垃圾围城：突围的原则、途径及其政策措施

垃圾围城已成为我国城市生态环境的突出问题。为了突围，使城市生活垃圾处理向着减量化、资源化、无害化的方向发展，必须遵循综合利用城市垃圾的原则，掌握综合利用的途径，制定和执行综合利用的政策措施。     

城市生活垃圾处理技术和资源化应用探讨

介绍我国城市生活垃圾处理技术和城市垃圾资源化现状,对北京阿苏卫生活垃圾综合处理进行详细分析,为城市生活垃圾的处理工艺选型和垃圾处理发展前景提供了参考依据。     

开拓我国城市食杂性有机生活垃圾资源化综合利用产业化的道路

近年来，我国城市生活垃圾历年堆放量已高达70多亿吨，全国近七百座城市年排放生活垃圾约2亿吨，并且今后每年还将以10％左右的增长率逐年增加，而城市生活垃圾处理产业化进程步履艰难。总结了数十年国内外工作实践经验和体会，提出了首先将城市生活垃圾中约占50％的食杂性有机生活垃圾分离了来，统一收集，统一处理，开创我国城市食杂性有机生活垃圾资源化综合利用产业化的道路，创建食杂性有机生活垃圾资源化综合利用产业化的良性绿色生态循环系统的建议及其可行途径与方法。     

城市生活垃圾处理现状与垃圾资源化

我国现有垃圾处理方式主要有卫生填埋、焚烧、堆肥等，但因资金缺乏，技术力量不够，管理体制不健全等诸多原因，城市生活垃圾有效处理率约为13％，无害化处理率约仅为5％左右，由此产生了较为严重的环境污染问题，建议采取有效措施，促进城市垃圾的资源化综合利用。     

城市生活垃圾的资源化利用

通过我国城市的发展现状,阐述现阶段垃圾处理中所面临的问题,指出资源化利用才是可行之道。经过对城市生活垃圾的组成分析、不同处理技术的优缺点对比,提出适合城市生活垃圾资源化利用的系统解决方案。     

城市生活垃圾生命周期分析及处理规划研究

生活垃圾处理规划是城市环境规划重要组成部分,为城市垃圾管理提供行动依据。本文以北京市为例,基于生活垃圾生命周期全过程的环境影响分析和资源化率核算,提出北京市生活垃圾优化处理框架,并纳入垃圾处理规划体系。结果表明规划方案优化了垃圾处理系统,环境影响可降低22％,资源化率可提高60％。     

浅议国外城市生活垃圾处理及思路

通过对国内外城市生活垃圾处理处置的现状叙述 ,阐明城市垃圾只有进行资源化处理 ,才是根本解决垃圾问题的重要途径。城市垃圾资源化处理从收集、运输、分选和最终处置形成系统 ,文章并提出我国较为适宜的垃圾处理对策     

城市垃圾的处理与资源化利用研究

在经济快速增长的背景下,人们的生活水平不断提高,但城市垃圾也在不断增多,这严重影响着人们的生活质量。本文对城市垃圾处理的填埋法、堆肥法、焚烧法三种主要方法以及垃圾资源化利用的养殖蚯蚓、制作农肥、焚烧发电三种方式进行分析,并对进一步改善城市垃圾的处理与资源化利用技术展开论述,希望能为城市垃圾处理相关工作者提供一些参考。     

我国城市生活垃圾处理行业发展与驱动力分析

我国特许经营制度化后,城市生活垃圾处理行业快速发展.通过对行业政策、经济投入、处理能力建设和处理技术四个方面进行分析,将我国城市生活垃圾处理行业的发展历程划分为五个阶段,并分析了用于固定资产建设的前补贴和用于购买行业服务及资源化产品的后补贴在行业发展历程中的作用,识别出后补贴机制是城市生活垃圾处理行业快速发展的直接驱动力.在我国城市垃圾静脉产业中,除了生活垃圾处理行业,还包括餐厨垃圾和建筑垃圾处理行业,但后两者发展滞后.应利用后补贴制度,针对利用餐厨垃圾生产的生物柴油、甲烷燃气等产品建立购销体系,对利用建筑垃圾资源化产品的建设和生产项目给与价格补贴,以激活产业快速发展.     

基于生态城市理念的城市垃圾资源化技术集成研究——以北京怀柔文化生态城为例

本文概述了生态城市的理念以及生态城市对于城市垃圾处理的基本要求,综述了目前遵循生态城市理念所采取的城市垃圾资源化处理的技术路径。以北京怀柔文化生态城为例,进行了城市垃圾资源化技术集成研究,提出区域垃圾资源化的基本项技术和推荐项技术,总结区域垃圾资源化产生的效益。最后,基于生态城市理念提出了针对城市垃圾资源化处理的一些建议。     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Sorption of 1-naphthol by plant cuticular fractions

The contribution of aliphatic-rich plant biopolymer to sorption of hydrophobic organic compounds is significantly important because of their preservation and accumulation in the soil environment,but sorption mechanism is still not fully understood.In this study, sorption of 1-naphthol by plant cuticular fractions was examined to better understand the contributions of respective fraction.Toward this end,cuticular materials were isolated from the fruits of tomato by chemical method.The tomato cuticle sheet consisted of waxes (6.5 wt%),cuticular monomer (69.5 wt%),and polysaccharide (24.0 wt%).Isotherms of l-naphthol to the cuticular fractions were nonlinear (N value (0.82-0.90)) at the whole tested concentration ranges.The KodKow ratios for bulk cuticle (TC1),dewaxed cuticle (TC2),cutin (TC4),and desugared cuticle (TC5) were larger than unity,suggested that tomato bulk cuticle and cutin are much powerful solption medium.Sorption capability of cutin (TC4) was 2.4 times higher than the nonsaponifiable fraction (TC3).The 1-naphthol interactions with tomato cuticular materials were governed by both hydrophobic-type interactions and polar (H-bonding) interactions. Removal of the wax and polysaccharide materials from the bulk tomato cuticle caused a significant increase in the sorption ability of the cuticular material.There was a linear negative trend between K_(oc) values and the amount of polysaccharides or fraction's polarities ((N O)/C);while a linear positive relationship between K_(oc) values and the content of cutin monomer (linear R~2=0.993) was observed for present in the cuticular fractions.Predominant sorbent of the hydrophobic organic compounds (HOCs) in the plant cuticular fraction was the cutin monomer,contributing to 91.7% of the total sorption of tomato bulk cuticle.     

Preparations of TiO2 film coated on foam nickel substrate by sol-gel processes and its photocatalytic activity for degradation of acetaldehyde

Anatase TiO2 films were successfully prepared on foam nickel substrates by sol-gel technique using tetrabutyl titanate as precursor. The characteristics of the TiO2 films were investigated by XPS, XRD, FE-SEM, TEM and UV-Vis absorption spectra. The photocatalytic activities of TiO2 films were investigated by photocatalytic degradation reactions of gaseous acetaldehyde, an indoor pollutant, under ultraviolet light irradiation. It was found that Ni^2＋ doping into TiO2 films due to the foam nickel substrates resulted in the extension of absorption edges of TiO2 films from UV region to visible light region. The pre-heating for foam nickel substrates resulted in the formation of NiO layer, which prevented effectively the injection of photogenerated electrons from TiO2 films to metal nickel. The TiO2 films displayed high photocatalytic activity for the degradation of acetaldehyde, and were enhanced by calcining the substrates and coating TiO2 films repeatedly. The high activity was mainly attributed to the improvement of the characteristics of substrate surface and the increase of active sites on photocatalyst.     

Biological control experiment of excess propagation of Cyclops for drinking water security

Cyclops of zooplankton propagated excessively in eutrophic water body and could not be effectively inactivated by the conventional disinfections process like chlorination due to its stronger resistance to oxidation. In this study, an ecological project was put forward for the excess propagation control of Cyclops by stocking the filter-feeding fishes such as silver carp and bighead carp under the condition of no extraneous nutrient feeding. The results of experiments with different stocking biomass showed that the propagation of Cyclops could be controlled effectively, and the water quality was improved simultaneously by impacting on nutriment level and plankton community structure at proper stocking density of 30 g/m^3 of water. The growth of Cyclops may not be effectually controlled with lower biomass of fish （10 g）, and the natural food chain relation may be destroyed for Cyclops dying out in water while the intense stocking of 120 g per cubic meter of water. In addition, the high predator pressure may accelerate supplemental rate of nutrients from bottom sediments to water body to add the content of total nitrogen and phosphorus in water.     

Effects of seed aerosols on the growth of secondary organic aerosols from the photooxidation of toluene

Hydroxyl radical （.OH）-initiated photooxidation reaction of toluene was carried out in a self-made smog chamber. Four individual seed aerosols such as ammonium sulfate, ammonium nitrate, sodium silicate and calcium chloride, were introduced into the chamber to assess their influence on the growth of secondary organic aerosols （SOA）. It was found that the low concentration of seed aerosols might lead to high concentration of SOA particles. Seed aerosols would promote rates of SOA formation at the start of the reaction and inhibit its formation rate with prolonging the reaction time. In the case of ca. 9000 pt/cm^3 seed aerosol load, the addition of sodium silicate induced a same effect on the SOA formation as ammonium nitrate. The influence of the four individual seed aerosols on the generation of SOA decreased in the order of calcium chloride〉sodium silicate and ammonium nitrate〉ammonium sulfate.     

Reaction mode between Si and Fe and evaluation of optimal species in poly-silicic-ferric coagulant

A kind of Fe-polysilicate polymer, poly-silicic-ferric （PSF） coagulant was prepared by co-polymerization （hydroxylation of mixture of Fe^3＋ and fresh polysilicic acid （PS））, in which PSF0.5, PSF1 or PSF3 denotes Si/Fe molar ratio of 0.5, 1 or 3, respectively. The effects of Si/Fe ratio and reaction time （co-polymerization time or aging time） on the reaction mode between Si and Fe were studies, and the optimal species of PSF was evaluated by pH change during the preparation of PSF and coagulation tests. The results showed that the characteristics of PSF are largely affected by both reaction time and Si/Fe ratio. PSF is found to be a essential complex of Si, Fe, and many other ions. The reaction mode between Si and Fe differs with various Si/Fe ratios. The pH of PSF0.5, PSF1 or PSF3 tended to be stable when reaction time is 10, 25 or 55 rain, respectively, which is almost consistent with the time reaching the relative stable morphology that is just the optimal species of higher coagulation efficiency. The optimal reaction time reaching optimal species can be evaluated by measuring the pH change during the polymerization process.     

汽车排气尾流中微粒分布及其变化特性的研究

根据微粒核化、凝并及凝结模型对汽车排气尾流中微粒分布的变化特性进行了分析.结果表明,微粒的核化增加了排气尾流中超细微粒的数量;微粒的凝并和凝结将改变排气尾流中的微粒分布.在核化、凝并及凝结过程同时存在时,核化对微粒分布的影响相对较小,微粒分布的变化主要受凝并和凝结的作用.在排气管出口处,微粒的核化、凝并及凝结过程比较剧烈,微粒分布变化较大;随着距排气管出口距离的增加,微粒演变逐渐减弱.研究工作可以为汽车排放控制策略的确定以及汽车微粒对人体健康影响的研究提供依据.     

Imazaquin degradation and metabolism in a sandy loam soil amended with farm litters

Irnazaquin applied in legume crops has a long residual time in soil, which often impacts safety of the susceptible crops. To increase safety of imazaquin application, two composted litters, bovine manure （BM） and chicken manure （CM）, were used to determine their effects on imazaquin environmental behavior by incorporating each kind of manure into the tested sandy loam soil at 10% （w/w）. The degradation of imazaquin in BM- and CM-amended soil was about 2.4 and 1.5 times, respectively, faster than that in unamended soil. The half-lives of imazaquin in BM-amended soil varied between 6.7 and 15.4 d over the temperature range of 20 to 40℃, and the degradation rate constant （k） increased by a factor of about 1.5 for every 10℃ change. Higher mix ratio did not significantly increase the degradation, and the optimal active degradation of imazaquin was observed approximately at the mix ratio of 10：1 of soil to BM. The different moisture levels had negligible effect on imazaquin degradation. In both unamended and BM-amended treatments, two metabolites were observed at 5, 10 and 30 d after treatment. One metabolite at retention time （RT） of 8.4 rain was identified as 2-（4- hydroxyl-5-oxo-2-imidazolin-2-yl） quinoline acid, originating from the loss of isopropyl group and hydroxylation at the 4-position of imidazolinone ring. The other at RT of 12.9 rain was identified as quinoline-2,3-dicarboxylic anhydride, resulting from detachment of imidazolinone ring and the forming of dicarboxylic anhydride. This finding suggested that the addition of farm litters into soil might be a good management option since it can not only increase soil fertility but also contribute to increase safety of imazaquin application to the following susceptible crops.