细水雾抑制熄灭K类火有效性的实验研究

本文通过全尺寸模拟实验研究了细水雾与K类火的相互作用,利用LDV／APV激光多普勒分析仪对细水雾特性进行了测量,分析了细水雾的粒径、速度及雾动量对灭火有效性的影响规律。分别改变喷头类型、工作压力、喷头与火源的垂直距离及喷射角度进行多种工况的灭火实验,结果表明,细水雾的灭火有效性随着压力的增大得到明显提高,喷头的雾化性能直接影响着细水雾的灭火有效性,同时喷射角度及喷射距离也影响着细水雾的灭火有效性。本文为细水雾灭火技术用于厨房环境的火灾防护提供了科学的参考依据和必要的设计参数。     

Performance evaluation of a water mist system in semiconductor wet bench fires

Wet benches are typically utilized in semiconductor facilities for wafer and parts cleaning. Heaters and some flammable liquids, such as acetone and isopropyl alcohol (IPA), are employed during the cleaning process. Wet bench fires have caused serious losses in the semiconductor industry. To assess the fire protection performance, several field tests were performed using a water mist system installed in the wet bench. In this study, acetone pan fuel was used as fire source. The test parameters were operational pressure, pan size, nozzle location, cylinder obstruction and degree of door closure. An appropriate design for operating pressure and the location of water mist nozzles extinguished wet bench fires effectively in the early fire stages. The nozzles are suggested to be fixed above or on the each side of the pan, ensuring that mist can completely cover a pan surface with sufficient momentum. With this suggested design, fires can be extinguished in the pan and do not spread over the wet bench.     

含微胶囊添加剂的低压细水雾厨房灭火实验研究

通过全尺寸实验研究低压细水雾对抑制和熄灭K类火灾的有效性。选用三种喷头进行灭火实验,并选择灭火效果最好的喷头进行含微胶囊F-500添加剂的细水雾灭火实验。结果表明,低压细水雾对抑制和熄灭食用油火灾具有一定的效果,但容易发生复燃。而添加了微胶囊F-500的低压细水雾,灭火效率较纯细水雾提高约3～10倍,且能有效地避免复燃,同时提高了火场的能见度。不同浓度的F-500溶液具有不同的灭火效果,综合考虑经济性和有效性因素,3％浓度的F-500溶液是厨房低压细水雾灭火系统的最佳灭火介质。     

储罐两环段喷淋圈管对供给强度的影响

国内储罐火灾爆炸事故时有发生,储罐消防冷却系统实施有效的冷却是控制火势和扑救初期火灾的主要因素之一。为了研究油罐消防喷淋系统在灭后冷却中的影响,本文选取4座5×10~3内浮顶罐组,开展消防冷却水系统喷洒实验,通过测试分析发现:实际的冷却水供给强度不满足规范的要求,并探讨了储罐固定冷却水系统供给强度不足的原因,结合分析的原因建议对规范中着火罐和临近罐供水强度要求统一均为2.5 L/(min·m^2),其冷却水喷淋圈管设置应为四段以上。     

气水喷嘴雾化特性实验研究

为研究不同类型气水喷嘴的雾化效果及气体流量和水流量对雾化效果的影响,基于实验室自行设计的气水喷雾实验系统,利用JL-3000型激光粒度分析仪及电磁流量计和转子流量计对气水喷嘴流量特性及最佳工况条件进行了实验研究。采用origin软件对数据进行分析得到雾化粒径及雾滴相对尺寸ΔS随气体流量及水流量的变化曲线,并以此衡量喷嘴的雾化效果。利用喷雾学、流体力学及多相流等理论对实验现象进行分析并得到喷嘴的最佳工况条件。实验结果表明:当水流量一定时,随着气体流量的增加,雾滴粒径减小速度由快变慢。当气体流量为80 L/min时,水流量为5 L/h即气液比为960时干雾喷嘴雾化效果最好,扇形喷嘴和锥形喷嘴气水流量分别为100 L/min,5 L/h和140 L/min,5 L/h,即气液比分别为1 200和1 680时其雾化效果最好。通过对比最佳雾化效果发现干雾喷嘴的雾滴粒径及雾滴相对尺寸最小,可以达到更好的雾化效果和经济效益。     

特高压换流变压器水喷雾灭火系统有效性实验研究

为考察在特高压换流变压器特殊火灾场景下水喷雾灭火系统的有效性,通过模拟不同数量喷头掉落情况下的冷喷实验,研究分析喷头工作压力、有效喷雾流量、水雾覆盖范围及全包络情况。结果表明：喷头工作压力、有效喷雾流量及水雾覆盖范围受掉落喷头占比影响显著,当掉落喷头占比超过10%时,喷头工作压力和有效喷雾流量均达不到标准规定要求,且喷头射程下降、覆盖范围缩小,无法全包络变压器;当喷头掉落后,消防水直接从消防支管以水柱射流形式喷射,不仅不具备水雾灭火的能力,而且有引发变压器热油火灾扩大的风险。     

喷雾降尘效率及喷雾参数匹配研究

采用压力型雾化喷嘴沉降煤矿粉尘简单实用。为了更好地利用喷雾技术高效沉降作业场所的粉尘,采用理论分析的方法得到水雾粒度与水压力之间的关系曲线,进一步得到喷雾降尘效率与水压力之间的关系曲线,并在煤矿井下进行试验验证。从而得出高效沉降粉尘应该用小口径喷嘴和较高的喷雾压力,但应限制在10MPa以下,超过该限值,降尘率提高甚微。2MPa以下的喷雾压力,降尘效率超不过50%,对水资源是一种浪费。当限定喷雾系统的水量消耗时,应采取减小喷嘴口径或减少喷嘴数量的方法获得较高的喷雾压力,从而获得较高的降尘效率。     

Characterization of a medium velocity deluge nozzle for offshore installations

It is important to study the characteristics of the nozzle of the deluge spray to comply with the standards developed by the petroleum industry for offshore installations in Norway. Due to the stochastic nature of the decomposition processes and geometrical features within the nozzle, the deluge spray has a complex flow field. Since the flow field determines the performance of the spray, the present study performs an experimental characterization of a medium velocity deluge nozzle for validation of computational fluid dynamics (CFD) models. The experiment was conducted for a maximum supply water pressure of 8.0 bar (g), which is identical to the operating pressures of offshore installations. Formerly, characterization studies of deluge or sprinkler spray were mostly targeted on residential usage with lower supply water pressures. I utilized a laser-based shadow imaging system to capture high-speed images, which were later processed in MATLAB. A linear patternator was used to validate the results of the shadow imaging technique. The geometrical features of the deluge nozzle played an important role in determining the characteristics of the spray. In addition, the supply water pressure significantly affected the size and velocity distributions of the droplets, applied density (volume flux), and area coverage. However, the Sauter mean diameter did not vary significantly with the azimuthal or radial position of the droplet within the inner region of the spray. The measurements obtained in this study can be used to estimate the extinguishing efficiency of a deluge system for offshore installations with elevated supply water pressures. Deviations between measurements with shadow imaging and patternator technique are discussed and discrepancies are discussed.     

细水雾灭火系统作用下特大断面公路隧道火灾特性数值模拟研究

细水雾灭火系统在公路隧道中的应用引发了较多关注,但是针对特大断面公路隧道的研究仍然不足。以2种大断面及4种特大断面公路隧道为研究对象,选取额定流量35 L/min、额定压力10 MPa的高压细水雾喷头,选择4种喷头布置形式,考虑火源功率、位置、遮挡物等影响因素,以隧道顶棚达到耐火极限的临界温度和相邻车辆被引燃的临界热辐射强度为判据,利用FDS模拟软件分析得到适用于隧道的细水雾喷头布置方案。结果表明对于特大断面隧道,细水雾单排顶喷布置不能有效抑制30 MW的大货车火灾,应采用增加顶喷或侧喷喷头的布置形式,从而保护隧道结构安全,防止相邻车辆被引燃。     

受限空间脉冲细水雾灭火数值模拟

为研究脉冲细水雾灭火效果和灭火机理,采用FDS软件对连续和脉冲细水雾熄灭受限空间油盘火进行了数值模拟。通过模拟和理论分析确定了脉冲细水雾周期为8 s开启、8 s暂停,并设置了冷却和窒息两种灭火条件,对两种细水雾熄灭不同尺寸的柴油池火进行了研究。结果表明:连续细水雾无法熄灭直径15 cm和20 cm的小尺寸油盘火,对直径25 cm中尺寸油盘火的灭火机理为冷却,对直径为30cm和35 cm大尺寸油盘火的灭火机理为窒息;脉冲细水雾能够熄灭不同尺寸的油盘火,且灭火效率高,火焰熄灭均发生在喷头暂停喷水期间,灭火机理为水雾蒸发稀释氧气而窒息。     

大型浮顶油罐新型灭火系统设计

针对大型浮顶油罐浮盘边缘式泡沫灭火系统存在的缺陷,设计了一种新型灭火系统。采用氮气加水雾代替传统的泡沫灭火,节约了成本;在现有的支管喷嘴上作了改进,使灭火效率得到了提高。从新型系统设计流程进行了介绍分析,对供给强度、流量和压强进行了计算说明。     

Research on the influence of foaming gas in compressed air/nitrogen foam on extinguishing the n-heptane tank fire

Tank fires threaten the lives of people and pollute the environment for their intense radiant heat, rapid fire spread and explosion hazard. Compressed air/nitrogen foam (CAF/CNF), a cleaner fire extinguishing technique used for the tank fire suppression because halogen-based agents were prohibited for environmental reasons. In this work, the influence of foaming gas in CAF/CNF on extinguishing the n-heptane tank fire was firstly investigated. Firstly, it was found that CNF spreads faster with rapid increase in foam thickness, mainly due to its better stability and less evaporation. Secondly, after foam was discharged, there existed a short increase of the combustion intensity, associated with three monotonous regions and two time delays in the whole extinguishing time. The two time delays were caused by Rayleigh–Taylor instability and flame sheet shift, respectively, and the shift distance was larger for CNF. Finally, the influential factors contributing to flame extinction were exhibited to be mainly related to the decrease in liquid burning rate and gas-phase Damkohler number. Among these factors, foam spreading rate and thickness dominated due to coupled chemical and physical extinguishing effects. Resulted from some competitive effects, CNF was slightly more efficient at extinguishing tank fires than CAF.     

Effect of bubble generation on hot zone formation in tank fires

Boilover is a phenomenon that both stakeholders and fire-fighters in the petrochemical industry try to avoid. This phenomenon results in an explosion of liquid hydrocarbon materials (e.g., crude oil) due to prolonged oil tank fires. The elevated temperature provides energy to vaporize the water sub-layer, which commonly resides at bottom of storage tanks, leading to tremendous fire enlargement as fuel tends to spill over around the tank. Boilover follows the formation of an isothermal layer called ‘hot zone’, and is typically accompanied by continuing bubble appearance in the hot zone. Previous studies have suggested that bubble generation could be a driving force for boilover, as it accelerates heat mixing. However, the effect of bubble generation on the mechanism of hot zone formation has not yet been systematically studied. This work investigates the effect of bubble formation on hot zone formation by installing a metal mesh in a burning fuel container. The size of the mesh grid and the position of the mesh are varied to generate bubbles with different volumes from different depths from the fuel surface. Experimental results demonstrate that the metal mesh definitely increases the volume of bubbles, and significantly reduces the time to form a hot zone. The mesh with small grids generates more bubbles than that with large grids. Additionally, bubbles start to generate earlier when the mesh is fixed nearer the fuel surface. Experimental results provide direct evidence of the bubble effect on hot zone formation.     

局部蒸汽系统抑制熄灭油池火的实验研究

选取乙醇为燃料试样,进行不同条件下蒸汽灭火的全尺寸实验,研究了局部蒸汽系统抑制熄灭油池火的有效性及其影响因素,并探讨其灭火机理.实验结果表明:喷口直径是影响蒸汽灭火的关键因素,中等直径的喷口具有较好的灭火效率;喷口方位和燃料浓度也会影响灭火有效性;局部蒸汽系统的有效保护面积大于直接覆盖面积,对可燃气和氧气的稀释置换作用...     

工作压力对细水雾雾场特性参数影响的实验研究

为了研究工作压力对细水雾雾场特性参数的影响,针对高、中低压细水雾喷头,测量、计算了不同工作压力下细水雾的雾化锥角、雾通量分布、粒径分布及雾动量,得到了高压细水雾与中低压细水雾雾场特性参数的区别及不同工作压力下细水雾雾场特性参数的变化规律,为细水雾喷头的开发及设计应用提供了相应的实验依据。     

综采面高压注水联合高压喷雾二级防尘技术研究

综采工作面的粉尘防治一直是煤矿安全工作的重点和难题之一。结合双鸭山矿区新安矿综采工作面的实际状况,采用现场煤层高压注水实验方法,研究了高压注水条件下煤体增湿的规律;运用注水实验数据进行反演数值试验,优化煤层高压注水数学模型内部参数,利用注水数值模拟试验确定了综采工作面煤层高压注水减尘技术的最优参数;运用了高压喷雾降尘效率模型数值模拟方法,分析确定了综采工作面采煤机外置高压喷雾降尘的最优参数,研发了孔径为1.2 mm的7孔高压集成喷嘴。新安二矿、三矿煤层高压注水联合高压喷雾二级防尘技术应用效果表明:通过二级联合防尘措施,工作面全尘去除率高达96%,呼吸性粉尘去除率高达94%。     

综采面高压注水联合高压喷雾二级防尘技术研究

综采工作面的粉尘防治一直是煤矿安全工作的重点和难题之一。结合双鸭山矿区新安矿综采工作面的实际状况,采用现场煤层高压注水实验方法,研究了高压注水条件下煤体增湿的规律;运用注水实验数据进行反演数值试验,优化煤层高压注水数学模型内部参数,利用注水数值模拟试验确定了综采工作面煤层高压注水减尘技术的最优参数;运用了高压喷雾降尘效率模型数值模拟方法,分析确定了综采工作面采煤机外置高压喷雾降尘的最优参数,研发了孔径为1.2 mm的7孔高压集成喷嘴。新安二矿、三矿煤层高压注水联合高压喷雾二级防尘技术应用效果表明:通过二级联合防尘措施,工作面全尘去除率高达96%,呼吸性粉尘去除率高达94%。     

Numerical modeling of water spray suppression of conveyor belt fires in a large-scale tunnel

Conveyor belt fires in an underground mine pose a serious life threat to miners. Water sprinkler systems are usually used to extinguish underground conveyor belt fires, but because of the complex interaction between conveyor belt fires and mine ventilation airflow, more effective engineering designs are needed for the installation of water sprinkler systems. A computational fluid dynamics (CFD) model was developed to simulate the interaction between the ventilation airflow, the belt flame spread, and the water spray system in a mine entry. The CFD model was calibrated using test results from a large-scale conveyor belt fire suppression experiment. Simulations were conducted using the calibrated CFD model to investigate the effects of sprinkler location, water flow rate, and sprinkler activation temperature on the suppression of conveyor belt fires. The sprinkler location and the activation temperature were found to have a major effect on the suppression of the belt fire, while the water flow rate had a minor effect.     

氯乙烯储罐注水堵漏腐蚀风险的预测方法研究*

为更好地解决氯乙烯储罐注水堵漏可能导致储罐发生腐蚀泄漏的实际问题,提出1种基于ASPEN和神经网络的氯乙烯储罐注水堵漏腐蚀风险的预测方法。运用ASPEN流程模拟软件,对氯乙烯储罐注水堵漏工艺进行模拟,得到不同泄漏孔径下注水速率和HCl浓度的关系;以HCl浓度作为导致腐蚀的主要影响因素,对不同种钢材进行挂片腐蚀实验;结合神经网络分析,得出HCl浓度与腐蚀速率之间的拟合式,预测储罐腐蚀情况。结果表明:神经网络预测结果平均相对误差7.63%,随注水速率的提高,HCl浓度变化呈下降趋势,腐蚀速率变化呈下降趋势;在等效泄漏孔径24 mm、注水速率0.87 m/s时,Q345R腐蚀速率13.93 mm/a,20#腐蚀速率10.48 mm/a,201不锈钢腐蚀速率7.09 mm/a为3者中最低,但此工况下,201不锈钢有点蚀倾向,储罐易发生穿孔,故201不锈钢不宜用作氯乙烯储罐母材,并提出对《石油化工企业设计防火标准(2018年版)》的修订建议。     

Improved models of failure time for atmospheric tanks under the coupling effect of multiple pool fires

Fire accidents of chemical installations may cause domino effects in atmospheric tank farms, where a large amount of hazardous substances are stored or processed. Pool fire is a major form of fire accidents, and the thermal radiation from pool fire is the primary hazard of domino accidents. The coupling of multiple pool fires is a realistic and important accident phenomenon that enhances the propagation of domino accidents. However, previous research has mostly focused on the escalation of domino accidents induced by a single pool fire. To overcome the drawback, in this study, the failure of a storage tank under the coupling effect of multiple pool fires was studied in view of spatial and temporal synergistic process. The historical accident statistics indicated that the accident scenario of two-pool fires accounted for 30.6% in pool fires. The domino accident scenario involving three tanks is analyzed, and the typical layout of tanks is isosceles right triangle based on Chinese standard “GB50341-2014”. The thermal response and damage of a target tank heated by pool fires were numerically investigated. The volume of 500 m³, 3000 m³, 5000 m³ and 10000 m³ were selected. Flame temperature was obtained by FDS, and then was input onto the finite element model. The temperature field and stress field of target tanks were simulated by ABAQUS. The results showed that the temperature rise rate of the target tanks under multiple pool fires was higher than that under a single pool fire. The failure time of the tank under the coupling effect of multiple fires was lower than that under the superposition of multiple fires without the first stage. The stress and yield strength were compared to judge the failure of the target tank. The model of failure time for the tank under the coupling effect of pool fires was established. Through the verification, the deviation of this model is 4.02%, which is better than the deviation of 15.76% with Cozzani's model.