urban ecolocsy and the air environment

A feature of the 62nd annual meeting of the Air Pollution Control Association, held June 22-26, 1969 in New York City, was a plenary session on Urban Ecology and the Air Environment. Moderated by Norman Cousins, editor of The Saturday Review of Literature, the session developed the theme through the outspoken and personal viewpoints of four distinguished panelists: Austin N. Heller, Aaron J. Teller, Barry Commoner, and Stewart L. Udall. The essence of their remarks appears on the following pages.     

Evaluation of hydrocarbon reactivity in urban air

Three a priori methods for estimating the potential for O₃ formation of hydrocarbon (HC) mixtures were applied to a large air pollution data set collected aloft over Tokyo during 16–17 July 1981 and 6–7 August 1980. Individual HC samples were compared using the concentration weighted OH-HC reaction rate constant, -k_OH the effective O₃ formation rate constant, k_e; and the maximum O₃, O₃(max), formed during 12 h of irradation with a NO₂ photolysis rate constant, k₁, of 0.4 min⁻¹. Values of k_e and O₃(max) were estimated using a carbon-bond photochemical smog model (CBM-III). The maximum incremental ozone (O₃(fp)) above observed levels (O₃¹) was also determined from O₃(max)—O₃¹. The HC data set consisted of 192 samples containing 18 components from 1981 and 66 samples containing 47 components from 1980. Each sample was accompanied by measurements of O₃, NMHC, NO, NO₂, temperature and relative humidity (r.h.). Sampling was mostly at altitudes between 350 and 600 m. Six flights, usually covering the same flight pattern, were spaced at approximately 3 h intervals throughout each day starting at sunrise. In essence, this provided six chemical ‘snapshots’ of the air over Tokyo for each day of sampling.All of the reactivity parameters were found to be reasonably consistent with each other when compared by individual samples for a given year. In addition, when comparisons were carried out on a run averaged basis. O₃ (max) appeared to be linearly related to the actual O₃ concentration 3 h later; and k_e and k_OH to the change in observed O₃ with time 3–4.5 h later. Trajectory analysis demonstrated that air moved slowly through the sampling region. This was physically consistent with the 3-h lag interpretation. From this evaluation it appears that any of the reactivity parameters are reasonable ways of comparing HC mixtures, with more detailed input information supplying more detailed results.     

Metal contamination of short-term snow cover near urban crossroads: correlation analysis of metal content and fine particles distribution

Snow samples were collected near crossroads in Novi Sad, Serbia, during December 2009 to assess metal concentrations (Ca, K, Zn, Fe, Cu, Mn, Al, Pb and Na), fine particle distribution and pH value. The filtered samples of melted snow were analysed, with a focus on particles smaller than a few μm. The most common values of the frequency number distribution curve were either in the range of 0.05-0.07 μm or one order of magnitude higher (0.2-0.5 μm). At examined locations metal concentrations varied from 0.0004 mg L⁻¹ for Pb to 18.9 mg L⁻¹ for Na. Besides Na, which mostly originated from de-icing salt, Ca is found to be the most abundant element in snow indicating the dominant influence of natural factors on snow chemistry. No significant difference was found in concentration of the elements at locations near crossroads with either low or high traffic volume, except for Na and Zn.To investigate how metals were related a correlation analysis was done for the concentrations of metals and with respect to the particle size distribution parameters and pH values. The major influence on the fine particle volume (mass) was concluded to be due to the elements from anthropogenic sources. This conclusion was based on the significant positive correlation between Fe, Zn and Al and the fine particle volume based distribution parameters.     

The occurrence of chlorinated and other organic trace compounds in urban air

The concentrations of 42 chlorinated hydrocarbons (boiling point range from 61 °C to 400 °C) and those of 16 selected volatile hydrocarbons were simultaneously measured in ambient air during the period of one year. The measurements were carried out at 12 sites with different air qualities in the city of Hamburg (FRG). Annual means, medians and peak concentrations are presented. Analyses of the concentration distributions and a comparison with emission data show that traffic is the dominant source of hydrocarbons, whereas chlorinated hydrocarbons are predominantly emitted by industrial sources. This results in a fairly uniform urban pattern of hydrocarbons, but highly variable concentrations of low boiling halogenated compounds.     

Particle-bound PAH content in ambient air

Ambient air samples from a traffic intersection, an urban site and a petrochemical-industrial site (PCI) were collected by using several dry deposition plates, two Microorifice uniform deposited impactors (MOUDIs), one Noll Rotary Impactor (NRI) and several PS-1 (General Metal Work) samplers from March 1994 to June 1995 in southern Taiwan, to characterize the atmospheric particle-bound PAH content of these three areas. Twenty-one individual polycyclic aromatic hydrocarbons (PAHs) were analyzed primarily by using a gas chromatograph/mass spectrometer (GC/MS). In general, the sub-micron particles have a higher PAH content. This is due to the fact that soot from combustion sources consists primarily of fine particles and has a high PAH content. In addition, a smaller particle has a higher specific surface area and therefore may contain more organic carbon, which allows for more PAH adsorption. For a particle size range between 0.31 and 3.2 microm, both Urban/Traffic and PCI/Traffic ratios of particle-bound total-PAH content have the lowest values, ranging from 0.25 to 0.28 (mean = 0.26) and from 0.07 to 0.13 (mean = 0.10), respectively. This indicates that, during the accumulation process, the PAH mass shifted from a particle phase to a gas phase, or the particles aggregated with lower PAH-content particles, resulting in a reduction in particle-bound PAH content. By using the particle size distribution data, the dry deposition model in this study can provide a good prediction for the PAH content of dry deposition materials. In general, lower molecular weight PAHs had a larger fraction of dry deposition flux contributed by the gas phase; for 2-ring PAH (50.4, 46.3 and 28.4%), 3-ring PAHs (15.2, 15.4 and 11.7%) and 4-ring PAHs (13.0, 3.60 and 5.01%) for the traffic intersection, urban and PCI sites, respectively. For higher molecular weight PAHs-5-ring, 6-ring and 7-ring PAHs-their cumulation fraction (F%) of dry deposition flux contributed by the gas phase was lower than 3.26%. At the traffic intersection, urban and PCI sites, the mass median diameter of dry deposition materials (MMD(F)) of individual PAHs was between 25.3 and 49.6 microm, between 27.6 and 43.9 microm, and between 19.1 and 41.9 microm, respectively. This is due to the fact that PAH dry-deposition primarily resulted from gravitational settling of the coarse particulates (> 10 microm).     

Temporal variability of mercury speciation in urban air

Semi-continuous measurements of ambient mercury (Hg) species were performed in Detroit, MI, USA for the calendar year 2003. The mean (±standard deviation) concentrations for gaseous elemental mercury (GEM), particulate mercury (HgP), and reactive gaseous mercury (RGM) were 2.2±1.3 ng m⁻³, 20.8±30.0, and 17.7±28.9 pg m⁻³, respectively. A clear seasonality in Hg speciation was observed with GEM and RGM concentrations significantly (p<0.001) greater in warm seasons, while HgP concentrations were greater in cold seasons. The three measured Hg species also exhibited clear diurnal trends which were particularly evident during the summer months. Higher RGM concentrations were observed during the day than at night. Hourly HgP and GEM concentrations exhibited a similar diurnal pattern with both being inversely correlated with RGM. Multivariate analysis coupled with conditional probability function analysis revealed the conditions associated with high Hg concentration episodes, and identified the inter-correlations between speciated Hg concentrations, three common urban air pollutants (sulfur dioxide, ozone, and nitric oxides), and meteorological parameters. This analysis suggests that both local and regional sources were major factors contributing to the observed temporal variations in Hg speciation. Boundary layer dynamics and the seasonal meteorological conditions, including temperature and moisture content, were also important factors affecting Hg variability.     

Trichlorofluoromethane as a tracer of urban air masses

Trichlorofluoromethane (CCl₃F) measurements in 34 air samples collected at remote Whiteface Mountain N.Y, (elevation 1.5 km) during September 26 through October 29,1978, using electron capture gas chromatography are described. The day-to-day CCl₃F concentration varies between values of 163 and 121 ppt (10⁻¹². v/v) with an average concentration of 137 ppt. Simultaneous measurements of ozone and Be along with relevant meteorological parameters are also presented. The O₃-CCl₃F concentration interrelation suggests that CCl₃F can be used as an area source urban tracer. Periods of elevated O₃ levels associated with high ⁷Be concentration concomitantly marked by low CCl₃F concentrations are explained qualitatively in terms of intrusion of upper atmospheric/stratospheric air into the lower tropospheric air masses. It is shown that the contribution of this factor is quite significant and it must be properly taken into account while establishing the role of CCl₃F as a tracer through its measurements in the lower troposphere.     

The potential of willow for remediation of heavy metal polluted calcareous urban soils

Growth performance and heavy metal uptake by willow (Salix viminalis) from strongly and moderately polluted calcareous soils were investigated in field and growth chamber trials to assess the suitability of willow for phytoremediation. Field uptakes were 2-10 times higher than growth chamber uptakes. Despite high concentrations of cadmium (≥80 mg/kg) and zinc (≥3000 mg/kg) in leaves of willow grown on strongly polluted soil with up to 18 mg Cd/kg, 1400 mg Cu/kg, 500 mg Pb/kg and 3300 mg Zn/kg, it is unsuited on strongly polluted soils because of poor growth. However, willow proved promising on moderately polluted soils (2.5 mg Cd/kg and 400 mg Zn/kg), where it extracted 0.13% of total Cd and 0.29% of the total Zn per year probably representing the most mobile fraction. Cu and Pb are strongly fixed in calcareous soils.     

Mapping air quality zones for coastal urban centers

This study presents a new method that incorporates modern air dispersion models allowing local terrain and land–sea breeze effects to be considered along with political and natural boundaries for more accurate mapping of air quality zones (AQZs) for coastal urban centers. This method uses local coastal wind patterns and key urban air pollution sources in each zone to more accurately calculate air pollutant concentration statistics. The new approach distributes virtual air pollution sources within each small grid cell of an area of interest and analyzes a puff dispersion model for a full year’s worth of 1-hr prognostic weather data. The difference of wind patterns in coastal and inland areas creates significantly different skewness (S) and kurtosis (K) statistics for the annually averaged pollutant concentrations at ground level receptor points for each grid cell. Plotting the S-K data highlights grouping of sources predominantly impacted by coastal winds versus inland winds. The application of the new method is demonstrated through a case study for the nation of Kuwait by developing new AQZs to support local air management programs. The zone boundaries established by the S-K method were validated by comparing MM5 and WRF prognostic meteorological weather data used in the air dispersion modeling, a support vector machine classifier was trained to compare results with the graphical classification method, and final zones were compared with data collected from Earth observation satellites to confirm locations of high-exposure-risk areas. The resulting AQZs are more accurate and support efficient management strategies for air quality compliance targets effected by local coastal microclimates.

Implications: A novel method to determine air quality zones in coastal urban areas is introduced using skewness (S) and kurtosis (K) statistics calculated from grid concentrations results of air dispersion models. The method identifies land–sea breeze effects that can be used to manage local air quality in areas of similar microclimates.     

Interactive design of urban level air quality monitoring network

An interactive optimization method for designing an air quality monitoring network in an urban area is proposed. The main purpose is to determine representative areas of monitoring stations rather than their precise locations. Two topologies are introduced to define similarities among pre-divided uniform meshes. The first is derived from the differences of long-term averages of pollutant concentrations between every two meshes and used in the Ward method clustering. The second is obtained by the cross-impacts between pairs of meshes and used as a constraint in the clustering process. Participation of specialists in the optimization process is allowed in such a way that they can modify the second topology by taking account of economic and physical conditions as well as inaccuracy of simulation models. This technique is applied to the NO_x monitoring network of Kyoto, Japan.     

Typical building arrangements for urban air pollution modelling

Typical building arrangements along urban roads and their parameters were determined for three cities in the south-western part of Germany. Some examples of the dispersion of vehicle emissions within idealized street canyons show how different building parameters influence the concentration of air pollutants.