共查询到3条相似文献,搜索用时 15 毫秒
1.
P. I. C. Claro A. R. S. Neto A. C. C. Bibbo L. H. C. Mattoso M. S. R. Bastos J. M. Marconcini 《Journal of Polymers and the Environment》2016,24(4):363-371
Poly(lactic acid) (PLA) is a biodegradable polymer that exhibits high elastic modulus, high mechanical strength, and feasible processability. However, high cost and fragility hinder the application of PLA in food packaging. Therefore, this study aimed to develop flexible PLA/acetate and PLA/chitosan films with improved thermal and mechanical properties without the addition of a plasticizer and additive to yield extruder compositions with melt temperatures above those of acetate and chitosan. PLA blends with 10, 20, and 30 wt% of chitosan or cellulose acetate were processed in a twin-screw extruder, and grain pellets were then pressed to form films. PLA/acetate films showed an increase of 30 °C in initial degradation temperature and an increase of 3.9 % in elongation at break. On the other hand, PLA/chitosan films showed improvements in mechanical properties as an increase of 4.7 % in elongation at break. PLA/chitosan film which presented the greatest increase in elongation at break proved to be the best candidate for application in packaging. 相似文献
2.
A Study of Physicomechanical and Morphological Properties of Starch/Poly(vinylalcohol) Based Films 总被引:2,自引:0,他引:2
Dipa Ray Papri Roy Suparna Sengupta Siba Prasad Sengupta Amar K. Mohanty Manjusri Misra 《Journal of Polymers and the Environment》2009,17(1):56-63
Starch/Poly(vinylalcohol) blends in two different ratios (60:40 and 50:50) were prepared with glycerol as a plasticizer. Films
were cast by a solution casting method. One set of films were filled with 10 wt% of unmodified bentonite clay and another
set of films were crosslinked with epichlorohydrin in an alkaline medium. The prepared film samples were subjected to X-ray
diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), mechanical characterization and scanning electron microscope
(SEM). Significant changes in the tensile properties were observed depending on the different chemical constituents of the
films. The presence of clay and crosslinking with epichlorohydrin were both found to have considerable effect on the morphology
and mechanical property of the films. The SEM investigations, XRD analysis and FTIR studies revealed the interaction between
the various chemical components of the films. 相似文献
3.
Dipa Ray Papri Roy Suparna Sengupta Siba Prasad Sengupta Amar K. Mohanty Manjusri Misra 《Journal of Polymers and the Environment》2009,17(1):49-55
Starch/Poly(vinylalcohol) blends in two different ratios (60:40 and 50:50) were prepared with glycerol as a plasticizer. Films
were cast by a solution casting method. One set of films were filled with 10 wt% of bentonite clay and another set of films
were crosslinked with epichlorohydrin in an alkaline medium. The prepared film samples were characterized with dynamic mechanical
analysis (DMA) and thermogravimetric analysis (TGA). The presence of clay and crosslinking with epichlorohydrin was found
to have considerable effect on the dynamic mechanical properties and thermal stability of the films. Intercomponent H-bonding
between starch, Poly(vinylalcohol) and glycerol enhanced the thermal stability of the films. But incorporation of clay and
crosslinking with epichlorohydrin enhanced the steric crowding and lowered the thermal stability of the films. 相似文献