SBR中好氧颗粒污泥的培养

采用竖式SBR作为反应器,利用城市污水处理厂剩余污泥作为接种污泥,通过不间断运行培养出好氧颗粒污泥。实验结果表明,采用非限量曝气模式好氧颗粒污泥降解模拟污水的效果较好,其COD去除率可达98％以上。曝气量对好氧颗粒污泥的形成和稳定具有重要影响,当气速为26．5m／h时,好氧颗粒污泥的性状和处理有机废水效果最佳。同时好氧颗粒污泥对pH值的变化不明显,当pH为5—8范围内,其COD去除率都可达到85％以上。但是未经驯化的好氧颗粒污泥对对硝基苯酚和对氯苯酚两种芳香类有机物较敏感,而对硝基苯酚对其毒性更大。当对硝基苯酚和。对氯苯酚浓度为10mg／L时,其COD去除率仅为42．5％和52％。     

咸淡水界面水敏性影响因素研究

通过砂柱的水击试验，对盐浓度、水流速度、pH值对咸淡水界面水敏性的影响进行了研究。试验结果表明，咸淡水界面上存在临界盐浓度值和临界流速值，当入流溶液浓度达到临界盐浓度和流速达到临界流速时，都会产生颗粒释放现象，导致砂柱的渗透率下降，水敏性发生。在相同的盐浓度和进水流速条件下，进水的pH值越低，颗粒释放的速度越慢，释放总量越少；进水的pH值越高，颗粒释放的速度越快，释放总量越多。     

炼油厂活性污泥膨胀控制措施

生化法对进水的有机物负荷要求比较严格,当进水条件突变时,易使活性污泥中毒而失去活性,并发生污泥膨胀。而炼油废水受生产情况的影响,水质、水量变化很大,因此使得生化处理设施的运行很不利,时常发生污泥膨胀,使污泥沉降性能恶化。针对这一问题,分析了造成污泥膨胀的机理和水质情况,并提出了相应的控制措施。     

印染废水处理生化系统运行效果的影响因素分析

印染企业废水处理生化系统运行不佳的现象较为普遍,通过对4家印染企业的生化系统跟踪监测和整改调试,分析影响生化系统处理效果的原因主要与溶解氧(DO)、水力停留时间(HRT)、进水pH、加药控制有关,并在调试过程中通过单因素控制获得工艺的最佳运行参数。调试结果表明：出水DO不低于6 mg/L,HRT≥48 h,进水pH控制在8.0～8.5,能使生化系统微生物保持良好的活性和降解污染物的能力。生化系统运行最优企业COD_Cr降解率可达96.25%,NH₃-N≤3 mg/L。出水DO不影响污泥沉降性能。     

溶解氧对好氧颗粒污泥影响的研究进展

好氧颗粒污泥技术是一种新颖废水处理技术。溶解氧(DO)是好氧颗粒污泥形成和稳定运行的一个重要参数。好氧颗粒污泥需要的曝气量大,能耗高。高曝气量带来的高DO浓度不利于氨氮通过SND去除。当DO扩散在颗粒内部受到限制时,颗粒中心形成的厌氧层不利于颗粒污泥的长期稳定运行。本文系统分析了DO浓度对好氧颗粒污泥影响的国内外研究现状,对好氧颗粒污泥中DO浓度这一重要参数的研究进行了总结。研究在低DO浓度下保持好氧颗粒污泥的稳定性有利于降低运行成本,采取合适的方法降低颗粒内部的扩散限制有利于增强颗粒的稳定性能。     

碱解处理对剩余污泥融胞效果及厌氧消化产气效果

主要研究了碱解处理的pH值对剩余污泥的融胞效果及厌氧消化产气效果的影响.通过观测碱处理污泥上清液中的SCOD以及溶解性蛋白质,发现两者变化规律相似,其融胞效果随pH值的升高,即碱投加量的增加而增加.此外随着pH值的升高,VS的去除率随之增加.当pH为11时,48h VS去除率可达将近22%.碱解处理后污泥的后续厌氧消化的特性可得到明显改善.碱解处理调节pH值分别为pH9、pH10、pH11的污泥进行厌氧消化30d总甲烷产量与未经碱解处理的污泥相比较,总甲烷产量分别提高了8%、23%、41%.其中经碱解处理至pH值为11的污泥的COD去除率为32%.     

好氧颗粒污泥降解邻苯二甲酸二甲酯的影响因素研究

本文研究了好氧颗粒污泥系统中,温度、pH、曝气强度、邻苯二酸(Phthalic Acid,PA)及氨氮(NH3-N)对邻苯二甲酸二甲酯(Dimethyl Phthahte,DMP)降解效果的影响,结果表明:好氧颗粒污泥降解DMP的最佳温度、最佳PH值范围、最佳曝气强度分别为25℃～45℃、7.0 ～9.0、1.38 cm/s.当PA浓度为100 mg/L、300 mg/L,PA对DMP降解起促进作用;当PA浓度为500 mg/L、800 mg/L,PA对DMP降解起抑制作用.进水中50 mg/L的氨氮浓度对DMP降解的影响不大.本研究中采用的19种运行工况条件中,除曝气强度为0.33 cm/s以外,其他18种运行工况条件下,当运行时间达到300 min时,DMP的浓度都小于1.0 mg/L,因此,当水力停留时间达到5h以上时,温度、pH、PA、氨氮对DMP降解速率的影响基本上可以忽略不计.     

厌氧膜生物反应器对乳品废水处理效果的研究

采用厌氧膜生物反应器(AnMBR)对乳品废水进行处理,装置连续运行100d,研究了不同进水COD_(Cr)浓度(3 000、5 000、7 000、9 000 mg/L)对出水水质及反应器内污泥特性的影响,并与常规厌氧生物反应器的处理效果进行对比。结果表明,温度为35℃,HRT为48h时,COD_(Cr)去除率和氨化率随着进水COD_(Cr)浓度的降低而升高,最高可达89%和38%以上。TN去除率随着进水COD_(Cr)浓度的增加先增高后降低,在7 000 mg/L条件下,去除率为55%。装置在运行过程中,MLVSS/MLSS平均值约为0. 7,SVI值在60～80 m L/g的范围内,污泥具有良好的活性与沉降性。AnMBR与常规厌氧生物反应器相比,在处理高浓度乳品废水时运行更加稳定,耐冲击负荷能力更强,出水水质更好。     

浊度传感器应用于连续监测污水厂进水悬浮颗粒浓度的研究

为使城市污水处理厂更合理高效的运营,可对进水悬浮颗粒浓度的实时监测来实现。通过对进水水样的悬浮颗粒浓度测量值与相应浊度值建立的关系曲线,达到对污水处理厂进水悬浮颗粒浓度（mg／L）的连续实时监测。文中给出了浊度传感器的校准方法,并建立浊度-悬浮颗粒浓度关系曲线,将其应用于某城市污水处理厂,得到单位时间进水悬浮颗粒总量的实时连续图。     

UASB反应器处理天然气厂检修废水的负荷变化试验研究

本文以某天然气净化厂检修废水为研究对象,采用上流式厌氧污泥床（UASB）反应器对该废水进行处理。当进水COD浓度已达最大时,小范围改变进水有机负荷,观察出水VFA、pH、COD及产气量的变化情况,研究负荷变化对该反应器的影响,最终确定反应器能承受的最适负荷。     

Studies on the toxic effects of pentachlorophenol on the biological activity of anaerobic granular sludge

In order to explore the pathway of the anaerobic biotreatment of the wastewater containing pentachlorophenol (PCP) and ensure the normal operation of Upflow Anaerobic Sludge Blanket (UASB) reactor, the anaerobic sludge under different acclimation conditions were selected to seed and start up UASB reactors. Anaerobic toxicity assays were employed to study the biological activity, the tolerance and the capacity to degrade PCP of different anaerobic granular sludge from UASB reactors. Results showed that the anaerobic granular sludge acclimated to chlorophenols (CPs) could degrade PCP more quickly (up to 9.50mg-PCPg(-1)TVSd(-1)). And the anaerobic granular sludge without acclimation to CPs had only a little activity of degrading PCP (less than 0.07mg-PCPg(-1)TVSd(-1)). Different PCP concentrations (2, 4, 6, 8mgL(-1)) had different inhibition effects on glucose utilization, volatile fatted acidity (VFA)-degrading and methanogens activity of PCP degradation anaerobic granular sludge, and the biological activity declined with the increase in PCP concentration. The methanogens activity suffered inhibition from PCP more easily. The different acclimation patterns of seeded sludge had distinctly different effects on biological activity of the degradation of PCP of anaerobic granular sludge from UASB reactors. The biological activity of the anaerobic granular sludge acclimated to PCP only was also inhibited. This inhibition was weak compared to that of anaerobic granular sludge acclimated to CPs, further, the activity could recover more quickly in this case. In the same reactor, the anaerobic granular sludge from the mid and base layers showed higher tolerance to PCP than that from super layer or if the sludge is unacclimated to CPs, and the corresponding recovery time of the biological activity in the mid and base layers were short. Acetate-utilizing methanogens and syntrophic propinate degraders were sensitive to PCP, compared to syntrophic butyrate degraders.     

The formation of aerobic granular sludge for the treatment of real landfill leachate using a granular sequencing batch reactor at a constant volume

Leachate generated in a landfill may not be treated by conventional biological treatment due to its nature and complexity. The process of forming aerobic granules in batch sequencing reactors having features such as; reducing the settling process time and saving energy consumption and high decomposition rate have been noticed by researchers. In the present study, the structure of sequencing batch reactors (SBRs) was evaluated for the formation of granules, which were subsequently utilized for the treatment of landfill leachate. The experiment was initiated by using the GSBR, containing 1200 ml with different apparatuses, to develop granular sludge, and synthetic wastewater was added to reinforcement. The selected parameters for the operational hydraulic retention time (HRT) of the wastewater (6-h cycles) included feeding, idle, aeration, settling, and discharge. Furthermore, the controlled conditions were the dissolved oxygen (DO) range of 2–2.2 mg/L, temperature range of 20–23℃, and pH of 7.5–8.3. The chemical oxygen demand (COD), mixed liquor suspended solids (MLSS), and sludge volume index (SVI) daily were measured at the influent and effluent of GSBR reactor. The main properties of aerobic granular sludge were identified during the research procedures, and the remarkable settling and potent, high-density microbial structure of the granules were confirmed. The mean size of the formulated granules was estimated at 7.46 ± 1.8 mm, and the volume of the biomass also increased from approximately 1607 to 4137 mg/L through the granulation process. Moreover, 98% of the influent chemical oxygen demand (COD) could be removed by the formulated granular sludge, and the final-stage organic loading rate was estimated at 5.65 COD/m³/day. According to the results, GSBRs could be employed for the formulation of aerobic granular sludge for the treatment of landfill leachate.     

UAFSB反应器处理畜禽废水的快速启动

对UASB反应器进行改型,得到UAFSB,并结合UASB反应器快速启动的驯化方式,比较分析用畜禽废水直接启动加颗粒活性炭与未加颗粒活性炭的运行过程和结果。试验结果表明：絮状污泥接种后经过54天的驯化,进料COD浓度由800mg／L提高到5000mg／L,去除率基本稳定在90％以上,均达到预期目的;在污泥中掺入颗粒活性炭,反应器的启动时间有所缩短、抗冲击能力有所加强。     

Bioconversion of selenate in methanogenic anaerobic granular sludge

The capacity of anaerobic granular sludge to remove selenate from contaminated wastewater was investigated. The potential of different types of granular sludge to remove selenate from the liquid phase was compared to that of suspended sludge and contaminated soil and sediment samples. The selenate removal rates ranged from 400 to 1500 microg g VSS(-1) h(-1), depending on the source of biomass, electron donor, and the initial selenate concentration. The granular structure protects the microorganisms when exposed to high selenate concentrations (0.1 to 1 mM). Anaerobic granular sludge "Eerbeek," originating from a UASB reactor treating paper mill wastewater, removed about 90, 50, and 36% of 0.1, 0.5, and 1 mM of Se, respectively, from the liquid phase when incubated with 20 mM lactate at 30 degrees C and pH 7.5. Selenite, elemental Se (Se(o)), and metal selenide precipitates were the conversion products. Enrichments from the anaerobic granular sludge "Eerbeek" were able to convert 90% of the 10-mM selenate to Se(o) at a rate of 1505 microg Se(VI) g cells(-1) h(-1), a specific growth rate of 0.0125 g cells h(-1), and a yield of 0.083 g cells mg Se(-1). Both microbial metabolic processes (e.g dissimilatory reduction) as well as microbially mediated physicochemical mechanisms (adsorption and precipitation) contribute to the removal of selenate from the Se-containing medium.     

ABSBR处理高浓度有机废水试验研究

试验研究了ABSBR重启动的条件,讨论了影响生物降解的主要因素。试验表明：进水流量、PH值与进水COD负荷是影响废水处理效能的重要参数。进水流量维持在4L／min、pH值在6．5～7．5时有利于提高COD去除率。研究发现对于驯化成熟的ABSBR存在适宜的进水COD负荷,COD负荷在4000mg／L时,生物降解速率最快。     

An experimental study on the influence of zeolite on changes of pH and alkalinity in anaerobic treatment of compost leachate

With the increase of urbanization, municipal solid waste has also increased. Therefore, the need for solid waste management is also increasing compared with earlier decades. Composting is a good option for the recycling of solid waste; however, it produces leachate, which requires proper treatment systems to prevent environmental degradation. Due to high chemical oxygen demand (COD) concentrations in compost leachate, anaerobic treatment is the best option for handling the effluent, and an anaerobic baffled reactor (ABR) is one such anaerobic reactor that can be used for its treatment. Because of high ammonia and heavy metal concentrations, as well as the possibility of sludge washout in ABRs, it is important to use proper media, such as zeolite, which can reduce inhibition effects and sludge washout from the reactor. Anaerobic treatment, especially during the methanogenesis phase, is sensitive, and pH and alkalinity are parameters that influence the treatment. Therefore, adjusting these parameters within a normal range is very important to the proper functioning of anaerobic systems. In this study, a pilot‐scale ABR was used, and the last 4 of the 8 ABR compartments were filled with zeolite. The bioreactor was operated at hydraulic retention times (HRT) of 3, 4, and 5 days, with zeolite filling ratios of 10%, 20%, and 30%, and influent COD concentrations of 10,000, 20,000, and 30,000 milligrams per liter (mg/L). In this study, pH value was 6.43 ± 0.1, 6.96 ± 0.3, and 6.96 ± 0.25 at filling ratios of 10%, 20%, and 30%, respectively. According to the results, in all filling ratios, no significant changes were observed in the pH value when the organic loading rate increased and its amount was within a constant range. Influent alkalinity was equal to 2015 ± 510, 2884 ± 505, and 4154 ± 233 milligrams of calcium carbonate per liter (mg CaCO₃/L) at influent COD concentrations of 10,000, 20,000, and 30,000 mg/L, respectively, and in effluent, they were 2536 ± 336, 3379 ± 639, and 4377 ± 325 mg CaCO₃/L, respectively. The amount of alkalinity in the effluent increased compared with the alkalinity in the influent. The results show that the amount of alkalinity in the influent and effluent was similar, and the alkalinity enhancement was lower when the filling ratio was increased from 10% to 20%, and 20% to 30%. Comparisons of the results from zeolite with and without biofilm showed that, in cases of zeolite with biofilm, the amounts of silica and oxygen decreased and the amount of carbon increased, and it showed the formation of biofilm on the surface of zeolite. In addition, the absence of sodium in the zeolite with the biofilm indicated that sodium was exchanged with ammonium ions. According to the results, zeolite can be used in anaerobic reactors as a medium, and it also reduces fluctuations in pH and alkalinity at different organic loading rates, providing a normal range for anaerobic treatment.     

一种厌氧颗粒污泥的微生物与化学组成研究初探

本文研究UASB反应器处理石灰法制浆的草浆蒸煮黑液,在较短时间内培养出首育良好沉淀性能和较高活性的厌氧颗粒污泥。并对其形态、结构和化学组份及不同生理类群的厌氧微生物特性等进行了观察和测试,结果表明厌氧颗粒污泥高活性的原因。为进一步探索厌氧颗粒污泥的形成机理提供了依据。     

提高曝气池污水处理能力的可行性实践

炼化企业污水场控制污泥膨胀,可以在一定限度内有效提高装置的污水处理能力。通过对大连石化公司污水场进行生产分析,在保持有机负荷F/M相对稳定的条件下,好氧生化单元的污泥浓度由设计值2000～2500mg/L,提高至3500～4000mg/L之间,进水COD去除量由设计值8880kg/d,提高到16000kg/d,使装置的处理能力提高了1.8倍。     

法国某生活污水厂污泥好氧消化工艺运行研究

为了提高出水质量,法国小镇Cagnes—sur—Mer的生活污水处理厂从2008年初开始实施高有机负荷的运行,但同时这也提高了出泥产量。由于污泥的处理费用及搬运污泥的交通费用很高,水厂对污泥进行了污泥好氧稳定工艺,工艺使用纯氧机（VSA装置）就地利用空气制氧。工艺投入运行后,每日对好氧消化池的入泥和出泥进行采样和检测（MLSS、MLVSS、pH、COD、DRYNESS etc）以建立完整的运行数据。污泥经好氧消化作用后其有机物含量减少60％以上,每月减少40吨的出泥。同时,消化池的使用还使水厂周日也能对曝气池中的污泥进行抽取,缓解了以往由于周日停止排泥而导致周一曝气池中污泥浓度过大的问题。从而达到优化出水水质的目的。消化池中的温度维持在40℃左右,因为反应为放热反应,所以无需加热设备。此项目所收集到的数据将为这种工艺的发展提供帮助。同时也可以为那些想要减少出泥量的水厂提供一种新的方法。因为它投资小,见效快,操作简单。