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1.
石家庄市大气颗粒物元素组分特征分析   总被引:2,自引:1,他引:1  
为研究石家庄市大气颗粒物的污染特征及其来源,于2013年4—5月在主城6区分别采集TSP、PM10和PM2.5颗粒物样品,利用ICP-MS分析其中的22种元素浓度。结果表明,石家庄市城区Ca、Fe元素在各粒径颗粒物中含量都较高,PM2.5中的S、K含量较高,PM10和TSP中Mg、Al的浓度相对较高。颗粒物的主要来源为燃煤尘、道路尘和建筑尘,TSP、PM10和PM2.5具有较好的统计相关性和同源性。  相似文献   

2.
This study is an analysis of the concentrations and components of heavy metals in PM2.5 and the total suspended particulate (TSP) collected at a mechanical industrial complex (IC) site in Changwon and at a residential site in Masan, Korea. Particulate was collected during two sampling periods, from the late summer to the early fall and from the middle to late fall, at the IC site and one sampling period, from the middle fall to the early winter, at the residential site. PM2.5 and TSP samples were taken by an annular denuder system and a hi-volume air sampler, respectively. The authors also identified the concentrations and components of heavy metals extracted from the PM2.5 and TSP filters, the acidic components extracted from the PM2.5 filters, and the polycyclic aromatic hydrocarbons (PAHs) extracted from polyurethane foam (PUF) plug. The average concentrations of the PM2.5 collected at the IC and residential sites were very similar. Major sources of PM2.5 at the study sites, however, were air emissions from vehicles and industry as well as emissions from residential heating and soil origins, respectively. The higher concentrations of the TSP at the IC site, as compared to those at the residential site, were due to either increased suspended dust from vehicle emissions or re-suspended road dust because of increased vehicle speeds near the IC site. Heavy metal concentrations in the TSPs were higher than those in the PM2.5. The heavy metal concentrations in the PM2.5 and TSP at the IC site with heavy traffic were substantially greater than those at the residential site. The concentrations of TSP and heavy metals and PAHs in PM during the period of the middle to late fall was much higher than those during the period of the late summer to early fall at the IC site. This is because of the difference in meteorological characteristics and energy uses between two periods. The residential site also showed higher concentrations of acidic anions while the IC site showed higher concentrations of acidic cation. Secondary aerosols or particulates, such as ammonium nitrate or ammonium nitrite, might have been important constituents of the PM2.5 at the residential site. The PAHs in the TSP collected at the IC site was greatly affected by traffic and industry emissions consisting mostly of high molecular weight PAHs with two to four rings. PAHs in the TSP at the site, however, were affected by residential heating and air emissions from small chemical plants having higher concentrations of low molecular weight PAHs with five to six rings.  相似文献   

3.
Ports can generate large quantity of pollutants in the atmosphere due to various activities like loading and unloading,transportation, and construction operations. Determination of the character and quantity of emissions from individual sources is an essential step in any project to control and minimize the emissions.In this study a detailed emission inventory of total suspendedparticulate matter (TSP), particulate matter less than 10 m(PM10), sulfur dioxide (SO2) and nitrogen oxides (NOx) for a port and harbour project near Mumbai is compiled. Results show that the total annual average contributions of TSP and PM10 from all the port activitieswere 872 and 221 t yr-1, respectively. Annual average emissions of gaseous pollutants SO2 and NOxwere 56 and 397 t yr-1, respectively, calculatedby using emission factors for different port activities. The maximum TSP emission (419 t yr -1) was from paved roads, while the least (0.4 t yr-1) was from bulk handling activity. The maximum PM10 emission (123 t yr-1) was from unpaved roads and minimum (0.2 t yr-1) from bulk handling operations. Similarly the ratio of TSP and PM10 emission was highest (5.18) from paved roads and least (2.17) from bulk handling operations. Regression relation was derivedfrom existing emission data of TSP and PM10 from variousport activities. Good correlation was observed between TSP andPM10 having regression coefficient >0.8.  相似文献   

4.
基于聚类分析的颗粒物监测网络优化研究   总被引:1,自引:0,他引:1  
为了优化香港环境监测网络,收集香港14个监测站2011年1月1日至2015年11月30日的颗粒物PM_(2.5)、PM_(10)的小时数据进行统计分析。对PM_(2.5)进行聚类,并利用日均浓度变化图进行验证,结果表明,可将监测站分为4类(A、B、C、D类),A类位于城市郊区,B类则位于港口附近,且A、B类的PM_(2.5)日变化特征均呈现双峰型分布,峰值分别出现在09:00和21:00。对PM_(10)进行类似分析结果表明,监测站同样可以分为4类,A类位于九龙区,B类则位于港口附近,而且A、B类的PM_(10)日变化双峰分别出现在11:00和20:00左右。说明污染源头及地形的相似致使某些监测站颗粒物浓度的变化出现相同的趋势,导致监测设备的浪费和管理的冗余。建议建立更高效的空气管理系统,将冗余设备转移到其他地区,扩大空气监控区域。对PM_(2.5)/PM_(10)聚类结果表明,将监测站分为4类,B类均属于路边站,C类则位于居民区。同时还发现同类监测站PM_(2.5)/PM_(10)数值变化相同,并且可以用其中一个站的PM_(2.5)和PM_(10)浓度及另一个站的PM_(2.5)或PM_(10)浓度预测PM_(2.5)或PM_(10)浓度,为优化监测资源提供了一种新的思路。  相似文献   

5.
Ambient concentrations of PM2.5 and PM10 are of concern with respect to effects on human health and environment. Increased levels of mortality and morbidity have been associated with respirable particulate air pollution. In India, it is not yet mandatory to monitor PM2.5 levels therefore very limited information is available on PM2.5 levels. To understand the fine particle pollution and also correlate with PM10 which are monitored regularly in compliance with ambient air quality standards. This study was carried out to monitor PM2.5, PM10, and NO2 for about one year in a residential cum commercial area of Mumbai city with a view to understand their correlation. The average PM2.5 concentration at ambient and Kerbsite was 43 and 69 μg/m3. The correlation coefficients between PM2.5 and PM10 at ambient and Kerbsite were 0.83 and 0.85 respectively thus indicating that most of the PM2.5 and PM10 are from similar sources. TSP, PM10 levels exceeded Central Pollution Control Board(CPCB) standard during winter season. PM2.5 levels also exceeded 24 hourly average USEPA standard during winter season indicating unhealthy air quality.  相似文献   

6.
This study monitored atmospheric pollutants during high wind speed (> 7 m s−1) at two sampling sites: Taichung Harbor (TH) and Wuci traffic (WT) during March 2004 to January 2005 in central Taiwan. The correlation coefficient (R 2) between TSP, PM2.5, PM2.5−10 particle concentration vs. wind speed at the TH and WT sampling site during high wind speed (< 7 m s−1) were also displayed in this study. In addition, the correlation coefficients between TSP, PM2.5 and PM2.5−10 of ionic species vs. high wind speed were also observed. The results indicated that the correlation coefficient order was TSP > PM2.5−10 > PM2.5 for particle at both sampling sites near Taiwan strait. In addition, the concentration of Cl, NO3 , SO4 2−, NH4 +, Mg2+, Ca2+ and Na+ were also analyzed in this study.  相似文献   

7.
基于北京市PM2.5和PM10质量浓度、组分浓度以及降水数据,利用数理统计、相关性分析等方法分别从降水总量、降水时长和降水前颗粒物浓度3个角度研究降水对PM2.5、PM10的清除作用,同时以一次典型降水过程为例,具体分析降水对颗粒物的影响。结果表明:降水总量的增加有助于促进PM2.5、PM10的清除,随着降水总量增加,PM2.5、PM10的平均清除率提高,有效清除的比例增加;连续降水可增强对大气颗粒物的湿清除作用,连续降水达3d可有效降低PM2.5、PM10浓度;降水对PM2.5、PM10浓度的清除率和大气颗粒物前一日的平均浓度有较好的正相关性。降水对大气颗粒物的清除可分为清除、回升和平稳3个阶段,各个阶段大气颗粒物的变化趋势不同。降水对于大气气溶胶化学组分和酸碱性的改变具有明显作用,对于大气颗粒物各种组分的清除效果不完全相同。对于大气中OC、NO3-、SO42-和NH4+去除率较高,且这4种组分主要以颗粒态形式被冲刷进入降水中,加剧了北京市降水酸化程度。  相似文献   

8.
Atmospheric aerosol particles and metallic concentrations, ionic species were monitored at the Experimental harbor of Taichung sampling site in this study. This work attempted to characterize metallic elements and ionic species associated with meteorological conditions variation on atmospheric particulate matter in TSP, PM2.5, PM2.5–10. The concentration distribution trend between TSP, PM2.5, PM2.5–10 particle concentration at the TH (Taichung harbor) sampling site were also displayed in this study. Besides, the meteorological conditions variation of metallic elements (Fe, Mg, Cr, Cu, Zn, Mn and Pb) and ions species (Cl, NO3 , SO4 2−, NH4 +, Mg2+, Ca2+ and Na+) concentrations attached with those particulate were also analyzed in this study. On non-parametric (Spearman) correlation analysis, the results indicated that the meteorological conditions have high correlation at largest particulate concentrations for TSP at TH sampling site in this study. In addition, the temperature and relative humidity of meteorological conditions that played a key role to affect particulate matter (PM) and have higher correlations then other meteorological conditions such as wind speed and atmospheric pressure. The parameter temperature and relative humidity also have high correlations with atmospheric pollutants compared with those of the other meteorological variables (wind speed, atmospheric pressure and prevalent wind direction). In addition, relative statistical equations between pollutants and meteorological variables were also characterized in this study.  相似文献   

9.
Port causes environmental and health concerns in coastal cities if its operation and development are not made environmentally compatible and sustainable. An emission inventory is necessary to assess the impact of port projects or growth in marine activity as well as to plan mitigation strategies. In this study, a detailed emission inventory of total suspended particulate (TSP) matter, respirable particulate matter (PM10), sulphur dioxide (SO2) and oxides of nitrogen (NOx) for a port having operation and construction activities in parallel is compiled. The study has been done for 1 year. Results show that the maximum contribution of emission of air pollutants in the port area was from TSP (68.5%) and the minimum was from SO2 (5.3%) to the total pollutants considered in this study. Total TSP emission from all activities of the port was 4,452 tyr???1 and PM10 emission was 903 tyr???1 in the year 2006. Re-suspension of dust from paved roads was the major contributor of TSP and PM10 in the road transport sector. Construction activities of the port had contributed 3.9% of TSP and 7.4% of PM10 to total emission of particulate matter. Of the total particulate emissions from various port activities approximately 20% of TSP could be attributed to PM10. The sectoral composition indicates that major contribution of SO2 emission in the port was from maritime sector and major contribution of NOx was from road transport sector.  相似文献   

10.
An air quality sampling program was designed and implemented to collect the baseline concentrations of respirable suspended particulates (RSP = PM10), non-respirable suspended particulates (NRSP) and fine suspended particulates (FSP = PM2.5). Over a three-week period, a 24-h average concentrations were calculated from the samples collected at an industrial site in Southern Delhi and compared to datasets collected in Satna by Envirotech Limited, Okhla, Delhi in order to establish the characteristic difference in emission patterns. PM2.5, PM10, and total suspended particulates (TSP) concentrations at Satna were 20.5 ± 6.0, 102.1 ± 41.1, and 387.6 ± 222.4 μg m−3 and at Delhi were 126.7 ± 28.6, 268.6 ± 39.1, and 687.7 ± 117.4 μg m−3. Values at Delhi were well above the standard limit for 24-h PM2.5 United States National Ambient Air Quality Standards (USNAAQS; 65 μg m−3), while values at Satna were under the standard limit. Results were compared with various worldwide studies. These comparisons suggest an immediate need for the promulgation of new PM2.5 standards. The position of PM10 in Delhi is drastic and needs an immediate attention. PM10 levels at Delhi were also well above the standard limit for 24-h PM10 National Ambient Air Quality Standards (NAAQS; 150 μg m−3), while levels at Satna remained under the standard limit. PM2.5/PM10 values were also calculated to determine PM2.5 contribution. At Satna, PM2.5 contribution to PM10 was only 20% compared to 47% in Delhi. TSP values at Delhi were well above, while TSP values at Satna were under, the standard limit for 24-h TSP NAAQS (500 μg m−3). At Satna, the PM10 contribution to TSP was only 26% compared to 39% in Delhi. The correlation between PM10, PM2.5, and TSP were also calculated in order to gain an insight to their sources. Both in Satna and in Delhi, none of the sources was dominant a varied pattern of emissions was obtained, showing the presence of heterogeneous emission density and that nonrespirable suspended particulate (NRSP) formed the greatest part of the particulate load.  相似文献   

11.
西宁市城区冬季PM2.5和PM10中有机碳、元素碳污染特征   总被引:1,自引:0,他引:1  
2014年11月—2015年1月对西宁市冬季开展PM_(2.5)和PM_(10)的连续监测。利用DRI 2001A型热光碳分析仪(美国)对有机碳和元素碳进行分析,结果表明:西宁市冬季PM_(2.5)和PM_(10)中碳气溶胶所占比例分别为33.13%±6.83%、24.21%±6.27%,说明碳气溶胶主要集中在PM_(2.5)中;OC/EC值均大于2,说明西宁市大气中存在二次污染;SOC占PM_(2.5)和PM_(10)的质量浓度比例分别为46.50%和57.40%,PM_(2.5)中SOC浓度占PM_(10)中SOC浓度的61.88%,说明SOC主要存在于PM_(2.5)中,且SOC形成的二次污染和直接排放的一次污染都是西宁市碳气溶胶的主要来源;与其他城市比较发现,西宁市冬季PM_(2.5)中的碳气溶胶含量普遍高于其他城市,PM_(10)中OC质量浓度相对其他城市较高,EC质量浓度偏低;OC和EC的相关性不显著,说明来源不统一;进一步对OC和EC各组分质量浓度进行分析知,西宁市冬季碳气溶胶主要来源于机动车汽油排放、燃煤和生物质燃烧。  相似文献   

12.
The variation in air quality was assessed from the ambient concentrations of various air pollutants [total suspended particle (TSP), particulate matter ≤10 μm (PM10), SO2, and NO2] for pre-Diwali, Diwali festival, post-Diwali, and foggy day (October, November, and December), Delhi (India), from 2002 to 2007. The extensive use of fireworks was found to be related to short-term variation in air quality. During the festival, TSP is almost of the same order as compared to the concentration at an industrial site in Delhi in all the years. However, the concentrations of PM10, SO2, and NO2 increased two to six times during the Diwali period when compared to the data reported for an industrial site. Similar trend was observed when the concentrations of pollutants were compared with values obtained for a typical foggy day each year in December. The levels of these pollutants observed during Diwali were found to be higher due to adverse meteorological conditions, i.e., decrease in 24 h average mixing height, temperature, and wind speed. The trend analysis shows that TSP, PM10, NO2, and SO2 concentration increased just before Diwali and reached to a maximum concentration on the day of the festival. The values gradually decreased after the festival. On Diwali day, 24-h values for TSP and PM10 in all the years from 2002 to 2007 and for NO2 in 2004 and 2007 were found to be higher than prescribed limits of National Ambient Air Quality Standards and exceptionally high (3.6 times) for PM10 in 2007. These results indicate that fireworks during the Diwali festival affected the ambient air quality adversely due to emission and accumulation of TSP, PM10, SO2, and NO2.  相似文献   

13.
宁波市区冬季大气颗粒物及其主要组分的污染特征分析   总被引:3,自引:4,他引:3  
为了更好地研究影响宁波市区环境空气质量的污染物变化特征,于2010年1月20—30日进行了加强监测。研究结果表明,宁波市区大气中PM10和PM2.5质量浓度较高,其中PM2.5/PM10为0.5~0.85。对PM10和PM2.5采样膜分析,水溶性粒子和含碳组分分别占PM10和PM2.5质量浓度的56.7%和66.9%,其中二次污染的水溶性离子SO42-、NO3-和NH4+是PM10和PM2.5中浓度较高的离子组分;PM2.5样品中OC与EC的相关性较好,表明OC与EC的来源相对一致,可能主要来自机动车尾气的贡献;但PM10样品中OC与EC的相关性较差,表明其来源相对复杂;其中SOC的浓度占OC的13%~35%,说明宁波市区冬季导致二次污染的光化学反应不活跃。  相似文献   

14.
The objective of the study is to investigate seasonal and spatial variations of PM10 (particulate matter with aerodynamic diameter less than or equal to 10 μm) and TSP (total suspended particulate matter) of an Indian Metropolis with high pollution and population density from November 2003 to November 2004. Ambient concentration measurements of PM10 and TSP were carried out at two monitoring sites of an urban region of Kolkata. Monitoring sites have been selected based on the dominant activities of the area. Meteorological parameters such as wind speed, wind direction, rainfall, temperature and relative humidity were also collected simultaneously during the sampling period from Indian Meteorological Department, Kolkata. The 24 h average concentrations of PM10 and TSP were found in the range 68.2–280.6 μg/m3 and 139.3–580.3 μg/m3 for residential (Kasba) area, while 62.4–401.2 μg/m3 and 125.7–732.1 μg/m3 for industrial (Cossipore) area, respectively. Winter concentrations of particulate pollutants were higher than other seasons, irrespective of the monitoring sites. It indicates a longer residence time of particulates in the atmosphere during winter due to low winds and low mixing height. Spread of air pollution sources and non-uniform mixing conditions in an urban area often result in spatial variation of pollutant concentrations. The higher particulate pollution at industrial area may be attributed due to resuspension of road dust, soil dust, automobile traffic and nearby industrial emissions. Particle size analysis result shows that PM10 is about 52% of TSP at residential area and 54% at industrial area.  相似文献   

15.
应用卫星遥感影像结合无人机现场核查数据,对2020年江苏省各设区市主城区工地和裸地2类扬尘源的时空分布变化和污染、管控情况开展了连续性监测,为生态环境监测部门业务化应用提供了思路和方法.研究结果显示,遥感解译精度优于95%,扬尘源数量、面积均呈上升趋势,至第4季度总数达1760个、总面积162.53 km2,总体管控情...  相似文献   

16.
系统研究建立高原典型城市拉萨市开放源(土壤风沙尘、道路扬尘、施工扬尘、采矿扬尘),移动源(机动车尾气尘),固定源(工业烟粉尘、生物质燃烧尘及餐饮油烟)共3类8种大气颗粒物(PM_(2.5)、PM_(10))污染源化学成分谱。研究结果表明:开放源以地壳类元素为主,自然背景特征明显;移动源源成分谱中元素碳含量明显高于其他城市,在PM_(2.5)、PM_(10)源谱中分别占60.15%、51.86%,有机碳含量也相对较高,均超过20%;固定源中,牛粪和松柏枝两类生物质燃烧污染源的有机碳含量显著高于其他组分,工业烟粉尘中Ca远高于其他组分,在PM_(2.5)、PM_(10)源谱中分别占21.32%、21.21%。移动源、固定源源成分谱均显示出高原城市的独特特征。  相似文献   

17.
In this study, the relationship between inhalable particulate (PM10), fine particulate (PM2.5), coarse particles (PM2.5 – 10) and meteorological parameters such as temperature, relative humidity, solar radiation, wind speed were statistically analyzed and modelled for urban area of Kolkata during winter months of 2003–2004. Ambient air quality was monitored with a sampling frequency of twenty-four hours at three monitoring sites located near traffic intersections and in an industrial area. The monitoring sites were located 3–5 m above ground near highly trafficked and congested areas. The 24 h average PM10 and PM2.5 samples were collected using Thermo-Andersen high volume samplers and exposed filter papers were extracted and analysed for benzene soluble organic fraction. The ratios between PM2.5 and PM10 were found to be in the range of 0.6 to 0.92 and the highest ratio was found in the most polluted urban site. Statistical analysis has shown a strong positive correlation between PM10 and PM2.5 and inverse correlation was observed between particulate matter (PM10 and PM2.5) and wind speed. Statistical analysis of air quality data shows that PM10 and PM2.5 are showing poor correlation with temperature, relative humidity and solar radiation. Regression equations for PM10 and PM2.5 and meteorological parameters were developed. The organic fraction of particulate matter soluble in benzene is an indication of poly aromatic hydrocarbon (PAH) concentration present in particulate matter. The relationship between the benzene soluble organic fraction (BSOF) of inhalable particulate (PM10) and fine particulate (PM2.5) were analysed for urban area of Kolkata. Significant positive correlation was observed between benzene soluble organic fraction of PM10 (BSM10) and benzene soluble organic fraction of PM2.5 (BSM2.5). Regression equations for BSM10 and BSM2.5 were developed.  相似文献   

18.
The USEPA replaced TSP with PM10 as the National Ambient Air Quality Standard for particulate matter. The commercially available PM10 sampler is a high-volume model using quartz fiber filters. In certain investigations, such as source apportionment studies, chemical analysis of the filter is necessary, however, many analyses cannot be run on quartz filters. An alternate filter such as Teflon is amenable to XRF and ion chemical analyses but is not amenable to analysis for carbon. To overcome these problems DRI constructed a medium-volume PM10 sampler that is capable of collecting particulates on both Teflon and quartz fiber filters simultaneously. This paper describes the design of the DRI medium-volume PM10 sampler, discusses a method for determining equivalence of two samplers, the results of applying the method to test the equivalence of the medium-volume sampler and a commerical high-volume sampler, and examines differences between PM10 and TSP measurements in a southwestern desert.  相似文献   

19.
A positive correlation has been established between increased levels of airborne particulate pollution and adverse health effects, the toxicological mechanisms of which are poorly understood. For toxicologists to unambiguously determine thesemechanisms, truly representative samples of ambient PM10 are required. This presents problems, as PM10 collecting equipment commonly employed, such as the Tapered Element Oscillating Microbalance (TEOM®), heat the inflow toexclude moisture or use fibrous filters, resulting in a PM10sample that may have undergone significant chemical change on thefilter surface or is contaminated by filter fibres. Other systems(i.e. Negretti and Partisol) can successfully collect PM10 without chemical alteration or filter contamination. Comparativecollections from Port Talbot, S. Wales suggest that TEOMs and Negretti/Partisol systems collect different PM10's; the principle difference arising from the TEOM's heating chamber, which precipitates water-soluble ions and volatilises some organic components. This results in both the mass and compositionof the PM10's being altered. Particle size distributionsfor Negretti and Partisol collections highlighted differences mainly attributed to different flow rates. The results of thiswork demonstrate that simple correlations between PM10 massand adverse health effects are problematic. Furthermore, elucidation of the complex fractionation and chemical changes indifferent collectors is necessary.  相似文献   

20.
为深入研究PM2.5和PM10质量浓度异常“倒挂”现象的成因及影响,在苏州市相城区国控点开展比对监测分析,回顾性分析了2016—2020年苏州全部国控点颗粒物浓度数据。苏州市相城区国控点PM2.5浓度的比对分析结果表明:该国控点频繁出现PM2.5浓度高于其他国控点PM2.5浓度和高于该站点PM10浓度(“倒挂”率高达34%)的“双高”现象,PM2.5平均浓度比其他9个国控点高12.5%~37.2%,比位于同一站点的备用监测仪器(“倒挂”率为0)高38.1%。2016—2020年,苏州全部国控点“倒挂”时间的总体趋势都是逐年递增,且集中发生在相对湿度较高的20:00至次日07:00。这5年间各国控点PM2.5浓度异常偏高导致的异常“倒挂”现象对全市年均浓度产生的正误差分别为1.6%、2.8%、6.0%、6.2%和4.1%,基本呈现出逐年递增的趋势。上述结果表明:苏州PM2.5浓度偏高是由动态加...  相似文献   

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