结合,是当今煤-电-化组合的优良模式.     

Applications of risk assessment techniques to hazardous waste management

Applications of risk assessment techniques to hazardous waste management are briefly discussed in terms of selecting appropriate waste management technologies, assessing operating sites, setting priorities for clean up of problem sites, determining the appropriate level of clean up and planning new facilities. A specific case history involving risk assessment for the siting of a waste management facility in the Province of Ontario, Canada is described in more detail. Risk estimates are provided for exposure via inhalation and ingestion of potentially contaminated local water, crops, meat and milk. The predicted risk are compared to risks of death from selected voluntary and involuntary exposures.