共查询到20条相似文献,搜索用时 15 毫秒
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Growing interest in green products has provided fresh impetus to the research in the field of renewable materials. Plant fibers are not only renewable but also light in weight and low in cost. Polymer composites manufactured using them find applications in diverse fields such as automobiles, housing, and furniture. However, their hydrophilic nature and inadequate adhesion with matrix limits their use in high performance applications. In this study, a novel method for improving adhesion characteristics of natural fibers has been developed. This method is carried out by treating hemp fibers with a fungus: Ophiostoma ulmi, obtained from elm tree infected with Dutch elm disease. Treated fibers showed improved acid–base characteristics and resistance to moisture. Improved acid–base interactions between fiber and resin are expected to improve the interfacial adhesion, whereas improved moisture resistance would benefit the durability of the composites. Finally, composites were prepared using untreated/treated fibers and unsaturated polyester resin. Composites with treated fibers showed slightly better mechanical properties, which is most probably due to improved interfacial adhesion. 相似文献
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Present work deals with the surface modification of Cannabis indica fiber through benzoylation and graft copolymerization of acrylonitrile (AN) onto C. indica fibers under the influence of microwave radiations. The Benzoylation of C. indica fiber was carried out by treating raw fiber with varying concentrations of benzoyl chloride solution. Different reaction parameters for graft copolymerization, such as reaction time, initiator concentration, nitric acid concentration, pH and monomer concentration were optimized to get the maximum percentage of grafting (25.54%). A suitable mechanism to explain benzoylation and graft copolymerization has been also proposed. Raw C. indica fiber, graft copolymerized and benzoylated fibers were subjected to evaluation of some of their properties like swelling behavior, moisture absorbance and resistance towards chemicals. Cannabis indica fibers treated with 5% benzoyl chloride solution and AN graft copolymerized fibers have been found to show more resistant towards moisture, water and chemicals when compared with that of untreated fibers. Morphological, structural changes, thermal stability and crystallanity of raw, graft copolymerized and benzoylated fibers have also been studied by SEM, FTIR, TGA and XRD techniques. It has been observed that the crystallinity of fiber decreases but thermal stability increases on surface modification. 相似文献
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生物法处理焦化废水评述 总被引:34,自引:0,他引:34
通过对焦化废水生物处理各种工艺的比较,认为A1-A2-O工艺是目前焦化废水处理比较好的一种工艺;采用生物膜高效反应器可提高微生物浓度并选用高效菌可提高焦化废水中COD、NH3-N去除率。总结了影响化废水CDO、NH3-N去除率的多种因素,从实际工程应用中统计提出A1-A2-O工艺处理焦化废水的处理成本不超过3.5元/t。 相似文献
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Holmberg Maria Mulder Jan Posch Maximilian Starr Michael Forsius Martin Johansson Matti Bak Jesper Ilvesniemi Hannu Sverdrup Harald 《Water, Air, & Soil Pollution: Focus》2001,1(1-2):91-101
We reviewed the current methods for calculatingcritical loads of acidity for forest soils. The consequencesof four sets of assumptions concerning the soil modelstructure, parameter values and the critical loads criterionwere explored by comparing the values of the averageaccumulated exceedance (AAE) calculated for Finland withdeposition values for the year 1995. The AAE index is given inthe unit of deposition and is a measure of how far a region isfrom being protected in terms of fulfilling a certaincriterion, taking into account the size of the ecosystem areas.Using a critical limit for the molar ratio of theconcentrations of base cations to aluminium in soil solutiongave the lowest average accumulated exceedance. Assumingorgano-aluminium complexes and leaching of organic anions gaveAAE = 4 eq ha-1 a-1, which was close to the valueobtained with the standard approach used in Finland, assuminggibbsite equilibrium and no leaching of organic anions,yielding AAE = 5 eq ha-1 a-1. With a critical basesaturation limit, instead of the concentrations criterion, theAAE index was 17 eq ha-1 a-1. The highest averageaccumulated exceedance (AAE = 25 eq ha-1 a-1),corresponding to the lowest critical load, was obtained whenthe effects-based criterion (critical concentration or criticalbase saturation) was substituted with one restricting thedeterioration of the neutralizing capacity of the soil, ANC
le(crit) = 0. These tests illustrate the variabilityof the critical load values for acidity that can be introducedby changing the criterion or by varying the calculation method,without, however, representing the extreme values of criticalloads that could be derived. 相似文献
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射流自吸式生物曝气塔处理废水的研究 总被引:2,自引:0,他引:2
用射流自吸式生物曝气塔对酒精生产废水及催化剂生产废水的处理进行了试验研究。与普通活性污泥法曝气池相比,射流自吸式生产曝气塔具有处理负荷高,停留时间短,处理量大的特点,是一种新型的生物反应器。 相似文献
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电化学法处理高盐苯酚废水的研究 总被引:9,自引:0,他引:9
对在氯盐电解质中用电化学方法处理含酚废水进行了研究,着重探讨了盐的种类与浓度、反应温度与溶液:pH、电流密度、苯酚初始浓度及阴阳极转换频率对苯酚去除率的影响。在Na2SO4的浓度为0.2mol/L,NaCl的浓度为0.1mol/L、苯酚初始质量浓度为200mg/L、电流密度为0.04A/cm^2、温度为35℃、pH为12.5、阴阳极转换频率为5min/次及反应时间为200min的条件下,苯酚的去除率为99.5%,COD去除率为5%,CIO^-把苯酚氧化成了其他有机化合物。 相似文献
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Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review 总被引:2,自引:0,他引:2
Xue Li Lope G. Tabil Satyanarayan Panigrahi 《Journal of Polymers and the Environment》2007,15(1):25-33
Studies on the use of natural fibers as replacement to man-made fiber in fiber-reinforced composites have increased and opened
up further industrial possibilities. Natural fibers have the advantages of low density, low cost, and biodegradability. However,
the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative
high moisture sorption. Therefore, chemical treatments are considered in modifying the fiber surface properties.
In this paper, the different chemical modifications on natural fibers for use in natural fiber-reinforced composites are reviewed.
Chemical treatments including alkali, silane, acetylation, benzoylation, acrylation, maleated coupling agents, isocyanates,
permanganate and others are discussed. The chemical treatment of fiber aimed at improving the adhesion between the fiber surface
and the polymer matrix may not only modify the fiber surface but also increase fiber strength. Water absorption of composites
is reduced and their mechanical properties are improved. 相似文献
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生物膜法A/O系统处理己内酰胺废水 总被引:3,自引:1,他引:3
采用缺氧-好氧淹没式生物膜系统处理己内酰胺废水,着重探讨了碳源对硝化、反硝化的影响.研究结果表明:缺氧池进水中可生物降解COD与NO x-N的质量比必须大于3,好氧池COD负荷应小于0.98kg/(m3.d),系统才能有效地同时脱氮和去除COD. 相似文献