Hybrid poplar and forest soil response to municipal and industrial by-products: a greenhouse study

Little research has been conducted in the Lake States (Minnesota, Wisconsin, and Michigan) to evaluate the effects of municipal and industrial by-product applications on the early growth of short rotation woody crops such as hybrid poplar. Anticipated shortages of harvestable-age aspen in the next decade can be alleviated and rural development can be enhanced through the application of by-products to forest soils. This study was conducted to evaluate the effects of inorganic fertilizer, boiler ash, biosolids, and the co-application of ash and biosolids application on tree growth and soil properties by measuring hybrid poplar clone NM-6 (Populus nigra L. x P. maximowiczii A. Henry) yield, nutrient uptake, and select post-harvest soil properties after 15 wk of greenhouse growth. Treatments included a control of no amendment; agricultural lime; inorganic N, P, and K; three types of boiler ash; biosolids application rates equivalent to 70, 140, 210, and 280 kg available N ha(-1); and boiler ash co-applied with biosolids. All of the by-products treatments showed biomass production that was equal to or greater than inorganic fertilizer and lime treatments. A trend of increased biomass with increasing rates of biosolids was observed. Soil P concentration increased with increasing rates of biosolids application. None of the by-products treatments resulted in plant tissue metal concentrations greater than metal concentrations of plant tissue amended with inorganic amendments. Biosolids, boiler ash, and the co-application of biosolids and boiler ash together on forest soils were as beneficial to plant growth as inorganic fertilizers.     

A modified risk assessment to establish molybdenum standards for land application of biosolids

The USEPA standards (40 CFR Part 503) for the use or disposal of sewage sludge (biosolids) derived risk-based numerical values for Mo for the biosolids --> land --> plant --> animal pathway (Pathway 6). Following legal challenge, most Mo numerical standards were withdrawn, pending additional field-generated data using modern biosolids (Mo concentrations <75 mg kg(-1) and a reassessment of this pathway. This paper presents a reevaluation of biosolids Mo data, refinement of the risk assessment algorithms, and a reassessment of Mo-induced hypocuprosis from land application of biosolids. Forage Mo uptake coefficients (UC) are derived from field studies, many of which used modern biosolids applied to numerous soil types, with varying soil pH values, and supporting various crops. Typical cattle diet scenarios are used to calculate a diet-weighted UC value that realistically represents forage Mo exposure to cattle. Recent biosolids use data are employed to estimate the fraction of animal forage (FC) likely to be affected by biosolids applications nationally. Field data are used to estimate long-term Mo leaching and a leaching correction factor (LC) is used to adjust cumulative biosolids application limits. The modified UC and new FC and LC factors are used in a new algorithm to calculate biosolids Mo Pathway 6 risk. The resulting numerical standards for Mo are cumulative limit (RPc)=40 kg Mo ha(-1), and alternate pollutant limit (APL) = 40 mg Mo kg(-1) We regard the modifications to algorithms and parameters and calculations as conservative, and believe that the risk of Mo-induced hypocuprosis from biosolids Mo is small. Providing adequate Cu mineral supplements, standard procedure in proper herd management, would augment the conservatism of the new risk assessment.     

Phosphorus restrictions for land application of biosolids: current status and future trends

The application of biosolids (sewage sludge) to agricultural soils provides P in excess of crop needs when applied to meet the N needs of most agronomic crops. These overapplications can result in the buildup of P in soils to values well above those needed for optimum crop yields and also may increase risk of P losses to surface and ground waters. Because of concerns regarding the influence of P on water quality in the USA, many state and federal agencies now recommend or require P-based nutrient management plans for animal manures. Similar actions are now under consideration for the land application of biosolids. We reviewed the literature on this subject and conducted a national survey to determine if states had restrictions on P levels in biosolids-amended soils. The literature review indicates that while the current N-based approach to biosolids management does result in increases of soil P, some properties of biosolids may mitigate the environmental risk to water quality associated with land application of P in biosolids. Results of the survey showed that 24 states have regulations or guidelines that can be imposed to restrict land application of biosolids based on P. Many of these states use numerical thresholds for P in biosolids-amended soils that are based on soil test phosphorus (STP) values that are much greater than the values considered to be agronomically beneficial. We suggest there is the need for a comprehensive environmental risk assessment of biosolids P. If risk assessment suggests the need for regulation of biosolids application, we suggest regulations be based on the P Site Index (PSI), which is the method being used by most states for animal manure management.     

Optimal Location and Management of Waste Disposal Facilities Affecting Ground Water Quality1

ABSTRACT: Numerical simulation of ground water solute transport is combined with linear programming to optimize waste disposal. A discretized form of the equation governing solute transport is included as a set of constraints in a linear program. Two problems are described. First, the management model is used to maximize ground water waste disposal. The model constrains disposal activities so that the quality of local ground water supplies is protected. Parametric programming is shown to be important in evaluating waste disposal tradeoffs at the various facilities. Changes in the velocity field induced by waste water injection cause a nonlinearity in the solute transport equation which is dealt with by employing an iterative procedure. The second problem is aimed at identifying all sites which are suitable for waste disposal in the subsurface. The management model is manipulated so that the optimal value of the dual variables are “unit source impact indicators.” This physical interpretation is valuable in identifying feasible disposal sites. The joint simulation and optimization approach permits the management of complex ground water systems where the aquifer is used simultaneously for waste disposal and water supply.     

The potential of public engagement in sustainable waste management: designing the future for biosolids in New Zealand

Strategies for beneficial use of biosolids in New Zealand and elsewhere are currently focused primarily on land application. The long-term success of these and other strategies is dependent not only on technical factors, but also on their environmental, economic, social and cultural sustainability. This paper briefly reviews the situation with respect to biosolids management in New Zealand, where land application is not yet widespread; the rise in public opposition to land application in the United States; and the biosolids industry's approach to public engagement. We argue that, at least until recently, the industry has misinterpreted the nature and meaning of public opposition and thus substituted public relations for public engagement. We argue that genuine public engagement is necessary and that its purpose cannot be to gain public acceptance for an already-decided-upon strategy. It therefore calls for humility among biosolids managers, including a willingness to open up the framing of 'the problem', to acknowledge areas of uncertainty, and to recognise the role of values in 'technical' decision-making. We then present and analyse an example of the use of the scenario workshop process for public participation in biosolids management policy in Christchurch, New Zealand, and conclude that scenario workshops and related methods represent an opportunity to enhance sustainable waste management when certain conditions are met.     

Estimating and valuing the carbon sequestered in softwood and hardwood trees, timber products and forest soils in Wales

Models of carbon storage in softwood and hardwood trees and forest soils and its emission from timber products and waste are developed and integrated with data on storage benefits to yield estimates of the value of the net carbon flux generated by afforestation. The long-term nature of the processes under consideration and the impact of varying the discount rate are explicitly incorporated within the model. A geographical information system (GIS) is used to apply carbon sequestration models to data on tree growth and soil type distribution for a large study area (the entire country of Wales). The major findings are: (1) all three elements under analysis (carbon sequestration in livewood, release from different products and waste, and storage or emission from soils) play a vital role in determining overall carbon flux; (2) woodland management has a substantial impact upon carbon storage in livewood however the choice of discount rate exerts the largest overall influence upon estimated carbon flux values; (3) timber growth rates (yield class) also have a major impact upon values; (4) tree species does affect storage values, however this is less important than the other factors listed above; (5) non-peat soils generally sequester relatively low levels of carbon. Planting upon peat soils can result in very substantial emissions of carbon which exceed the level of storage in livewood.The GIS is used to produce valuation maps which can be readily incorporated within cost-benefit analyses regarding optimal locations for conversion of land into forestry.     

碳达峰碳中和目标下固体废物治理的法律因应

我国在联合国大会上提出了“2030年碳达峰2060年碳中和”的目标。为达成此目标,固体废物治理领域也需要积极作出响应。固体废物治理体系的核心是固体废物的处置。不同的固体废物处置方式有着不同的碳排放结果,填埋或焚烧方式处置所排放的温室气体量都远大于循环利用的方式。应以固体废物领域碳排放统一核算制度为基石,从推进政策实施和立法修改等的多个层面上去因应。立法面向上,《固体废物污染环境防治法》《清洁生产促进法》《循环经济促进法》乃至编纂中的“环境法典”都应当围绕减碳模式的固体废物处置方式改进和制定相关法律规范;制度建设面向上,以固体废物碳排放强制核算法律制度建设为主,通过碳排放强制核算制度规范相关主体及其权利义务关系并深度挖掘固体废物处置的碳减排潜力。     

Energy savings from solid waste management options

An essential difference in solid waste management systems lies in their treatment of the large paper component. This study reveals that in most cases considered for southern Ontario, net energy savings are attributable to recycling waste paper rather than using it as a source of energy. It was also found that recycling waste paper could result in a net decrease in air and water pollution. The energy savings attributable to reduction at source options are assessed separately.     

Potential for enhanced phytoremediation of landfills using biosolids – a review

Despite the use of recyclable materials increasing worldwide, waste disposal to landfill remains the most common method of waste management because it is simple and relatively inexpensive. Although landfill disposal is an effective waste management system, if not managed correctly, a number of potential detrimental environmental impacts have been identified including soil and ground water contamination, leachate generation, and gas emissions. In particular, improper post-closure treatment of landfills or deterioration of the conventional clay landfill capping were shown to result in land degradation which required remediation to secure contaminants within the landfill site.Phytoremediation is an attractive technology for landfill remediation, as it can stabilize soil and simultaneously remediate landfill leachate. In addition, landfill phytoremediation systems can potentially be combined with landfill covers (Phytocapping) for hydrological control of infiltrated rainfall. However, for the successful application of any phytoremediation system, the effective establishment of appropriate, desired vegetation is critical. This is because the typically harsh and sterile nature of landfill capping soil limits the sustainable establishment of vegetation. Therefore, the physicochemical properties of landfill capping soils often need to be improved by incorporating soil amendments. Biosolids are a common soil amendment and will often meet these demanding conditions because they contain a variety of plant nutrients such as nitrogen, phosphate, potassium, as well as a large proportion of organic matter. Such amendment will also ameliorate the physical properties of the capping soils by increasing porosity, moisture content, and soil aggregation. Contaminants which potentially originate from biosolids will also be remediated by activities congruent with the establishment of plants and bacteria.     

医疗废物集中焚烧处置技术的研究与应用

通过分析各种医疗废物处理技术的特点,指出医疗废物集中焚烧处置技术能够有效处理医疗废物、满足国家对医疗废物处理的要求,适宜在医疗废物集中处置项目中广泛应用。但该技术在实际工程应用中,还存在如处理成本高、设备使用寿命短和二英排放不易控制等问题,尚需进一步研究加以克服。     

Copper availability in seven Israeli soils incubated with and without biosolids

Land application is becoming a preferred option for disposal of sewage sludge (biosolids) from wastewater treatment plants. However, it creates potential risks due to the heavy metal contents of these materials, with copper (Cu) being of chief concern. The long-term fate of biosolid metals applied to agricultural soils is not well understood, particularly in the soils of the Middle East. This investigation was conducted to determine whether the availability of Cu changes with time in biosolid-amended and nonamended soils from Israel. Seven soils, typifying the span of properties and formation environments encountered in Israel, were incubated with and without biosolids for 7 yr, and changes in organic carbon (OC) content and labile Cu concentration were determined. Isotopic exchange techniques, using 64Cu, and ion activity measurements, using a Cu2+ ion selective electrode, revealed that the available Cu concentration remained relatively low and stable over the 7-yr incubation. This was despite substantial reductions in OC. This study shows that, with regard to Cu, application of such biosolids to these soils at rates of up to 250 Mg ha(-1) does not pose a threat to the environment in the short to medium term.     

Changes in Soil Particulate Organic Matter, Microbial Biomass, and Activity Following Afforestation of Marginal Agricultural Lands in a Semi-Arid Area of Northeast China

Afforestation of agricultural lands has been one of the major land use changes in China in recent decades. To better understand the effect of such land use change on soil quality, we investigated selected soil physical, chemical and microbial properties (0–15 cm depth) in marginal agricultural land and a chronosequence of poplar (Populus euramericana cv. ‘N3016’) plantations (5-, 10-, 15- and 20-years old) in a semi-arid area of Northeast China. Soil bulk density significantly declined after conversion of agricultural lands to poplar plantations. Soil total organic carbon (TOC) and nitrogen (TN) concentrations, microbial biomass C (MBC) and potential N mineralization rate (PNM) decreased initially following afforestation of agricultural lands, and then increased with stand development. However, soil metabolic quotient (qCO₂) exhibited a reverse trend. In addition, soil particulate organic matter C (POM-C) and N (POM-N) concentrations showed no significant changes in the first 10 years following afforestation, and then increased with stand age. These findings demonstrated that soil quality declined initially following afforestation of agricultural lands in semi-arid regions, and then recovered with stand development. Following 15 years of afforestation, many soil quality parameters recovered to the values found in agricultural land. We propose that change in soil quality with stand age should be considered in determining optimum rotation length of plantations and best management practices for afforestation programs.     

Effect of dissolved organic carbon on zinc solubility in incubated biosolids-amended soils

Soil organic carbon (SOC) and dissolved organic carbon (DOC) affect long-term heavy metal solubility in biosolids-amended soils, but their role needs to be further studied under Mediterranean climatic conditions. We investigated Zn solubility, as assessed by water extraction, in two typical Greek soils amended with biosolids at 0, 20, and 100 Mg ha(-1) during a 310-d incubation period. It was found that SOC decreased by nearly 30% over time in the 100 Mg ha(-1) treatment. There was evidence that DOC affected Zn solubility, because DOC increased significantly on Day 23, probably due to a flush in microbial activity, and water-extractable Zn followed the same trend. After that, both DOC and water-extractable Zn decreased back to values similar to those of the unamended soils. Although Zn solubility did not increase overall even at high biosolids application rates, this study shows that time-limited fluctuations in Zn solubility due to sudden DOC flushes, can be significant, and need to be further investigated.     

Indicators for managing biosolids in Ireland

Sustainable development indicators (SDIs) have emerged as a tool to measure progress towards sustainable development for a number of fields. However, no indicator initiative to date has been aimed at biosolids management at local authority, regional or national levels. This paper presents a study where stakeholders involved in the management of biosolids in Ireland participated in the development of SDIs for managing biosolids at the local/regional level. A significant 81% of participating stakeholders find SDIs either 'useful' or 'very useful' as a tool for managing biosolids. A suite of 22 indicators has been developed and arranged according to the driving force-pressure-state-impact-response (DPSIR) indicator framework. The indicators address all the domains of biosolids management namely, production, quality, cost, legislation/regulation, training/research and recycling/disposal. The stakeholder approach is recognition that no effective indicator set can be developed without the input of stakeholders.     

An approach to tackling the environmental and health impacts of municipal solid waste disposal in developing countries

Indiscriminate disposal of municipal solid waste in developing countries poses severe environmental and health threats. The study proposes a new method for dealing with these problems. The hybrid structural interaction matrix (HSIM) was used to prioritise major identifiable environmental health factors arising from improper solid waste disposal. The simplistic resource allocation model was adopted to ensure optimality in the allocation of resources to prioritised factors. The study indicates that tackling environmental health impacts from the most prioritised negative disposal factors through optimal allocation of resources, will either reduce or eliminate the impacts associated with subsequent less prioritised factors that are direct consequences of the highly prioritised negative factors. The method proposed will aid decision makers in knowing which set of systemic factors are to be given preference and to what extent at given periods in time.     

Performance assessments for the geological storage of carbon dioxide: Learning from the radioactive waste disposal experience

The geological storage of carbon dioxide is currently being considered as a possible technology for reducing emissions to atmosphere. Although there are several operational sites where carbon dioxide is stored in this way, methods for assessing the long-term performance and safety of geological storage are at an early stage of development. In this paper the similarities and differences between this field and the geological disposal of radioactive wastes are considered. Priorities are suggested for the development of performance assessment methods for carbon dioxide storage based on areas where experience from radioactive waste disposal can be usefully applied. These include, inter alia, dealing with the various types of uncertainty, using systematic methodologies to ensure an auditable and transparent assessment process, developing whole system models and gaining confidence to model the long-term system evolution by considering information from natural systems. An important area of data shortage remains the potential impacts on humans and ecosystems.     

Risk characterization, assessment, and management of organic pollutants in beneficially used residual products

A wide array of organic chemicals occur in biosolids and other residuals recycled to land. The extent of our knowledge about the chemicals and the impact on recycling programs varies from high to very low. Two significant challenges in regulating these materials are to accurately determine the concentrations of the organic compounds in residuals and to appropriately estimate the risk that the chemicals present from land application or public distribution. This paper examines both challenges and offers strategies for assessing the risks related to the occurrence of organic compounds in residuals used as soil amendments. Important attributes that must be understood to appropriately characterize and manage the potential risks for organic chemicals in biosolids include toxicity and dose response, transport potential, chemical structure and environmental stability, analytical capability in the matrix of interest, concentrations and persistence in waste streams, plant uptake, availability from surface application versus incorporation, solubility factors, and environmental fate. This information is complete for only a few chemicals. Questions persist about the far greater number of chemicals for which toxicity and environmental behavior are less well understood. This paper provides a synopsis of analytical issues, risk assessment methodologies, and risk management screening alternatives for organic constituents in biosolids. Examples from experience in Wisconsin are emphasized but can be extrapolated for broader application.     

Occurrence and fate of pharmaceuticals and personal care products (PPCPs) in biosolids

Each year, large quantities of pharmaceuticals and personal care products (PPCPs) are used worldwide. Once conveyed to wastewater treatment plants, PPCPs can remain unchanged or undergo partial or complete transformation during wastewater treatment processes before discharge into the environment via effluent and biosolids for land application. Biosolids can be a major sink for some PPCPs. Previous investigations have indicated that land application of biosolids may be a potential important route through which PPCPs enter the environment. However, no information is available on exactly how closely the concentrations of PPCPs in the environmental media are related to the land application of PPCP-containing biosolids. This paper reviews currently available information on the occurrence of PPCPs in biosolids, methods of analysis, the potential fate of PPCPs in biosolids-applied soils, and composting as a potential means for removal of PPCPs from biosolids.     

Analysis of Scavengers’ Activities and Recycling in Some Cities of Nigeria

The state of solid waste recycling by scavengers in Onitsha, a heavily commercial city in Anambra State, and some other urban areas such as Nsukka, Enugu, and Port Harcourt was analyzed. Data were obtained through interviews of scavengers who deal with recyclables. Although the activities of scavengers are sub-optimal, they can have a great impact on Nigerian economy with respect to resource conservation, creation of job opportunities, and reduction of the magnitude of waste disposal problems. A cost analysis is presented to compare the different forms of recycling utilized by municipal solid waste management. It is shown that a well-planned recycling program with recycling and composting would result in 18.6% savings in waste management costs and 57.7% in landfill avoidance costs. However, if the compost materials are not recycled, the corresponding savings in cost become 8.6% and 28.6%, respectively. The option with the lowest cost involves encouraging individual households to separate at the source their recyclables, which are bought by scavengers. This results in 78.0% savings in waste management cost and 79.5% landfill avoidance cost. A low-cost approach aimed at the integration of scavenging activities into conventional solid waste management is presented.     

Bermudagrass sod growth and metal uptake in coal combustion by-product-amended media

Coal combustion by-products (CCB) include fly ash and bottom ash and are generated nationally at rates of 10(8) Mg yr(-1). Land applications of CCB have improved physicochemical properties of soil, yet inherent bulkiness and trace metal content of CCB often limit their use. Likewise, utilization of biosolids and manure as fertilizer can be problematic due to unfavorable nutrient ratios. A 2-yr field study evaluated environmental and technical parameters associated with CCB-organic waste utilization as growth media in turfgrass sod production. Experimental growth media formulated with CCB and organic waste and a sand-compost control mixture were uniformly spread at rates from 200 to 400 m3 ha(-1) and sprigged with hybrid bermudagrass [Cynodon dactylon (L.) Pers. x C. transvaalensis Burtt-Davy]. Leaf clippings were collected and analyzed for total elemental content each year. In Year 2, growth media samples were collected during establishment 47 and 84 days after planting (DAP) and viable Escherichia coli organisms were quantified. At harvest (99 or 114 DAP), sod biomass and physicochemical properties of the growth media were measured. During sod propagation, micronutrient and metal content in leaf clippings varied by growth media and time. After 47 d of typical sod field management, viable E. coli pathogens were detected in only one biosolids-amended plot. No viable E. coli were measured at 84 DAP. In both years, sod biomass was greatest in media containing biosolids and fly ash. Following installation of sod, evaluations did not reveal differences by media type or application volume. Using CCB-organic waste mixes at the rates described herein is a rapid and environmentally safe method of bermudagrass sod production.