Analysis of organic compounds in coal gasification wastewater

A procedure for analysis of organic pollutants in coal gasification wastewater was developed, including a series extraction steps at different pH, followed by LC separation or resin adsorption, then analyzed by GC or GC/MS. More than 200 organic pollutants in 22 categories were determined. CH2CL2 extraction at NaHCO3 presence was used to separate carboxylic acids with phenolic compounds in aqueous. Derivatization with acetic anhydride was used for analyses of mono-, di-, poly-hydroxyl phenolic compounds. 21 mono-hydroxyl phenols and 13 di-hydroxyl phenols were determined from the coai gasification wastewater samples. Derivatization with BF3-CH3OH was used for analysis of carboxylic acid. 17 mono-carboxyl, 4 di-carboxyl acids and 6 aromatic acids were determined from coal gasification wastewater samples.     

含酚废水处理系统中苯酚降解菌的分离及分离物多样性分析

用富集培养和直接涂平板培养的方法,从含酚废水处理系统的悬浮污泥中分别分离了57株和55株苯酚降解菌.112株分离物经ERIC-PCR指纹图谱分析,共显示了15种差异明显的ERIC-PER指纹图谱,表明至少应有15种不同的菌株.其中直接涂平板法得到的分离物占有11种,富集培养法得到的分离物占4种.将直接涂平板得到的分离物,与来自不同种属苯酚降解菌的LmPH(the largest subunit of multi-component phenol hydroxylase)等位基因分子进行杂交显示,该11种分离物可分为3种以上不同的LmPH代谢类型;而富集培养获得的分离物巾只显示1种LmPH代谢类型.对显示不同ERIC-PCR指纹图的15个代表荫株的生长和苯酚降解效率进行研究发现,其中F-6菌株在苯酚浓度0.4～1.4g·L-1范围内,其苯酚降解效率达到了70%～100%.     

贵州省县域废水排放与社会经济发展的相关分析

随着社会经济的加速发展，废水排放量也在不断的增加，使得环境质量大大降低，从而反作用于社会经济发展，影响社会经济的可持续发展。对于一个欠发达地区而言，协调社会经济与环境保护之间的关系至关重要。以贵州省2005、2010年88个县级面板数据为依据，利用空间计量方法，探究影响废水排放量的主要因子，建立贵州省废水排放量变化的经典线性回归模型和空间滞后模型，结果显示，第三产业的发展是导致贵州废水排放量增加的主要原因。     

城市污水处理工艺的对比研究

介绍了包头市现有五座城市污水处理厂概况,分析了处理工艺低温的适应性。通过分析其中三座采用不同工艺相似水质污水处理厂的进、出水水质,研究不同处理工艺的处理效果。通过设定相同处理规模,分析三种不同工艺相同规模污水处理厂的经济性。最终得出目前包头市处理效果最佳、经济性最优的城市污水处理工艺,为包头市城市污水处理厂提标改造提供参考。     

上海地区大型公共建筑中水工程成本效益分析

针对上海地区大型公共建筑中水回用问题,采用蒙特卡罗模拟技术,对其全生命周期成本效益进行了分析,并讨论了水价对中水工程成本效益的影响.成本计算结果表明生物接触氧化工艺在全生命周期内总成本集中在240.27~276.00万元之间.不同水价方案计算结果表明,在上海现行水价的条件下,生物接触氧化工艺全生命周期效益主要集中在-53.98~-37.54万元之间,50年内不存在投资回收期;当水价为3.8元/t时,生物接触氧化工艺的全生命周期效益主要集中在23.03~51.94万元之间,投资回收期为18~19a;当水价为6.10元/t时,工程效益主要集中在192.47~263.36万元之间,投资回收期为4~5a.因此单从中水工程的成本效益角度来看,上海现行水价偏低,中水回用工程缺乏推广优势,建议适当提高水价或对中水回用工程进行补贴.     

废水生化处理中有机物的分析和转化

有机物的种类、含量、物化特性、分子量等性质直接影响废水处理工艺的处理效果。本文综述了近年来废水生化处理中有机物的分析方法及废水生化处理过程中有机物的转化规律。     

Granulation of filamentous microorganisms in a sequencing batch reactor with saline wastewater

Proliferation of filamentous microorganisms frequently leads to operational failure for activate sludge systems. In this study, it was found that filamentous microorganisms could grow in compact granular structure with 5% sodium chloride in the substrate. In the early period of experiment, coccoid and rode-like bacteria predominated in the yellowish-brown granules, and later the white and the black granules were developed by filamentous microorganisms. The filamentous granules exhibited low porosity and fas...     

日本污水处理厂的监测探讨

探讨了日本滋贺县湖南中部净化中心化验室水质分析管理、在线仪表管理、监测数据分析利用和相关监测试验.介绍了化验室水质分析项目,常用水质分析仪器的维护管理,工艺在线仪表监测管理,以及常用在线仪表的维护管理等内容.揭示了溶解氧、氧化还原电位、五日生化需氧量污泥负荷、污泥龄、好氧污泥龄和PAC添加量等监测数据的综合分析利用有助于提高脱氮除磷效率和节约运行成本.指出相关监测试验是提升运行管理水平的重要手段.     

Towards real-time detection of wastewater in surface waters using fluorescence spectroscopy

The presence of municipal wastewater at the intake of a major drinking water treatment facility located on Lake Ontario was examined using fluorescence data collected during a period of continuous monitoring. In addition, controlled mixing of lake water and wastewater sampled from a local treatment facility were conducted using a bench-scale fluorescence system to quantify observed changes in natural organic matter. Multivariate linear regression was applied to components derived from parallel factors analysis. The resulting mean absolute error for predicted wastewater level was 0.22% (V/V, wastewater/lake water), indicating that wastewater detection at below 1.0% (V/V) was possible. Analyses of sucralose, a wastewater indicator, were conducted for treated wastewater as well as surface water collected at two intake locations on Lake Ontario. Results suggested minimal wastewater contribution at the drinking water intake. A wastewater detection model using a moving baseline was developed and applied to continuous fluorescence data collected at one of the drinking water intakes, which agreed well with sucralose results. Furthermore, the simulated addition of 1.0% (V/V) of wastewater/wastewater was detectable in 89% of samples analyzed, demonstrating the utility of fluorescence-based wastewater monitoring.     

亚甲蓝分光光度法测定水体阴离子表面活性剂方法的探讨

LAS是地表水和地下水水质的必测项目,国标（GB7494—87）方法操作复杂,要重复萃取四次后再洗涤,有机溶剂消耗量大,而且相当的耗时,本文通过同步实验对比与分析,得出：一次性加入20mL氯仿萃取加洗涤的方法其测定结果较好,而且极大地减轻了氯仿对分析人员身体的损害程度。测定结果有较好的精密度和准确度。本方法具有可观的经济性、安全性和可操作性。