水质在线监测中的若干问题

以环境水质自动监测子站的采样和配水系统为切入点，针对不同环节上极易出现的问题，分别提出具体的解决方案。     

天津水质自动监测通讯系统—电源易损及信息传输

本文对引进的天津水自动监测系统在运行期间，通讯系统出现的故障作了全面的剖析研究，并提出了解决这些问题的方法。     

广东省水质自动监测的现状及发展规划

介绍了广东省在东江、小东江、珠江、北江、武江、九洲江和顺德水道7个江河流域设立了7个水质自动监测站，控制流域面积约57093km^2。“十五”期间每年建成1－2个省界断面和3－4个地级市界断面，形成全省的水质自动监测网络。     

天津市环境监测中心大气监测部

正大气监测部是天津市环境监测中心骨干业务部门之一,业务范围涉及环境空气质量监测与评价;环境空气常规监测;环境空气自动监测系统运行维护管理;空气质量日报、预报与预警发布;计算机网络安全管理与维护;环境监测信息系统规划与管     

我国湖泊生态环境变化监测网络的发展构想—以太湖生态站为例

以太湖生态站为例,从指标体系、数据分析、组织结构、网络共享与服务等方面阐述了我国湖泊生态环境监测网络建立与发展的构想。     

天津水质自动监测通讯系统─—电源易损及信息传输

本文对引进的天津水质自动监测系统在运行期间，通讯系统出现的故障作了全面的剖析研究，并提出了解决这些问题的方法。     

长江干流近三十年来水质变化探析

本文根据我国水利部水文年鉴中的水质监测资料和全球水质监测计划中长江站的水质监测资料,对长江干流六十至八十年代水质变化的三个问题：河水碱度降低及Ｃａ＾２＋和ＳＯ＾２－４含量增高与环境酸化的关系;     

垃圾焚烧装置连续排放监测

TA Luft 1986,即1986年空气污染控制技术指南,描述了德国排放监测的基本要求。本文讨论了主要污染物的排放测定设备和手工基准方法的技术现状。具有特殊意义的是用计算机获得每天监测记录的自动数据评价。     

近30年来黄河水质变化趋势及原因分析

根据我国水利部水文年鉴黄河监测站及全球水质监测计划中国济南站的水化学资料,对黄河流域４４个主要水文站自六十年代以来河水水质进行了分析研究。结果发现黄河流域河水各主要离子及离子总量有缓慢增长趋势。     

广州地区稻田甲烷排放连续自动监测

本文介绍了采用甲烷自动采集及分析测量系统在广州地区进行稻田甲烷排放通量监测的试验设计。     

能源植物黄连木油脂及其脂肪酸含量的地理变化规律

为更好地开发利用生物柴油木本能源植物黄连木（Pistacia chinensis Bunge）,研究了其油脂及其脂肪酸质量分数的地理变化规律。结果表明,黄连木果实与种子油脂质量分数随着地理经度和纬度的增加而降低,果肉油脂质量分数随着地理经度的增加而升高,而其纬向变化不显著。黄连木油脂中的脂肪酸有棕榈酸（C16：0）、油酸（C18：1）、亚油酸（C18：2）、棕榈油酸（C16：1）、硬脂酸（C18：0）、亚麻酸（C18：3）、花生酸（C20：4）等7种,其碳链长度集中在C16～C18之间,非常适合用来生产生物柴油。棕榈酸质量分数随着地理经度和纬度的增加而升高;油酸质量分数随着地理纬度的增加而降低,而其经向变化不显著;亚油酸质量分数随着地理经度的增加而降低,随着地理纬度的增加而升高;棕榈油酸质量分数随着地理纬度的增加而升高,而其经向变化不显著;硬脂酸和亚麻酸质量分数随着地理经度和纬度的增加而降低;花生酸质量分数随着地理经度的增加而降低,而其纬向变化不显著。     

Differential sperm expenditure by male sailfin mollies, Poecilia latipinna, in a unisexual–bisexual species complex and the influence of spermiation during mating

Selection should favor strategies that reduce costs associated with spermatogenesis. This is especially true when males are sympatric with closely related species, and must avoid heterospecific matings, as in the unisexual–bisexual species complex of mollies. Male sailfin mollies, Poecilia latipinna, are sexually parasitized by Amazon mollies (P. formosa), and produce more sperm in the presence of female sailfin mollies than in the presence of Amazon mollies. We tested the hypothesis that male sailfin mollies differentially expend sperm when mating with either conspecific or heterospecific females. We measured sperm expenditure by determining the amount of sperm males have remaining after mating. Male sailfin mollies had more sperm available after mating with female sailfin mollies than after mating with Amazon mollies. While this result could indicate higher sperm expenditure to Amazon mollies, males mating with female sailfin mollies had more sperm available after mating than their baseline sperm reserves. Spermiation, the last stage of spermatogenesis, could be triggered by physical contact with females, and could increase sperm availability during mating. We examined the relationship between sperm availability and the amount of time that males mated with females. We found that sperm availability increased as mating trial time increased with female sailfin mollies, but not with Amazon mollies. Spermiation in the presence of conspecific female stimuli could reduce physiological costs associated with spermatogenesis while increasing the amount and quality of sperm available for sperm competition. We suggest that future studies examining sperm priming and expenditure should consider the potential for spermiation.     

致突变的致癌剂和非致癌剂在引发DNA股间交联上的显著差别

借碱洗脱法证明：具有致突变能力的致癌剂1,2－二溴乙烷和肼在经过代谢活化后,均剂理相关地引起L1210细胞中DNA的股间交联。相反,动物致癌试验表现阴性的突变剂溴乙烷,以及通过各种致癌动物试验均显示阴性的传统常用致突变剂羟胺,在代谢活化以后的同样条件下均不能引起L1210细胞中DNA的股间交联。这证明了双区理论的致癌观点,即致癌剂必须是双官能烷化剂,其同时引起互补碱对的交联将引起癌变。相反,股内单一碱基的变异则可能引起致突变作用。并用APCI／SIM（大气压化学电离／选择离子质谱）证明：1,2－二溴乙烷与DNA碱基对的模型反应,与致突实验一致主要引起G－C对的交联和发生G－C→A－T突变。     

影响雨生红球藻797株生长和虾青素积累的某些因素

研究了雨生红球藻 (Haematococcuspluvialis) 797株的N源需求和营养盐吸收 ,并利用高光强和乙酸钠处理该藻 ,研究虾青素累积情况以及超氧化物歧化酶 (SOD)活性、营养盐、细胞状态的变化 .NH+ 4 N培养的生长速率明显高于NO-3 N培养 ,平均生长速率分别为 0 .2 79d-1和 0 .190d-1.NH+ 4 N培养所消耗的N、P营养盐比NO-3 N培养的消耗少 .两种N源下强光照处理 1d和 7d均导致雨生红球藻细胞数减少而静细胞比例增加 .在虾青素合成阶段 ,藻液N含量急剧下降而P含量基本保持稳定 ,说明虾青素合成对N的需要量大而对P的需要小 .在NO-3 N培养下 ,乙酸钠的加入则对虾青素的生产无显著影响 .在NH+ 4 N培养下SOD活性下降而虾青素含量升高 ;在NO-3 N培养下SOD活性与虾青素含量同时升高 .图 2表 4参 15     

饮用水中卤乙酸和三卤甲烷的形成及影响因素研究

以浙江省钱塘江流域的七种水源水为代表，分析了前体物、pH值、投氯量、氯化时间和温度等因素对氯化消毒副产物(DBPs)中三种卤乙酸(HAAs)和三种三卤甲烷(THMs)的影响，研究表明，总有机碳(TOC)和UV-254与HAAs前体物呈正相关，而与THMs前体物的相关性较差；在pH5-10的范围内，pH值对HAAs的形成影响较小，pH值愈高HAAs总量愈小，而对THMs的形成影响较大，THMs总量随pH值的增高而增大；HAAs和THMs的形成量与投氯量、氯化时间均呈正相关；在正常气温条件下，随温度的增加而增加。     

A Large-Eddy Simulation Study of the Convective Boundary Layer over Philadelphia during the 1999 Summer NE-OPS Campaign

This study presents a large-eddy simulation (LES) study of the convective boundary layer on August 1, 1999 over Philadelphia, PA during a summer ozone episode. The study is an evaluation of the Colorado State University's Regional Atmospheric Modeling System Version 4.3 (RAMS4.3) with the LES option using Northeast Oxidant and Particulate Study (NE-OPS) data. Simulations were performed with different imposed sensible heat fluxes at the ground surface. The model was initialized with the atmospheric sounding data collected at Philadelphia at 1230 UTC and model integrations continued till 2130 UTC. The resulting mean profiles of temperature and humidity obtained from the LES model were compared with atmospheric soundings, tethered balloon and aircraft data collected during the NE-OPS 1999 field campaign. Also the model-derived vertical profiles of virtual temperature were compared with NE-OPS Radio Acoustic Sounder System (RASS) data while the humidity profiles were compared with NE-OPS lidar data. The comparison of the radiosonde data with the LES model predictions suggests that the growth of the mixing layer is reasonably well simulated by the model. Overall, the agreement of temperature predictions of the LES model with the radiosonde observations is good. The model appears to underestimate humidity values for the case of higher imposed sensible heat flux. However, the humidity values in the mixing layer agree quite well with radiosonde observations for the case of lower imposed sensible heat flux. The model-predicted temperature and humidity profiles are in reasonable agreement with the tethered balloon data except for some small overestimation of temperature at lower layers and some underestimation of humidity values. However, the humidity profiles as simulated by the model agree quite well with the tethered balloon data for the case of lower imposed sensible heat flux. The model-predicted virtual temperature profile is also in better agreement with RASS data for the case of lower imposed sensible heat flux. The model-predicted temperature profile further agrees quite well with aircraft data for the case of lower imposed heat flux. However, the relative humidity values predicted by the model are lower compared with the aircraft data. The model-predicted humidity profiles are only in partial agreement with the lidar data. The results of this study suggest that the explicitly resolved energetic eddies seem to provide the correct forcing necessary to produce good agreement with observations for the case of an imposed sensible heat flux of 0.1 K m s^–1 at the surface.     

不同有机质含量的土壤中DDT对小麦根系的生物有效性

对不同有机质含量的土壤中，分别选用水、正己烷、正己烷／丙酮混合溶剂作为DDT的提取剂，用这3种提取剂逐级连续提取，研究了这3级提取剂所提取的DDT量的差别及其与小麦根吸收的关系。结果表明，有机氯的水提取量随土壤D0c的增加而上升，正己烷提取量随土壤TOC的增加而下降，正己烷／丙酮提取量随土壤TOC的增加而上升。根吸收与水提取量没有确定的关系，但与正己烷提取量具正相关关系，与正己烷／丙酮提取量有负相关关系。     

保护性耕作对潮土结构特性的影响

研究不同保护性耕作措施对潮土结构特性的影响,探求不同秸秆还田方式下土壤结构的变化规律.以河北省石家庄市栾城县长期定位试验为研究基础,采用了传统翻耕、翻耕秸秆还田、旋耕秸秆还田、免耕覆盖还田、免耕立秆还田和免耕粉碎还田6种处理,分别对不同耕层的土壤容重、有机碳含量、团聚体及有机无机复合体进行了测定,对比分析了不同保护性耕作对潮土结构特性的影响.结果表明:免耕覆盖还田的土壤容重值最低;干筛情况下,免耕秸秆覆盖还田的MWD值显著高于其它处理30.4%～47.4%,而湿筛情况下,免耕立秆还田与粉碎还田MWD值高于其它处理;立秆还田的土壤分散系数最低,而粉碎还田的分散系数比其它处理高20.48%～330.93%;翻耕处理的原土复合量、原土复合度分别高于免耕处理10.82%～21.62%、8.97%～20.97%.不同秸秆还田方式对土壤结构稳定性的影响有很大差异:覆盖还田能改善田间土壤结构;立秆还田能提高微团聚体的稳定性;粉碎还田通过增加土壤有机碳含量而增加水稳性大团聚体的含量.     

缓释微胶囊EDTA强化玉米提取土壤中铅铜的效应研究

将EDTA转化成具有缓释性能的微胶囊EDTA（Cap-EDTA）作为螯合剂,采用大宝山矿区周边重金属复合污染农田土壤进行重金属连续批浸提及盆栽试验,比较研究Cap-EDTA和未微胶囊化EDTA（Ncap-EDTA）对土壤铅铜活化的动态变化及其对玉米吸收提取铅铜的影响。结果表明：Cap-EDTA处理土壤溶液中初始增溶的铅铜质量分数显著低于Ncap-EDTA处理,且使土壤溶液中的铅铜质量分数长时间持续保持在适度范围内。添加Cap-EDTA的处理显著提高玉米吸收提取铅铜的效率,如实施3 mmol·kg-1的Cap-EDTA使玉米地上部Pb的积累高达1.26 mg·pot-1,是对照处理的1.9倍,是等量Ncap-EDTA处理的1.4倍。因此,在进行污染土壤植物修复的EDTA调控时,采用微胶囊化EDTA,能降低因直接实施EDTA而带来的污染地下水风险,且显著提高玉米修复效率。     

土壤与酸的反应时间对土壤酸度及土壤溶液中铝离子形态分布的影响

用两种土壤研究土壤与酸的反应时间对土壤酸度及土壤溶液中铝离子形态分布的影响。结果表明,土壤溶液pH随反应时间增加而增加,安徽红壤pH的增幅大于江西红壤。在pH3.0的HNO3溶液中,土壤溶液中的总铝及Al3 均随反应时间增加而减少,而在pH3．5的HNO3溶液中,土壤溶液中总铝及Al－F络合物先随反应时间的增加而减小．然后又有所增加。