Measuring reactive nitrogen emissions from point sources using visible spectroscopy from aircraft

Accurate measurements of nitrogen dioxide (NO2), a key trace gas in the formation and destruction of tropospheric ozone, are important in studies of urban pollution. Nitrogen dioxide column abundances were measured during the Texas Air Quality Study 2000 using visible absorption spectroscopy from an aircraft. The method allows for quantification of the integrated total number of nitrogen dioxide molecules in the polluted atmosphere and is hence a useful tool for measuring plumes of this key trace gas. Further, we show how such remote-sensing observations can be used to obtain information on the fluxes of nitrogen dioxide into the atmosphere with unique flexibility in terms of aircraft altitude, and the height and extent of mixing of the boundary layer. Observations of nitrogen dioxide plumes downwind of power plants were used to estimate the flux of nitrogen oxide emitted from several power plants in the Houston and Dallas metropolitan areas and in North Carolina. Measurements taken over the city of Houston were also employed to infer the total flux from the city as a whole.     

Fruit Stones from Industrial Waste for the Removal of Lead Ions from Polluted Water

Lead, one of the earliest metals recognized and used by humans, has a long history of beneficial use. However, it is now recognized as toxic and as posing a widespread threat to humans and wildlife. Treatment of lead from polluted water and wastewater has received a great deal of attention. Adsorption is one of the most common technologies for the treatment of lead-polluted water. This technique was evaluated here, with the goal of identifying innovative, low-cost adsorbent. This study presents experiments undertaken to determine the suitable conditions for the use of peach and apricot stones, produced from food industries as solid waste, as adsorbents for the removal of lead from aqueous solution. Chemical stability of adsorbents, effect of pH, adsorbents dose, adsorption time and equilibrium concentration were studied. The results reveal that adsorption of lead ions onto peach stone was stronger than onto apricot stone up to 3.36% at 3 h adsorption time. Suitable equilibrium time for the adsorption was 3–5 h (% Pb adsorption 93% for apricot and 97.64% for peach). The effective adsorption range for pH in the range was 7–8. Application of Langmuir and Freundlich isotherm models show high adsorption maximum and binding energies for using these adsorbents for the removal of lead ions from contaminated water and wastewater.     

Methane emission from naturally ventilated livestock buildings can be determined from gas concentration measurements

Determination of emission of contaminant gases as ammonia, methane, or laughing gas from natural ventilated livestock buildings with large opening is a challenge due to the large variations in gas concentration and air velocity in the openings. The close relation between calculated animal heat production and the carbon dioxide production from the animals have in several cases been utilized for estimation of the ventilation air exchange rate for the estimation of ammonia and greenhouse gas emissions. Using this method, the problem of the complicated air velocity and concentration distribution in the openings is avoided; however, there are still some important issues remained unanswered: (1) the precision of the estimations, (2) the requirement for the length of measuring periods, and (3) the required measuring point number and location. The purpose of this work was to investigate how estimated average gas emission and the precision of the estimation are influenced by different calculation procedures, measuring period length, measure point locations, measure point numbers, and criteria for excluding measuring data. The analyses were based on existing data from a 6-day measuring period in a naturally ventilated, 150 milking cow building. The results showed that the methane emission can be determined with much higher precision than ammonia or laughing gas emissions, and, for methane, relatively precise estimations can be based on measure periods as short as 3 h. This result makes it feasible to investigate the influence of feed composition on methane emission in a relative large number of operating cattle buildings and consequently it can support a development towards reduced greenhouse gas emission from cattle production.     

Phytoremediation facilitates removal of nitrogen and phosphorus from eutrophicated water and release from sediment

Phosphorus (P) fractions and the effect of phytoremediation on nitrogen and phosphorus removal from eutrophicated water and release from sediment were investigated in the eco-remediation experiment enclosures installed in the Hua-jia-chi pond (Hangzhou city, Zhejiang province, China). The main P fraction in the sediment was inorganic phosphorus (IP). For the mesotrophic sediments, IP mainly consisted of HCl-extractable P (Ca-P). The annual-average concentration of total nitrogen (TN), total phosphorus (TP) in water and the content of TN, TP in different vertical depth of sediment in the experiment enclosures with hydrophyte were always much lower than those in the control enclosure without hydrophyte and those outside of experiment enclosures. It is suggested that phytoremediation was an effective technology for N and P removal from eutrophicated water and release from sediment.     

Methane emissions from natural wetlands

Methane is considered one of the most important greenhouse gases in the atmosphere. Because of the strict anaerobic conditions required by CH₄-generating microorganisms, natural wetland ecosystems are one of the main sources of biogenic CH₄. The total natural wetland area is estimated to be 5.3 to 5.7 × 10¹² m², making up less than 5% of the Earth's land surface. However, natural wetland plays a disproportionately large role in CH₄ emissions. Wetlands are likely the largest natural sources of CH₄ to the atmosphere, accounting for about 20% of the current global annual emission. Out of the total amount of CH₄ emitted, northern wetlands contribute 34%, temperate wetlands 5%, and tropical systems about 60%.Because of the unique characteristics and high productivity, wetland ecosystems are important in the global carbon cycle. Natural wetlands are permanently or temporarily saturated. Strict anaerobic conditions consequently develop, which allows methanogenesis to occur. But the thin oxic layer and the oxic plant rhizophere promote activity of CH₄-oxidizing bacteria or methanotrophs. Thus, both CH₄ formation and consumption in wetland systems are microbiological processes and are controlled by many factors. Eight of the controlling factors, including carbon supply, soil oxidation-reduction status, pH, temperature, vegetation, salinity and sulfate content, soil hydrological conditions and CH₄ oxidation are discussed in this paper.     

Modelling Tracer Dispersion from Landfills

Several wind tunnel experiments of tracer dispersion from reduced-scale landfill models are presented in this paper. Different experimental set-ups, hot-wire anemometry, particle image velocimetry and tracer concentration measurements were used for the characterisation of flow and dispersion phenomena nearby the models. The main aim of these experiments is to build an extensive experimental data set useful for model validation purposes. To demonstrate the potentiality of the experimental data set, a validation exercise on several mathematical models was performed by means of a statistical technique. The experiments highlighted an increase in pollutant ground level concentrations immediately downwind from the landfill because of induced turbulence and mean flow deflection. This phenomenon turns out to be predominant for the dispersion process. Tests with a different set-up showed an important dependence of the dispersion phenomena from the landfill height and highlighted how complex orographic conditions downwind of the landfill do not affect significantly the dispersion behaviour. Validation exercises were useful for model calibration, improving code reliability, as well as evaluating performances. The Van Ulden model proved to give the most encouraging results.     

Mercury accumulation in fish species from the Persian Gulf and in human hair from fishermen

Total and methylmercury concentrations were assessed in muscle and liver of 141 fish samples from the northern part of the Persian Gulf. All fish samples belonged to five different species: grunt, flathead, greasy grouper, tiger-tooth croaker, and silver pomfret. In addition, Hg and methylmercury were analyzed in scalp hair of 19 fishermen living in the same coastal stations of the Persian Gulf and consuming several fish meals a week. Total mercury concentrations in fish muscle and liver ranged from 0.01 to 1.35 μg g^???1 w.w. and from 0.02 to 1.30 μg g^???1 w.w., respectively. In fish muscle, 3% of the Hg concentrations were higher than 0.5 μg g^???1 w.w., which corresponds to the maximum acceptable WHO level, while 9% were in the range of polluted fish (between 0.3 and 0.5 μg g^???1 w.w.). The highest mercury concentrations in fish muscle were observed in flathead fish at Abadan (average of 0.68 μ g g^???1 w.w.). Methylmercury fractions in fish muscle and liver amount to 34–99% (median 64%) and 24–70% (median 43%), respectively. The mean total Hg concentration in the fishermen’s scalp hair amounted to 2.9 ± 2.2 μ g g^???1, with 68% in the form of methylmercury. Ninety-five percent of the Hg levels in the fishermen’s hair were below 10 μ g g^???1, which is the WHO warning limit. In addition, relationships between the mercury levels in hair, on the one hand, and exposure-related factors such as Hg levels in specific fish species, regional differences, and number of fish meals, on the other hand, are discussed. It appears that a significant correlation for example exists between Hg levels human hair and fish muscle or human hair and age and that mean mercury levels in fish muscle and human hair decreased from western (Abadan) to eastern (Abbas port) coastal sites.     

Volatile organic compounds (VOCs) emitted from materials collected from buildings affected by microorganisms

In this study mould damaged materials, including carpet, concrete, gypsum board, insulation, plastic, sand and wood, from 20 different buildings with moisture problems were collected. To study emissions from these materials both conventional methods for sampling, such as collection on Tenax TA, were used as well as complementary methods for sampling a wider spectrum of compounds, such as more volatile VOCs, amines and aldehydes. Analysis was carried out using gas chromatography and high-performance liquid chromatography. Mass spectrometry was used for identification of compounds. Alcohols and ketones were almost exclusively emitted from the materials after they had been wet for a week. Acids were also emitted in large quantities from wet gypsum board and plastic. No primary or secondary amines could be identified, but two tertiary amines, trimethylamine and triethylamine, were emitted from sand contaminated by Bacillus. The most common moulds found were Penicillium and Aspergillus. A multivariate method (partial least squares, PLS) was used to investigate the emission patterns from the materials. Materials with bacterial growth had a different VOC profile to those with only mould growth.     

Exploring the effect of air pollution on settlement intentions from migrants: Evidence from China

Based on the China Migrants Dynamic Survey (CMDS) from 2015 to 2017, this paper uses IV-Probit model to investigate the effects of air pollution on migrants' settlement intentions in China. The results show that: First, air pollution has a significant and negative effect on intentions in settling down of the migrants. Specifically, when the concentration of PM_2.5 increases by 1 μg/m³, the probability of migrants settling down in the city which they have moved to for work or business will significantly decrease by 1.89%. Second, there is heterogeneity in the effects of air pollution on migrants' settlement intentions. In detail, the sensitivity to air pollution is higher among female groups, who have higher education levels and prefer better air quality in the living place to settle down, and there is an inverted U-shaped relationship between age and settlement intentions. On the one hand, the conclusion of this paper enriches the relevant theoretical achievements of air pollution and migration. On the other hand, it also has a high reference value for developing more reasonable policies related to urban environmental governance and labor mobility.     

Mercury concentrations in fish from a Sierra Nevada foothill reservoir located downstream from historic gold-mining operations

This study examined mercury concentrations in whole fish from Camp Far West Reservoir, an 830-ha reservoir in northern California, USA, located downstream from lands mined for gold during and following the Gold Rush of 1848–1864. Total mercury (reported as dry weight concentrations) was highest in spotted bass (mean, 0.93 μg/g; range, 0.16–4.41 μg/g) and lower in bluegill (mean, 0.45 μg/g; range, 0.22–1.96 μg/g) and threadfin shad (0.44 μg/g; range, 0.21–1.34 μg/g). Spatial patterns for mercury in fish indicated high concentrations upstream in the Bear River arm and generally lower concentrations elsewhere, including downstream near the dam. These findings coincided with patterns exhibited by methylmercury in water and sediment, and suggested that mercury-laden inflows from the Bear River were largely responsible for contaminating the reservoir ecosystem. Maximum concentrations of mercury in all three fish species, but especially bass, were high enough to warrant concern about toxic effects in fish and consumers of fish.     

Effect of combustion variables on PAHs emission from incineration of cellulose waste filters from acrylic industry

Incineration of cellulose waste filter from acrylic industry showed the presence of 13–16 polycyclic aromatic hydrocarbons (PAHs) from the list of 16 priority pollutants with an airflow rate of 1, 2, 3, and 4 L min^???1 in laboratory scale quartz tube vertical incinerator at 700–1,000°C at an interval of 100°C. The amount of total 16 PAHs increases with the increase in temperature with airflow rate of 1 L min^???1 and was found to be 9.4 times at 1,000°C than at 700°C. Studies at 800–1,000°C showed the decrease in total 16 PAHs with increase in airflow rate from 1 to 2 L min^???1. The amount of total 16 PAHs increases at 700, 800, and 1,000°C with increase in airflow rate from 2–4 L min^???1. At 900°C, amount of 16 PAHs decreases with increase in flow rate from 1 to 3 and increases at 4 L min^???1. The lesser amount of 2A PAHs was found at 700–900°C with airflow rates of 1–3 L min^???1, while less amount of 2B PAHs was found at 700°C and 800°C (with airflow rate of 1–2 L min^???1), at 900°C (with airflow rate of 1–3 L min^???1) and at 1,000°C (with airflow rate of 3 L min^???1). However, the sum total of 2A and 2B PAHs were found to be less at 700–900°C with airflow rate of 1–2 L min^???1.     

Nitrous oxide emissions from waste water

The estimation of nitrous oxide emissions is complicated by the high degree of uncertainty on the emission factors involved and by the limited acquaintance with all significant nitrous oxide sources. A potentially important source for which emission data are lacking is the sewage system transporting waste water from human activities. For this study an experimental measurement campaign has been carried out on waste water sampled at different sewage treatment plants. The nitrous oxide developing from the water samples was monitored by means of gas chromatography. The methodological analysis was based on the concentration/time curves obtained. Our results indicate that the formation of nitrous oxide from the waste water matrices results from microbiological denitrification. We deduced tentative emission factors for the waste water types studied.     

不同布置方式220 kV变电所对周围环境的电磁辐射分布

通过对不同布置方式220 kV电压等级变电所在运行中对周围环境产生的工频电场、磁感应强度和无线电干扰的监测分析,了解了不同布置方式220 kV电压等级变电所对周围环境电磁辐射的分布规律.指出在建设220 kV电压等级变电所的同时,只要做好建筑屏蔽和电缆入地等工作,就可以降低对周围环境的电磁辐射影响.     

Greenhouse gas emissions from Australian open-cut coal mines: contribution from spontaneous combustion and low-temperature oxidation

Spontaneous combustion and low-temperature oxidation of waste coal and other carbonaceous material at open-cut coal mines are potentially significant sources of greenhouse gas emissions. However, the magnitude of these emissions is largely unknown. In this study, emissions from spontaneous combustion and low-temperature oxidation were estimated for six Australian open-cut coal mines with annual coal production ranging from 1.7 to more than 16 Mt. Greenhouse emissions from all other sources at these mines were also estimated and compared to those from spontaneous combustion and low-temperature oxidation. In all cases, fugitive emission of methane was the largest source of greenhouse gas; however, in some mines, spontaneous combustion accounted for almost a third of all emissions. For one mine, it was estimated that emissions from spontaneous combustion were around 250,000 t CO₂-e per annum. The contribution from low-temperature oxidation was generally less than about 1% of the total for all six mines. Estimating areas of spoil affected by spontaneous combustion by ground-based surveys was prone to under-report the area. Airborne infrared imaging appears to be a more reliable method.     

Cyanobacterial Flora from Polluted Industrial Effluents

Effluents originating from pesticides, agro-chemicals, textile dyes and dyestuffs industries are always associated with high turbidity, colour, nutrient load, and heavy metals, toxic and persistent compounds. But even with such an anthropogenic nature, these effluents contain dynamic cyanobacterial communities. Documentation of cyanobacterial cultures along the water channels of effluents discharged by above mentioned industries along the west coast of India and their relationship with water quality is reported in this study. Intensity of pollution was evaluated by physico-chemical analysis of water. Higher load of solids, carbon and nutrients were found to be persistent throughout the analysis. Sediment and water samples were found to be colored in nature. Cyanobacterial community structure was found to be influenced by the anthropogenic pollution. 40 different cyanobacterial species were recorded from 14 genera of 5 families and an elevated occurrence of Phormidium, Oscillatoria and Chroococcus genera was observed in all the sampling sites.     

Cyanobacterial Flora from Polluted Marine Shores

Citation of cyanobacterial cultures from the shores of south west coast of Gujarat, India and their relationship with sea water quality, influenced by extensive pollutant runoff is reported in this study. Intensity of pollution was evaluated by physico-chemical analysis of water. Higher load of suspended solids (60–1000 mg l⁻¹) and nutrients (PO₄ ⁻P: 1.3–4 μmole l⁻¹ and NO₃ ⁻N: 12.5–17.8 μmole l⁻¹) were persistent throughout the analysis. Community structure is seen to be influenced by such persistent pollution. Twenty nine cyanobacterial species were isolated belonging to 9 genera of 4 families, with an elevated occurrence of Oscillatoria and Lyngbya species. No heterocystous cyanobacteria were isolated throughout the study.     

Non-Conventional Construction Materials from Dredging Spoils

As a result of increasing environmental concerns on offshore dumping, dredging spoils arising from reclamation and harbour works will create another problem of disposal. The spoils are usually not suitable for use as landfill materials as they have little bearing capacities. The disposal problem could, however, be reduced if there is an alternative use for it. This paper describes a laboratory study on the use of dredging spoils together with limestone as raw materials for the production of cementitious building materials. Different compositions of the raw materials were ground and incinerated to produce cement. The cementitious material produced after incineration was also mixed with ordinary Portland cement for use as blended cement. The study shows that dredging spoils could be used to produce cement satisfying the strength requirements for masonry cement. When used as blended cement, it can replace up to 30% by weight of ordinary Portland cement without reducing the strength.     

Predicting biological impairment from habitat assessments

The goal of biological monitoring programs is to determine impairment classification and identify local stressors. Biological monitoring performs well at detecting impairment but when used alone falls short of determining the cause of the impairment. Following detection a more thorough survey is often conducted using extensive biological, chemical, and physical analysis coupled with exhaustive statistical treatments. These methods can be prohibitive for small programs that are limited by time and budget. The objective of this study was to develop a simple and useful model to predict the probability of biological impairment based on routinely collected habitat assessments. Biological communities were assessed with the Index of Biotic Integrity (IBI), and habitat was assessed with the Qualitative Habitat Evaluation Index. Two models were constructed from a validation dataset. The first predicted a binary outcome of impaired (IBI < 35) or non-impaired (IBI ≥ 35) and the second predicted a categorical gradient of impairment. Categories include very poor, poor, fair, good, and excellent. The models were then validated with an independently collected dataset. Both models successfully predicted biological integrity of the validation dataset with an accuracy of 0.84 (binary) and 0.75 (categorical). Based on the binary outcome model, 22 sites were observed to be impaired while the model predicted them to not be impaired. The categorical model misclassified 47 samples while only seven of those were misclassified by two or more categories. The impairment source was subsequently identified by known stressors. The models developed here can be easily applied to other datasets from the Eastern Corn Belt Plain to aid in stressor identification by predicting the probability of observing an impaired fish community based on habitat. Predicted probabilities from the models can also be used to support conclusions that have already been determined.     

Metals in horseshoe crab eggs from Delaware Bay,USA: temporal patterns from 1993 to 2012

The health of horseshoe crab (Limulus polyphemus) eggs is important not only to maintain horseshoe crab populations, but because they are a resource for higher trophic levels, such as fish and shorebirds. We examined the concentrations of arsenic, cadmium, chromium, lead, manganese, mercury, and selenium in the eggs of horseshoe crabs from Delaware Bay (between New Jersey and Delaware, USA) in 1993, 1994, 1995, 1999, 2000, and 2012 to determine if there were significant temporal changes and if levels appear to pose a health risk to the crabs themselves, or to predators that consume them. All metal levels declined in horseshoe crab eggs between 1994 and 2012, although the declines were much less consistent for lead and chromium than that for mercury and cadmium. Levels of contaminants found in these eggs are well below those known to cause adverse effects in the crabs themselves or to organisms that consume them, such as migrating shorebirds.