贵州高原典型喀斯特县域生境质量时空演变及定量归因

揭示贵州高原喀斯特县域生境质量时空演变规律及其驱动因素,为平衡喀斯特区域生态保护和可持续发展提供科学依据.利用1989年、2003年、2010年和2020年4期土地利用数据、DEM数据、气象数据和社会经济数据,采用InVEST模型阐明普定县近30年生境质量时空分布格局及演变特征,并对其空间分异的驱动力进行了定量探测.结果表明：①耕地和林地是普定县的主要土地利用类型,构成了地表覆盖景观基质.2003~2010年土地利用变化最显著,其中林地的增幅最大,达86.42%,耕地是流失最严重的土地利用类型,面积减少157.57 km²,主要流向林地和建设用地;②1989~2020年普定县生境质量指数平均值由0.60上升至0.73,空间上由东北部向西南部大体呈现出“高-低-高”的分布格局,生境质量高值区主要分布在东北部林地和草地区,低值区集中在中部和南部的建设用地,生境质量等级上升的区域主要集中在东部及西北部的大部分地区;③土地利用类型是影响生境质量时空分布的首要因素,解释程度为91.00%.在交互作用探测中,任意两种影响因素的交互作用大于单个因素的单独作用,土地利用类型和年均降水量的交互作用最强,达到96.00%,其与岩性因子的交互作用达到94.00%,自然与人文因素共同主导生境质量的时空变化.1989~2020年普定县生境质量总体较好,土地利用类型变化与生境质量关系密切,优化土地利用结构、减小人类活动的影响对提高普定县生境质量具有重要意义.     

基于PLUS-InVEST模型的江西省生态系统碳储量时空演变与预测

土地利用变化是影响陆地生态系统碳储量变化的重要因素,研究土地利用变化与碳储量之间关系对优化区域土地利用结构,维持区域碳平衡可提供可靠的数据支撑.以江西省为例,分析1990~2020年土地利用变化,基于PLUS模型,结合自然发展情景、生态优先情景和经济发展情景设置,对2030年江西省土地利用格局进行模拟分析,运用InVEST模型测算1990~2020年及未来不同情景下江西省碳储量变化,利用空间自相关分析探索江西省不同情景下陆地生态系统碳储量时空变化特征,并提出相应的政策建议.结果表明:①1990~2020年江西省碳储量整体呈下降趋势,共减少4.58×10⁷ t.其中,水域和建设用地的面积增加,耕地、林地、草地及未利用地面积减少是导致碳储量减少的主要原因.②2030年江西省陆地生态系统碳储量在自然发展情景、生态优先情景和经济发展情景下分别为2.20×10⁹、2.24×10⁹和2.19×10⁹ t.③3种情景下的碳储量值在空间分布上具有相似性,碳储量高值区域在江西省北部、西北部及西部区域出现集聚,低值区域则在中部区域聚集.研究结果可为江西省未来国土空间规划,提升陆地生态系统碳储量提供数据支撑.     

陕西渭北旱塬区生境质量及碳储量时空演变分析与模拟

探析生境质量与碳储量的时空格局演化规律,对建立陕西渭北旱塬区生态安全屏障、优化国土空间格局具有积极反馈作用.以渭北旱塬区为研究案例,基于PLUS模型模拟2035年不同发展情景下土地利用空间格局,并采用InVEST模型分析研究区1980~2020年及未来多情景下生境质量和碳储量分布特征.结果表明:①近40年间,研究区内生境质量低等级区面积扩大462.55 km²,碳储量共减少7.85×10⁶t,二者总体呈逐年下降趋势; ②研究期间,生境质量降级区域集中在研究区东北部延安市域内,质量提升区域呈条状分布在靠近水源或海拔较高的地区.碳储量高值区集中分布在研究区内地势复杂、人口稀疏的区域,碳储量减少区域呈点状零散分布在研究区全域,未出现明显聚集现象; ③2035年碳储量除自然发展情景外,其他状态碳储量均有不同程度减少.经济优先发展情景中生境质量低等级区面积20787.41 km²,是较模拟初期低等级区增速最快和高等级区减幅最大的模拟情景.研究结果可为研究区低碳绿色发展、生态修复提供决策参考和数据支撑.     

基于InVEST和GeoSoS-FLUS模型的黄河源区碳储量时空变化特征及其对未来不同情景模式的响应

区域土地利用变化是导致生态系统碳储量变化的主要原因,预测未来土地利用变化对碳储量的影响对于碳储功能的可持续发展具有重要意义.近年来,在自然和人为因素的共同作用下,黄河源区土地利用变化显著,其碳储功能也相应发生改变.本研究结合InVEST和GeoSoS-FLUS模型,评估黄河源区2000~2020年以及不同情景下2020~2040年土地利用变化及其对碳储量的影响.结果表明：① 2000~2020年黄河源区碳储量整体呈上升趋势,共增加11.59×10⁶ t.② 20年间,黄河源区土地利用变化以低覆盖度草地、建设用地和湿地的面积增加和高覆盖度草地、中覆盖度草地和未利用地面积减少为主,未利用地大面积减少以及草地和湿地的面积增加是导致碳储量增加的主要原因.③ 2040年自然变化情景下黄河源区生态系统碳储量为871.34×10⁶ t,较2020年增加3.92×10⁶ t.生态保护情景下碳储量增幅明显,较2020年增加13.53×10⁶ t.该研究结果可以为黄河源区土地利用管理决策以及碳储功能的可持续发展提供科学参考.     

长江经济带生态系统服务权衡与协同及其驱动因素

生态系统服务及其变化是多种因素驱动的复杂过程,了解生态系统服务之间的权衡与协同作用及其驱动因素,对于实现生态系统服务有效管理和人类福祉至关重要.以长江经济带为研究区域,分析了2000~2020年产水、土壤保持、碳固定和粮食供给这4项生态系统服务的时空变化特征,运用相关性分析和地理加权回归识别和量化了生态系统服务间的权衡与协同关系,在此基础上应用偏最小二乘结构方程模型探究自然与人类活动对生态系统服务的影响,再通过地理探测器分析生态系统服务关系变化的驱动机制.结果表明:①近20年来,碳固定服务年均值由946.14 t·km^-2增至1 202.73 t·km^-2,粮食供给均值则由32.73万元·km^-2增至127.22万元·km^-2;产水和土壤保持服务增加幅度较小.②整体上,碳固定与土壤保持、粮食供给与产水为协同关系,其他生态系统服务之间为权衡关系;生态系统服务间的关系在不同地区存在一定的差异.③地形和气候是生态系统服务及多对生态系统服务权衡与协同关系的重要驱动因素,其中结构方程模型结果表明,气候对产水为正向影响（S = 0.73）,地形对粮食供给为负向影响（S = -0.57）;地理探测器结果揭示,影响碳固定与产水在空间上关系的主要驱动因子为海拔（q = 0.38）和降水（q = 0.19）.研究结果可为长江经济带生态系统服务可持续管理和实现该区域生态环境保护与社会经济的协同发展提供科学参考.     

1991～2016年黄河三角洲湿地变化的遥感监测

以1991、2000、2010和2016年的Landsat TM/OLI影像数据为基础,采用面向对象和目视解译的分类方法,提取了黄河三角洲湿地信息。同时,利用空间分析、动态度模型、非等间距序列灰色模型等分析方法,分析了湿地的时空变化特征,并结合相关文献资料讨论了湿地变化的驱动因素。结果表明,1991～2016年间,黄河三角洲湿地总面积逐渐减少,约91.39 km²。其中,以2000～2010年期间面积变化最为剧烈,自然湿地面积以30.21 km²/a的速度减少,而人工湿地以32.77 km²/a的速度增加。在各类型湿地中,草甸湿地面积减少最多,为312.83 km²;而人工湿地面积大幅增长,且以养殖池和盐田的增加最为迅速,增加了544.63 km²。从空间分布上来看,研究区人工湿地面积有逐渐向滨海区扩张的趋势。湿地养殖、农业开垦、工程修建等人类活动是导致黄河三角洲自然湿地减少的主要因素。     

广东省土地利用驱动下红树林潜在生境预测

为探索土地利用变化对红树林潜在生境分布的影响,融合MaxEnt模型和Dyna-CLUE模型,建立了土地利用驱动下红树林生境变化的定量预测方法.以中国红树林分布面积最大的广东省作为研究区,利用MaxEnt模型模拟红树林在自然条件下的理论适生区,采用Dyna-CLUE模型预测2030年的三种土地利用变化情景,最后将模拟的土地利用格局作为限制条件估算未来可供红树林生境分布的空间.结果表明,2020年广东省红树林潜在生境面积约34531hm²,2030年趋势情景下湿地将减少58.61%,红树林潜在生境面积将退化至24375hm²;可持续发展情景下通过改进土地利用策略并开展一定规模的退塘还湿,红树林潜在生境面积将增加至38125hm²;生态保护情景下,如能开展全面的生态保护和恢复,红树林潜在生境面积可达到47525hm².本研究的研究方法可有效预测不同海岸带土地利用驱动下红树林潜在生境的空间变化.研究结果发现,不同土地利用政策会对红树林潜在生境分布造成明显影响;通过改进政策,可显著提升红树林潜在生境的面积和完整性.本结论可为区域红树林保护与生境修复的空间规划及政策制定等提供科学支持.     

基于参数最优地理探测器的福州市生境质量时空格局与驱动力分析

揭示生境质量的时空演变特征和影响因素可为区域可持续发展提供参考依据。基于2000年、2010年和2020年的土地利用数据,运用InVEST模型、土地利用转移矩阵和参数最优地理探测器等方法,综合分析福州市生境质量时空演变及其驱动因素。结果表明：福州市2000年、2010年和2020年生境质量指数分别为0.812、0.806和0.793,生境质量改善的面积小于生境质量退化的面积,福州主城区和东南沿海区域的生境状况亟须改善。3 km网格为本研究的最佳空间尺度,最佳数据离散化分类数为6,自然间断点法更能解释驱动因素的驱动程度。高程、坡度和夜间灯光是福州市生境质量空间分异的主要影响因素,坡度和夜间灯光的交互作用对生境质量变化的解释力最强。     

基于InVEST-PLUS模型的淮北市碳储量时空演变及预测

研究土地利用时空演变对生态系统碳储量的影响,对研究区未来的国土空间规划以及减排增汇提供理论依据.基于1985、1995、2005、2015和2020年这5期土地利用数据,结合InVEST模型分析了研究区碳储量时空变化,运用PLUS模型预测研究区2035年自然发展情景、耕地保护情景、生态保护情景以及耕地和生态双保护情景土地利用变化并估算不同情景下的生态系统碳储量.结果表明:①1985~2020年研究区耕地面积持续减少,2015~2020年土地利用变化较快,综合土地利用动态度达到了34.62 %;②1985~2020年碳储量呈下降趋势,减少1.55×10⁵ t,其中在2005~2015年间,碳储量减少了1.22×10⁵ t,年均减少量达1.22×10⁴ t;③碳储量较高区域分布在研究区的东部,碳储量较低区域分布在研究区中部和西北部;耕地碳储量占比从66.89 %下降到57.73 %,但耕地仍是研究区最主要的碳库;其他地类向草地和林地转化有利于生态系统碳储量的增加;④2035年,自然发展情景、耕地保护情景、生态保护情景以及双保护情景下的碳储量分别为81.77×10⁵ 、82.45×10⁵、82.82×10⁵和82.51×10⁵ t.     

基于SSP-RCP情景的黄土高原土地变化模拟及草原碳储量

探索未来气候变化情景下土地利用/覆盖变化（LUCC）和生态系统碳储量的空间分布,可以为优化土地资源再分配和制定社会经济可持续发展政策提供科学依据.研究整合了斑块生成土地利用模拟（PLUS）模型和生态系统服务与权衡综合评价（InVEST）模型,基于CMIP6提供的共享社会经济路径和代表性浓度路径（SSP-RCP）情景,评估了黄土高原LUCC和生态系统碳储量的时空动态变化,分析驱动因素对不同区域的影响程度,探讨各区域碳储量空间相关性.结果表明：①未来3种情景LUCC变化模式相似,耕地、草地和未利用地面积都有不同程度的减少,建设用地急剧扩张,3种情景下的增幅分别为29.23%~53.56%（SSP126）、34.59%~63.28%（SSP245）和42.80%~73.27%（SSP585）.②与2020年相比,2040年SSP126情景碳储量增加1.813 8×10⁶ t,其余情景持续下降;到2060年,3种情景草原碳储量分别减少13.391×10⁶、33.548×10⁶和85.871×10⁶ t.③从空间相关性来看,黄土高原碳储量在市域间存在相关性,未来情景差异不显著,热点分布在研究区中部及中部以北地区,没有明显的冷点区域.④土地利用变化会增加或损失碳储量.林地、耕地和草地比其它土地类型有更多的碳储量,增加它们的面积和限制向其它土地类型转换会增加生态系统碳储量.     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.