SENSORY RESEARCH FOR THE ESTABLISHMENT OF SECONDARY MAXIMUM CONTAMINANT LEVELS1

ABSTRACT: Individuals naturally engage in sensory evaluation of water quality during daily consumption. Efforts to ensure that all consumers receive high quality water must attend to sensory evaluation; otherwise individuals can obtain repeated evidence of compromised quality that reduces confidence in public purveyors and regulating agencies. Sensory quality is currently regulated by the United States Environmental Protection Agency (USEPA) by promulgation of secondary maximum contaminant levels (SMCLs) governing taste and odor in drinking water. Efforts to establish new SMCLs for identified organic contaminants has been thwarted by a lack of research data even though standardized methods for sensory evaluation presently exist. The present paper recommends a broad based national research program designed to produce odor detection thresholds, flavor detection thresholds, flavor acceptability functions, flavor recognition thresholds, and flavor intensity functions for each current contaminant of concern which will provide a substantial basis for the desired SMCLs, and offer an unprecedented comparative evaluation of currently standardized sensory evaluation procedures.     

农村水源地水质重金属健康风险评估研究

介绍了饮用水水源地中基因毒物质和躯体毒物质所致的健康危害的风险度计算模型,并根据雅安市雨城区农村水源地水质实测资料,进行健康风险评价与分析。结果表明:(1)基因毒物质由饮水途径所致健康危害的个人年风险按大小排列为Cr(VI)>As>Cd,而躯体毒物质的个人年风险按大小排列为Hg>Pb>Mn>Fe,但前者的影响远大于后者;(2)水源地中的3种基因毒物质所致健康危害的个人年风险,远远超过瑞典环保局、荷兰建设和环境部推荐的最大可接受水平1.00×10-6a-1,且Cr(VI)的健康风险危害超过国际辐射防护委员会(ICRP)推荐的最大可接受值5.00×10-5a-1,应将Cr(VI)视为本区饮水的优先治理污染物。     

Approaches and initial findings of a state-sponsored research programme on population exposure to toxic substances

Summary Population exposure to toxic chemicals in the environment has become one of the most important, if not the most important, environmental issue of the 1980's. In response to finding high cancer mortality rates, the State of New Jersey organized an extensive program of research to determine public exposure to toxic substances in the environment. Three parts of that research are described. One focusing on toxic substances in the water has detected very low concentrations of many substances. These substances tend to be found in three distinct chemical groups: pesticides, light chlorinated hydrocarbons, and heavy metals. Gross pesticide contamination tends to occur in agricultural and forest areas; gross light chlorinated hydrocarbon pollution is in urban areas. The second component of the research is toxic substances in the air. Like the water studies, low levels of contamination have been found. Limited sampling to date has found groupings of ubiquitous organic chemicals in urban areas, two groups of specialized organic chemicals near industrial sites, and high lead levels near major highways. The third project is developing a computerized information bank about the use and disposal of 155 chemicals and will look for associations between industrial disposal practices and contamination of the environment.     

ESTIMATING TMDL BACKGROUND SUSPENDED SEDIMENT LOADING TO GREAT LAKES TRIBUTARIES FROM EXISTING DATA1

ABSTRACT: The total maximum daily load (TMDL) for suspended sediment is the maximum quantity of suspended sediment that can enter a waterway without affecting the beneficial uses of the waterway. It is calculated as the sum of permissible allotments of point sources of suspended sediment, permissible allotments of nonpoint sources of suspended sediment, background (natural) loading of suspended sediment, and a margin of safety. The goal of this project was to develop methods for estimating background levels of sediment loads in tributaries of the Great Lakes. Such quantification is key to determining permissible TMDL in waters that do not meet water quality standards under the Clean Water Act of 1972. Suspended sediment loading for 46 rivers was estimated from data collected at U.S. Geological Survey (USGS) gages. Land use and physiographic attributes were estimated for these gaged basins with a geographic information system (GIS). Basin attributes and sediment yield data are the basis for examining two approaches to estimating background suspended sediment loads. One method, based upon envelope curves of sediment yield and drainage area, will be shown to have considerable merit. A second method, based upon correlation of sediment yield to various basin attributes such as drainage area and land use, will be shown to be fraught with difficulties.     

Oversight of shale gas production in the United States and the disclosure of toxic substances

With the encouragement of shale gas production in the United States, governments have considered a range of legislative and regulatory proposals to manage health and environmental damages that may accompany extraction activities. Exceptions adopted by Congress to major federal environmental legislation have meant that individual US states have deemed it necessary to provide oversight through regulations to protect people and safeguard environmental quality. In responding, states have legal structures under which drilling firms may not need to disclose the toxic substances used in fracturing wells. Yet, with increasing numbers of drilling sites, more people are at risk from accidents and exposure to harmful substances used at fractured wells. To provide for meaningful health and safety protection, governments may need to reevaluate legal provisions offering trade secret protection for toxic substances used in fracturing.     

Trade union approach to control of toxic substances

Summary The paper deals with some of the problems associated with toxic substances in the work environment, it illustrates these by reference to case studies. It also looks at the involvement of Trade Unions in health and safety issues. It points out flaws and limitations of the present legislative measures; the need to detect toxic substances before they are introduced into the workplace. There is a strong argument for new procedures and regulations to control and license toxic substances; it sets out criteria advocated by Trade Unions towards achieving this. It shows how a whole new strategy has to be agreed to, a strategy that puts as its priority the health of the population as a whole.General Secretary of the Association of Technical and Managerial Staffs. A major Trade Union for scientist, technologists and technicians etc. in the UK.     

A Comparative Approach for Ranking Contaminated Sites Based on the Risk Assessment Paradigm Using Fuzzy PROMETHEE

A ranking system for contaminated sites based on comparative risk methodology using fuzzy Preference Ranking Organization METHod for Enrichment Evaluation (PROMETHEE) was developed in this article. It combines the concepts of fuzzy sets to represent uncertain site information with the PROMETHEE, a subgroup of Multi-Criteria Decision Making (MCDM) methods. Criteria are identified based on a combination of the attributes (toxicity, exposure, and receptors) associated with the potential human health and ecological risks posed by contaminated sites, chemical properties, site geology and hydrogeology and contaminant transport phenomena. Original site data are directly used avoiding the subjective assignment of scores to site attributes. When the input data are numeric and crisp the PROMETHEE method can be used. The Fuzzy PROMETHEE method is preferred when substantial uncertainties and subjectivities exist in site information. The PROMETHEE and fuzzy PROMETHEE methods are both used in this research to compare the sites. The case study shows that this methodology provides reasonable results.     

Air quality assessment for land disposal of industrial wastes

Air pollution from hazardous waste landfills and lagoons is largely unknown. Routine monitoring of toxic air contaminants associated with hazardous waste facilities is difficult and very costly. The method presented in this paper would be useful for air quality assessment in the absence of monitoring data. It may be used as a screening process to examine the question of whether or not volatilization is considered to be significant for a given contaminant and also to evaluate permit applications for new hazardous waste facilities concerning waste volatilization problems.     

CO-KRIGING TO INCORPORATE SCREENING DATA: HUDSON RIVER SEDIMENT PCBs1

ABSTRACT: Kriging methods of geostatistical analysis provide valuable techniques for analysis of sediment contamination problems, including interpolation of concentration maps from point data and estimation of global mean concentrations. Sample collection efforts frequently include preliminary screening data of considerably more extensive coverage than the laboratory analyses on which estimation is usually based. How should these be incorporated in kriging? Screening and laboratory analysis constitute two separate estimates of the same spatial field but of very different characteristics. A modified version of co-kriging is developed to include the imprecise screening information in the analysis of contaminant distribution. Use of the method is demonstrated on a data set of sediment PCB samples from the Upper Hudson River, for which preliminary categorical mass spectrometry screening was used to select a smaller set of samples for gas chromatograph analysis. The method is widely applicable to many situations of contaminant and natural resource estimation.     

Development of drinking water standards for perchlorate in the United States

Perchlorate, an anion that originates as a contaminant in ground and surface waters, is both naturally occurring and manmade. Because of its toxicity, there has been increased interest in setting drinking water safety standards and in health effects when perchlorate is present at low (parts per billion (ppb)) levels. In January 2009, the EPA issued a heath advisory to assist state and local officials in addressing local contamination of perchlorate in drinking water. The interim health advisory level of 15 micrograms per liter (μg/L), or ppb, is based on the reference dose recommended by the National Research Council (NRC) of the National Academy of Sciences (NAS). This paper describes scope and extent of contaminant issues and a legal process of setting standards for perchlorate concentration in drinking water in the United States of America.     

Tolerance and phytoremediation potential of Calopogonium mucunoides to boron

Soil contamination by trace elements (TEs) is a problem of great concern since the industrial revolution. However, not all TEs are essentially toxic, and several micronutrients such as boron (B) play essential roles during plant development and, in this case, B acts in plants as a structural element. Soil B levels above 3.0 mg dm^–3 may be toxic to many plants and the greatest input of B to the environment occurs through the anthropic way. An environmentally promising alternative is phytoremediation, in which contaminant‐tolerant plants are used to remove or stabilize TEs in soils. Therefore, this work has been carried out to aim C. mucunoides’ tolerance to increasing B concentrations and its potential as a phytoremediator. We found out that C. mucunoides tolerates B doses up to 480 mg dm^?3, the B uptaken is transported at a 1:1 ratio between root and shoot, suggesting that C. mucunoides can be used as a phytostabilizer and phytoextractor due to its potential to be used in phytoremediation techniques because it can tolerate toxic concentrations of B.     

Reduction of nitrate leaching with haying or grazing and omission of nitrogen fertilizer

In some high-fertility, high-stocking-density grazing systems, nitrate (NO(3)) leaching can be great, and ground water NO(3)-N concentrations can exceed maximum contaminant levels. To reduce high N leaching losses and concentrations, alternative management practices need to be used. At the North Appalachian Experimental Watershed near Coshocton, OH, two management practices were studied with regard to reducing NO(3)-N concentrations in ground water. This was following a fertilized, rotational grazing management practice from which ground water NO(3)-N concentrations exceeded maximum contaminant levels. Using four small watersheds (each approximately 1 ha), rotational grazing of a grass forage without N fertilizer being applied and unfertilized grass forage removed as hay were used as alternative management practices to the previous fertilized pastures. Ground water was sampled at spring developments, which drained the watershed areas, over a 7-yr period. Peak ground water NO(3)-N concentrations before the 7-yr study period ranged from 13 to 25.5 mg L(-1). Ground water NO(3)-N concentrations progressively decreased under each watershed and both management practices. Following five years of the alternative management practices, ground water NO(3)-N concentrations ranged from 2.1 to 3.9 mg L(-1). Both grazing and haying, without N fertilizer being applied to the forage, were similarly effective in reducing the NO(3)-N levels in ground water. This research shows two management practices that can be effective in reducing high NO(3)-N concentrations resulting from high-fertility, high-stocking-density grazing systems, including an option to continue grazing.     

Corporate occupational exposure limits: An example of a strategy

Occupational exposure limits (OELs) developed by authorities play a key role in the implementation of programs to protect workers against hazardous chemicals. Unfortunately, many hazardous substances do not have OELs or the OEL could be outdated. To assure the health of the workers, it is therefore useful for companies to develop corporate OELs. An inhouse strategy will be presented hereafter. Expertise in toxicology, industrial hygiene, and occupational health should be available within the company and clear selection criteria for substances are needed. A corporate OEL is only developed for hazardous substances (e.g., carcinogenic or reprotoxic) with a high potential for worker exposure when an appropriate national OEL or threshold limit value is not available. The methodology to calculate corporate OELs is based on the existing methods for national or community OELs and also on the guidance from the European Union's (EU) regulation on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). For carcinogenic substances with a nonthreshold mode of action, there is always a residual chance that a cancer develops even when the exposure of workers is low. To establish an OEL for these substances, the “German traffic light model” is recommended. It is pragmatic, defines an unacceptable, tolerable, and acceptable risk level when workers are exposed to these substances, and determines risk management for exposure reduction. Overall, the professional practice to develop OELs is a good example of corporate leadership to proactively protect the health of workers.     

ESTIMATING THE PROBABILITY OF EXCEEDING GROUNDWATER QUALITY STANDARDS1

ABSTRACT: A model for estimating the probability of exceeding groundwater quality standards at environmental receptors based on a simple contaminant transport model is described. The model is intended for locations where knowledge about site-specific hydrogeologic conditions is limited. An efficient implementation methodology using numerical Monte Carlo simulation is presented. The uncertainty in the contaminant transport system due to uncertainty in the hydraulic conductivity is directly calculated in the Monte Carlo simulations. Numerous variations of the deterministic parameters of the model provide an indication of the change in exceedance probability with change in parameter value. The results of these variations for a generic example are presented in a concise graphical form which provides insight into the topology of the exceedance probability surface. This surface can be used to assess the impact of the various parameters on exceedance probability.     

Maximum permissible and negligible concentrations for some organic substances and pesticides

The aim of the paper is to provide interested parties the methods that were used for generic hazard assessment in The Netherlands, and the resulting so-called maximum permissible concentrations (MPCs) and the negligible concentrations (NCs) for approximately 150 organic substances and pesticides. The MPCs and NCs were derived for water, sediment, and soil. The concentration in the environment above which the risk of adverse effects was considered unacceptable to ecosystems is called the MPC. The MPCs take into account that the substances are distributed among the different environmental compartments, and are harmonized accordingly. The MPCs served as a basis for the Dutch government to set generic environmental quality standards (EQS) in The Netherlands (IWINS,[15]). EQS in turn are used by the Dutch Government to assess the environmental quality and for other environmental policy purposes. Concentrations in the environment below which the occurrence of adverse effects is considered to be negligible are called NCs. Hazards must be reduced when the environmental concentration of a substance exceeds its MPC. In-between this limits reduction of hazards is preferable. The MPC is a scientifically derived hazard limit. The NC is simply defined as 1% of the MPC. In general, there is a great demand for ecotoxicological data that currently limits a more reliable estimate of many MPCs. For water, approximately half of the MPCs are derived on the basis of four or more NOECs (no observed effect concentrations). For the other half, MPCs are based on only a few chronic or acute tests. For soil and sediment, however, almost no ecotoxicological data are available, and MPCs for those compartments have, in many cases, been derived from MPCs in water applying the equilibrium partitioning method (EqP-method), resulting in MPCs with greater uncertainty. Some of the methods and underlying assumptions that have been used may need improvement. For example, the factor between MPC and NC, the statistical extrapolation method, the method that is used for secondary poisoning, the role of the background concentrations of ‘naturally’ occurring substances, and the bioavailability and the EqP-method. There is a great need for hazard limits, and the present compilation tries to provide those as well as identifying research gaps.     

An integrated fuzzy-stochastic modeling approach for risk assessment of groundwater contamination

An integrated fuzzy-stochastic risk assessment (IFSRA) approach was developed in this study to systematically quantify both probabilistic and fuzzy uncertainties associated with site conditions, environmental guidelines, and health impact criteria. The contaminant concentrations in groundwater predicted from a numerical model were associated with probabilistic uncertainties due to the randomness in modeling input parameters, while the consequences of contaminant concentrations violating relevant environmental quality guidelines and health evaluation criteria were linked with fuzzy uncertainties. The contaminant of interest in this study was xylene. The environmental quality guideline was divided into three different strictness categories: "loose", "medium" and "strict". The environmental-guideline-based risk (ER) and health risk (HR) due to xylene ingestion were systematically examined to obtain the general risk levels through a fuzzy rule base. The ER and HR risk levels were divided into five categories of "low", "low-to-medium", "medium", "medium-to-high" and "high", respectively. The general risk levels included six categories ranging from "low" to "very high". The fuzzy membership functions of the related fuzzy events and the fuzzy rule base were established based on a questionnaire survey. Thus the IFSRA integrated fuzzy logic, expert involvement, and stochastic simulation within a general framework. The robustness of the modeling processes was enhanced through the effective reflection of the two types of uncertainties as compared with the conventional risk assessment approaches. The developed IFSRA was applied to a petroleum-contaminated groundwater system in western Canada. Three scenarios with different environmental quality guidelines were analyzed, and reasonable results were obtained. The risk assessment approach developed in this study offers a unique tool for systematically quantifying various uncertainties in contaminated site management, and it also provides more realistic support for remediation-related decisions.     

Time‐Dependent Health Risk from Contaminated Groundwater Including Use of Reliability,Resilience, and Vulnerability as Measures

Traditionally, assessment of human health risk caused by contamination of a water supply focuses on the maximum risk to an individual. Here, we introduce a time‐dependent risk assessment method and adapt and explore the reliability, resilience, and vulnerability (RRV) criteria from the surface‐water literature as possible tools for assessing this risk. Time‐dependent risk assessment, including RRV, is applied to two synthetic examples where water quality at a well varies over time. We calculate time‐dependent health risks for discrete periods of exposure to the contaminated water for a variable population. The RRV criteria provide information about time‐dependent risk: probability of an acceptable risk, probability of system recovery, maximum risk, and average exceedance of a prescribed risk threshold. The results demonstrate that episodic contamination events produce fundamentally different time‐dependent risks than long‐term events: these differences, such as generally lower risks for the episodic contamination, can be captured via plots of the risk and the RRV criteria. Furthermore, the evaluation of time‐dependent health risk and the RRV criteria demonstrates significant sensitivity to the shape of the contaminant breakthrough curve, length of exposure, and variability within the population. Overall, analysis of time‐dependent health risks provides substantial insight into the structure of risk, with RRV providing a reasonable framework for the evaluation of these risks.     

Probabilistic fugacity analysis of Lake Pontchartrain pollution after Hurricane Katrina

After Hurricane Katrina passed through the US Gulf Coast in August 2005, floodwaters covering New Orleans were pumped into Lake Pontchartrain as part of the rehabilitation process in order to make the city habitable again. The long-term consequences of this environmentally critical decision were difficult to assess at the time and were left to observation. In the aftermath of these natural disasters, and in cases of emergency, the proactive use of screening level models may prove to be an important factor in making appropriate decisions to identify cost effective and environmentally friendly mitigation solutions. In this paper, we propose such a model and demonstrate its use through the application of several hypothetical scenarios to examine the likely response of Lake Pontchartrain to the contaminant loading that were possibly in the New Orleans floodwaters. For this purpose, an unsteady-state fugacity model was developed in order to examine the environmental effects of contaminants with different physicochemical characteristics on Lake Pontchartrain. The three representative contaminants selected for this purpose are benzene, atrazine, and polychlorinated biphenyls (PCBs). The proposed approach yields continuous fugacity values for contaminants in the water, air, and sediment compartments of the lake system which are analogous to concentrations. Since contaminant data for the floodwaters are limited, an uncertainty analysis was also performed in this study. The effects of uncertainty in the model parameters were investigated through Monte Carlo analysis. Results indicate that the acceptable recovery of Lake Pontchartrain will require a long period of time. The computed time range for the levels of the three contaminants considered in this study to decrease to maximum contaminant levels (MCLs) is about 1 year to 68 years. The model can be implemented to assess the possible extent of damage inflicted by any storm event on the natural water resources of Southern Louisiana or similar environments elsewhere. Furthermore, the model developed can be used as a useful decision-making tool for planning and remediation in similar emergency situations by examining various potential contamination scenarios and their consequences.     

Real-time contaminant detection and classification in a drinking water pipe using conventional water quality sensors: Techniques and experimental results

Accurate detection and identification of natural or intentional contamination events in a drinking water pipe is critical to drinking water supply security and health risk management. To use conventional water quality sensors for the purpose, we have explored a real-time event adaptive detection, identification and warning (READiw) methodology and examined it using pilot-scale pipe flow experiments of 11 chemical and biological contaminants each at three concentration levels. The tested contaminants include pesticide and herbicides (aldicarb, glyphosate and dicamba), alkaloids (nicotine and colchicine), E. coli in terrific broth, biological growth media (nutrient broth, terrific broth, tryptic soy broth), and inorganic chemical compounds (mercuric chloride and potassium ferricyanide). First, through adaptive transformation of the sensor outputs, contaminant signals were enhanced and background noise was reduced in time-series plots leading to detection and identification of all simulated contamination events. The improved sensor detection threshold was 0.1% of the background for pH and oxidation–reduction potential (ORP), 0.9% for free chlorine, 1.6% for total chlorine, and 0.9% for chloride. Second, the relative changes calculated from adaptively transformed residual chlorine measurements were quantitatively related to contaminant-chlorine reactivity in drinking water. We have shown that based on these kinetic and chemical differences, the tested contaminants were distinguishable in forensic discrimination diagrams made of adaptively transformed sensor measurements.     

含汞气田汞污染控制技术研究

痕量组分汞可能出现在大多数天然气气藏中。汞及其化合物均是剧毒物质,在含汞天然气处理过程中可能危害操作人员健康、腐蚀管线设备以及污染环境。针对某气田含汞天然气处理工艺,分析汞在天然气处理过程中分布情况,评价汞对天然气处理工艺及环境的影响,提出了含汞气田汞污染的控制技术以及防护措施,对降低含汞气田开发风险、保护人身健康及防止环境污染具有现实意义。