GOLD-MINING EFFECTS ON STREAM HYDROLOGY AND WATER QUALITY,CIRCLE QUADRANGLE,ALASKA1

Effects of placer mining on the hydrology and water quality of several interior Alaska streams were studied as part of a project on the impacts of placer mining on stream ecosystems. Surface and subsurface waters were analyzed in the field for conductivity, pH, temperature, alkalinity, total and calcium hardnesses, iron, copper, manganese, ammonia-N, nitrate-N, nitrite-N, settleable solids, and turbidity. Total, nonfiltrable, and filtrable residues were determined in the laboratory. In the streams placer mining increased turbidity, settleable solids, nonfiltrable and filtrable residues and total iron. Surface and subsurface water levels, as measured in wells driven in the stream beds, were correlated with stream flow. Fine sediment deposited on stream beds in mined drainages reduced the hydraulic contact between the surface and subsurface waters of the stream and caused the piezometric water level to be below the surface water level of the mined streams. This resulted in higher specific conductance and significantly lower dissolved oxygen concentrations in the subsurface waters of mined streams compared to their surface waters. No significant differences were found for any water quality characteristics comparing surface to subsurface waters for the unmined streams.     

EFFECTS OF A DAIRY LOAFING LOT-BUFFER STRIP ON STREAM WATER QUALITY1

ABSTRACT: A loafing or sacrifice lot is an area located outside of the free stall barn, where a dairy herd spends several hours per day. Sacrifice lots are usually denuded of vegetation and have high concentrations of manure and urine that can contribute significant amounts of sediment, nutrients, and pathogens to nearby surface waters. In this study, stream water quality impacted by direct runoff from a sacrifice lot was monitored for a period of 20 months. Ambient stream water quality was monitored by grab sampling upstream and downstream of the sacrifice lot. During runoff events, stream water quality downstream of the sacrifice lot was monitored with an automatic sampler. Laboratory analyses were conducted for total suspended solids and nutrients (nitrogen and phosphorus compounds). A grass filter strip (GFS) was installed as a buffer downslope of the sacrifice lot 10 months into the study period. The impact of the buffer strip on the standardized pollutant concentrations and loads was evaluated using the non-parametric Wilcoxon test. The Wilcoxon test indicated that there was no significant difference (α= 0.05) in the standardized yield of sediment and dissolved pollutants before and after the GFS installation, except for phosphate-phosphorus and filtered total phosphorus concentrations, and sediment-bound total phosphorus and total kjeldahl nitrogen loads that decreased significantly. However, load decrease could have been partially caused by the smaller rainfall volumes after the GFS installation as compared to the existing condition.     

WATER QUALITY IN AGRICULTURAL WATERSHEDS: IMPACT OF RIPARIAN VEGETATION DURING BASE FLOW1

ABSTRACT: Water quality was monitored for 17 months during base flow periods in six agricultural watersheds to evaluate the impact of riparian vegetation on suspended solids and nutrient concentrations. In areas without riparian vegetation, both instream algal production and seasonal low flows appeared to be major determinants of suspended solids, turbidity, and phosphorus concentrations. Peak levels of all parameters were reached during the summer when flows were reduced and benthic algal production was high. Similar summer peaks were reached in streams receiving major point inputs but peaks occurred downstream from the input. Instream organic production was less important in regulating water quality in areas with riparian vegetation and permanent flows. Concentrations of suspended solids remained relatively constant, while phosphorus and turbidity increased in association with leaf fall in autumn. Intermittent flow conditions in summer increased the importance of instream organic production in controlling water quality, even when riparian vegetation was present. Efforts to improve water quality in agricultural watersheds during base flow should emphasize maintenance of riparian vegetation and stable flow conditions.     

WATER QUALITY AND SOURCE OF FRESHWATER DISCHARGE TO THE CALOOSAHATCHEE ESTUARY,FLORIDA1

ABSTRACT: The Caloosahatchee River has two major sources of freshwater one from its watershed and the other via an artificial connection to Lake Okeechobee. The contribution of each source to the freshwater discharge reaching the downstream estuary varies and either may dominate. Routine monitoring data were analyzed to determine the effects of total river discharge and source of discharge (river basin, lake) on water quality in the downstream estuary. Parameters examined were: color, total suspended solids, light attenuation, chlorophyll a, and total and dissolved inorganic nitrogen and phosphorus. In general, the concentrations of color, and total and dissolved inorganic nitrogen increased, and total suspended solids decreased, as total discharge increased. When the river basin was the major source, the concentrations of nutrients (excepting ammonia) and color in the estuary were relatively higher than when the lake was the major source. Light attenuation was greater when the river basin dominated freshwater discharge to the estuary. The analysis indicates that water quality in the downstream estuary changes as a function of both total discharge and source of discharge. Relative to discharge from the river basin, releases from Lake Okeechobee do not detectably increase concentrations of nutrients, color, or TSS in the estuary.     

URBANIZATION IMPACT ON WATER QUALITY DURING A FLOOD IN SMALL WATERSHEDS1

ABSTRACT: The impact of various urban land uses on water flow and quality in streams is being studied by monitoring small streams in the Milwaukee urban area. This paper compares the responses of an urban watershed and an agricultural watershed to an autumn rainfall of 2.2 cm. Flow from the urban basin showed a substantially greater response to the rain than that from the rural. Dilution, resulting from the greater quantities of surface runoff in the urban watershed, caused lower concentrations of sodium, chloride, calcium, magnesium, bicarbonate and total dissolved solids in the urban stream. The total quantity of these materials removed per unit drainage area of the urban basin was much greater, however. Road salt was still among the dominant dissolved materials in the urban water chemistry seven months after the last road salting. Sodium was apparently being released from adsorption by clays in the urban basin. Suspended sediment concentrations and total loads were higher in the urban stream.     

WATER QUALITY AND MACROINVERTEBRATE POPULATIONS BEFORE AND AFTER A HAZARDOUS WASTE CLEANUP1

ABSTRACT: Water samples and macroinvertebrates were collected from Finley Creek, Indiana, both before and two years after the cleanup of a nearby hazardous waste site. Water quality constituents were compared between years. Below the disposal site higher concentrations of constituents were found before and after the cleanup. However, two years after the cleanup, an improvement of water quality was observed. Total dissolved solids decreased by 52% and macroinvertebrate taxa increased by 44%.     

CHARACTERIZATION OF SURFACE WATER QUALITY ALONG A WATERSHED DISTURBANCE GRADIENT1

ABSTRACT. Characterizing ecological indicators such as water quality is necessary to effectively manage human-dominated systems such as the New Jersey Pinelands. Pinelands surface waters are naturally acidic and low in nutrients and other dissolved substances. Water quality for 14 Pinelands stream sites monitored by the U.S. Geological Survey was characterized in relation to land use. A gradient of increasing pH, specific conductance, and concentration of dissolved calcium, dissolved magnesium, total nitrite + nitrate-nitrogen, total ammonia-nitrogen, and total phosphorus was associated with a watershed disturbance gradient of increasing land use intensity and waste water flow. These two parallel gradients emphasized the significant effect that watershed disturbance can have on natural water chemistry in the Pinelands. The results of this study can be applied to planning and regulatory programs in the Pinelands.     

Water Quality in the Near Coastal Waters of the Gulf of Mexico Affected by Hurricane Katrina: Before and After the Storm

Water quality was assessed following Hurricane Katrina in the affected waters of Alabama, Mississippi, and Louisiana. Post-landfall water quality was compared to pre-hurricane conditions using indicators assessed by EPA’s National Coastal Assessment program and additional indicators of contaminants in water and pathogens. Water quality data collected after Hurricane Katrina suggest that the coastal waters affected by the storm exhibited higher salinity and concentrations of chlorophyll a, dissolved inorganic phosphorus, and total suspended solids following the storm compared to the previous 5-year averages. Higher bottom dissolved oxygen concentrations and light attenuation were also observed. Contaminant concentrations measured in the water column were very low or undetectable, as were the presence of pathogens. Overall water quality did not significantly differ from water quality assessed in the five years preceding the storm. Statistical analyses indicate that use of a probabilistic survey design is appropriate for making pre-storm and post storm comparisons for water quality condition on an areal basis. The information in this article has been funded wholly (or in part) by the U.S. Environmental Protection Agency. It has been subjected to review by the National Health and Environmental Effects Research Laboratory and approved for publication. Approval does not signify that the contents reflect the views of the Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. This is contribution number 1280 from the Gulf Ecology Division.     

DROUGHT EFFECTS ON WATER QUALITY IN THE SOUTH PLATTE RIVER BASIN,COLORADO1

ABSTRACT: Twenty‐three stream sites representing a range of forested, agricultural, and urban land uses were sampled in the South Platte River Basin of Colorado from July through September 2002 to characterize water quality during drought conditions. With a few exceptions, dissolved ammonia, Kjeldahl nitrogen, total phosphorus, and dissolved orthophosphate concentrations were similar to seasonal historical levels in all land use areas during the drought. At some agricultural sites, decreased dilution of irrigation return flow may have contributed to higher concentrations of some nutrient species, increased primary productivity, and higher dissolved oxygen concentrations. At some urban sites, decreased dilution of base flow and wastewater treatment plant effluent may have contributed to higher dissolved nitrite‐plus‐nitrate concentrations, increased primary productivity, and higher dissolved oxygen concentrations. Total pesticide concentrations in urban and agricultural areas were not consistently higher or lower during the drought. At most forested sites, decreased dilution of ground water‐derived calcium bicarbonate type base flow likely led to elevated pH and specific‐conductance values. Water temperatures at many of the forested sites also were higher, contributing to lower dissolved oxygen concentrations during the drought.     

IDENTIFICATION OF DISSOLVED-CONSTITUENT SOURCES IN MINE-SITE GROUND WATER USING BATCH MIXING1

ABSTRACT: Batch-mixing experiments were used to help identify lithologic and mineralogic sources of increased concentrations of dissolved solids in water affected by surface coal mining in northwestern Colorado. Ten overburden core samples were analyzed for mineral composition and mixed with distilled water for 90 days until mineral-water equilibrium was reached. Between one day and 90 days after initial contact, specific conductance in the sample mixtures had a median increase of 306 percent. Dissolved-solids concentrations ranged from 200 to 8,700 mg/L in water samples extracted from the mixtures after 90 days. Mass. balance simulations were conducted using the geochemical models BALANCE and WATEQF to quantify mineral-water interactions occurring in five selected sample mixtures and in water collected from a spring at a reclaimed mine site. The spring water is affected by mineral-water interactions occurring in all of the lithologic units comprising the overburden. Results of the simulations indicate that oxidation of pyrite, dissolution of dolomite, gypsum, and epsomite, and cation-exchange reactions are the primary mineral-water interactions occurring in the overburden. Three lithologic units in the overburden (a coal, a sandstone, and a shale) probably contribute most of the dissolved solids to the spring water. Water sample extracts from mixtures using core from these three units accounted for 85 percent of the total dissolved solids in the 10 sample extracts. Other lithologic units in the overburden probably contribute smaller quantities of dissolved solids to the spring water.     

TEMPORAL VARIABILITY OF WATER QUALITY IN THE ST. LUCIE ESTUARY,SOUTH FLORIDA1

ABSTRACT: Four years of monthly freshwater discharge and constituent concentration data from three tributaries were related to a concurrent series of data for three segments of the St. Lucie Estuary in South Florida using multiple regression and time-series analysis techniques. Water quality parameters examined were dissolved inorganic and total nitrogen and phosphorus, chlorophyll a, total suspended solids, turbidity, and color. On monthly time scales, a multiple regression, which included freshwater discharge, freshwater constituent concentration, and dilution with ocean water (salinity) as independent variables, explained 50 percent or less of the variability in estuarine constituents. No single independent variable explained more variation than another. By contrast, on seasonal (wet, dry) time scales, freshwater discharge explained the bulk of variation in estuarine water quality (up to 93 percent). On monthly time scales, variability in concentrations of nutrients and other constituents may be largely controlled by processes internal to the system. At seasonal time scales, freshwater discharge appears to drive variability in most estuarine water quality parameters examined. Results indicate that management of tributary input on a seasonal basis, with the expectation of achieving seasonal concentration goals in the estuary, would have a higher probability of success than managing on a monthly basis.     

WATER QUALITY IN AGRICULTURAL,URBAN, AND MIXED LAND USE WATERSHEDS1

ABSTRACT: Water quality and nonpoint source (NPS) pollution are important issues in many areas of the world, including the Inner Bluegrass Region of Kentucky where urban development is changing formerly rural watersheds into urban and mixed use watersheds. In watersheds where land use is mixed, the relative contributions of NPS pollution from rural and urban land uses can be difficult to separate. To better understand NPS pollution sources in mixed use watersheds, surface water samples were taken at three sites that varied in land use to examine the effect of land use on water quality. Within the group of three watersheds, one was predominately agriculture (Agricultural), one was predominately urban (Urban), and a third had relatively equal representation of both types of land uses (Mixed). Nitrogen (N), phosphorus (P), total suspended solids (TSS), turbidity, pH, temperature, and streamflow were measured for one year. Comparisons are made among watersheds for concentration and fluxes of water quality parameters. Nitrate and orthophosphate concentrations were found to be significantly higher in the Agricultural watershed. Total suspended solids, turbidity, temperature, and pH, were found to be generally higher in the Urban and Mixed watersheds. No differences were found for streamflow (per unit area), total phosphorus, and ammonium concentrations among watersheds. Fluxes of orthophosphate were greater in the Agricultural watershed that in the Urban watershed while fluxes of TSS were greater in the Mixed watershed when compared to the Agricultural watershed. Fluxes of nitrate, ammonium, and total phosphorus did not vary among watersheds. It is apparent from the data that Agricultural land uses are generally a greater source of nutrients than the Urban land uses while Urban land uses are generally a greater source of suspended sediment.     

EFFECTS OF SUSPENDED SOLIDS ON THE ACUTE TOXICITY OF ZINC TO DAPHNIA MAGNA AND PIMEPHALES PROMELAS1

ABSTRACT: Current procedures for setting site-specific water quality criteria consider abiotic and biotic factors. Suspended solids were shown to be important in reducing zinc toxicity to water column organisms. At zinc concentrations of ～ 1 mg/L in solutions with < 100 mg/L of all suspended solids tested, zinc toxicity to D. magna was reduced. Sorption of zinc to suspended solids and/or changes in water chemistry due to the addition of suspended solids appear to have been the factors causing reductions in zinc toxicity to D. magna. Only suspended solids levels of 483–734 mg/L of a type that increased total alkalinity, total hardness, and total dissolved carbon clearly reduced the toxicity of ～ 20 mg/L zinc to P. promelas. The toxic form of zinc to these organisms appears to reside in the aqueous phase. Characteristics of suspended solids did not influence the partition coefficient of zinc in sorption experiments of 96 h. The slopes of dose-response curves proved to be useful for assessing the potential of an organism to respond to changes in aqueous phase zinc concentrations, and may be a useful biological parameter when considering site-specific water quality criteria for chemicals.     

WATER QUALITY OF AN INTENSWE AGRICULTURAL WATERSHED IN QUEBEC1

ABSTRACT: . Under a watershed based approach being examined by the Quebec Ministry of Agriculture to accelerate the adoption of conservation practices, a study on the impacts of agricultural practices on the St. Esprit watershed was initiated in the fall of 1993. The water quality of this 26 km² intensive agricultural watershed was studied over an 18 month period. Water samples taken at the outlet of the watershed were analyzed for nitrate, phosphate, suspended sediment, and atrazine. Water quality data were analyzed to establish seasonal trends in pollutant concentration and load in the watercourse. Spring snowmelt was identified as a significant period of pollutant material export. All pollutant materials displayed seasonal variability in the export process. Peak pollutant concentrations were associated with high flow events. Mean observed pollutant concentrations did not exceed drinking water quality standards.     

OREGON WATER QUALITY INDEX A TOOL FOR EVALUATING WATER QUALITY MANAGEMENT EFFECTIVENESS1

ABSTRACT: The Oregon Water Quality Index (OWQI) is a single number that expresses water quality by integrating measurements of eight water quality variables (temperature, dissolved oxygen, biochemical oxygen demand, pH, ammonia+nitrate nitrogen, total phosphorus, total solids, and fecal coliform). Its purpose is to provide a simple and concise method for expressing the ambient water quality of Oregon's streams for general recreational use, including fishing and swimming. The OWQI, originally developed in the 1970s, has been updated based upon improved understanding about water quality behavior. This report describes the historical basis of the OWQI and defines the improved design of the present OWQI. The index allows users to easily interpret data and relate overall water quality variation to variations in specific categories of impairment. This report demonstrates the value of the OWQI in presenting spatial and temporal water quality information. The OWQI improves comprehension of general water quality issues, communicates water quality status, and illustrates the need for and effectiveness of protective practices.     

QUALITY STUDY OF GRAYWATER TREATMENT SYSTEMS1

ABSTRACT: A residential single family dwelling was retrofitted to recycle graywater for landscape irrigation and toilet flushing. The objective of this study was to determine improvements in graywater quality by evaluating five simple graywater treatment systems that were easily adapted to the household plumbing. The treatment systems consisted of (1) water hyacinths and sand filtration, (2) water hyacinths, copper ion disinfection, and sand filtration, (3) copper ion disinfection and sand filtration, (4) copper/silver ion disinfection and sand filtration, and (5) 20–μm cartridge filtration. Water quality parameters measured were fecal and total coliform indicator bacteria, nitrates, suspended solids, and turbidity. Reductions in bacterial concentration, suspended solids and turbidity were achieved by all systems tested. Treatment reduced nitrate concentrations to an average of 2.6 mg/liter. Reductions in suspended solids, and turbidity were influenced more by the quality of the graywater entering the treatment system than the efficiency of the systems themselves. The water hyacinths and sand filtration system provided the best graywater quality in terms of the concentrations of fecal indicator bacteria. The system providing the best water quality in regard to average suspended solids after treatment was the water hyacinths, copper ion, and sand filtration system, and the best average turbidity was achieved by the copper/silver ion generating unit with sand filtration. All systems were capable of significant reductions in fecal indicator bacteria, suspended solids, and turbidity; however, additional treatment or disinfection would be necessary to further reduce the level of coliform and fecal coliform bacteria to achieve regulatory standards in the State of Arizona.     

WATER QUALITY ANALYSIS OF THE HALIFAX RIVER,FLORIDA1

ABSTRACT: An application of the receiving water block of the EPA Storm Water management Model (SWMM) is presented to quantify water quality impacts and evaluated control alternatives for a 208 areawide waste water management plan in Volusia Country, Florida. The water quality impact analyses were conducted for dry-and wet-weather conditions to simulate dissolved oxygen (DO), chlorides, total nitrogen (TN), and total phosphorus (TP) in the Halifax Rivers, Florida, a 40-kilometer-long tidal estuary located on the Atlantic coast of Florida near Daytona Beach. Dry-weather analysis was performed using conventional 7-day, 10-year low flow conditions to determine a set of unit transfer coefficients which estimate the pollutant concentration transferred to any point in the estuary from a constant unit discharge of pollutants at the existing waste water treatment plant outfall locations. Wet-weather analysis was performed by continuous simulation of a typical three-month summer wet season in Florida. Three-month cumulative duration curves of DO, TN and TP concentrations were constructed to estimate the relative value of controlling urban runoff of waste water treatment plant effluent on the Halifax River. The three-month continuous simulation indicated that the greatest change in DO, TN, and TP duration curves is possible by abatement of waste water treatment plant pollution.     

Applications of Turbidity Monitoring to Forest Management in California

Many California streams have been adversely affected by sedimentation caused by historic and current land uses, including timber harvesting. The impacts of timber harvesting and logging transportation systems on erosion and sediment delivery can be directly measured, modeled, or inferred from water quality measurements. California regulatory agencies, researchers, and land owners have adopted turbidity monitoring to determine effects of forest management practices on suspended sediment loads and water quality at watershed, project, and site scales. Watershed-scale trends in sediment discharge and responses to current forest practices may be estimated from data collected at automated sampling stations that measure turbidity, stream flow, suspended sediment concentrations, and other water quality parameters. Future results from these studies will provide a basis for assessing the effectiveness of modern forest practice regulations in protecting water quality. At the project scale, manual sampling of water column turbidity during high stream flow events within and downstream from active timber harvest plans can identify emerging sediment sources. Remedial actions can then be taken by managers to prevent or mitigate water quality impacts. At the site scale, manual turbidity sampling during storms or high stream flow events at sites located upstream and downstream from new, upgraded, or decommissioned stream crossings has proven to be a valuable way to determine whether measures taken to prevent post-construction erosion and sediment production are effective. Turbidity monitoring at the project and site scales is therefore an important tool for adaptive management. Uncertainty regarding the effects of current forest practices must be resolved through watershed-scale experiments. In the short term, this uncertainty will stimulate increased use of project and site-scale monitoring.     

EFFECTS OF LAND USE AND TOPOGRAPHY ON SOME WATER QUALITY VARIABLES IN FORESTED EAST TEXAS1

ABSTRACT: Spatial variation of five water quality variables were analyzed using composite water samples collected periodically from eight small watersheds (11.4–71.6 km²) in forested East Texas during 1977 through 1980. Based on 31 observations during the four-year period the average yield of nitrate-nitrite nitrogen (NNN), total kjeldahl nitrogen (TKN), total phosphorus (PO4), chloride (CHL), and total suspended sediment (TSS) were 1.43, 21.96, 3.09, 50.11, and 90.39 ka/ha/yr, respectively. Compared to the water quality standards of the U.S. Environmental Protection Agency (1976) and the Texas Department of Water Resources (1976) for CHL, TSS, and NNN, none of the observations exceeded the limits for public water supplies. The study showed that forested watersheds normally yielded stream flow with better quality than that from agricultural watersheds. Watersheds of greater percent of pasture area, mean slope, stream segment frequency, and drainage density produced greater concentrations for these five chemical parameters in water samples. Meaningful equations were developed for estimating mean average yields for each chemical parameter for each watershed with R² ranging from 0.77 to 0.96 and standard error of estimates from 17 to 33 percent of the observed means.     

SEDIMENT RESUSPENSION AND DRAWDOWN IN A WATER SUPPLY RESERVOIR1

ABSTRACT: The magnitudes and patterns of sediment resuspension are assessed in Cannonsville Reservoir, New York, to quantify and characterize this internal source of sediment. The assessment is based on analyses of sediment trap collections from 10 sites over the spring to fall interval of two years. Temporal and spatial patterns in sediment deposition are demonstrated to be driven by resuspension/redeposition processes. Sediment that had been resuspended and redeposited represented 80 to 96 percent, on average, of the depositing solids collected along the main axis of the lake. About 90 percent of the redeposited sediment was inorganic. Increased resuspension caused by drawdown of the reservoir surface and fall turnover resulted in 10 to 50‐fold increases in deposition rates compared to levels observed when the reservoir was full and strongly thermally stratified. Elevated levels of redeposition from resuspension in the reservoir have been driven by both higher water column concentrations of suspended solids and settling velocities. Recurring longitudinal and lateral gradients in resuspension are delineated, establishing that resuspended solids are transported from the riverine to the lacustrine zone and from near‐shore to pelagic areas. Resuspension is demonstrated to cause increases in inanimate particle (tripton) concentrations. Higher tripton levels have been observed in years with greater drawdown. Water quality impacts of the resuspension phenomenon are considered.