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1.
ABSTRACT: Nutrient loading from beef pastures located within the northern Lake Okeechobee watershed in Florida, has been identified as a source of phosphorus contributing to the accelerated eutrophication of the lake. Since 1989 within the watershed, 557 agricultural drainage sites, mainly beef pasture, have been monitored for compliance under a regulatory program. Of those sites, 154 were actively monitored for phosphorus concentrations from October 1, 1998, to September 30, 1999. Of these 154 sites, 77 were considered to be out of compliance (OOC). An OOC site is defined as having runoff with a 12‐month average phosphorus concentration exceeding the permitted discharge limit. The average annual phosphorous load from the 77 OOC sites for an eight‐year study period from October 1, 1991, to September 30, 1999, was estimated using measured concentration values and simulated runoff obtained from an agricultural nonpoint source pollution model, CREAMS‐WT. The 77 OOC sites produced an estimated average annual 46 metric tonnes of phosphorus load, of which an estimated 22 tonnes of phosphorus reached Lake Okeechobee on an average annual basis. The remaining estimated average annual 24 tonnes of phosphorus load was retained by streams and wetlands in the discharge transport system between the sites and the lake. The estimated average annual load reaching Lake Okeechobee from the OOC sites represented 11 percent of the phosphorus load above a five‐year average annual target load for the lake. However, the OOC site drainage areas represented only 3 percent of the northern watershed that drains into the lake. Of the 77 OOC sites, 12 sites had an average annual phosphorus loading rate equal to or greater than 3.0 kg/ha and were placed on the priority list for the Critical Restoration Project in the Lake Okeechobee watershed. To estimate the possible phosphorus load reductions from the 77 sites, two scenarios were modeled. The first scenario reduced phosphorus concentrations in runoff to the permitted discharge limits under the Lake Okeechobee regulatory program. The second scenario changed current land uses to native rangeland with an estimated annual offsite total phosphorus areal loading rate of 0.114 kg/ha. These two scenarios are hypothetical with assumed concentration values and loading rate. Model results showed that the first management scenario reduced the average annual phosphorus load to the lake by an estimated 15 tonnes. The second scenario reduced the average annual phosphorus load to the lake by an estimated 21 tonnes.  相似文献   

2.
ABSTRACT: Existing land use data were used to estimate nonpoint source phosphorus loads to Lake Champlain (Vermont/New York/Quebec) in a loading function model that combined P concentration coefficients with regional hydrologic data. The estimates were verified against monitored loading data, then used to assess the relative magnitudes of contributions from major land uses and regions of the Lake Champlain Basin. The Basin is comprised of 62 percent forest, 28 percent agricultural land, 3 percent urban land, and 7 percent water. The best-fit model estimated an annual total P load of 457 mt/year, which did not differ significantly from the 458 metric tons/year measured for an average hydrologic year, and accurately predicted loads from major tributaries. Agriculture contributes 66 percent of the annual nonpoint source P load to Lake Champlain; urban and forest land contribute 18 percent and 16 percent, respectively. Because agricultural land contributes most nonpoint source P to Lake Champlain, load reduction effort must deal with agricultural sources. However, because the urban 3 percent of the basin contributes 18 percent of the estimated load, high load reduction efficiencies might be achieved by addressing urban sources. This assessment clearly demonstrated the relationship between land use and P loads in the Lake Champlain Basin, a prerequisite for policy-makers to endorse a P management strategy requiring changes in land use and management.  相似文献   

3.
Abstract: Over the past 35 years, a trend of decreasing water clarity has been documented in Lake Tahoe, attributable in part to the delivery of fine‐grained sediments emanating from upland and channel sources. The overall objective of the research reported here was to determine the amount of fine sediment delivered to Lake Tahoe from each of the 63 contributing watersheds. The research described in this report used combinations of field‐based observations of channel and bank stability with measured and simulated data on fine‐sediment loadings to estimate fine‐sediment loadings from unmonitored basins throughout the Lake Tahoe Basin. Loadings were expressed in the conventional format of mass per unit time but also in the number of particles finer than 20 μm, the latter for future use in a lake‐clarity model. The greatest contributors of fine sediment happened to be those with measured data, not requiring extrapolation. In descending order, they are as follows: Upper Truckee River [1,010 tonnes per year (T/year)], Blackwood Creek (846 T/year), Trout Creek (462 T/year), and Ward Creek (412 T/year). Summing estimated values from the contributing watersheds provided an average, annual estimate of fine‐sediment (<0.063 mm) loadings to the lake of 5,206 T/year. A total of 7.79E + 19 particles in the 5‐20 μm fraction were calculated to enter Lake Tahoe in an average year with the Upper Truckee River accounting for almost 25% of the total. Contributions from Blackwood, Ward, Trout, and Third creeks account for another 23% of these very fine particles. Thus, these five streams making up about 40% of the basin area, account for almost 50% of all fine‐sediment loadings to the lake. Contribution of fine sediment from streambank erosion were estimated by developing empirical relations between measured or simulated bank‐erosion rates with a field‐based measure of the extent of bank instability along given streams. An average, annual fine‐sediment loading from streambank erosion of 1,305 T/year was calculated. This represents about 25% of the average, annual fine‐sediment load delivered to the lake from all sources. The two largest contributors, the Upper Truckee River (639 T/year) and Blackwood Creek (431 T/year), account for slightly more than 80% of all fines emanating from streambanks, representing about 20% of the fine sediment delivered to Lake Tahoe from all sources. Extrapolations of fine‐sediment loadings to the unmonitored watersheds are based on documented empirical relations, yet contain a significant amount of uncertainty. Except for those values derived directly from measured data, reported results should be considered as estimates.  相似文献   

4.
ABSTRACT: A Geographic Information System (GIS) based non‐point source runoff model is developed for the Las Vegas Valley, Nevada, to estimate the nutrient loads during the years 2000 and 2001. The estimated nonpoint source loads are compared with current wastewater treatment facilities loads to determine the non‐point source contribution of total phosphorus (TP), total nitrogen (TN), and total suspended solids (TSS) on a monthly and annual time scale. An innovative calibration procedure is used to estimate the pollutant concentrations for different land uses based on available water quality data at the outlet. Results indicate that the pollutant concentrations are higher for the Las Vegas Valley than previous published values for semi‐arid and arid regions. The total TP and TN loads from nonpoint sources are approximately 15 percent and 4 percent, respectively, of the total load to the receiving water body, Lake Mead. The TP loads during wet periods approach the permitted loads from the wastewater treatment plants that discharge into Las Vegas Wash. In addition, the GIS model is used to track pollutant loads in the stream channels for one of the subwatersheds. This is useful for planning the location of Best Management Practices to control nonpoint pollutant loads.  相似文献   

5.
Richards, R. Peter, Ibrahim Alameddine, J. David Allan, David B. Baker, Nathan S. Bosch, Remegio Confesor, Joseph V. DePinto, David M. Dolan, Jeffrey M. Reutter, and Donald Scavia, 2012. Discussion –“Nutrient Inputs to the Laurentian Great Lakes by Source and Watershed Estimated Using SPARROW Watershed Models” by Dale M. Robertson and David A. Saad. Journal of the American Water Resources Association (JAWRA) 1‐10. DOI: 10.1111/jawr.12006 Abstract: Results from the Upper Midwest Major River Basin (MRB3) SPARROW model and underlying Fluxmaster load estimates were compared with detailed data available in the Lake Erie and Ohio River watersheds. Fluxmaster and SPARROW estimates of tributary loads tend to be biased low for total phosphorus and high for total nitrogen. These and other limitations of the application led to an overestimation of the relative contribution of point sources vs. nonpoint sources of phosphorus to eutrophication conditions in Lake Erie, when compared with direct estimates for data‐rich Ohio tributaries. These limitations include the use of a decade‐old reference point (2002), lack of modeling of dissolved phosphorus, lack of inclusion of inputs from the Canadian Lake Erie watersheds and from Lake Huron, and the choice to summarize results for the entire United States Lake Erie watershed, as opposed to the key Western and Central Basin watersheds that drive Lake Erie’s eutrophication processes. Although the MRB3 SPARROW model helps to meet a critical need by modeling unmonitored watersheds and ranking rivers by their estimated relative contributions, we recommend caution in use of the MRB3 SPARRROW model for Lake Erie management, and argue that the management of agricultural nonpoint sources should continue to be the primary focus for the Western and Central Basins of Lake Erie.  相似文献   

6.
There is a growing evidence that the ecological and biological integrity of the lagoon has declined during the last 50 years, probably due to the decline in water quality. Establishment of a watershed scale seagrass-based nutrient load assessment is the major aim of water quality management in the Indian River Lagoon (IRL). Best estimate loadings incorporate wet and dry deposition, surface water, groundwater, sediment nutrient flux, and point source effluent discharge data. On the average, the IRL is receiving annual external loadings of 832, 645 and 94,476kg of total nitrogen (TN) and total phosphorus (TP), respectively, from stormwater discharges and agricultural runoff. The average internal cycling of TN and TP from sediment deposits in the IRL was about 42,640kg TN and 1050kg TPyr(-1). Indirect evidence suggests that atmospheric deposition has played a role in the ongoing nutrient enrichment in the IRL. The estimated total atmospheric deposition of TN and TP was about 32,940 and 824kgyr(-1), while groundwater contribution was about 84,920 and 24,275kgyr(-1), respectively, to the surface waters of the IRL. The estimated annual contribution of point effluent discharge was about 60,408kg TN and 7248kg TP. In total, the IRL basin is receiving an annual loading of about 1,053,553kg TN and 127,873kg TP. With these results, it is clear that the current rate of nutrient loadings is causing a shift in the primary producers of the IRL from macrophyte to phytoplankton- or algal-based system. The goal is to reverse that shift, to attain and maintain a macrophyte-based estuarine system in the IRL.  相似文献   

7.
ABSTRACT: This study employs a simple nonlinear statistical approach to establish nitrogen, phosphorus, and sediment concentration and unit area load thresholds to aid in the evaluation of aquatic biological health of watersheds within the state of Pennsylvania. Flow, nitrogen and phosphorus species, sediment, basin area, land cover, and biological assessment data were assembled for 29 Pennsylvania watersheds. For each watershed, rating curves depicting flow versus load relationships were developed using the U.S. Environmental Protection Agency's (USEPA's) storage and retrieval database (STORET) flow and concentration data, then applied to daily flow data obtained from U.S. Geological Survey (USGS) daily flow gauging stations to estimate daily load between 1989 and 1999. The load estimates and concentration data were then sorted into six sets of data: mean annual unit area nitrogen, phosphorus, and sediment loads; and average nitrogen, phosphorus, and sediment concentrations. Results of Mann‐Whitney tests conducted on each of the six datasets indicate that there is a statistically significant difference between the concentrations and unit area loads of nitrogen, phosphorus, and sediment in impaired and unimpaired watersheds. Concentration thresholds, calculated as the midpoint between the impaired and unimpaired watersheds’ 95 percent confidence interval for the median, were estimated to be 2.01 mg/L, 0.07 mg/L, and 197.27 mg/L for nitrogen, phosphorus, and sediment, respectively. Annual unit area load thresholds were estimated to be equal to 8.64 kg/ha, 0.30 kg/ha, and 785.29 kg/ha, respectively, for nitrogen, phosphorus, and sediment species.  相似文献   

8.
Since 1980, the Lake Tahoe Interagency Monitoring Program (LTIMP) has provided stream‐discharge and water quality data—nitrogen (N), phosphorus (P), and suspended sediment—at more than 20 stations in Lake Tahoe Basin streams. To characterize the temporal and spatial patterns in nutrient and sediment loading to the lake, and improve the usefulness of the program and the existing database, we have (1) identified and corrected for sources of bias in the water quality database; (2) generated synthetic datasets for sediments and nutrients, and resampled to compare the accuracy and precision of different load calculation models; (3) using the best models, recalculated total annual loads over the period of record; (4) regressed total loads against total annual and annual maximum daily discharge, and tested for time trends in the residuals; (5) compared loads for different forms of N and P; and (6) tested constituent loads against land use‐land cover (LULC) variables using multiple regression. The results show (1) N and P loads are dominated by organic N and particulate P; (2) there are significant long‐term downward trends in some constituent loads of some streams; and (3) anthropogenic impervious surface is the most important LULC variable influencing water quality in basin streams. Many of our recommendations for changes in water quality monitoring and load calculation methods have been adopted by the LTIMP.  相似文献   

9.
Abstract: We present a simple modular landscape simulation model that is based on a watershed modeling framework in which different sets of processes occurring in a watershed can be simulated separately with different models. The model consists of three loosely coupled submodels: a rainfall‐runoff model (TOPMODEL) for runoff generation in a subwatershed, a nutrient model for estimation of nutrients from nonpoint sources in a subwatershed, and a stream network model for integration of point and nonpoint sources in the routing process. The model performance was evaluated using monitoring data in the watershed of the Patuxent River, a tributary to the Chesapeake Bay in Maryland, from July 1997 through August 1999. Despite its simplicity, the landscape model predictions of streamflow, and sediment and nutrient loads were as good as or better than those of the Hydrological Simulation Program‐Fortran model, one of the most widely used comprehensive watershed models. The landscape model was applied to predict discharges of water, sediment, silicate, organic carbon, nitrate, ammonium, organic nitrogen, total nitrogen, organic phosphorus, phosphate, and total phosphorus from the Patuxent watershed to its estuary. The predicted annual water discharge to the estuary was very close to the measured annual total in terms of percent errors for both years of the study period (≤2%). The model predictions for loads of nutrients were also good (20‐30%) or very good (<20%) with exceptions of sediment (40%), phosphate (36%), and organic carbon (53%) for Year 1.  相似文献   

10.
Effective watershed management requires an accurate assessment of the pollutant loads from the associated point and nonpoint sources. The importance of wet weather flow (WWF) pollutant loads is well known, but in semi‐arid regions where urbanization is significant the pollutant load in dry weather flow (DWF) may also be important. This research compares the relative contributions of potential contaminants discharged in DWF and WWF from the Ballona Creek Watershed in Los Angeles, California. Models to predict DWF and WWF loads of total suspended solids, biochemical oxygen demand, nitrate‐nitrogen, nitrite‐nitrogen, ammonia‐nitrogen, total Kjeldahl nitrogen, and total phosphorus from the Ballona Creek Watershed for six water years dating from 1991 to 1996 were developed. The contaminants studied were selected based on data availability and their potential importance in the degradation of Ballona Creek and Santa Monica Bay beneficial uses. Wet weather flow was found to contribute approximately 75 percent to 90 percent of the total annual flow volume discharged by the Ballona Creek Watershed. Pollutant loads are also predominantly due to WWF, but during the dry season, DWF is a more significant contributor. Wet weather flow accounts for 67 to 98 percent of the annual load of the constituents studied. During the dry season, however, the portion attributable to DWF increases to greater than 40 percent for all constituents except biochemical oxygen demand and total suspended solids. When individual catchments within the watershed are considered, the DWF pollutant load from the largest catchment is similar to the WWF pollutant load in two other major catchments. This research indicates WWF is the most significant source of nonpoint source pollution load on an annual basis, but management of the effects of the nonpoint source pollutant load should consider the seasonal importance of DWF.  相似文献   

11.
邛海水质变化趋势及保护对策研究   总被引:1,自引:0,他引:1  
本文通过对邛海流域现状污染源进行调查,邛海流域COD、氨氮、总氮和总磷产生量分别为5892.1t/a、995.6t/a、2888.2t/a和1105.1t/a,污染负荷主要来自面源污染.通过2002 ~ 2011年邛海水质监测数据分析,邛海水质近10年总体保持Ⅱ~Ⅲ类,处于中营养状态,2004~ 2006年水质相对较差,2006年以后水质逐渐好转.总磷、总氮是邛海主要污染因子,海河口是邛海污染最严重的区域.为实现邛海水质和流域生态环境持续改善,从产业结构优化、流域污染源治理、生态保育和流域生态环境综合监管等方面提出对策建议.  相似文献   

12.
Riparian buffers have the potential to improve stream water quality in agricultural landscapes. This potential may vary in response to landscape characteristics such as soils, topography, land use, and human activities, including legacies of historical land management. We built a predictive model to estimate the sediment and phosphorus load reduction that should be achievable following the implementation of riparian buffers; then we estimated load reduction potential for a set of 1598 watersheds (average 54 km2) in Wisconsin. Our results indicate that land cover is generally the most important driver of constituent loads in Wisconsin streams, but its influence varies among pollutants and according to the scale at which it is measured. Physiographic (drainage density) variation also influenced sediment and phosphorus loads. The effect of historical land use on present-day channel erosion and variation in soil texture are the most important sources of phosphorus and sediment that riparian buffers cannot attenuate. However, in most watersheds, a large proportion (approximately 70%) of these pollutants can be eliminated from streams with buffers. Cumulative frequency distributions of load reduction potential indicate that targeting pollution reduction in the highest 10% of Wisconsin watersheds would reduce total phosphorus and sediment loads in the entire state by approximately 20%. These results support our approach of geographically targeting nonpoint source pollution reduction at multiple scales, including the watershed scale.  相似文献   

13.
In recent years, improvements in point-source depuration technologies have highlighted the problems regarding agricultural nonpoint (diffuse) sources, and this issue has become highly relevant from the environmental point of view. The considerable extension of the areas responsible for this kind of pollution, together with the scarcity of funds available to local managers, make minimizing the impacts of nonpoint sources on a whole basin a virtually impossible task. This article presents the results of a study intended to pinpoint those agricultural areas, within a basin, that contribute most to water pollution, so that operations aimed at preventing and/or reducing this kind of pollution can be focused on them. With this aim, an innovative approach is presented that integrates a field-scale management model, a simple regression model, and a geographic information system (GIS). The Lake Vico basin, where recent studies highlighted a considerable increase in the trophic state, mainly caused by phosphorus (P) compounds deriving principally from the intensive cultivation of hazelnut trees in the lake basin, was chosen as the study site. Using the management model Groundwater Loading Effects of Agricultural Management Systems (GLEAMS), the consequences, in terms of sediment yield and phosphorus export, of hazelnut tree cultivation were estimated on different areas of the basin with and without the application of a best management practice (BMP) that consists of growing meadow under the trees. The GLEAMS results were successively extended to basin scale thanks to the application of a purposely designed regression model and of a GIS. The main conclusions can be summarized as follows: The effectiveness of the above-mentioned BMP is always greater for erosion reduction than for particulate P reduction, whatever the slope value considered; moreover, the effectiveness with reference to both particulate P and sediment yield production decreases as the slope increases. The proposed approach, being completely distributed, represents a considerable step ahead compared to the semidistributed or lumped approaches, which are traditionally employed in research into tools to support the decision-making process for land-use planning aimed at water pollution control.  相似文献   

14.
ABSTRACT: The three basins of Reelfoot Lake, which is located in northwestern Tennessee, were investigated using the Cs-137 tracer technique to determine rates of sediment deposition and to estimate the time before the basins will fill with sediment. Blue Basin, the largest of the three basins with 2922 ha, had an average annual sedimentation rate of 0.9 cm/yr from 1984 to 1984. The basin will become too shallow for most boating and recreational activities in about 200 years. Buck Basin, the central basin with 774 ha, had an average annual sedimentation rate of 1.1 cm/yr and will become too shallow for most recreational uses in about 100 years. Upper Blue Basin, the most upstream and smallest basin with 439 ha, had an average annual sedimentation rate of 1.7 cm/yr and will become too shallow for most recreational uses in about 60 years. Two important sources of sediment to Reelfoot Lake are erosion from a large number of soybean fields and channelization of many of the streams that flow into the lake. Changes in land management that would reduce erosion could increase the time the lake would remain usable for recreational activities.  相似文献   

15.
The integration of the phosphorus (P) bioavailability concept into a P loading analysis for Cayuga Lake, New York, is documented. Components of the analyses included the: (1) monitoring of particulate P (PP), soluble unreactive P (SUP), and soluble reactive P (SRP), supported by biweekly and runoff event‐based sampling of the lake's four largest tributaries; (2) development of relationships between tributary P concentrations and flow; (3) algal bioavailability assays of PP, SUP, and SRP from primary tributaries and the three largest point sources; and (4) development of P loading estimates to apportion contributions according to individual nonpoint and point sources, and to represent the effects of interannual variations in tributary flows on P loads. Tributary SRP, SUP, and PP are demonstrated to be completely, mostly, and less bioavailable, respectively. The highest mean bioavailability for PP was observed for the stream with the highest agriculture land use. Point source contributions to the total bioavailable P load (BAPL) are minor (5%), reflecting the benefit of reductions from recent treatment upgrades. The BAPL represented only about 26% of the total P load, because of the large contribution of the low bioavailable PP component. Most of BAPL (>70%) is received during high flow intervals. Large interannual variations in tributary flow and coupled BAPL will tend to mask future responses to changes in individual inputs.  相似文献   

16.
ABSTRACT: Loading functions are proposed as a general model for estimating monthly nitrogen and phosphorus fluxes in stream flow. The functions have a simple mathematical structure, describe a wide range of rural and urban nonpoint sources, and couple surface runoff and ground water discharge. Rural runoff loads are computed from daily runoff and erosion and monthly sediment yield calculations. Urban runoff loads are based on daily nutrient accumulation rates and exponential wash off functions. Ground water discharge is determined by lumped parameter unsaturated and saturated zone soil moisture balances. Default values for model chemical parameters were estimated from literature values. Validation studies over a three-year period for an 850 km2 watershed showed that the loading functions explained at least 90 percent of the observed monthly variation in dissolved and total nitrogen and phosphorus fluxes in stream flow. Errors in model predictions of mean monthly fluxes were: dissolved phosphorus - 4 percent; total phosphorus - 2 percent; dissolved nitrogen - 18 percent; and total nitrogen - 28 percent. These results were obtained without model calibration.  相似文献   

17.
ABSTRACT: The total maximum daily load (TMDL) for suspended sediment is the maximum quantity of suspended sediment that can enter a waterway without affecting the beneficial uses of the waterway. It is calculated as the sum of permissible allotments of point sources of suspended sediment, permissible allotments of nonpoint sources of suspended sediment, background (natural) loading of suspended sediment, and a margin of safety. The goal of this project was to develop methods for estimating background levels of sediment loads in tributaries of the Great Lakes. Such quantification is key to determining permissible TMDL in waters that do not meet water quality standards under the Clean Water Act of 1972. Suspended sediment loading for 46 rivers was estimated from data collected at U.S. Geological Survey (USGS) gages. Land use and physiographic attributes were estimated for these gaged basins with a geographic information system (GIS). Basin attributes and sediment yield data are the basis for examining two approaches to estimating background suspended sediment loads. One method, based upon envelope curves of sediment yield and drainage area, will be shown to have considerable merit. A second method, based upon correlation of sediment yield to various basin attributes such as drainage area and land use, will be shown to be fraught with difficulties.  相似文献   

18.
ABSTRACT A linear programming model to assess the cost-effectiveness of appropriate point and nonpoint phosphorus control measures was constructed for Carnegie Lake, an eutrophic lake located in Mercer County, New Jersey. The resultant model was tested for present and future conditions. Feasible solutions were obtained only after significant relaxation of receiving water quality standards. The high levels of point source treatment required to meet the in-stream water quality standards and the mesotrophic loading conditions suggest that a source control solution may not be feasible.  相似文献   

19.
ABSTRACT: The tailwater of Bridgewater Dam, below Lake James, North Carolina, is a designated trout stream. It has environmental attributes for a good cold water fishery with the exception of high suspended sediments. Muddy Creek, a tributary about 1.5 km downstream of the dam, is a major source of sediments. The Muddy Creek Watershed Restoration Initiative was established to develop and implement a sediment control plan. The Watershed Analysis Risk Management Framework was applied to simulate soil erosion and sedimentation and to help determine appropriate action. The simulated sediment concentrations of the river were comparable to observed data from November 1994 to November 2001. For the base condition, the sediment load was 135,000 kg/d from surface erosion and 1,300,000 kg/d from bank erosion. Increasing the buffer strip from existing 50 to 80 percent to 100 percent of stream segments would only reduce surface erosion to 70,400 kg/d with little change in sediment concentrations. Eliminating riverbank erosion would reduce the sediment load from 920,000 to 87,700 kg/d. The bank stabilization project would not only lower suspended sediment concentrations for Muddy Creek, but also reduce the lake sediment accumulation in the downstream Lake Rhodhiss by approximately 13 percent.  相似文献   

20.
Lake sediment has long been recognized as an important source of nutrients such as phosphorus. To gain a better understanding of phosphorus flux at the sediment-water interface, it is crucial to investigate the sediment porewater. There is also growing concern and interest in identifying whether organic-rich sediment is an important source of greenhouse gases such as CO(2) and CH(4). In the present study, we took sediment samples from West Lake, a shallow hypereutrophic lake in Hangzhou, Zhejiang Province, China and incubated subsamples under anaerobic conditions at 25 degrees C for 182 d using a specially designed microcosm that permits repeated extraction of sediment porewater and sampling of headspace gases. Anaerobic phosphate fluxes and mineralization of sediment organic carbon were measured. Average diffusive flux of soluble phosphorus was 0.81 mg P m(-2) d(-1) during the initial 18 d of incubation. Decomposition of sediment organic C followed zero-order reaction kinetics and methane accounted for about 50% of the mineralization products. The results suggest that organic-rich sediments can be important sources of P and methane under anaerobic conditions. Laboratory studies simulating field conditions and field studies are necessary to determine the contribution of sediment as a source of P and greenhouse gases.  相似文献   

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