Numerical simulation of flow and dispersion around an isolated cubical building: The effect of the atmospheric stratification

The aim of this work is to investigate atmospheric flow and dispersion of contaminants in the vicinity of single buildings under different stability conditions. The mathematical model used is based on the solution of equations of conservation of mass, linear momentum and energy with the use of a non-standard κ–? turbulence model. The modifications proposed in the κ–? model are the inclusion of the Kato and Launder correction in the production of turbulent kinetic energy and the use of a modified wall function. Results are presented of numerical simulations of dispersion around a cubical obstacle, under neutral, stable and unstable atmospheric conditions. Experimental data from wind tunnel and field trials obtained by previous authors are used to validate the numerical results. The numerical simulation results show a reasonable level of agreement with field and wind tunnel concentration data. The deviation between model results and field experimental data is of the same order as the deviation between field and wind tunnel data.     

Evaluation of dynamic subgrid-scale models in large-eddy simulations of neutral turbulent flow over a two-dimensional sinusoidal hill

Large-eddy simulation (LES) is used to simulate neutral turbulent boundary-layer flow over a rough two-dimensional sinusoidal hill. Three different subgrid-scale (SGS) models are tested: (a) the standard Smagorinsky model with a wall-matching function, (b) the Lagrangian dynamic model, and (c) the recently developed scale-dependent Lagrangian dynamic model [Stoll, R., Porté-Agel, F., 2006. Dynamic subgrid-scale models for momentum and scalar fluxes in large-eddy simulation of neutrally stratified atmospheric boundary layers over heterogeneous terrain. Water Resources Research 42, W01409. doi:10.1029/2005WR003989]. The simulation results obtained with the different models are compared with turbulence statistics obtained from experiments conducted in the meteorological wind tunnel of the AES (Atmospheric Environment Service, Canada) [Gong, W., Taylor, P.A., Dörnbrack, A., 1996. Turbulent boundary-layer flow over fixed aerodynamically rough two-dimensional sinusoidal waves. Journal of Fluid Mechanics 312, 1–37]. We find that the scale-dependent dynamic model is able to account, without any tuning, for the local changes in the eddy-viscosity model coefficient. It can also capture the scale dependence of the coefficient associated with regions of the flow with strong mean shear and flow anisotropy. As a result, the scale-dependent dynamic model yields results that are more realistic than the ones obtained with the scale-invariant Lagrangian dynamic model.     

The influence of atmospheric stability on pollutant transport by slope winds

The results of a field investigation into pollutant transport by slope flows are presented. During the study, ozone levels were monitored for eight days at three locations along a mountain slope extending above the Los Angeles Air Basin. In addition, tracer tests were conducted during two afternoons during the study period. The tests were conducted on days with widely varying atmospheric stability and indicate the effect of a strongly stable capping layer on pollutant transport by upslope flows. The experimental results indicated at least two mechanisms for the return of polluted air to the valley below. Under weakly stable conditions, the often noted return of pollutants via night-time downslope winds was observed. In addition, under more strongly stable conditions, a daytime recirculation mechanism consistent with that described by Vergeiner (1982) was observed. The tests also indicated that the slope flow layer depth and speed decreased with increasing atmospheric stability. In addition, the rate of transport and dilution of pollutants in a slope flow appears to be influenced by the entrainment and growth of the boundary layer, limiting the applicability of models that neglect these processes.     

The effect of improved nowcasting of precipitation on air quality modeling

The predictive potential of air quality models and thus their value in emergency management and public health support are critically dependent on the quality of their meteorological inputs. The atmospheric flow is the primary cause of the dispersion of airborne substances. The scavenging of pollutants by cloud particles and precipitation is an important sink of atmospheric pollution and subsequently determines the spatial distribution of the deposition of pollutants. The long-standing problem of the spin-up of clouds and precipitation in numerical weather prediction models limits the accuracy of the prediction of short-range dispersion and deposition from local sources. The resulting errors in the atmospheric concentration of pollutants also affect the initial conditions for the calculation of the long-range transport of these pollutants. Customary the spin-up problem is avoided by only using NWP (Numerical Weather Prediction) forecasts with a lead time greater than the spin-up time of the model. Due to the increase of uncertainty with forecast range this reduces the quality of the associated forecasts of the atmospheric flow.In this article recent improvements through diabatic initialization in the spin-up of large-scale precipitation in the Hirlam NWP model are discussed. In a synthetic example using a puff dispersion model the effect is demonstrated of these improvements on the deposition and dispersion of pollutants with a high scavenging coefficient, such as sulphur, and a low scavenging coefficient, such as cesium-137. The analysis presented in this article leads to the conclusion that, at least for situations where large-scale precipitation dominates, the improved model has a limited spin-up so that its full forecast range can be used. The implication for dispersion modeling is that the improved model is particularly useful for short-range forecasts and the calculation of local deposition. The sensitivity of the hydrological processes to proper initialization implies that the spin-up problem may reoccur with changes in the model and increased model resolution. Spin-up should be an ongoing concern for atmospheric modelers.     

Global atmospheric cycle of mercury: a model study on the impact of oxidation mechanisms

Mercury (Hg) is a global pollutant since its predominant atmospheric form, elemental Hg, reacts relatively slowly with the more abundant atmospheric oxidants. Comprehensive knowledge on the details of the atmospheric Hg cycle is still lacking, and in particular, there is some uncertainty regarding the atmospherically relevant reduction-oxidation reactions of mercury and its compounds. ECHMERIT is a global online chemical transport model, based on the ECHAM5 global circulation model, with a highly customisable chemistry mechanism designed to facilitate the investigation of both aqueous- and gas-phase atmospheric mercury chemistry. An improved version of the model which includes a new oceanic emission routine has been developed. Results of multiyear model simulations with full atmospheric chemistry have been used to examine the how changes to chemical mechanisms influence the model’s ability to reproduce measured Hg concentrations and deposition flux patterns. The results have also been compared to simple fixed-lifetime tracer simulations to constrain the possible range of atmospheric mercury redox rates. The model provides a new and unique picture of the global cycle of mercury, in that it is online and includes a full atmospheric chemistry module.     

Atmospheric composition change: Climate–Chemistry interactions

Chemically active climate compounds are either primary compounds like methane (CH₄), removed by oxidation in the atmosphere, or secondary compounds like ozone (O₃), sulfate and organic aerosols, both formed and removed in the atmosphere. Man-induced climate–chemistry interaction is a two-way process: Emissions of pollutants change the atmospheric composition contributing to climate change through the aforementioned climate components, and climate change, through changes in temperature, dynamics, the hydrological cycle, atmospheric stability, and biosphere-atmosphere interactions, affects the atmospheric composition and oxidation processes in the troposphere. Here we present progress in our understanding of processes of importance for climate–chemistry interactions, and their contributions to changes in atmospheric composition and climate forcing. A key factor is the oxidation potential involving compounds like O₃ and the hydroxyl radical (OH). Reported studies represent both current and future changes. Reported results include new estimates of radiative forcing based on extensive model studies of chemically active climate compounds like O₃, and of particles inducing both direct and indirect effects. Through EU projects like ACCENT, QUANTIFY, and the AeroCom project, extensive studies on regional and sector-wise differences in the impact on atmospheric distribution are performed. Studies have shown that land-based emissions have a different effect on climate than ship and aircraft emissions, and different measures are needed to reduce the climate impact. Several areas where climate change can affect the tropospheric oxidation process and the chemical composition are identified. This can take place through enhanced stratospheric–tropospheric exchange of ozone, more frequent periods with stable conditions favoring pollution build up over industrial areas, enhanced temperature induced biogenic emissions, methane releases from permafrost thawing, and enhanced concentration through reduced biospheric uptake. During the last 5–10 years, new observational data have been made available and used for model validation and the study of atmospheric processes. Although there are significant uncertainties in the modeling of composition changes, access to new observational data has improved modeling capability. Emission scenarios for the coming decades have a large uncertainty range, in particular with respect to regional trends, leading to a significant uncertainty range in estimated regional composition changes and climate impact.     

The dependence of airborne particulate deposition on atmospheric stability and surface conditions

The deposition of airborne Pb particulates has been experimentally investigated in different fields. Three fields with different surface conditions were selected for which the roughness sizes have been determined under neutral atmospheric conditions. A modified low-pressure Andersen impactor was used to determine the particle-size distribution. The sampler classifies particle size in ultra-fine range down to 0.08 μm aerodynamic diameter. The flux of particulate Pb was measured on the surfaces of: alfalfa leaves, real grass and soil under stable and unstable atmospheric conditions.Data from a meteorological tower were analysed to determine the standard deviation of horizontal wind direction from which the atmospheric stability class was determined. The deposition surfaces were wet-ashed with HNO₃ and analysed for Pb by atomic absorption spectrophotometry and the particulate fluxes were obtained. The particulate fluxes were also calculated from the size-distribution data and values of deposition velocity were obtained from two deposition models (Sehmel and Hodgson, 1978; El-Shobokshy and Sharaf El-Din, 1984).It is concluded that both surface roughness and atmospheric stability are the main controlling factors in particulate deposition, together with particle diameter. For unstable conditions, there was quite good agreement between measured and calculated particulate flux using both of the above theoretical models. For stable conditions, Sehmel and Hodgson's model failed to predict accurate fluxes because their model shows the independence of deposition velocity on atmospheric stability.     

Optimization of the coating layer for the measurement of ammonia by diffusion denuders

The performance of citric acid, oxalic acid and phosphorous acid as denuder coating layers for the determination of atmospheric ammonia have been studied by means of laboratory and field tests. The parameters evaluated during the study include: collection efficiency, selectivity of the coating layer, stability of the reaction product, operative capacity and stability of the coating layer. The results of this study show that phosphorous acid is a suitable coating layer for a denuder line intended to determine both gaseous ammonia and particulate ammonium in the atmosphere. It has been found that the citric acid coating suffers from an insufficient strength of the bond between collected ammonia and the coating layer, which causes a release of the collected ammonia both towards the air flow and towards the active sites of the denuder glass. The performance of oxalic acid was very good in the determination of gaseous ammonia, but this coating showed to be unsuitable for denuder sampling lines which are intended also for the determination of atmospheric ammonium. The volatilisation of oxalic from the denuder surface, in fact, causes a displacement of nitrate from the Teflon filter and an excess of nitrate ion on the back-up filter.Phosphorous acid-coated denuders were added to the sampling line employed in the EMEP station of Montelibretti. Reliable and interesting results were obtained, which allowed us to detect the presence of gaseous ammonia adsorbed on atmospheric particles.     

A model for NOx–O3–terpene chemistry in chamber measurements of plant gas exchange

Cuvette measurements are a tool to analyse CO₂ exchange, transipiration and deposition/emission of different trace gases by plants. To verify these experimental methods and to use them efficiently we have developed a numerical model with atmospheric chemical reactions. The model includes reactions between 54 different chemical species in the gas phase. Using the model we are able to determine optimal size/flow rate ratios and cuvette cycles (closure times) from an experimental point of view. Using the cuvette model with atmospheric chemistry more accurate estimates for emissions/deposition rates of different species can be found. Some chemical reactions are significant, e.g. for NO and terpenes, as regards the analysis and interpretation of measured concentrations. With slower flow rates through a cuvette the significance of reactions is more pronounced. However, there are some species like ozone, where stomatal deposition is a dominant phenomenon and chemistry plays a minor role.     

Street canyon ventilation and atmospheric turbulence

Operational models for pollutant dispersion in urban areas require an estimate of the turbulent transfer between the street canyons and the overlying atmospheric flow. To date, the mechanisms that govern this process remain poorly understood. We have studied the mass exchange between a street canyon and the atmospheric flow above it by means of wind tunnel experiments. Fluid velocities were measured with a Particle Image Velocimetry system and passive scalar concentrations were measured using a Flame Ionisation Detector. The mass-transfer velocity between the canyon and the external flow has been estimated by measuring the cavity wash-out time. A two-box model, used to estimate the transfer velocity for varying dynamical conditions of the external flow, has been used to interpret the experimental data. This study sheds new light on the mechanisms which drive the ventilation of a street canyon and illustrates the influence of the external turbulence on the transfer process.     

Computational Fluid Dynamics (CFD) Simulations on the Effect of Rough Surface on Atmospheric Turbulence Flow Above Hilly Terrain Shapes

The behavioral distribution of the atmospheric turbulence flow over the terrain with changes in a rough surface has become one of the most important topics of air pollution research, among such other topics as transportation and dispersion pollutants. In this study, a computational model on atmospheric turbulence flow over a terrain hill shaped with rough surface was investigated under neutral atmospheric conditions. The flow was assumed to be 2D and modeled using computational fluid dynamics (CFD) models, which were numerically solved using Reynolds-averaged Navier-Stokes equations. Rough surface conditions were modeled using a number of windbreak fences regularly spaced on the hill. The mean velocity and turbulent structures such as turbulence intensity and turbulent kinetic energy were investigated in the upwind and downwind regions over the hill, and the numerical models were validated against the wind-tunnel results to optimize the turbulence model. The computational results agreed well with the results obtained from the wind tunnel experiments. The computational results indicate that the mean velocity was observed to increase dramatically around the crest of the upwind slope of the hill. A thick internal boundary layer was observed with a fence on the crest and downwind region of the hill. The reversed flow and recirculation zone were formed in the wake region behind the hill. It was thus determined that turbulent kinetic energy decreases as the mean velocity increases.     

Prediction of gas diffusion in complicated terrain by a potential flow model

A numerical model was developed to simulate gaseous diffusion in complicated terrain. This model calculates the air flow as a potential flow by the Boundary Element Method, and gaseous diffusion by an analytical Gaussian equation in the potential flow. Plume spreads σ_y and σ_z are modified by multiregression equations derived from wind tunnel experiments, and the terrain height is elongated depending on the atmospheric stability.First, tracer data from Cinder Cone Butte in the U.S. measured by the U.S.-EPA were predicted by the model in order to examine the prediction accuracy under stable conditions. The averaged ratio of the observed concentration to predicted concentration for 12 runs was better than a factor of 10. Next, tracer data from the Geysers area in the U.S. measured by the U.S.-DOE were used to examine the prediction accuracy under neutral conditions. The ratio of the observed concentration to predicted concentration for two runs under neutral conditions was better than factor of two at most locations, but prediction capability is poor in blocked or separated flow conditions.     

Numerical simulation of smoke plumes from large oil fires

A large eddy simulation (LES) model of smoke plumes generated by large outdoor pool fires is presented. The plume is described in terms of steady-state convective transport by a uniform ambient wind of heated gases and particulate matter introduced into a stably stratified atmosphere by a continuously burning fire. The Navier-Stokes equations in the Boussinesq approximation are solved numerically with a constant eddy viscosity representing dissipation on length scales below the resolution limits of the calculation. The effective Reynolds number is high enough to permit direct simulation of the large-scale mixing over two to three orders of magnitude in length scale. Particulate matter, or any non-reacting combustion ;product, is represented by Lagrangian particles which are advected by the fire-induced flow field. Background atmospheric motion is described in terms of the angular fluctuation of the prevailing wind, and represented by random perturbations to the mean particle paths. Results of the model are compared with two sets of field experiments.     

Estimating atmospheric turbidity from climate data

Aerosols have several important influences on the climate system. Among the more important of these are their roles in absorbing and scattering radiation, and as condensation nuclei in cloud-forming processes. Despite their importance, knowledge of their spatial and temporal variability and, in turn, their influence on climate, is incomplete. Constraints associated with conventional approaches to measuring atmospheric turbidity – including the requirements for clear skies and costly equipment – have contributed to a paucity of turbidity data. This paper presents a methodology for estimating atmospheric turbidity from readily available surface-weather data, regardless of cloud cover. Using a high-resolution spectral radiation model, clear-sky beam irradiance is parameterized as a function of atmospheric attenuation processes, including scattering and absorption by aerosols. The model is integrated over the day to obtain an expression for estimating potential daily clear-sky beam irradiation. Turbidity can then be estimated by forcing the model with monthly averaged climate data. The methodology can be applied at any location where the requisite climate data are available and therefore holds promise for a more complete, and possibly global, climatology of aerosols.     

Some aspects of air pollution in Buenos Aires city

This paper presents three aspects of air pollution in the city of Buenos Aires (Argentina). First, we describe the main features of air pollution climatology in the city: the characteristics of wind flow, atmospheric stability and mixing heights. Then, we present the results of the application of DAUMOD and ISCST3 atmospheric dispersion models to calculate spatial and temporal distributions of carbon monoxide and nitrogen oxides background concentrations. Finally, we present the main features of carbon monoxide concentrations observed in a narrow street canyon located downtown.     

On efficient numerical solution of one-dimensional convection–diffusion equations in modelling atmospheric processes

A new approach is proposed to the numerical solution of one-dimensional convection–diffusion equations that arise in modelling atmospheric processes and air pollution modelling. The technique is based on upstream-type difference approximations for first-order derivatives and non-standard difference approximations for second-order derivatives of convection–diffusion equations. This approach leads to the significant qualitative improvements in the numerical solutions behaviour. The relative contribution of convection and diffusion is directly incorporated into the corresponding numerical scheme in such a way that large spatial grids can be taken without affecting solution stability. The method is compared with the contemporary computational schemes for solving problems with severe internal and boundary gradients and is shown to be stable and computationally efficient. The results of a numerical experiment are given.     

Assimilation of conventional and satellite wind observations in a mesoscale atmospheric model for studying atmospheric dispersion

A mesoscale atmospheric model PSU/NCAR MM5 is used to provide operational weather forecasts for a nuclear emergency response decision support system on the southeast coast of India. In this study the performance of the MM5 model with assimilation of conventional surface and upper-air observations along with satellite derived 2-d surface wind data from QuickSCAT sources is examined. Two numerical experiments with MM5 are conducted: one with static initialization using NCEP FNL data and second with dynamic initialization by assimilation of observations using four dimensional data assimilation (FDDA) analysis nudging for a pre-forecast period of 12 h. Dispersion simulations are conducted for a hypothetical source at Kalpakkam location with the HYSPLIT Lagrangian particle model using simulated wind field from the above experiments. The present paper brings out the differences in the atmospheric model predictions and the differences in dispersion model results from control and assimilation runs. An improvement is noted in the atmospheric fields from the assimilation experiment which has led to significant alteration in the trajectory positions, plume orientation and its distribution pattern. Sensitivity tests using different PBL and surface parameterizations indicated the simple first order closure schemes (Blackadar, MRF) coupled with the simple soil model have given better results for various atmospheric fields. The study illustrates the impact of the assimilation of the scatterometer wind and automated weather stations (AWS) observations on the meteorological model predictions and the dispersion results.     

Road traffic impact on urban water quality: a step towards integrated traffic,air and stormwater modelling

Methods for simulating air pollution due to road traffic and the associated effects on stormwater runoff quality in an urban environment are examined with particular emphasis on the integration of the various simulation models into a consistent modelling chain. To that end, the models for traffic, pollutant emissions, atmospheric dispersion and deposition, and stormwater contamination are reviewed. The present study focuses on the implementation of a modelling chain for an actual urban case study, which is the contamination of water runoff by cadmium (Cd), lead (Pb), and zinc (Zn) in the Grigny urban catchment near Paris, France. First, traffic emissions are calculated with traffic inputs using the COPERT4 methodology. Next, the atmospheric dispersion of pollutants is simulated with the Polyphemus line source model and pollutant deposition fluxes in different subcatchment areas are calculated. Finally, the SWMM water quantity and quality model is used to estimate the concentrations of pollutants in stormwater runoff. The simulation results are compared to mass flow rates and concentrations of Cd, Pb and Zn measured at the catchment outlet. The contribution of local traffic to stormwater contamination is estimated to be significant for Pb and, to a lesser extent, for Zn and Cd; however, Pb is most likely overestimated due to outdated emissions factors. The results demonstrate the importance of treating distributed traffic emissions from major roadways explicitly since the impact of these sources on concentrations in the catchment outlet is underestimated when those traffic emissions are spatially averaged over the catchment area.     

Experimental investigation of the residence of contaminants in the wake of an obstacle under different stability conditions

The detrainment behaviour of contaminants in the wake of an isolated building was investigated in the field under atmospheric stability conditions ranging from very stable to very unstable. The model building used was a 2 m cube and two orientations were investigated, with the cube either normal or at 45° to the wind. Tracer gas was first entrained into the wake from a source located a short distance upwind of the cube, the gas being released continuously for a limited period in order to fill the wake. Thereafter, the source was switched off, and the concentration (measured using several fast-response gas detectors located in the wake) was observed to decay in an exponential manner. This procedure was repeated in a total of 118 experiments to provide confidence in statistics. The residence time (T_d), which is defined as the time it takes for the concentration to decay to 1/e of its original value, was measured. The decay duration (t), which is the time it takes for the gas to become fully detrained from the wake, was found to be greater in stable atmospheric conditions, mainly due to the lower wind speeds and higher concentrations observed under these conditions. However, the non-dimensional residence time (τ) was found to be independent of atmospheric stability. The values of τ for a cube normal (τ=6.2) or at 45° to the flow (τ=9.5) are in very good agreement with values calculated using empirical formulae derived from wind tunnel experiments.     

Experimental verification for real-time environmental emergency response system: WSPEEDI by European tracer experiment

Japan Atomic Energy Research Institute has developed an emergency response system WSPEEDI to forecast long-range atmospheric dispersions of radionuclides discharged into the atmosphere. The latest version of WSPEEDI consists of an atmospheric dynamic model MM5 for calculating meteorological fields and a particle random-walk model for atmospheric dispersion. The performance of WSPEEDI was evaluated by data obtained from a field tracer experiment over Europe (ETEX) in this paper. The model validation was done with respect to the following points: (1) the dependence of model accuracy on the temporal and spatial resolutions of the meteorological fields and (2) the superiority of an atmospheric dynamic model over a mass-consistent wind model. Regarding (1), it was shown that the calculation accuracy of the new version with high temporal resolution was improved, especially at the edge of the plume. Moreover, although the increase in horizontal spatial resolution of the old version had no substantial effect on the model performance, increase in horizontal resolution of the new version contributed to the significant improvement of the calculation accuracy. These results showed that the dynamically calculated meteorological field with the spatial resolution of the meso-β–γ scale greatly improved calculation accuracy.