IDENTIFICATION OF DISSOLVED-CONSTITUENT SOURCES IN MINE-SITE GROUND WATER USING BATCH MIXING1

ABSTRACT: Batch-mixing experiments were used to help identify lithologic and mineralogic sources of increased concentrations of dissolved solids in water affected by surface coal mining in northwestern Colorado. Ten overburden core samples were analyzed for mineral composition and mixed with distilled water for 90 days until mineral-water equilibrium was reached. Between one day and 90 days after initial contact, specific conductance in the sample mixtures had a median increase of 306 percent. Dissolved-solids concentrations ranged from 200 to 8,700 mg/L in water samples extracted from the mixtures after 90 days. Mass. balance simulations were conducted using the geochemical models BALANCE and WATEQF to quantify mineral-water interactions occurring in five selected sample mixtures and in water collected from a spring at a reclaimed mine site. The spring water is affected by mineral-water interactions occurring in all of the lithologic units comprising the overburden. Results of the simulations indicate that oxidation of pyrite, dissolution of dolomite, gypsum, and epsomite, and cation-exchange reactions are the primary mineral-water interactions occurring in the overburden. Three lithologic units in the overburden (a coal, a sandstone, and a shale) probably contribute most of the dissolved solids to the spring water. Water sample extracts from mixtures using core from these three units accounted for 85 percent of the total dissolved solids in the 10 sample extracts. Other lithologic units in the overburden probably contribute smaller quantities of dissolved solids to the spring water.     

SALINITY ISSUES AND WATER DEVELOPMENT IN THE GREEN RIVER BASIN,WYOMING1

Water development in the Green River Basin of Wyoming is projected to increase salinity downstream in the Green River and Colorado River, and thereby increase salinity costs to users of water from these two rivers. Despite these water quality and economic impacts to downstream water users, Wyoming will probably be able to develop its currently unused but allocated water supplies of the Green River Basin. The Colorado River Compact and Upper Colorado River Basin Compact are binding, and protect Wyoming's share of the Colorado River System waters for future use. The argument that water may be used to greater profit downstream is not sufficient to reduce Wyoming's allocation. In addition, the no-injury rule under the appropriation doctrine of law does not appear to protect prior downstream appropriations from increasing salinity in this case.     

GENERALIZED WATERSHED LOADING FUNCTIONS FOR STREAM FLOW NUTRIENTS1

ABSTRACT: Loading functions are proposed as a general model for estimating monthly nitrogen and phosphorus fluxes in stream flow. The functions have a simple mathematical structure, describe a wide range of rural and urban nonpoint sources, and couple surface runoff and ground water discharge. Rural runoff loads are computed from daily runoff and erosion and monthly sediment yield calculations. Urban runoff loads are based on daily nutrient accumulation rates and exponential wash off functions. Ground water discharge is determined by lumped parameter unsaturated and saturated zone soil moisture balances. Default values for model chemical parameters were estimated from literature values. Validation studies over a three-year period for an 850 km² watershed showed that the loading functions explained at least 90 percent of the observed monthly variation in dissolved and total nitrogen and phosphorus fluxes in stream flow. Errors in model predictions of mean monthly fluxes were: dissolved phosphorus - 4 percent; total phosphorus - 2 percent; dissolved nitrogen - 18 percent; and total nitrogen - 28 percent. These results were obtained without model calibration.     

SALT PICKUP BY OVERLAND FLOW IN THE PRICE RIVER BASIN,UTAH1

ABSTRACT: This study emphasized a field investigation of salt release to overland flow from Mancos shale lands of the Price River Basin, Utah. Although a high degree of natural variation existed in the data, which precluded the separation of factors affecting diffuse salt loading that occurs during overland flow, a simplistic nonpoint source loading function developed on empirical concepts was fit to the data. This function was then used to calculate the average annual salt yield to the Price River by overland flow. It was found that even under severe conditions, the salt yields from Mancos shale lands due to overland flow is relatively minor, accounting for less than 1.5 percent of the average annual salt mass transported from the basin by the Price River.     

ALTERNATIVES FOR SALINITY MANAGEMENT IN THE COLORADO RIVER BASIN1

ABSTRACT The Colorado River Basin faces the dilemma of an increasing demand for water while presently struggling with salinity concentrations approaching critical levels for some water uses. Based upon projected development salinity concentrations are predicted to exceed 1200 mg/1 at Imperial Dam by the year 2010. Annual losses to the basin economy associated with increased salinity will exceed $50 million by the year 2010. Although methods of controlling salt discharges are relatively unrefined, certain conclusions, based upon Bayesian statistical methods, can be reached. Five basic alternatives for coping with the problem are presented and evaluated in this paper: (1) do nothing; (2) adopt arbitrary salinity standards; (3) limit development; (4) control salt discharges at a cost equal to the cost of doing nothing, or (5) minimize total costs to the basin. Total costs associated with any given alternative, or the given salinity resulting, are the sum of salinity detriments (cost to users for water of increased salinity plus economic multiplier effects) plus the cost of constructing salt discharge control works. These impacts upon basin economy and Colorado River water quality for each alternative are presented and related to questions of equity which will play a role in arriving at any long-term solution to the Basin's problem.     

NITROGEN AND PHOSPHORUS IN SURFACE WATERS OF THE UPPER COLORADO RWER BASIN1

ABSTRACT: As part of a basinwide water-quality study, nitrogen and phosphorus data for the Upper Colorado River Basin from the Colorado-Utah State line to the Continental Divide were analyzed for spatial distributions, concentrations associated with various land uses, and temporal trends. Nitrogen and phosphorus concentrations generally increased in a downstream direction. Some nutrient concentrations were elevated at some sites in the upper parts of the basin in areas influenced by increasing urbanization. Sites were grouped according to land use and site type, and median nutrient concentrations were compared among groups. Sites within the agricultural areas of the basin generally had the highest concentrations of nitrogen and phosphorus; concentrations for main-stem, tributary, and urbanization sites were slightly lower than for the agricultural sites. Background sites, or sites with minimal land-use impacts, had very low median nutrient concentrations. Several sites with long-term data were analyzed for temporal trends in concentrations. Several statistically significant downward trends of low and moderate magnitude were observed for nitrogen and phosphorus species. No upward trends were observed in the data at any site.     

Soluble Mineral Content in Surficial Alluvium and Associated Mancos Shale1

ABSTRACT: The Mancos Shale area of the Upper Colorado River basin produces large quantities of solutes. In order to develop an understanding of the mechanism of salt production and to determine the source of salinity, a study of the soluble mineral content (SMC) of Mancos Shale and associated alluvium was undertaken. SMC is highly variable in alluvium and associated surficial Mancos Shale. However, lithomorphological units can be identified in terms of their SMC. Results from this study demonstrate that crusts are leached in deep alluvial fills and they contain somewhat less soluble minerals than underlying Mancos Shale on hillslopes. The crusts are saline, sometimes efflorescent, in shale bedrock channels or where channels abutt against the shale. SMC increases in alluvium with decrease in depth of alluvial fill, does not vary significantly with depth in deep of alluvial fills, and increases with depth in shallow ones.     

WATER FOR ENERGY: AN APPROACH TO COMPREHENSIVE IMPACT ASSESSMENT1

ABSTRACT: The effects of energy development on the water resources of the Colorado River and Great Basin regions is expected to be substantial. Complex physical, economic and institutional interactions may be expected. Most research on these impacts appears single purpose, fragmented, uncoordinated, and often inaccessible to potential users - particularly those with responsibility for energy/water policy and program decisions. A comprehensive, integrative framework for assessing alternative water allocation decisions is outlined, taking a heuristic decision making model for evaluating impacts on maximization of gross (or net) regional product, and regional social welfare, and for assessing the region's contribution to national objectives. The suggested model provides a structure for application and integration of data of various kinds to a range of situations arising from possible impacts from energy proposals. The focus is on water and energy relationships but the model may provide a framework for comprehensive analysis of a variety of environmental actions and resulting system perturbations and effects.     

SEQUENTIAL WATER REUSE EFFECT ON STREAM SALINITY1

ABSTRACT: Sequential water reuse by various users, i.e., municipal, industrial, agricultural, is common practice in all river systems. In the arid and semiarid western United States where streams are not large and water demands are high relative to the virgin water supply, the practice causes a reduction in stream flow and an increase in stream salinity. This paper outlines a quick and easy application of the materials balance principle to approximate the effects of increasing the level of sequential reuse on residual stream flow and salinity.     

DINOSAUR NATIONAL MONUMENT: THE EVOLUTION OF A FEDERAL RESERVED WATER RIGHT1

ABSTRACT: Dinosaur National Monument, in northwestern Colorado, has become a test case in the establishment of a federal reserved water right to instream flows. For the first time, the Interior Department was forced to rigorously defend its claims in a watershed where the federal government did not control the upstream reaches. Inadequate quantification of minimum flow requirements, court orders, and an apparent Congressional ban on the spending of Water Resources Program funds by the Park Service to quantify its water rights have already placed the Service in a difficult position to protect instream flows for maintaining the ecological integrity of the Monument. As late as 1983, administrators of the Park Service were divided over their legal strategy, many wanting to pursue a policy of claiming “natural, historic” flows rather than “minimum” flows. The conditional right to instream flows panted to the Park Service in 1978 was subject to quantification within five years. That deadline has been extended, but it is not likely that the case will reach final settlement this decade. Until the design and conduct of federal water rights quantifications better integrate public policy and law with science, the principle lesson from Dinosaur may have to be repeated.     

A GAMING EVALUATION OF COLORADO RWER DROUGHT MANAGEMENT INSTITUTIONAL OPTIONS1

ABSTRACT: Researchers representing each of the Colorado River Basin states as well as the Secretary of the Interior were presented with an interactive computer simulation of a progressively increasing drought and were given the collective opportunity to change the ways in which basin-wide and within-state water management were conducted. The purpose of this “gaming” exercise was to identify rules for managing the Colorado River which are effective in preventing drought-caused damages to basin water users. This water management game was conducted three times, varying the collective choice roles for management of the river yet staying substantially within the current institution for management of the Colorado River known as the “Law of the River.” The Law of the River was quite effective in minimizing drought impacts upon consumptive water uses. Additional effective drought-coping measures to protect consumptive uses consisted mostly of intrastate water management improvements which states were able to implement independently. The Law of the River did not protect non-consumptive water uses, such as hydroelectric power generation, water-based recreation, endangered species, and water quality from drought, as well as it protected consumptive water uses. Players reached collective choice decisions to cope with rising salinity, equalize storage between the upper and lower basins, and protect endangered species. While these measures had some success, only reductions in withdrawals for consumptive uses, particularly in the upper basin, could have substantially lessened adverse impacts.     

A SYSTEMATIC ANALYSIS OF THE CONSTRAINTS TO URBAN STREAM ENHANCEMENTS1

ABSTRACT: The environment surrounding urban streams imposes constraints upon stream enhancement projects. Constraints include bridges, culverts, highways, sewer and water lines, lack of easements, and other floodplain structures. The consequences of failure of these infrastructure constraints can be significant and should be considered in the design process. Fault tree analysis provides a systematic technique for analyzing the interactions of events that could lead to infrastructure failure. A case study of a stream in Pittsburgh, Pennsylvania, shows that fault tree analysis can effectively model the interactions between the stream system and the infrastructure constraints and predict the most likely modes of failure. In addition, the relative success of alternative designs and failure mitigation techniques can be assessed using this analysis tool, lending insight into the urban stream enhancement design process. The method could also provide justification in the design permitting process and input for risk assessment.     

Evaluation of the Temporal Transferability of a Model Describing Dissolved Solids in Streams of the Upper Colorado River Basin1

Kenney, Terry A. and Susan G. Buto, 2012. Evaluation of the Temporal Transferability of a Model Describing Dissolved Solids in Streams of the Upper Colorado River Basin. Journal of the American Water Resources Association (JAWRA) 48(5): 1041‐1053. DOI: 10.1111/j.1752‐1688.2012.00667.x Abstract: The application of a nonlinear least‐squares regression model describing the sources and transport of dissolved solids in streams of the Upper Colorado River Basin, and that was calibrated using data from water year 1991, was evaluated for use in predicting annual dissolved‐solids loads for the years 1974 through 1998. Simulations for each water year were run using annual climate data. To evaluate how well the model captures the observed annual variability across the basin, differences in predicted annual dissolved‐solids loads for each simulated year and 1991 were compared with differences in monitored annual loads. The temporal trend of the differences between predicted annual loads for the simulated years and the load for 1991 generally followed the trend of the monitored loads. The model appears to underpredict the largest annual loads and overpredict some of the smaller annual loads. An underprediction bias for wetter years was evident in the residuals as was an overprediction bias, to a lesser degree, for drier years. A regression analysis on the residuals suggests that the underprediction bias is associated with precipitation differences from 1991 and with previously defined downward trends in dissolved‐solids concentrations in the basin. In general, given the representative climatic conditions, the model adequately performs throughout the period examined. However, the model is most transferable to years with climatic conditions similar to 1991.     

SELENIUM BUDGETS FOR LAKE POWELL AND THE UPPER COLORADO RWER BASIN1

ABSTRACT: A selenium budget for Lake Powell, Utah-Arizona was determined based on selenium loads at the principal stream input sites to and the output site from the lake. Based on data collected during 1985-1994, 83 percent of the selenium entering Lake Powell is accounted for at the output site. The rest of the selenium may be incorporated by lake sediment or used by the biota. Considerably more selenium per unit area is produced from the Colorado River Basin above the Colorado River-Green River confluence than from the Green River Basin and the San Juan River Basin combined. The Gunnison River Basin and the Grand Valley in Colorado produce an estimated 31 and 30 percent of the selenium that reaches Lake Powell, respectively. Irrigation-related activities are thought to be responsible for mobilizing 71 percent of the selenium that reaches Lake Powell. Selenium concentrations in water at Imperial Dam on the Colorado River upstream of the United States-Mexico international border are similar to those at the output site of Lake Powell. Therefore, most selenium observed in downstream areas of the Colorado River therefore probably is derived mostly from the Colorado River Basin above Lake Powell.     

AN EVALUATION OF PHYSICAL STREAM HABITAT ATTRIBUTES USED TO MONITOR STREAMS1

ABSTRACT: The last few decades have seen an increased reliance on the use of stream attributes to monitor stream conditions. The use of stream attributes has been criticized because of variation in how observers evaluate them, inconsistent protocol application, lack of consistent training, and the difficulty in using them to detect change caused by management activity. In this paper, we evaluate the effect of environmental heterogeneity and observer variation on the use of physical stream attributes as monitoring tools. For most stream habitat attributes evaluated, difference among streams accounted for greater than 80 percent of the total survey variation. To minimize the effect that variation among streams has on evaluating stream conditions, it may be necessary to design survey protocols and analysis that include stratification, permanent sites, and/or analysis of covariance. Although total variation was primarily due to differences among streams, observers also differed in their evaluation of stream attributes. This study suggests that if trained observers conducting a study that is designed to account for environmental heterogeneity can objectively evaluate defined stream attributes, results should prove valuable in monitoring differences in reach scale stream conditions. The failure to address any of these factors will likely lead to the failure of stream attributes as effective monitoring tools.     

DISTRIBUTION OF BENTHIC MACROINVERTEBRATES IN A STREAM EXPOSED TO URBAN RUNOFF1

ABSTRACT: A study of benthic macroinvertebrate community composition was conducted at eight sites along Shabakunk Creek, a small stream in Mercer County, New Jersey, which receives urban runoff. The relationship between changes in substrate composition and the nature of the benthic macroinvertebrate community has been examined. Organisms were collected seasonally from natural substrates in riffles. Attempts to employ artificial substrates for invertebrate collection proved unsuccessful, as the population on the samplers was not representative of that in the stream bed. Number of total benthic macroinvertebrate taxa collected declined from 13 in relatively undeveloped upstream areas to four below heavily developed areas, while population density decreased simultaneously in the same areas. Periphyton samples collected from natural substrates were analyzed for selected heavy metals. Significantly higher heavy metal concentrations are reported from substrates sampled below heavily developed areas, and changes in these values are discussed with regard to changes in benthic macroinvertebrate distribution.     

MICROBIOLOGICAL QUALITY OF PUGET SOUND BASIN STREAMS AND IDENTIFICATION OF CONTAMINANT SOURCES1

ABSTRACT: Fecal coliforms, Escherichia coli, enterococci, and somatic coliphages were detected in samples from 31 sites on streams draining urban and agricultural regions of the Puget Sound Basin Lowlands. Densities of bacteria in 48 and 71 percent of the samples exceeded U.S. Environmental Protection Agency's freshwater recreation criteria for Escherichia coli and enterococci, respectively, and 81 percent exceeded Washington State fecal coliform standards. Male‐specific coliphages were detected in samples from 15 sites. Male‐specific F⁺RNA coliphages isolated from samples taken at South Fork Thornton and Longfellow Creeks were serotyped as Group II, implicating humans as potential contaminant sources. These two sites are located in residential, urban areas. F⁺RNA coliphages in samples from 10 other sites, mostly in agricultural or rural areas, were serotyped as Group I, implicating non‐human animals as likely sources. Chemicals common to wastewater, including fecal sterols, were detected in samples from several urban streams, and also implicate humans, at least in part, as possible sources of fecal bacteria and viruses to the streams.     

NATURAL VEGETATION AS A SOURCE OF DIFFUSE SALT WITHIN THE COLORADO RIVER BASIN1

Abstract: Foliage and litter leachate from selected natural vegetation in the Price River Basin (within the Upper Colorado River basin) was studied to determine the probable impact of plants on the amount of diffuse salt movement from rangeland watersheds. Calculations using concentrations of various leachates and characteristics of range sites expected to be high salt annual salt load to the Price River. It was therefore concluded that plants are not a significant source of diffuse salt within the Colorado River Basin.     

WEATHER MODIFICATION: AN ECONOMIC ALTERNATIVE FOR AUGMENTING WATER SUPPLIES1

ABSTRACT. Experimental results of cloud seeding in Southwestern Colorado suggest that runoff can be increased by 25 percent over a 3,300 mile area. There is a need to estimate the economic consequences in the Colorado River Basin. The evidence presented suggests that weather modification is an economically feasible means to provide additional water for the basin. Compared with other proposed means of augmenting water supplies, weather modifications appear to be one of the least cost alternatives. A very low proportion of weather modification costs are fixed; thus the program is easily reversible. Also, a relatively small increase in daily precipitation covers the direct costs of operation. Benefits of water produced by weather modification included power production and irrigation of forage crops. In the long run, if additional water is used for higher valued fruit and vegetable production, or for domestic and industrial purposes, its value would rise sharply. Preliminary investigation of extra-market costs and benefits suggests that while they have little effect on the benefit-cost ratio, they may be very important to individuals and groups affected. The distribution of costs and benefits is important as the benefits accrue to downstream users and some of the costs are incurred by Coloradoans. There is a need for further research on the long-run economic effects of weather modification programs, particularly with respect to extra-market factors.