共查询到17条相似文献,搜索用时 156 毫秒
1.
阳涂感光胶含酚废水处理1前言阳涂感光胶是由感光性树脂、酚醛树脂、染料及溶剂组成的高粘度液体。其中制酚醛树脂的主要原料是混合甲酚,在树脂合成过程中有含酚废水产生,其主要污染成分是混合甲酚,废水静置后可分层,上层为水层,含酚2228mg/L;下层为酚层,... 相似文献
2.
3.
生产酚醛树脂时产生的含酚、醛废水,分为高浓度和低浓度两级。高浓度含酚量约50%,低浓度含酚量约7%,含醛量约3%。根据酚醛催化缩合原理,高浓度含酚废水,补加甲醛后缩合生产油溶性酚醛树脂220-1;低浓度含酚废水先经碱性催化缩合生成醇溶性酚醛树脂,再改性成为油溶性酚醛树脂220-2。220-1和220-2用于生产酚醛漆料和配制酚醛色漆。 相似文献
4.
5.
6.
含酚废水的综合利用及处理 总被引:1,自引:0,他引:1
我厂是生产酚醛树脂、酚醛塑料的老厂,每年排放含酚废水约1500吨,废水中酚含量为30000—35000ppm,甲醛含量2.5%左右,pH=1,该废水排入环境会造成严重污染。1981年8月我厂建成含酚废水处理车间,采用缩聚反应回收酚醛树脂及加脲酸性(加尿素和盐酸)反应二步法处理工艺进行了试运转。处理后,废水挥发酚含量低于0.5ppm,达到国家排放标准。今将处理的两步工艺分述如下: 相似文献
7.
8.
以废弃线路板热解油为原料,采用碱溶—中和—萃取工艺提取其中以苯酚为主的粗酚,并合成改性酚醛树脂。合成硼酸改性酚醛树脂的优化工艺条件为n(粗酚)∶n(外加苯酚)=2∶3,n(粗酚+外加苯酚)∶n(甲醛)∶n(NaOH)∶n(硼酸)=1∶1.5∶0.15∶0.17;合成有机硅改性酚醛树脂的优化工艺条件为n(粗酚)∶n(外加苯酚)=2∶3,n(粗酚+外加苯酚)∶n(甲醛)∶n(NaOH)∶n(正硅酸乙酯)=1∶1.3∶0.1∶0.1。所合成的硼酸改性和有机硅改性酚醛树脂的主要性能指标均满足YB/T4131—2005《耐火材料用酚醛树脂》中牌号为PFn-5301的热固性液体树脂性能的要求。 相似文献
9.
10.
11.
12.
A. M. Issam B. T. Poh H. P. S. Abdul Khalil W. C. Lee 《Journal of Polymers and the Environment》2009,17(3):165-169
Solid and soft forms of waste polystyrene have been treated with coumarone–indene resin and benzene to produce a new adhesive.
The adhesive is prepared from various compositions of polystyrene (13–38 wt%), coumarone-indene resin (5–7%) and benzene (57–80%).
Viscosity, peel strength and tensile shear strength of the adhesive is determined by a HAAKE Rotary Viscometer, Lloyd Adhesion
Tester and Instron machine, respectively. Rolling ball technique was used to measure the tackiness of the adhesive. Results
show that the adhesion property increases with increase in polystyrene composition and coating thickness. This observation
is attributed to the increasing wettability of adhesive on the substrate. 相似文献
13.
Viscosity, peel and shear strength of epoxidized natural rubber (ENR)-based pressure-sensitive adhesive was studied by using
hybrid tackifiers consisting of a mixture of coumarone-indene resin and petro resin. The coumarone-indene resin concentration
was fixed at 40 parts per hundred parts of rubber (phr). The concentration of petro resin, however, was varied from 20 to
80 phr. Toluene and polyethylene terephthalate (PET) film were used as the solvent and coating substrate respectively throughout
the experiment. Viscosity of adhesive was determined by a HAAKE Rotary Viscometer whereas peel and shear strength was measured
by a Lloyd Adhesion Tester. Results show that viscosity and shear strength decreases with increasing petro resin concentration.
However, peel strength exhibits a maximum value at 40 phr petro resin, an observation which is attributed to maximum wettability
and compatibility of adhesive on the substrate. ENR 25-based adhesive exhibits higher viscosity and peel strength but lower
shear strength compared to the ENR 50 adhesive system. 相似文献
14.
Vanessa Cheesbrough Kurt A. Rosentrater Jerry Visser 《Journal of Polymers and the Environment》2008,16(1):40-50
Interest in renewable biofuel sources has intensified in recent years, leading to greatly increased production of ethanol
and its primary coproduct, Distillers Dried Grain with Solubles (DDGS). Consequently, the development of new outlets for DDGS
has become crucial to maintaining the economic viability of the industry. In light of these developments, this preliminary
study aimed to determine the suitability of DDGS for use as a biofiller in low-cost composites that could be produced by rapid
prototyping applications. The effects of DDGS content, particle size, curing temperature, and compression on resulting properties,
such as flexural strength, modulus of elasticity, water activity, and color were evaluated for two adhesive bases. The composites
formed with phenolic resin glue were found to be greatly superior to glue in terms of mechanical strength and durability:
resin-based composites had maximum fiber stresses of 150–380 kPa, while glue composites had values between 6 kPa and 35 kPa;
additionally, glue composites experienced relatively rapid microbial growth. In the resin composites, both decreased particle
size and increased compression resulted in increased mechanical strength, while a moderate DDGS content was found to increase
flexural strength but decrease Young’s modulus. These results indicate that DDGS has the potential to be used in resin glue-based
composites to both improve flexural strength and improve potential biodegradability. 相似文献
15.
采用二次缩合反应预处理高浓度酚醛树脂生产废水。一次反应的最佳工艺条件为:甲醛加入量0.010 0 mL/mL,Ba(OH)2加入量0.005 g/mL,反应时间3 h,反应温度85 ℃。最佳工艺条件下的一次反应COD去除率为 52.9%。二次反应中,当反应温度为80 ℃、反应时间为3 h、尿素加入量为3 g/L时,二次反应COD去除率最高,为31.5%。COD=85 000 mg/L、ρ(挥发酚)= 12 000 mg/L、ρ(甲醛)=6 740 mg/L的废水经两次缩合反应处理后,出水中COD=27 400 mg/L,COD的总去除率为67.8%;ρ(挥发酚)=2 400 mg/L,挥发酚的总去除率达80.0%;ρ(甲醛)= 980 mg/L,甲醛的总去除率达84.9%。处理1 t废水还可回收酚醛树脂6.75 kg。 相似文献
16.
微电解-UASB-接触氧化处理酚醛树脂废水 总被引:2,自引:1,他引:1
采用微电解一上流式厌氧污泥床(Upflow Anaerobic Sludge Bed,简称UASB)-接触氧化工艺处理酚醛树脂生产废水(简称废水)。实验结果表明:采用微电解法对废水进行预处理,不仅去除了约36%COD,还大幅度提高了废水的可生化性;微电解出水经UASB厌氧生物处理后,COD去除率达80%;水解酸化COD去除率约为30%;最后经二级接触氧化处理,出水COD为100mg/L以下,达到GB8978--1996《污水综合排放标准》中化工类废水的二级排放标准。 相似文献
17.
聚氯乙烯生产中副产高沸物的综合利用 总被引:5,自引:0,他引:5
介绍了以PVC生产中副产的高沸物精制后作溶剂,降解后的废聚苯乙烯泡沫塑料的作主料,制造塑化防腐漆的工艺流程,产品性能及经济效益。 相似文献