Gaudeamus lavocati sp. nov. (Rodentia, Hystricognathi) from the early Oligocene of Zallah, Libya: first African caviomorph?

A new African species of hystricognathous rodent, Gaudeamus lavocati sp. nov., is described herein from the early Oligocene deposits of Zallah locality (Sirt basin, Central Libya). The dental morphology of this species is very close to that of some earliest South American caviomorphs. It allows a reinterpretation of molar crest homologies among earliest caviomorphs, pentalophodonty being confirmed as the plesiomorphic molar condition in Caviomorpha. This morphological resemblance argues for close affinities between Gaudeamus and earliest South American hystricognaths. Cladistic analysis supports Gaudeamus lavocati sp. nov. as the first known African representative of Caviomorpha, implying that its ancestors were part of the African phiomyid group that crossed the South Atlantic by a direct immigration route. Alternatively, the series of derived dental features of Gaudeamus could also be interpreted as evolutionary synchronous convergences of an African hystricognath lineage towards the specialized pattern of some caviomorphs. However, the high level of similarities concerning teeth morphology and enamel microstructure and the similar age of fossiliferous strata on both continents make this interpretation less probable. The phylogenetic position of this taxon is of considerable importance because it represents an enigmatic component of the phiomorph–caviomorph radiation in Africa and appears as a new clue toward the understanding of caviomorph origins.     

Fate of organophosphate esters from the Northwestern Pacific to the Southern Ocean:Occurrence,distribution, and fugacity model simulation

Eleven organophosphate esters (OPEs) in the air and seawater were investigated from the northwestern Pacific Ocean to the Southern Ocean during the 2018 Chinese 34th Antarctic Scientific Expedition.The concentration of total OPEs ranged from 164.82 to 3501.79 pg/m³in air and from 4.54 to 70.09 ng/L in seawater.Two halogenated OPEs,tri(chloropropyl) phosphate (TCPP) and tri (2-chloroethyl) phosphate (TCEP),were generally more abundant than the non-halogenated OPEs.A level Ⅲ fugacity mo...     

Is the EU WFD suitable to support IWRM planning in non-European countries? Lessons learnt from the introduction of IWRM and River Basin Management in Mongolia

The Water Framework Directive (EU WFD, 2000/60EC, European Commission, 2000) is a comprehensive tool for water management taking Europe’s diverse national and local policy contexts into account. This has positioned the EU WFD as a potential tool to enhance the implementation of the globally-promoted integrated water resources management concept (IWRM) in developing and transition countries that to date lack comparable regulations. Using the case of Mongolia, a country that has shown interest in using aspects of the EU WFD for implementing its IWRM concept, we will discuss the extent to which the EU WFD also provides a framework for IWRM outside Europe. We find that the EU WFD may provide guidance for the implementation of ecosystem-based River Basin Management (RBM) within an existing national IWRM concept, in terms of public participation and in terms of economic analysis. However, the application of concepts EU WFD is easier if strong political will, good monitoring capacities and a legislative backbone covering key IWRM principles and the capacity for enforcement are in place. Also, the EU-WFD does not provide guidance in terms of water-related issues that are e.g. addressing gender, poverty and capacity development. Thus, the EU WFD cannot serve as a blueprint, as it requires adaptation to the different socio-economic, cultural and political contexts of the implementing country and it does not inform all aspects of IWRM.     

The interplay between knowledge and governance: Insights from the governance of recreational boating in the Dutch Wadden Sea area, 1981–2014

Through shifts toward interactive and participatory forms of environmental governance, knowledge dynamics may come into play that differ from those of traditional forms of policy-making. This paper investigates how shifts of environmental governance and knowledge are related. In order to do so, it reconstructs the development of the governance of recreational boating in the Dutch Wadden Sea on the empirical basis of interviews, document analysis, and a focus group. Moreover, it analyzes this development by means of an analytical framework that combines governance modes, knowledge systems and knowledge–governance interfaces. Our results show that in the last decades partly an accumulation and partly a sequence of various governance arrangements concerning recreational boating has occurred; this has entailed a shift from predominantly centralized governance to a combination of governance modes with a stronger emphasis on decentralized, interactive and self-governance. This shift has occurred together with an increasing prominence of qualitative local knowledge, stakeholders’ knowledge, and the integration of various forms of knowledge. Furthermore, a shift has taken place toward more participatory knowledge–governance interfaces. Our analysis suggests that environmental governance and knowledge are interconnected in various ways: the regulatory and epistemic aspects of environmental issues are bound up with each other, and governance and knowledge are coproduced and mutually constitutive. Key lessons from this analysis are that room for experimentation is an important factor in improving environmental governance, and that increasing stakeholder involvement in governance implies that new modes of jointly creating and exchanging knowledge may need to be taken into account.     

Geochronology and geochemistry of eclogites from the Mariánské Lázne Complex, Czech Republic: Implications for Variscan orogenesis

The Mariánské Lázn complex (MLC) is located in the Bohemian Massif along the north-western margin of the Teplá-Barrandian microplate and consists of metagabbro, amphibolite and eclogite, with subordinate amounts of serpentinite, felsic gneiss and calcsilicate rocks. The MLC is interpreted as a metaophiolite complex that marks the suture zone between the Saxothuringian rocks to the north-west and the Teplá-Barrandian microplate to the south-east. Sm-Nd geochronology of garnet-omphacite pairs from two eclogite samples yields ages of 377±7, and 367±4 Ma. Samples of eclogite and amphibolite do not define a whole rock Sm-Nd isochron, even though there is a large range in Sm/Nd ratio, implying that the suite of samples may not be cogenetic. Eclogites do not have correlated _Nd values and initial ⁸⁷Sr/⁸⁶Sr ratios. Five of the eight eclogite samples have high _Nd values (+10.2 to +7.1) consistent with derivation from a MORB-like source, but variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7059) which probably reflect hydrothermal seawater alteration. Three other eclogite samples have lower _Nd values (+ 5.4 to –0.8) and widely variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7096). Such low _Nd values are inconsistent with derivation from a MORB, source and may reflect a subduction or oceanic island basalt component in their source. The MLC is an important petrotectonic element in the Bohemian Massif, providing evidence for Cambro-Ordovician formation of oceanic crust and interaction with seawater, Late Devonian (Frasnian-Famennian) high- and medium-pressure metamorphism related to closure of a Saxothuringian ocean basin, Early Carboniferous (Viséan) thrusting of the Teplá terrane over Saxothuringian rocks and Late Viséan extension.     

Intrinsic chemiluminescence production from the degradation of haloaromatic pollutants during environmentally-friendly advanced oxidation processes: Mechanism, structure–activity relationship and potential applications

The ubiquitous distribution of halogenated aromatic compounds(XAr) coupled with their carcinogenicity has raised public concerns on their potential risks to both human health and the ecosystem. Recently, advanced oxidation processes(AOPs) have been considered as an"environmentally-friendly" technology for the remediation and destruction of such recalcitrant and highly toxic XAr. During our study on the mechanism of metal-independent production of hydroxyl radicals(UOH) by halogenated quinones and H_2O_2, we found, unexpectedly, that an unprecedented UOH-dependent two-step intrinsic chemiluminescene(CL) can be produced by H_2O_2 and tetrachloro-p-benzoquinone, the major carcinogenic metabolite of the widely used wood preservative pentachlorophenol. Further investigations showed that, in all UOH-generating systems, CL can also be produced not only by pentachlorophenol and all other halogenated phenols, but also by all XAr tested. A systematic structure–activity relationship study for all 19 chlorophenolic congeners showed that the CL increased with an increasing number of Cl-substitution in general. More importantly, a relatively good correlation was observed between the formation of quinoid/semiquinone radical intermediates and CL generation. Based on these results, we propose that UOH-dependent formation of quinoid intermediates and electronically excited carbonyl species is responsible for this unusual CL production; and a rapid, sensitive,simple, and effective CL method was developed not only to detect and quantify trace amount of XAr, but also to provide useful information for predicting the toxicity or monitoring real-time degradation kinetics of XAr. These findings may have broad chemical, environmental and biological implications for future studies on halogenated aromatic persistent organic pollutants.     

Contribution of winter fluxes to the annual CH4, CO2 and N2O emissions from freshwater marshes in the Sanjiang Plain

Introduction C arbon dioxide, m ethane and nitrous oxide play im portant roles in the radiation balance of the earth contributing to the greenhouse effect (Rodhe, 1990). N 2O also takes part in the destruction of stratospheric ozone (W ang, 1999). N atura…     

A new post-Kyoto climate regime based on per-capita cumulative CO<Subscript>2</Subscript>-emission rights—rationale,architecture and quantitative assessment of the implication for the CO<Subscript>2</Subscript>-emissions from China,India and the Annex-I countries by 2050

Climate change is one of the most severe global problems in the 21st century. Main drivers are the combustion of fossil fuels, the emissions of industrial gases, emissions from agricultural sites and animal husbandry as well as deforestation. A new cooperative climate regime is necessary to meet the World’s energy and environmental problems against the background of China’s and India’s energy consumption growth. For the second commitment period of the Kyoto Protocol after 2012, a successor regime has to be agreed on. The current approaches, however, have a common weakness. They at the same time (a) do not acknowledge the historical responsibilities of the industrialized countries for the historical greenhouse gas emissions and the responsibility of developing countries for a large fraction of the current future emissions, and (b) do not provide for a fair distribution of emission rights. Against this background, this article aims at forecasting China’s and India's CO₂-emissions up to 2050 and developing a new suggestion for a post Kyoto climate regime based on a cumulated per capita CO₂-emission rights taking the weaknesses of the currently discussed post Kyoto approaches into account.