Sound management of brominated flame retarded (BFR) plastics from electronic wastes: State of the art and options in Nigeria

Management of flame retarded plastics from waste electrical and electronic equipment (WEEE) has been posing a major challenge to waste management experts because of the potential environmental contamination issues especially the formation of polybrominated-dioxins and -furans (PBDD/F) during processing. In Nigeria, large quantities of electronic waste (e-waste) are currently being managed—a significant quantity of which is imported illegally as secondhand electronics. As much as 75% of these illegal imports are never reused but are rather discarded. These waste electronic devices are mostly older equipment that contains brominated flame retardants (BFRs) such as penta-brominated diphenyl ethers (PBDEs), and polybrominated biphenyls (PBBs) which are presently banned in Europe under the EU WEEE and RoHS Directives. Risk assessment studies found both to be persistent, bio-accumulative and toxic. The present management practices for waste plastics from WEEE in Nigeria, such as open burning and disposal at open dumps, creates potential for serious environmental pollution. This paper reviews the options in the environmentally sound management of waste plastics from electronic wastes. Options available include mechanical recycling, reprocessing into chemicals (chemical feedstock recycling) and energy recovery. The Creasolv^® and Centrevap^® processes, which are the outcome of the extensive research at achieving sound management of waste plastics from WEEE in Europe, are also reviewed. These are solvent-based methods of removing BFRs and they presently offer the best commercial and environmental option in the sound management of waste BFR-containing plastics. Because these developments have not been commercialized, WEEE and WEEE plastics are still being exported to developing countries. The industrial application of these processes and the development of eco-friendlier alternative flame retardants will help assure sound management of WEEE plastics.     

Producer responsibility for e-waste management: key issues for consideration - learning from the Swiss experience

E-waste, a relatively recent addition to the waste stream in the form of discarded electronic and electric equipment, is getting increasing attention from policy makers as the quantity being generated is rising rapidly. One of the most promising policy options to address this issue is to extend the producers responsibility for their products beyond the point of sale, until end-of-product-life. This paper briefly introduces the concept of extended producer responsibility (EPR) and its applicability in the area of the end-of-life management of electronic and electrical equipment (EEE). It then examines the decade-long experience of Switzerland in using EPR to manage its e-waste, elaborating on the experience of the Swiss system in overcoming specific issues, and finally wrapping up with a synopsis of the lessons for policy makers. We consider each issue as an enquiry of questions confronting a policy maker and the choices that may present themselves. The five issues discussed are: (i) the challenges in getting an EPR based system started; (ii) securing financing to ensure a self-sustaining and smooth functioning system; (iii) organising a logistics network for the take back and collection of the e-waste; (iv) ensuring compliance of the various actors involved; and finally (v) reducing the threat of monopolistic practices.     

Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.     

Cathode ray tube recycling

Lead and polybrominated flame retardants are the two hazardous materials that can be found in electronic appliances. Particularly, cathode ray tubes (CRT) contain leaded glasses. In a computer monitor, over 98% of the lead is in the CRT. This material is generally not accepted for reuse as a component; only those from televisions can be reused. However, this currently represents only a very small market. Envirocycle (a US company) has developed a process to recycle all glasses contained in CRTs; this process includes cleaning and sorting glass. The product obtained is used for the manufacture of new CRT glass. Some industries have used pulverized glass from CRTs in smelting processes as slagging material instead of sand or slag. In this paper, some environmental issues related to the recycling of computers and television sets, and CRTs from computers are presented and discussed. Different processes used to recycle CRTs are described along with an economic analysis.     

Present status of the recycling of waste electrical and electronic equipment in Korea

In Korea due to rapid economical growth followed by urbanisation, breakage of large traditional families into small nuclear families, continuous changes in equipment features and capabilities causes tremendous increase in sale of new electrical and electronic equipment (EEE) and decrease in sale of used EEE. Subsequently, the ever-increasing quantity of waste electrical and electronic equipment (WEEE) has become a serious social problem and threat to the environment. Therefore, the gradual increase in the generation of WEEE intensifies the interest for recycling to conserve the resources and protect the environment. In view of the above, a review has been made related to the present status of the recycling of waste electrical and electronic equipment in Korea. This paper describes the present status of generation and recycling of waste electrical and electronic equipment, namely TVs, refrigerators, washing machines, air conditioners, personal computers and mobile phones in Korea. The commercial processes and the status of developing new technologies for the recycling of metallic values from waste printed circuit boards (PCBs) is also described briefly. Since 1998, three recycling centers are in full operation to recycle WEEE such as refrigerators, washing machines and air conditioners, having the total capacity of 880,000 units/year. All waste TVs are recently recycled on commission basis by several private recycling plants. The recycling of waste personal computers and mobile phones is insignificant in comparison with the amount of estimated obsolete those. Korea has adopted and enforced the extended producer responsibility (EPR) system. Korea is making consistent efforts to improve the recycling rate to the standards indicated in the EU directives for WEEE. Especially environmentally friendly and energy-saving technologies are being developed to recycle metal values from PCBs of WEEE.     

膨胀型阻燃聚丙烯材料的耐湿热性能研究

聚丙烯(PP)以其优异的力学性能、密度小、质量轻等特点而广泛用于汽车、家电、建筑等行业.但是聚丙烯容易燃烧,其氧指数只有18左右,且燃烧时还会产生大量熔滴,极易传播火焰,这大大限制了其应用.近年来,膨胀型阻燃剂(IFR)在阻燃PP中的应用受到了人们高度的重视.本文主要介绍膨胀型阻燃剂微胶囊制备及其微胶囊在聚丙烯中阻燃性...     

Decision factors for e-waste in Northern Mexico: To waste or trade

Currently, around the globe, environmental and social problems derive from the inappropriate recycling of electronic products. Moreover, improper recycling is not the only issue to address in electronic products. Others include: energy intensity in their manufacture, employment generation related to the international trade in used electronics, and access to technology by low-income communities. Nevertheless, policies and controls created to provide socially and environmentally sound management of used electronics do not match the complexity of the system. In order to understand the e-waste system, particularly used computers, as a whole, a field study was done between 2010 and 2011 in ten Mexican cities. Ninety-five diverse stakeholders were interviewed to uncover factors regarding the decision to waste or trade still-usable computers. Structured analysis was used to create Data Flow Diagrams (DFDs) to describe the critical parts of the system. The results show that perceived value and geographical location determine the rate in which computers are disposed and the opportunities to waste or trade them, including the trade of their materials. Among businesses and other organizations, legislation has a stronger effect. Technological change is another important factor, largely driving the change in materials and new products. Designing policies responding to this diversity may prevent unforeseen problems and stimulate solutions.     

Financing electronic waste recycling Californian households' willingness to pay advanced recycling fees

The growth of electronic waste (e-waste) is of increasing concern because of its toxic content and low recycling rates. The e-waste recycling infrastructure needs to be developed, yet little is known about people's willingness to fund its expansion. This paper examines this issue based on a 2004 mail survey of California households. Using an ordered logit model, we find that age, income, beliefs about government and business roles, proximity to existing recycling facilities, community density, education, and environmental attitudes are significant factors for explaining people's willingness to pay an advanced recycling fee (ARF) for electronics. Most respondents are willing to support a 1% ARF. Our results suggest that policymakers should target middle-aged and older adults, improve programs in communities with existing recycling centers or in rural communities, and consider public-private partnerships for e-waste recycling programs.     

Environment-friendly technology for recovering nonferrous metals from e-waste: Eddy current separation

The current generation pattern of e-waste consisted of dead electronic and electrical equipments poses one of the world's greatest pollution problem due to the lack of appropriate recovery technology. Crude recovery methods of resource materials (aluminum, zinc, copper, lead, gold) from e-waste caused serious pollution in China in the past years. Thus, environment-friendly technologies have been the pressing demand in e-waste recovering. Eddy current separation (ECS) was advised as the preferable technology for recovering nonferrous metals from e-waste. However, just a few reports focused on the application of ECS in e-waste recovering. This paper introduced the information about ECS including the models of eddy current force and movement behavior of nonferrous metallic particle in the separation process. Meanwhile, the developing process of eddy current separator was summarized. New industrial applications of ECS in e-waste (waste toner cartridges and refrigerator cabinets) recovering were also presented. Finally, for improving separation rate of ECS in industrial application of e-waste recovering, some suggestions were proposed related to crushing process, separator design, and separator operation. The aim of this paper is to demonstrate the effectiveness of ECS technology as practical and available tool for recovering non-ferrous metals from e-waste which is now being ignored.     

生产者责任延伸制与电子废弃物管理——环境法规

日益增加的固体废弃物和工业废弃物已成为主要的社会问题。回收服务相对来说还很不足,导致很多废弃物只能进行简单的填埋、焚烧处理。这将导致严重的环境污染。借鉴国外一些发达国家废物管理领域的政策趋势,我国近年来出台了一系列关于电子废弃物管理的政策法规,但也暴露出正规的废物处理企业无法取得规模收益,入不敷出,电子废弃物处理基金的征收及补贴对象不明确等诸多问题。引入生产者责任延伸制将外部影响内部化,在理念和功能等方面适应了电子废弃物管理的需要。     

The influence of collection facility attributes on household collection rates of electronic waste: The case of televisions and computer monitors

In the US, household electronic waste collected for recycling is primarily by voluntary drop-off at designated collection facilities. This study examines the influence of specific collection facility attributes (recycling fees charged, number of days open, and driving distance) on the household collection rate of e-waste in the US state of Maine. Data were collected for household computer monitor and television collection for 92 municipal waste transfer facilities representing 30% of the state's population for one year. Results suggest that recycling fees are negatively correlated with the number of televisions and computer monitors collected; furthermore, the more frequently facilities were open, the more televisions and computer monitors were collected per capita. The distance from the facility had no correlation, which prompted an analysis of whether the existence of a curbside collection system in the municipality was influential. Results show a negative correlation between computer monitor and television collection and a municipality having recycling (but not e-waste) curbside collection. Based on the results of this study, policymakers may be able to increase the collection rate of household e-waste by eliminating or lowering recycling fees, expanding collection days and hours to increase convenience, and/or considering curbside collection of e-waste.     

Environmental injustice of informal e-waste recycling in Agbogbloshie-Accra: urban political ecology perspective

This paper provides additional empirical knowledge of injustice embedded in the urban governance of informal-sector electronic waste (e-waste) recycling in Ghana. It uses Urban Political Ecology and Environmental Justice perspectives to explain how divergent interest and power among diverse actors in the e-waste sector engender social and environmental (in)justice in Accra. Using the case study approach, this paper reveals that the persistent struggles over interest and power which characterise the governance and management of informal e-waste recycling generate inequity, false accusations, misrecognition, disrespect, devaluation, neglect, exclusion, and abuse of freedom and rights. Inclusive of the finding is the development of local resistance and social movement in defence of interests and against state aggression, oppression, domination and neglect. The study concludes to suggest that the governance of urban socio-economic and ecological space of Accra should involve coordination, participation, holistic inclusion of diverse interest, so as to minimise trade-offs and reap synergies.     

Facilitating substance phase‐out through material information systems and improving environmental impacts in the recycling stage of a product

The amount of electrical and electronic products is increasing rapidly, and this inevitably leads to the generation of large quantities of waste from these goods. Some of the generated e‐waste ends up in regions with sub‐standard recycling systems and may be processed under poor conditions. During uncontrolled incineration, halogenated dioxins and furans can be generated from brominated and chlorinated compounds in the products. In order to reduce the health and environmental risks involved in the recycling stage of the life cycle of electronics, an effective design‐for‐environment process must be established during the product development phase. Knowledge of the chemical substances in the product is crucial to being able to make informed decisions. Through full knowledge of the material content of procured components, phase‐outs of unwanted substances, such as halogenated substances, can be performed in an effective manner. Therefore, information is the key to success in phasing‐out substances; facilitating compliance of legal provisions for manufacturers of electrical and electronic devices; and improving the environmental footprint of products as they reach the end of the life cycle. After an introduction to the challenges of electronics waste management, this paper describes supply chain information systems and how they are used to facilitate substance phase‐outs in the electronics industry. Sony Ericsson has been working with phase‐outs of unwanted substances since it was founded in 2001. Through the introduction of a material declaration system that keeps track of all substances in the components used in the company's products, Sony Ericsson has been able to replace unwanted substances to improve environmental impacts at the recycling stage of a product.     

How much e-waste is there in US basements and attics? Results from a national survey

The fate of used electronic products (e-waste) is of increasing concern because of their toxicity and the growing volume of e-waste. Addressing these concerns requires developing the recycling infrastructure, but good estimates of the volume of e-waste stored by US households are still unavailable. In this context, we make two contributions based on a national random survey of 2136 US households. First, we explain how much e-waste is stored by US households using count models. Significant explanatory variables include age, marital and employment status, ethnicity, household size, previous e-waste recycling behavior, and to some extent education, home ownership, and understanding the consequences of recycling, but neither income nor knowledge of e-waste recycling laws. Second, we estimate that on average, each US household has 4.1 small (≤10 pounds) and 2.4 large e-waste items in storage. Although these numbers are likely lower bounds, they are higher than recent US Environmental Protection Agency (EPA) estimates (based on narrower product categories). This suggests that the backlog of e-waste in the US is likely larger than generally believed; it calls for developing the recycling infrastructure but also for targeted recycling campaigns.     

GB4943与UL94的水平燃烧试验的区别

就GB4943-2001《信息技术设备的安全》的附录A8与UL94中关于50W水平燃烧试验的区别,说明了水平燃烧试验过程中应注意的几个问题,以及确定材料燃烧等级试验的重要性。通过分析,加深对标准中水平燃烧试验要求的理解。     

California households' willingness to pay for ‘green’ electronics

Concerns about rapid increases in the volume of electronic waste (e-waste) and its potential toxicity have sharpened policy makers' interest for extended producer responsibility to encourage manufacturers of consumer electronic devices (CEDs) to ‘design for the environment’. This paper examines consumer willingness to pay for ‘green’ electronics based on a 2004 mail survey of California households. Using ordered logit models, it was found that significant predictors of willingness to pay for ‘greener’ computers and cell phones include age, income, education, beliefs about the role of government for improving environmental quality, as well as environmental attitudes and behaviors, but neither gender nor political affiliation. Although most respondents are willing to pay only a 1% premium for ‘greener’ CEDs, innovation and EU directives may soon make them competitive with conventional CEDs.     

Toward Active Community Environmental Policing: Potentials and Limits of a Catalytic Model

This paper offers a field tested community environmental policing model to address the pressing environmental management challenges of reducing e-waste burning in informal e-waste hubs, and enforcement against informal polluting industries more broadly. This is based on our intervention to reduce e-waste burning in a substantial informal e-waste hub in the West Bank, Palestine, a 45 km2 region in which an estimated 5–10 metric tonnes of cables are burnt daily, causing serious environmental and public health consequences. In analogous e-waste hubs in the global South, environmental management solutions have focused on economically attractive alternatives to replace cable burning or policies that integrate informal recyclers with formal e-waste management systems—achieving little success. Our paper describes a two-pronged intervention in Palestine’s e-waste hub, which reduced e-waste burning by 80% through a combination of economically competitive cable grinding services and an “active” community environmental policing initiative that lowered barriers to and successfully advocated for governmental policing of e-waste burning. Our discussion of this intervention addresses the community environmental policing literature, which has documented few successes stories of real improvements to the enforcement of environmental violations. We argue that existing strategies have relied on “passive” approaches comprised of monitoring and reporting environmental violations to advocate for change. Our strategy offers a template to improve outcomes through a more “active” approach, moving from monitoring environmental violations through understanding the rationale and dynamics of violators, identifying environmental policing barriers, and implementing a feasible and persuasive strategy to overcome them.     

E‐waste in the world today: An overview of problems and a proposal for improvement in Brazil

Environmental issues have been at the center of society's concerns for a long time. Recently, this kind of concern is growing even more due to the damage caused to the environment by electrical and electronic product waste. Based on this same concern, this work aimed to analyze, through a literature review, the production and treatment of electronic waste in today's world, with an emphasis on Brazil and China. The articles reviewed point to an increase in the production of this type of waste, in both Brazil and China, and reveal that the current processes of treatment of electronic waste mostly aim to obtain profit through the recovery of precious metals such as copper. This paper concluded that although Brazil is one of the major producers of e‐waste, more than 90% of its e‐waste has not had a proper final destination. This deficiency in e‐waste treatment in Brazil is mainly due to financial factors and the lack of a robust educational policy focused on the environment. Thus, this work suggests the implementation of an effective educational policy aimed at environmental conservation, as well as investments in research on recycling methods in Brazil, especially on the use of e‐waste as an aggregate in the manufacture of concrete.     

Waste management issues for the UK ready-mixed concrete industry

The UK government has recognised the vital contribution that the construction industry has to play in contributing towards sustainable development. While the issue of hardened concrete waste has received considerable attention, process waste arising from the manufacture of ready-mixed concrete is relatively unexplored. It is apparent that initiatives such as the landfill tax have encouraged UK ready-mixed concrete manufacturers to reduce substantially the amount of waste they produce. Environmental pressures continue to increase and ready-mixed concrete producers are being forced towards a closed loop production system.     

Waste-based composites—Poverty reducing solutions to environmental problems

This paper highlights an innovative model of waste management combined with poverty reduction, which has been developed by the organisation Waste for Life (wasteforlife.org) - a network of academics, students, practitioners and on the ground cooperative partners in low income communities. The Waste for Life teams work with local cooperatives to create waste-based composites, which may be sold in local markets, thereby creating an income stream. The application of this model to the context of cartoneros (waste picker) cooperatives in Buenos Aires, Argentina, reveals that viable products can be made from paper and plastic waste, with low-impact material preparation that circumvents the need for chemically intensive, polluting and mechanically degrading procedures, preserving recycled fibre integrity. Tests on material samples indicate mechanical properties comparable to products made with more complex processing. The production model is based on the philosophy that not only the waste materials, but also the production equipment should be locally sourced and manufactured and products created to suit local markets. A simple reproducible model has been developed for the local manufacture of composites from waste, which can provide an income source for waste pickers as well as providing an innovative waste management solution.