Advanced in situ spectroscopic techniques and their applications in environmental biogeochemistry: introduction to the special section

Understanding the molecular-scale complexities and interplay of chemical and biological processes of contaminants at solid, liquid, and gas interfaces is a fundamental and crucial element to enhance our understanding of anthropogenic environmental impacts. The ability to describe the complexity of environmental biogeochemical reaction mechanisms relies on our analytical ability through the application and developmemnt of advanced spectroscopic techniques. Accompanying this introductory article are nine papers that either review advanced in situ spectroscopic methods or present original research utilizing these techniques. This collection of articles summarizes the challenges facing environmental biogeochemistry, highlights the recent advances and scientific gaps, and provides an outlook into future research that may benefit from the use of in situ spectroscopic approaches. The use of synchrotron-based techniques and other methods are discussed in detail, as is the importance to integrate multiple analytical approaches to confirm results of complementary procedures or to fill data gaps. We also argue that future direction in research will be driven, in addition to recent analytical developments, by emerging factors such as the need for risk assessment of new materials (i.e., nanotechnologies) and the realization that biogeochemical processes need to be investigated in situ under environmentally relevant conditions.     

Nonpoint source water pollution abatement and the feasibility of voluntary programs

This article details a case study of a voluntary, decentralized institutional arrangement for nonpint source water pollution control used in the Root River watershed in southeastern Wisconsin. This watershed was chosen because of its mix of urban, agricultural, and urbanizing land uses. The project objectives were to monitor and draw conclusions about the effectiveness of a voluntary, decentralized institutional system, to specify deficiencies of the approach and suggest means to correct them, and to use the conclusions to speculate about the need for regulations regarding nonpoint source pollution control or the appropriateness of financial incentives for nonpoint source control. Institutional factors considered include diversity of land uses in the watershed, educational needs, economic conditions, personality, water quality, number of agencies involved, definition of authority, and bureaucratic requirements     

Land use change in California,USA: Nonpoint source water quality impacts

California’s population increased 25% between 1980 and 1990, resulting in rapid and extensive urbanization. Of a total 123,000 ha urbanized in 42 of the state’s 58 counties between 1984 and 1990, an estimated 13% occurred on irrigated prime farmland, and 48% on wildlands or fallow marginal farmlands. Sixty-six percent of all new irrigated farmland put into production between 1984 and 1990 was of lesser quality than the prime farmland taken out of production by urbanization. Factors dictating the agricultural development of marginal farmlands include the availability and price of water and land, agricultural commodity prices, and technical innovations such as drip irrigation systems that impact the feasibility and costs of production. The increasing amount of marginal farmland being put into production could have significant water quality consequences because marginal lands are generally steeper, have more erodible soils, poorer drainage, and require more fertilizer than prime farmlands. Although no data exist to test our hypothesis, and numerous variables preclude definitive predictions, the evidence suggests that new irrigated marginal lands can increase nonpoint source (NPS) pollution for a given size area by an order of magnitude in some cases.     

Agroforestry systems and environmental quality: introduction

Investments in agroforestry research during the past three decades-albeit modest-have yielded significant gains in understanding the role of trees on farmlands, and the ecological and economic advantages of integrated farming systems. While early research focused mostly on farm or local levels, broader-level ecosystem services of agroforestry systems (AFS) have raised high expectations in recent years. The nine papers included in this special collection deal with three of such environmental benefits of AFS: water-quality enhancement, carbon sequestration, and soil improvement. These benefits are based on the perceived ability of (i) vegetative buffer strips (VBS) to reduce surface transport of agrochemical pollutants, (ii) large volumes of aboveground and belowground biomass of trees to store high amounts of C deeper in the soil profile, and (iii) trees to enhance soil productivity through biological nitrogen fixation, efficient nutrient cycling, and deep capture of nutrients. The papers included have, in general, substantiated these premises and provided new insights. For example, the riparian VBS are reported to increase the reservoir life, in addition to reducing transport of agrochemicals; the variations in C storage in different soil-fraction sizes suggest that microaggregate (250-53 μm) dynamics in the soil could be a good indicator of its C-storage potential; and the use of vector analysis technique is recommended in AFS to avoid consequences of inaccurate and overuse of fertilizers. The papers also identified significant knowledge gaps in these areas. A common theme across all three environmental quality issues covered is that more and varied research datasets across a broad spectrum of conditions need to be generated and integrated with powerful statistical tools to ensure wide applicability of the results. Furthermore, appropriate management practices that are acceptable to the targeted land users and agroforestry practitioners need to be designed to exploit these environmental benefits. The relative newness of research in environmental quality of AFS will pose some additional challenges as well. These include the lack of allometric equations for tree-biomass determination, absence of standardized norms on soil sampling depth, and limitations of fixed-effect models arising from issues such as pseudo-replication and repeated measures that are common in studies on preexisting field plots. Overall, this special collection is a timely effort in highlighting the promise of AFS in addressing some of the environmental quality issues, and the challenges in realizing that potential.     

Introduction to the special issue: Place,identity and environmental behaviour

Research on identity has proliferated in recent decades, particularly within environmental psychology; the physical environment has been shown to have strong connections to a sense of self, and identity has proved to be an important mediator of behaviour. The concept of identity has been defined and measured, however, in a wide variety of ways. The goal of this special issue is to present some of the recent work tying identity to place and behaviour. In our opening essay we describe some of the distinctions among approaches to identity at different levels of specificity and scale and suggest some criteria to determine meaningful sources of identity, including impacts on cognitive processing, emotional responses, and behaviour. Although a monolithic framework is neither practical nor desirable, we encourage greater conceptual and methodological integration in future research on the interconnections among place, identity, and behaviour.     

安全、健康与环境风险识别和评价概述

安全,健康与环境（HSE）管理的根本目的是最大限度地降低风险,防止人员伤害,财产损失及环境破坏,而风险识别和评价是搞好风险管理的关键所在。文中就风险识别和评价的目的、过程、方法等做了简单论述。     

Vehicular air pollution and asthma: implications for education for health and environmental sustainability

Studies show a direct relationship between occurrence of asthma and increases of particulate matter in the air. Private transportation is found to be a significant contributor to this problem. The objective of this article is to explore this link between air pollution, asthma and vehicular dependency in order to provide recommendations for health and transport policy. This article focuses on the survey of literature on the relationship between vehicular air pollution and asthma; combining it with the literature on vehicular dependency or ‘car culture’ in the global context and in The Netherlands. This article exposes the imbalance of power between patient groups and polluting industries, and the government failure to protect the weaker party can be explained by corporate pressures. It will be argued that since air pollution is tied to the corporate support for the car industry and vested interests in promoting a ‘car culture’, strategic policy that claims to be concerned with public health should explicitly link the present pattern of mobility to public health. This article concludes with a recommendation for raising environmental health awareness by explicitly linking vehicular dependency to respiratory health through a combination of holistic and citizenship education.     

Environmental occurrences, behavior, fate, and ecological effects of nanomaterials: an introduction to the special series

The release of engineered nanomaterials (ENMs) into the biosphere will increase as industries find new and useful ways to utilize these materials. Scientists and engineers are beginning to assess the material properties that determine the fate, transport, and effects of ENMs; however, the potential impacts of released ENMs on organisms, ecosystems, and human health remain largely unknown. This special collection of four review papers and four technical papers identifies many key and emerging knowledge gaps regarding the interactions between nanomaterials and ecosystems. These critical knowledge gaps include the form, route, and mass of nanomaterials entering the environment; the transformations and ultimate fate of nanomaterials in the environment; the transport, distribution, and bioavailability of nanomaterials in environmental media; and the organismal responses to nanomaterial exposure and effects of nanomaterial inputs, on ecological communities and biogeochemical processes at relevant environmental concentrations and forms. This introductory section summarizes the state of knowledge and emerging areas of research needs identified within the special collection. Despite recent progress in understanding the transport, transformations, and fate of ENMs in model environments and organisms, there remains a large need for fundamental information regarding releases, distribution, transformations and persistence, and bioavailability of nanomaterials. Moreover, fate, transport, bioaccumulation, and ecological impacts research is needed using environmentally relevant concentrations and forms of ENMs in real field materials and with a broader range of organisms.     

Organotin pollution in China: an overview of the current state and potential health risk

In recent years, considerable amounts of organotin compounds have entered the environment due to the wide industrial applications in China. Organotins were found in various environmental media. An overview of organotin contamination and distribution in China from various environmental samples, including waters and sediments, is presented to better understand the current state of organotin pollution in China and to improve environmental monitoring and management of organotin contamination. Exposure to organotin contaminated water and sediments induces accumulation of organotins in molluscs and biological effects such as imposex. Potential harmful effects on human health may also result from consumption of contaminated seafoods. Detailed information on distribution, impacts and assessment of risk to human health and marine ecosystems is discussed and monitoring of TBT using biomarkers is described. This review highlights the serious organotin contamination of coastal cities in China and emphasizes the need for long-term monitoring and the development of an effective regulatory program.     

Novel manure management technologies in no-till and forage introduction to the special series

Surface application of manures leaves nitrogen (N) and phosphorus (P) susceptible to being lost in runoff, and N can also be lost to the atmosphere through ammonia (IH3) volatilization. Tillage immediately after surface application of manure moves manure nutrients under the soil surface, where they are less vulnerable to runoff and volatilization loss. Tillage, however, destroys soil structure, can lead to soil erosion, and is incompatible with forage and no-till systems. A variety of technologies are now available to place manure nutrients under the soil surface, but these are not widely used as surface broadcasting is cheap and long established as the standard method for land application of manure. This collection of papers includes agronomic, environmental, and economic assessments of subsurface manure application technologies, many of which clearly show benefits when comparedwith surface broadcasting. However, there remain significant gaps in our current knowledge, some related to the site-specific nature of technological performance, others related to the nascent and incomplete nature of the assessment process. Thus, while we know that we can improve land application of manure and the sustainability of farming systems with alternatives to surface broadcasting, many questions remain concerning which technologies work best for particular soils, manure types, and farming and cropping systems.     

Integrated water management for the Rhine river basin, from pollution prevention to ecosystem improvement

The river Rhine has been in humanity's use for many centuries for a variety of activities. However, in our time, considerable changes in the course and the natural conditions of the river and the increasing use of the river for the discharge of wastewater has caused serious floods and major ecological problems. Since 1950, the International Commission for the Protection of the Rhine (ICPR) acts as the coordination point between the states bordering the Rhine for the development of programmes for river protection. The Sandoz disaster in 1986 was a turning point in the approach of the ICPR and the starting point for the present strategy of integrated riverbasin management. Recent developments have indicated the success of the current approach.     

Response to environmental flows in the lower Tarim River, Xinjiang, China: ground water

In China's west since the 1950s large-scale ecosystem degeneration has occurred through water diversions for agricultural purposes. Since 2000, 1038 x 10(6) m(3) of water have been released into the Tarim River with the result that water reached the terminal Taitema Lake for the first time in 30 years. This environmental flow raised water-table levels along 350 km of the river. To assess the response of the water-table, a comparison "pristine" site is compared with downstream monitored sites. The results show huge changes in water-table levels. The study verifies that the water-table is extremely responsive to environmental flows, that strong internal similarities exist along the length of the river, and that the effect on the water-table and hence likely riparian vegetation recovery can be tentatively predicted. The actual impacts of the restoration strategy are less than those originally expected politically, socially and within the scientific community. We make recommendations on more effective release strategies.     

Assessment and prediction of overall environmental quality of Zhuzhou City,Hunan Province,China

Fuzzy comprehensive assessment was applied to assess the quality of air, water and soil in Zhuzhou City, Hunan Province, China based on the monitoring data of 1997 and National Environmental Quality Standards of China. Results show that Zhuzhou air quality belonged to Class II with industry and traffic as the main control areas and SO2 as the major pollutant. Water quality within the Zhuzhou section of the Xiang River belonged to Class IV, with the Xiawan section as the main control area and NH3-N as the major pollutant. Soil environmental quality with respect to heavy metal pollution belonged to Class III, with Cd as the major pollutant. For those pollutants showing significant differences between the years of 1990-1997, predictions were made for the environmental quality for the period 1998-2003. According to the assessment results, cleaner production in the key pollution sources and the establishment of a municipal sewage treatment plant are proposed to improve the environmental quality of Zhuzhou City.     

Industrial pollution and social deprivation: Evidence and complexity in evaluating and responding to environmental inequality

The local impacts of industrial pollution can take many forms and—whilst uncertain in their scale, severity and distribution—are widely recognised. The question of who in society potentially experiences these impacts through living near to emission sources has been little explored, at least in the UK. This paper reports on a study carried out for the Environment Agency, which examined the distribution of sites coming within the Industrial Pollution Control (IPC) regime against patterns of deprivation. Our analysis provides evidence of a socially unequal distribution of IPC sites in England, with sites disproportionately located and clustered together in deprived areas and near to deprived populations. In discussing these results we emphasise the methodological limitations of this form of environmental justice analysis and the crucial differences between proximity, risk and impact. We also consider the distinction between inequality and injustice and the difficult policy questions which arise when evaluating evidence of environmental inequality, including potential grounds for policy intervention.     

Sources of water pollution and evolution of water quality in the Wuwei basin of Shiyang river, Northwest China

Based on surveys and chemical analyses, we performed a case study of the surface water and groundwater quality in the Wuwei basin, in order to understand the sources of water pollution and the evolution of water quality in Shiyang river. Concentrations of major chemical elements in the surface water were related to the distance downstream from the source of the river, with surface water in the upstream reaches of good quality, but the river from Wuwei city to the Hongya reservoir was seriously polluted, with a synthetic pollution index of 25. Groundwater quality was generally good in the piedmont with dominant bicarbonate and calcium ions, but salinity was high and nitrate pollution occurs in the northern part of the basin. Mineralization of the groundwater has changed rapidly during the past 20 years. There are 23 wastewater outlets that discharge a total of 22.4 x 10(6)m(3)y(-1) into the river from Wuwei city, which, combined with a reduction of inflow water, were found to be the major causes of water pollution. Development of fisheries in the Hongya reservoir since 2000 has also contributed to the pollution. The consumption of water must be decreased until it reaches the sustainable level permitted by the available resources in the whole basin, and discharge of wastes must also be drastically reduced.     

Strategic environmental assessment in China: motivations, politics, and effectiveness

This paper examines how strategic environmental assessment has been practiced at the national level in China through 2005 and why it has been practiced in the manner observed. Based on literature reviews and interviews carried out in 2005 and 2006, we find that bureaucratic politics between environmental and nonenvironmental ministries has limited the legislation and implementation of strategic environmental assessment to environmental assessment (EA) for a set of government plans defined in the 2003 Environmental Impact Assessment Law. Interviewees from environmental and nonenvironmental ministries and key research institutes have reported that few planning EAs have been performed at the sectoral level. Nonenvironmental ministries have either evaded the 2003 Environmental Impact Assessment Law and have not undertaken required planning EA or have organized planning EA on their own without participation by the State Environmental Protection Administration. The rising tension between the environmental and nonenvironmental ministries has limited the role of planning EA as a participatory decision-making tool. In addition to bureaucratic politics, we find that weak public participation and underemphasis on social analysis in planning EA may have further compromised the utility of planning EA.     

Forecasting environmental equity: air quality responses to road user charging in Leeds, UK

Sustainable development requires that the goals of economic development, environmental protection and social justice are considered collectively when formulating development strategies. In the context of planning sustainable transport systems, trade-offs between the economy and the environment, and between the economy and social justice have received considerable attention. In contrast, much less attention has been paid to environmental equity, the trade-off between environmental and social justice goals, a significant omission given the growing attention to environmental justice by policy makers in the EU and elsewhere. In many countries, considerable effort has been made to develop clean transport systems by using, for example, technical, economic and planning instruments. However, little effort has been made to understand the distributive and environmental justice implications of these measures. This paper investigates the relationship between urban air quality (as NO2) and social deprivation for the city of Leeds, UK. Through application of a series of linked dynamic models of traffic simulation and assignment, vehicle emission, and pollutant dispersion, the environmental equity implications of a series of urban transport strategies, including road user cordon and distance-based charging, road network development, and emission control are assessed. Results indicate a significant degree of environmental inequity exists in Leeds. Analysis of the transport strategies indicates that this inequity will be reduced through natural fleet renewal, and, perhaps contrary to expectations, road user charging is also capable of promoting environmental equity. The environmental equity response is, however, sensitive to road pricing scheme design.     

Restoration,stewardship, environmental health,and policy: understanding stakeholders' perceptions

In recent years there has been considerable interest in the health of humans and the environment, restoration of contaminated or otherwise degraded lands, and in long-term stewardship of public lands. Unfortunately, it is unclear whether governmental agencies and the public hold similar views about the meanings of these concepts, making policy decisions about restoration and stewardship difficult. In this paper, I explore how the public conceptualizes restoration and stewardship by examining the relative rating of several attributes of restoration, stewardship, environmental health, ecological health, environmental restoration, and ecological restoration. People were interviewed in Santa Fe, New Mexico, USA, near the Department of Energy's Los Alamos National Laboratory. The ratings of attributes of environmental health and ecological health reported in this paper can be used to understand how the public understands these concepts. The attributes rated most highly by the subjects were more similar to definitions in the scientific literature for these terms than they were to those used by the Department of Energy. For environmental health, the highest rating related to human sanitation, while for ecological health the highest rating was for maintaining functioning ecosystems. Reduction of exposure to hazardous substances was rated the second highest for both environmental and ecological health. The wise use of natural resources, preservation of natural resources, and hazardous waste site cleanup were rated the highest attributes of stewardship. These data suggest that both expert and nonexpert perceptions about restoration and stewardship should be incorporated into environmental management decisions.