Spatial–temporal variation and comparative assessment of water qualities of urban river system: a case study of the river Bagmati (Nepal)

The study presents the assessment of variation of water qualities, classification of monitoring networks and detection of pollution sources along the Bagmati River and its tributaries in the Kathmandu valley of Nepal. Seventeen stations, monitored for 23 physical and chemical parameters in pre-monsoon, monsoon, post-monsoon and winter seasons, during the period 1999-2003, were selected for the purpose of this study. The study revealed that the upstream river water qualities in the rural areas were increasingly affected from human sewage and chemical fertilizers. In downstream urban areas, the river was heavily polluted with untreated municipal sewage. The contribution of industries to pollute the river was minimal. The higher ratio of COD to BOD (3.74 in the rural and 2.06 in the urban) confirmed the increased industrial activities in the rural areas. An increasing trend of nitrate was found in the rural areas. In the urban areas, increasing trend of phosphorus was detected. The water quality measurement in the study period showed that DO was below 4 mg/l and BOD, COD, TIN, TP and TSS above 39.1, 59.2, 10.1, 0.84 and 199 mg/l, respectively, in the urban areas. In the rural areas, DO was above 6.2 mg/l and BOD, COD, TIN, TP and TSS below 15.9, 31, 5.24, 0.41 and 134.5 mg/l, respectively. The analysis for data from 1988 to 2003 at a key station in the river revealed that BOD was increasing at a rate of 1.8 mg/l in the Bagmati River. A comparative study for the water quality variables in the urban areas showed that the main river and its tributaries were equally polluted. The other comparison showed the urban water qualities were significantly poor as compared with rural. The cluster analysis detected three distinct monitoring groups: (1) low water pollution region, (2) medium water pollution region, (3) heavy water pollution region. For rapid assessment of water qualities using the representative sites could serve to optimize cost and time without loosing any significance of the outcome. The factor analysis revealed distinct groups of sources and pollutions (organics, nutrients, solutes and physicochemical).     

Variations in seasonal phytoplankton assemblages as a response to environmental changes in the surface waters of a hypo saline coastal station along the Bhagirathi�CHooghly estuary

Due to the close proximity of the Bay of Bengal and the freshwater inflow of Bhagirathi-Hooghly, Diamond Harbour appeared as an important coastal station of the Bhagirathi-Hooghly estuary. The spatial and temporal composition and abundance of microphytoplankton species was examined in relation to physical and chemical surface water variables (i.e., salinity, nutrient, and temperature).The primary objective of the study was to observe the variations in phytoplankton species assemblages as a response to environmental variables. Hierarchical cluster analysis and non-metric multidimensional scaling were used to find out distinct seasonal groups based on the composition of phytoplankton. The results indicate that several key environmental factors like temperature, DIN content, and molar ratio of nutrients like DIN-DIP and DIN-DSi influenced seasonal phytoplankton assemblages within the estuary. The distribution of phytoplankton population showed two main groups where the blue-green and green algal populations favored the warmer conditions of summer and monsoon months, whereas the diatom population primarily flourished in the cooler months of autumn and winter.     

Genotoxicity screening of the river Rasina in Serbia using the Allium anaphase–telophase test

Evaluation of the presence of genotoxic substances is especially important in rivers that serve as a source of drinking water. Nine water samples collected along the river Rasina in Serbia were analyzed for potential toxic and genotoxic effects using the Allium anaphase-telophase test. Inhibition of root growth relative to the negative control (synthetic water) was observed in all samples. Analysis of the genotoxic potential, through scoring anaphase and telophase aberrations, showed that in seven of the nine samples the level of aberrations was significantly increased relative to the negative control but was lower than that obtained for the positive control (methyl methanesulfonate). Changes in the relation between spindle and chromosome types of aberrations were found in some samples, indicating differences in the potential genotoxic substances present at the analyzed sites. The data, which were obtained from samples collected at the highest level of river water, warn that during periods of low flow the values could reach genotoxic activity. The Allium anaphase-telophase test can be recommended as an monitoring system, that can serve as the first alert for the presence of genotoxic environmental pollutants.     

Assessment of land cover changes & water quality changes in the Zayandehroud River Basin between 1997–2008

Water quality of rivers is strongly influenced by landscape characteristics of their watershed, including land use /cover types, and their spatial configuration. This research evaluates the effects of land cover changes on the water quality of the Zayandehroud River, which is the most important river in the center of Iran. The main goal of this study was to quantify the change in rangelands, forests, and bare lands in the Zayandehroud river basin, which suffered intense human interference, in a period of 11 years (1997–2008), and to evaluate how landscape patterns (including the number of patches, edge density, percentage of rangelands, forests, and bare lands) influence on the 14 water quality indices (including BOD5, EC, NO3, P, and TDS) measured in 10 stations along the river. Results showed that from 1997 to 2008, bare lands increased from 5.8 to 20 %, while rangelands decreased from 70 to 55 % in the whole basin. The results indicated that water quality was significantly correlated with both the proportions and configuration of rangeland and bare land areas. The total edge (TE) of rangeland area had positive effects on water quality, especially on BOD5 and EC. Percentage of landscape (PLAND) and largest patch index (LPI) metrics of rangeland had positive effect on decreasing nutrient (NO₃, PO₄). The results showed that water quality was more likely degraded when there was high edge density (ED) of bare lands. Results of this study also revealed that degradation of rangeland lead to the degradation of water quality. Finding of this study highlights the importance of rangeland conservation in water quality management at landscape scale.     

Analysis of long-term water quality for effective river health monitoring in peri-urban landscapes—a case study of the Hawkesbury–Nepean river system in NSW, Australia

The Hawkesbury–Nepean River (HNR) system in South-Eastern Australia is the main source of water supply for the Sydney Metropolitan area and is one of the more complex river systems due to the influence of urbanisation and other activities in the peri-urban landscape through which it flows. The long-term monitoring of river water quality is likely to suffer from data gaps due to funding cuts, changes in priority and related reasons. Nevertheless, we need to assess river health based on the available information. In this study, we demonstrated how the Factor Analysis (FA), Hierarchical Agglomerative Cluster Analysis (HACA) and Trend Analysis (TA) can be applied to evaluate long-term historic data sets. Six water quality parameters, viz., temperature, chlorophyll-a, dissolved oxygen, oxides of nitrogen, suspended solids and reactive silicates, measured at weekly intervals between 1985 and 2008 at 12 monitoring stations located along the 300 km length of the HNR system were evaluated to understand the human and natural influences on the river system in a peri-urban landscape. The application of FA extracted three latent factors which explained more than 70 % of the total variance of the data and related to the ‘bio-geographical’, ‘natural’ and ‘nutrient pollutant’ dimensions of the HNR system. The bio-geographical and nutrient pollution factors more likely related to the direct influence of changes and activities of peri-urban natures and accounted for approximately 50 % of variability in water quality. The application of HACA indicated two major clusters representing clean and polluted zones of the river. On the spatial scale, one cluster was represented by the upper and lower sections of the river (clean zone) and accounted for approximately 158 km of the river. The other cluster was represented by the middle section (polluted zone) with a length of approximately 98 km. Trend Analysis indicated how the point sources influence river water quality on spatio-temporal scales, taking into account the various effects of nutrient and other pollutant loads from sewerage effluents, agriculture and other point and non-point sources along the river and major tributaries of the HNR. Over the past 26 years, water temperature has significantly increased while suspended solids have significantly decreased (p?<?0.05). The analysis of water quality data through FA, HACA and TA helped to characterise the key sections and cluster the key water quality variables of the HNR system. The insights gained from this study have the potential to improve the effectiveness of river health-monitoring programs in terms of cost, time and effort, particularly in a peri-urban context.     

Identification of the hydrogeochemical processes in groundwater using major ion chemistry: a case study of Penna–Chitravathi river basins in Southern India

Hydrogeochemical studies were carried out in the Penna–Chitravathi river basins to identify and delineate the important geochemical processes which were responsible for the evolution of chemical composition of groundwater. The area is underlain by peninsular gneissic complex of Archaean age, Proterozoic meta-sediments, and strip of river alluvium. Groundwater samples were collected covering all the major hydrogeological environs in pre- and post-monsoon seasons. The samples were analyzed for major constituents such as Ca^2?+?, Mg^2?+?, Na^?+?, K^?+?, CO₃ ^???, HCO₃ ^???, Cl^???, SO₂ ^???4, NO₃ ^???, and F^???. The groundwater in general is of Na^?+?–Cl^???, Na^?+?–HCO₃ ^???, Ca^2?+?–Mg^2?+?–HCO₃ ^???, and Ca^2?+?–Mg^2?+?–Cl^??? types. Na^?+? among cations and Cl^??? and/or HCO₃ ^??? among anions dominate the water; Na^?+? and Ca^2?+? are in the transitional state with Na^?+? replacing Ca^2?+? and HCO₃ ^??? Cl^??? due to physiochemical changes in the aquifer and water–rock interactions. The Ca^2?+?–Mg^2?+?–Cl^??? HCO₃ ^??? type water in one third samples suggest that ion exchange and dissolution processes are responsible for its origin. Change in storage of aquifer in a season does not influence the major geochemical makeup of groundwater. Gibbs plots indicate that the evolution of water chemistry is influenced by water–rock interaction followed by evapotranspiration process. The aquifer material mineralogy together with semiarid climate, poor drainage system, and low precipitation factors played major role in controlling groundwater quality of the area.     

Assessment of the redistribution of soil carbon using a new index—a case study in the Haihe River Basin,North China

Soil carbon redistribution is an important process in the terrestrial carbon cycle. This study describes a new index, soil carbon redistribution (SCR) index, that can be used to assess long-term soil carbon redistribution at a large watershed scale. The new index is based on the theoretical preconditions that soil carbon redistribution is mainly controlled by vegetation type, precipitation, topography/slope, and soil carbon concentration. The Haihe River Basin served as an example for this analysis. The SCR index was calculated, and a GIS-based map shows its spatial patterns. The results suggested that soil carbon was usually prone to being carried away from mountainous regions with natural vegetation, while it was prone to deposition in the plain and plateau regions with cultivated vegetation. The methods in the paper offer a tool that can be used to quantify the potential risk where soil carbon is prone to being carried away and deposited in a large watershed.     

Determining recreational, scenic, and historical–cultural potentials of landscape features along a segment of the ancient Silk Road using factor analyzing

Generally, roads are structures connecting areas of special importance to each other (e.g., from urban areas to villages). In addition to functioning as transportation mediums, roads have aesthetic qualities by means of their recreational, scenic, and cultural functions. One of these unexplored roads, the Trabzon–Gümü?hane old state highway in the Northeast Turkey, the subject of this study, is quite unique for being a part of the historical Silk Road. The aim of the study is to determine the recreational, scenic, and cultural potentials of this road and to identify the landscape qualities based on these potentials. After dividing the road into three sections for comparison purposes, data gathered from basic digital maps obtained from The General Directorate of Rural Services (the governmental agency that is responsible for producing such digital maps) and field trips were entered into maps using geographic information system followed by creating demonstration films using photographs and video camera images of the natural and cultural characteristics of the area. Then, these films were evaluated by an expert team to identify the road’s recreational, scenic, and cultural potentials. The results of the evaluation process, the relationships between determined landscape characteristics for each function, and the contribution scores of different functions assigned for the artificial features were statistically analyzed. The analyses showed a very strong relationship between the sections and the contribution scores of the recreation and the scenic functions. The results of these analyses also revealed some landscape characteristics having high contribution values for all the functions. This, in turn, helped in determining a potential of the study area to become a greenway.     

Comparison of environmental flow assessment methods with a case study on a runoff river–type hydropower plant using hydrological methods

This paper focuses on the environmental flow assessment (EFA) methods that maintain the river ecosystem and its integrity for hydropower plants (HPP) with their implementations on a run-off river type HPP. EFA is a crucial phenomenon in terms of electricity production and sustaining river integrity simultaneously. The novelty of this study is that it consists both a comparison of widely used preferred EFA methods and a detailed investigation of the river with pre and post-dam flow regimes. The research shows that by expanding the content and scope of the methods, their relative reliabilities increase. However, this situation requires much more expert, money, and time. Apart from most of the relevant literature, pre and post-dam situations are investigated with a flow duration curve (FDC). It is concluded that the dramatic difference between the flow characteristics of pre and post-dam situations affects long-term aquatic life. Furthermore, a case study is conducted using the selected hydrological flow assessment methods, Tennant and Tessman methods, and comparisons are made. The calculated flows are compared with monthly average flow values before dam construction, projected environmental flow data, and the current situation. Accordingly, Tennant’s “good classification” is proposed to determine the environmental flow (EF) for the considered case study.     

Assessment of benthic changes during 20 years of monitoring the Mexican Salina Cruz Bay

In this work a non-parametric multivariate analysis was used to assess the impact of metals and organic compounds in the macro infaunal component of the mollusks benthic community using surface sediment data from several monitoring programs collected over 20 years in Salina Cruz Bay, Mexico. The data for benthic mollusks community characteristics (richness, abundance and diversity) were linked to multivariate environmental patterns, using the Alternating Conditional Expectations method to correlate the biological measurements of the mollusk community with the physicochemical properties of water and sediments. Mollusks community variation is related to environmental characteristics as well as lead content. Surface deposit feeders are increasing their relative density, while subsurface deposit feeders are decreasing with respect to time, these last are expected to be more related with sediment and more affected then by its quality. However gastropods with predatory carnivore as well as chemosymbiotic deposit feeder bivalves have maintained their relative densities along time.     

Assessment of organic pollution of an industrial river by synchronous fluorescence and UV–vis spectroscopy: the Fensch River (NE France)

To rapidly monitor the surface water quality in terms of organic pollution of an industrial river undergoing restoration, optical methods (UV–visible spectrometry and fluorescence) were applied in parallel to classical physical–chemical analyses. UV–visible spectra were analyzed using the maximum of the second derivative at 225 nm (related to nitrates), specific absorbance at 254 nm (SUVA₂₅₄), and the spectral slope between 275 and 295 nm (S _275–295) (related to the aromaticity and molecular weight of dissolved organic carbon). The synchronous fluorescence spectra (wavelength difference = 50 nm) exhibited a high variability in the composition of dissolved organic material between the upstream and downstream sections and also versus time. The principal components analysis of the entire set of synchronous fluorescence spectra helped to define three river sections with different pollution characteristics. Spectral decomposition was applied to the two most upstream sections: five fluorophores, classical in rivers impacted by domestic sewage and related to protein-like (λ _ex = 280 nm) and humic-like fluorescence (M-type with λ _ex ≈ 305–310 nm and C-type with λ _ex ≥ 335 nm), were identified. The irregular shape of the synchronous fluorescence spectra in the most downstream section is likely due to organic pollutants of industrial origin; however, their variability and the complexity of the spectra did not allow the further elucidation of their nature.     

Heavy metal enrichment in the soil along the Delhi–Ulan section of the Qinghai–Tibet railway in China

The pollutants that are discharged from roads and traffic have attracted much attention recently. Nonetheless, most studies have mainly focused on highways and seldom on railways. In this study, soil samples were selected at the embankment and perpendicularly at different distances (2, 5, 10, 20, 30, 50, 60, 70, 80, 100, and 150 m) from the embankment bottom of the Qinghai–Tibet railway. Furthermore, soils were selected at four soil depths (5, 10, 20, and 30 cm) of each sample at the flat. The enrichment of nine heavy metals (V, Cr, Co, Ni, Cu, Zn, Rb, Cd, and Pb) in soils along the Delhi–Ulan section of the Qinghai–Tibet railway was studied. The results indicated that the mean concentrations of Cr, Ni, Cu, Zn, Pb, and Cd were highest at the embankment. The Cu concentrations in soils decreased by an S-curve-shaped function with increasing distance from the embankment, while Cd, Pb, and Zn decreased by inverse functions (p?<?0.0001). The concentrations of other studied metal did not show significant changes with increasing distance. After performing a statistical analysis, Pb, Cd, and Zn in soils were considered to be influenced by railway operations. However, the influence was weak and only spanned less than 5 m from the bottom of the embankment horizontally and 10 cm from the surface vertically. The mean concentrations of heavy metals in soils along the Delhi–Ulan section of the Qinghai–Tibet railway were considered lower compared with those along other railways.     

An Assessment of the Ecological Condition of Long Island Sound, 1990–1993

Data from the Environmental Protection Agency's (EPA) Environmental Monitoring and Assessment Program (EMAP) from 1990 to 1993 were used to assess the condition of the Long Island Sound (LIS) estuary. Ambient water, sediment and biota were collected during the summer months from 53 LIS stations using an unbiased sampling design. The design consists of two LIS subunits, LIS proper, and small estuaries (<2.6 km2) at the margins of the Sound. Selected indicators of condition included: benthic species composition, abundance and biomass; fish species composition and gross external pathology; sediment physical and chemical characterization and sediment toxicity; and water clarity and quality. Results of the four-year sampling indicated that 28(±11)% of the areal extent of LIS proper had a benthic index < zero (impacted) and 51(±12)% of the area of small estuaries was impacted. Analysis of the results of other indicators also shows that small estuaries were particularly affected. For example, 42(±10)% of the areal extent of small estuaries exhibited sediment toxicity, and significant chemical contamination was evident in 22% of the area of small estuaries. Low dissolved oxygen (D.O.) concentrations (<5 ppm), however, appeared to affect only the deeper open waters of western LIS. Approximately 48(±12)% of the areal extent of LIS proper documented exposure to at least moderate D.O. stress (<5 ppm). The overall results of this monitoring study indicate that significant anthropogenic impacts have occurred in LIS and that if remediation was to take place, specific localized sediment problems would need attention. Point source and non-point source nutrient inputs to the Sound, which are believed to be the primary causative factor for the observed hypoxic conditions, would also need attention.     

The value of the environment – Is it a matter of approach?

This paper discusses why estimates of the benefits of reduced air pollution differ in accordance with the approach used. Estimates based on bottom-up studies of the damage costs related to air pollution usually turn out much lower than estimates based on assessments of the utility of reduced air pollution, obtained for instance by willingness to pay assessments. This is usually explained by the fact that the willingness to pay approach includes the utility aspect of non-market values, and for this reason, it is often preferred to the damage cost approach. This is, however, not the whole story. The paper shows why alternative approaches should not be considered as being in conflict, but rather as means to get supplementary information necessary to put a value on environmental quality. Information from bottom-up assessments of damage costs and from studies of the willingness to pay is used in a macroeconomic model to carry out an evaluation of the social costs of energy saving measures in Hungary.     

Assessment of dietary intakes of nineteen pesticide residues among five socioeconomic sections of Hyderabad—a total diet study approach

Total diet study approach was used to assess the dietary intakes of pesticide residues among the select population in Hyderabad. When assessed by a food frequency questionnaire, it was found that the food intakes varied among five socioeconomic sections (SES). Therefore, we intended to compare the intakes of pesticide residues through these foods among the five SES. A total of 195 foods from different markets were collected and analyzed for 19 pesticides. The residues were analyzed with a gas chromatograph and were confirmed with mass spectrometry. About 51 % of the samples were detected with one or more residues. Thirteen out of the 19 residues were present in levels above detection limits in various concentrations. The median concentrations of the residues in all the samples tested, ranged from 0.00010 to 0.33 mg/kg. Highest median concentration was for β-HCH in water samples. Exposures to all the residues were below the respective ADIs at both mean and 95th percentile levels of food intakes with highest estimated dietary intakes (EDIs) of β-HCH in both the cases. The EDIs of β-HCH were the highest among all the residues at both the intake levels among all the SES. The EDIs of β-HCH were significantly higher in lower SES than higher SES possibly due to the consumption of rice cooked in water contaminated with β-HCH. EDIs for other residues did not differ significantly among the five SES.     

The validation analysis of the INSHORE system��a precise and efficient coastal survey system

Government and environmental entities are becoming increasingly concerned with qualifying and quantifying the erosion effects that are observed in sandy shores. Correspondingly, survey methodologies that gather data for such erosion studies are increasingly being demanded. The responsible entities are continually broadening their areas of interest, are concerned in the establishment of regular monitoring programmes and are demanding high accuracy from the geo-spatial data that is collected. The budget available for such monitoring activities, however, does not parallel the trend in the increasing demand for quality specifications. Survey methodologies need improvement to meet these requirements. We have developed a new land-based survey system--the INSHORE system--that is ideal for low cost, highly efficient and highly precise coastal surveys. The INSHORE system uses hi-tech hardware that is based on high-grade global positioning system (GPS) receivers and a laser distance sensor combined with advanced software algorithms. This system enables the determination of the ground coordinates of the surveyed areas with a precision of 1 to 2 cm, without having a sensor in contact with the ground surface. The absence of physical contact with the ground makes this system suitable for high-efficiency surveys. The accuracy of the positioning, which is based on advanced differential GPS processing, is enhanced by considering the estimated attitude of the GPS receiver holding structure and eliminates undesirable offsets. This paper describes the INSHORE survey system and presents the results of validation tests that were performed in a sandy shore environment.     

Effect of water quality parameters on the distribution of Pleuromamma (Copepoda–Calanoida) species in the Indian Ocean: a statistical approach

The region between 10 degrees N and 10 degrees S latitude was known to be congenial for distribution of Pleuromamma species. Diel and ontogenetic migrations were observed for Pleuromamma xiphias. Multivariate analyses such as factor analysis on species' abundance and predictive step-up multiple regression models of water quality parameters: temperature, salinity, dissolved oxygen and their first order interaction effects on Pleuromamma species' abundance, were carried out in the regions, off 10 degrees N, 10 degrees N to 10 degrees S, 10 degrees S to 30 degrees S, along the Somali Coast (38 degrees S-40 degrees S) and a fifth region along the western boundary of the above four regions. Relation between Pleuromamma species' abundance and the water quality parameters showed a decreasing trend in the variability explained (VE) from region 1 (VE = 55.19%) to region 4 (VE = 31.15%) in the models, indicating that the influence of other ecological factors was of higher significance in the south than in the north, with a north south gradient. Indices of diversity (Shannon-Weaver) and evenness (Heips) were calculated and lognormal distributions fitted for these indices were found to be a good fit (p < 0.05). The five regions were compared, based on critical ratio of the diversity index. Shannon-Weaver diversity showed higher values during night collections than day collections, justifying the tendency for diurnal variations. Diversity and dominance were highly (r = 0.95) correlated. A multilinkage cluster analysis by group averaging method for the species, based on the standardised values of log(10) (X + 1) transformed species' abundance, showed that Pleuromamma indica, Pleuromamma gracilis and Pleuromamma abdominalis were not segregated in any of the five regions. Bray and Curtis (1957) coefficient of similarity for the species in the five regions combined together, showed 50% similarity for the cluster containing circum-global species, Pleuromamma piseki, P. gracilis, P. abdominalis and P. borealis. The species, P. indica and P. xiphias entered this cluster at 22% similarity level. Multivariate factor analysis by row normalisation (for species) and column normalisation (for stations), using varimax rotation to simple structure for unique grouping of species as well as stations, carried out in the five regions, showed that the maximum number of species' clusters were obtained in region 2, indicating a higher variability in the ecological conditions in this region than in the other four regions. The significance of the factor model and the differential factor groups of species were also determined in the studied regions. On a broader scale, based on the ecological aspect, the first four regions could be reduced to two regions, viz, region 1 including the north off 10 degrees N, Central Indian Ocean and the area of subtropical convergence, and region 2 consisting exclusively of the equatorial region between 10 degrees N and 10 degrees S based on distribution of Pleuromamma species. The plot of the species abundance with respect to latitude also showed such a demarcation.     

The orientation of water quality variation from the metropolis river–Huangpu River, Shanghai

The Huangpu River supplies eighty percent of daily water used for life and industry for about 20 million people in Shanghai, China. Industry and human sewerage from the metropolis is mainly released into the Huangpu River, which flows past the Shanghai city area. The pollution caused by city life and production in the Huangpu River has occurred for years. In this paper, the contents of heavy metals (Cu, Pb, Cr, Cd, and Hg), total organic carbon (TOC), and polynuclear aromatic hydrocarbons (PAHs) in the Huangpu River are discussed. Data from environmental monitoring from 1991 to 2002 are compared to understand the variation and trends of the pollution. Results indicate that metals have been reduced efficiently, but organic pollutants develop in aggravating trend as human sewage increase. The variation of the organic pollutant concentration, which are lower than other similar river's of China, US, and Canada, in the Huangpu River suggests that the organic pollution maybe a problem of water quality evolvement in metropolis river protection, which should be accentuated in the world today.