Lanthanum cobaltite perovskite supported onto mesoporous zirconium dioxide: nature of active sites of VOC oxidation

Novel catalytic nano-sized materials based on LaCoO(x) perovskite nanoparticles incapsulated in the mesoporous matrix of zirconia were prepared, characterized by physicochemical methods and tested in complete methanol oxidation. LaCoO(x) nanoparticles were prepared inside the mesopores of ZrO(2) by decomposition of bimetallic La-Co glycine precursor complexes. The catalysts have been studied by diffuse-reflectance FTIR-spectroscopy using such probe molecules as CO, CD(3)CN and CDCl(3) to test low-coordinated metal ions. At low temperatures of decomposition of complexes (up to 400°C), low-coordinated Co(3+) ions predominate in the LaCoO(x) nanoparticles, whereas basically Co(2+) ions are found upon increasing the decomposition temperature to 600°C. The novel nano-sized perovskite catalysts exhibit a very high catalytic activity in the abatement of volatile organic compounds present in air, like methanol and light hydrocarbons.     

New international long-term ecological research on air pollution effects on the Carpathian Mountain forests,Central Europe

An international cooperative project on distribution of ozone in the Carpathian Mountains, Central Europe was conducted from 1997 to 1999. Results of that project indicated that in large parts of the Carpathian Mountains, concentrations of ozone were elevated and potentially phytotoxic to forest vegetation. That study led to the establishment of new long-term studies on ecological changes in forests and other ecosystems caused by air pollution in the Retezat Mountains, Southern Carpathians, Romania and in the Tatra Mountains, Western Carpathians on the Polish-Slovak border. Both of these important mountain ranges have the status of national parks and are Man & the Biosphere Reserves. In the Retezat Mountains, the primary research objective was to evaluate how air pollution may affect forest health and biodiversity. The main research objective in the Tatra Mountains was to evaluate responses of natural and managed Norway spruce forests to air pollution and other stresses. Ambient concentrations of ozone (O(3)), sulfur dioxide (SO(2)), nitrogen oxides (NO(x)) as well as forest health and biodiversity changes were monitored on densely distributed research sites. Initial monitoring of pollutants indicated low levels of O(3), SO(2), and NO(x) in the Retezat Mountains, while elevated levels of O(3) and high deposition of atmospheric sulfur (S) and nitrogen (N) have characterized the Tatra Mountains. In the Retezat Mountains, air pollution seems to have little effect on forest health; however, there was concern that over a long time, even low levels of pollution may affect biodiversity of this important ecosystem. In contrast, severe decline of Norway spruce has been observed in the Tatra Mountains. Although bark beetle seems to be the immediate cause of that decline, long-term elevated levels of atmospheric N and S depositions and elevated O(3) could predispose trees to insect attacks and other stresses. European and US scientists studied pollution deposition, soil and plant chemistry, O(3)-sensitive plant species, forest insects, and genetic changes in the Retezat and Tatra Mountains. Results of these investigations are presented in a GIS format to allow for a better understanding of the changes and the recommendations for effective management in these two areas.     

Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes

Over the past few years, pharmaceuticals are considered as an emerging environmental problem due to their continuous input and persistence to the aquatic ecosystem even at low concentrations. Advanced oxidation processes (AOPs) are technologies based on the intermediacy of hydroxyl and other radicals to oxidize recalcitrant, toxic and non-biodegradable compounds to various by-products and eventually to inert end-products. The environmental applications of AOPs are numerous, including water and wastewater treatment (i.e. removal of organic and inorganic pollutants and pathogens), air pollution abatement and soil remediation. AOPs are applied for the abatement of pollution caused by the presence of residual pharmaceuticals in waters for the last decade. In this light, this paper reviews and assesses the effectiveness of various AOPs for pharmaceutical removal from aqueous systems.     

Adverse health effects of outdoor air pollutants

Much research on the health effects of outdoor air pollution has been published in the last decade. The goal of this review is to concisely summarize a wide range of the recent research on health effects of many types of outdoor air pollution. A review of the health effects of major outdoor air pollutants including particulates, carbon monoxide, sulfur and nitrogen oxides, acid gases, metals, volatile organics, solvents, pesticides, radiation and bioaerosols is presented. Numerous studies have linked atmospheric pollutants to many types of health problems of many body systems including the respiratory, cardiovascular, immunological, hematological, neurological and reproductive/ developmental systems. Some studies have found increases in respiratory and cardiovascular problems at outdoor pollutant levels well below standards set by such agencies as the US EPA and WHO. Air pollution is associated with large increases in medical expenses, morbidity and is estimated to cause about 800,000 annual premature deaths worldwide [Cohen, A.J., Ross Alexander, H., Ostro, B., Pandey, K.D., Kryzanowski, M., Kunzail, N., et al., 2005. The global burden of disease due to outdoor air pollution. J Toxicol Environ Health A. 68: 1-7.]. Further research on the health effects of air pollution and air pollutant abatement methods should be very helpful to physicians, public health officials, industrialists, politicians and the general public.     

我国技术变迁对环境影响的计量分析

为了促进技术变迁因素在我国环境保护中发挥更大的作用,需要分析其以往对环境的影响,为我国的技术政策提供支持。使用动态基期,用统计方法定量计算了 1994~2004年各年度技术变迁因素对我国主要空气和水污染物排放量的影响。按是否以削减污染为直接目标,可将技术变迁分为2类：(1)生产工艺的变化。这种技术变化不以污染削减为直接目标,但会影响到生产投入物的数量和种类、生产过程中污染物的产生量并因此影响到最终的污染强度和排放量。(2)污染削减技术的变化。这种技术变化以污染削减为直接目标。利用环境统计年鉴中的污染削减量数据将技术效应分解为2部分：源自污染削减技术和源自生产工艺,发现从总体上看技术变迁降低了所有污染物的排放量,其中污染削减技术对所有污染排放量的下降都起了积极作用,但伴随较大的年度变化。生产工艺变化对不同污染物的影响方向不同。可见中国目前的污染削减主要依靠“末端”污染削减技术,“过程控制型”生产工艺没有充分发挥应有作用,也反映出目前技术变迁尚未向“环境友好型”演进。因此,要促使我国技术变迁向“环境友好型”演进,特别需要促进清洁生产技术的开发和推广,在生产过程中减少污染物的产生.     

Development of an aggregate Air Quality Index for an urban Mediterranean agglomeration: relation to potential health effects

It is very useful for the authorities and the people to have daily easy understandable information about the levels of air pollution and the proper measures to be taken for the protection of human health. In this paper we develop an aggregate Air Quality Index (AQI) based on the combined effects of five criteria pollutants (CO, SO2, NO2, O3 and PM10) taking into account the European standards. We evaluate it for each monitoring station and for the whole area of Athens, Greece, an area with serious air pollution problems. A comparison was made with a modified version of Environmental Protection Agency/USA (USEPA) maximum value AQI model adjusted for European conditions. Hourly data of air pollutants from 4 monitoring stations, available during 1983-1999, were analysed for the development of the proposed index. The analysis reveals the Athenian population exposure reaches high levels and during last years a gradual increase of days with unhealthy conditions was detected. The proposed aggregate model estimates more effectively the exposure of citizens comparing with the modified USEPA maximum value model, because counts the impact of all the pollutants measured. Towards the informing and protection of the citizens in an urban agglomeration this model advantages as a political and administrative tool for the design of abatement strategies and effective measures of intervention.     

Toxic risk of surface water pollution--six years of experience

Assessment of an ecological quality of surface water is necessary for effective protection, abatement and successive revitalisation of river ecosystems. This quality is primarily given by biological impact of surface water pollution. Substances contained in pollution are frequently toxic to aquatic organisms. Risk of chronic impact of surface water pollution is very often underestimated due to hidden long time action of pollutants. Proper estimation of the risk is not possible from results of chemical analyses and data of substances' toxicity. Chemical analyses are not able to detect all substances presented in water including the products of reactions between them. In addition, a simultaneous presence of substances can modify their final effect on aquatic organisms. Therefore, a complex method of assessment of toxic risk of surface water pollution based on ecotoxicological approach was developed. The toxic risk of surface water pollution is determined from results of evaluation of toxic risk of organic part and inorganic part of surface water pollution. Resultant degree of toxic risk of total pollution is given by the highest degree detected in any part of the water pollution. Presented method, which is routinely used for monitoring in the Czech part of the Odra river basin, was fully standardised and published in the form of the Czech branch technical norm of water management (TNV) in the year 2000.     

Spatial variability of shallow groundwater level, electrical conductivity and nitrate concentration, and risk assessment of nitrate contamination in North China Plain

In recent years, nitrate (NO3) contamination of groundwater has become a growing concern for people in rural areas in North China Plain (NCP) where groundwater is used as drinking water. The objective of this study was to evaluate groundwater resource level, to determine groundwater quality and to assess the risk of NO3 pollution in groundwater in Quzhou County in the NCP. Ordinary Kriging (OK) method was used to analyze the spatial variability of shallow groundwater level, groundwater electrical conductivity (EC) and NO3-N concentrations, and Indictor Kriging (IK) method was used to analyze the data with NO3-N concentrations equal or greater than the groundwater NO3 pollution threshold (20 mg L(-1)). The results indicated that groundwater level averaged 9.81 m, a level 6 m lower than in 1990. The spatial correlation distances for groundwater level, EC and NO3-N concentration were 21.93, 2.19 and 3.55 km, respectively. The contour map showed that shallow groundwater level areas extended from north to south across the County. Groundwater EC was above 3 dS m(-1) in the most part of the northern county. Groundwater NO3 pollution (NO3-N> or =20 mg L(-1)) mainly occurred in the County Seat areas due to wastewater irrigation and excessive fertilizer leaching from agricultural fields. At Henantuang town, besides suburban of the County Seat, groundwater was also contaminated by NO3 shown by the map generated using the IK method, which was not reflected in the map generated using the OK method. The map generated using the OK method could not reflect correctly the groundwater NO3 pollution status. The IK method is useful to assess the risk of NO3 pollution by giving the conditional probability of NO3 concentration exceeding the threshold value. It is suggested that risk assessment of NO3 pollution is useful for better managing groundwater resource, preventing soil salinization and minimizing NO3 pollution in groundwater.     

Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: A review

In the last years, the decontamination and disinfection of waters by means of direct or integrated electrochemical processes are being considered as a very appealing alternative due to the significant improvement of the electrode materials and the coupling with low-cost renewable energy sources. Many electrochemical technologies are currently available for the remediation of waters contaminated by refractory organic pollutants such as pharmaceutical micropollutants, whose presence in the environment has become a matter of major concern. Recent reviews have focused on the removal of pharmaceutical residues upon the application of other important methods like ozonation and advanced oxidation processes. Here, we present an overview on the electrochemical methods devised for the treatment of pharmaceutical residues from both, synthetic solutions and real pharmaceutical wastewaters. Electrochemical separation technologies such as membrane technologies, electrocoagulation and internal micro-electrolysis, which only isolate the pollutants from water, are firstly introduced. The fundamentals and experimental set-ups involved in technologies that allow the degradation of pharmaceuticals, like anodic oxidation, electro-oxidation with active chlorine, electro-Fenton, photoelectro-Fenton and photoelectrocatalysis among others, are further discussed. Progress on the promising solar photoelectro-Fenton process devised and further developed in our laboratory is especially highlighted and documented. The abatement of total organic carbon or reduction of chemical oxygen demand from contaminated waters allows the comparison between the different methods and materials. The routes for the degradation of the some pharmaceuticals are also presented.     

中国工业环境规制强度的行业差异及收敛性研究

针对不同行业环境规制强度的差异性,本文运用收敛理论研究了行业环境规制强度的敛散性。传统上利用单位成本或产出的污染治理费用表示的行业环境规制强度可能存在有偏性,本文基于单位污染排放的污染治理费用测算行业环境规制强度,利用Theil指数和收敛检验模型,分析了2001—2015年中国35个工业行业环境规制强度差异、收敛性质及收敛机制。研究发现:(1)一些行业的环境规制强度与其污染强度未表现出相应的强关联性。(2)中国工业行业环境规制强度差异呈现"M"型变化趋势,污染行业与清洁行业之间的环境规制强度差异呈现先发散后收敛的倒"U"型趋势。(3)泰尔指数及其分解还表明,污染行业内部的子行业间环境规制强度差异很大,且是造成工业行业环境规制强度差异的最主要来源。(4)工业行业环境规制强度存在较长时段的σ收敛和较短时长的俱乐部收敛的同时,还存在绝对β收敛和条件β收敛,即低规制行业向高规制行业看齐,不同行业环境规制强度向各自的稳态水平靠近,此外,污染行业环境规制强度收敛速度慢于清洁行业。(5)企业规模成长和市场化水平提升有利于促进企业提高环境规制水平。(6)对收敛机制的进一步研究表明,出口学习效应和进口技术溢出对行业环境规制强度变化的提升效应随着环境规制强度的提高而扩大,即两者对行业环境规制强度变化具有提升效应,但无促进其收敛的作用。扩大企业规模、提升市场化和对外开放水平,有利于提升企业应对环境规制的能力,并为下一阶段实施更为合理有效的环境规制政策提供支撑。     

Coupling fishery dynamics,human health and social learning in a model of fish-borne pollution exposure

Pollution-induced illnesses are caused by toxicants that result from human activity and are often entirely preventable. However, where industrial priorities have undermined responsible governance, exposed populations must reduce their exposure by resorting to voluntary protective measures and demanding emissions abatement. This paper presents a coupled human–environment system model that represents the effects of water pollution on the health and livelihood of a fishing community. The model is motivated by an incident from 1949 to 1968 in Minamata, Japan, where methylmercury effluent from a local factory poisoned fish populations and humans who ate them. We model the critical role of risk perception in driving both social learning and the protective feedbacks against pollution exposure. These feedbacks are undermined in the presence of social misperceptions such as stigmatization of the injured. Through numerical simulation and scenario analysis, we compare our model results with historical datasets from Minamata, and find that the conditions for an ongoing pollution epidemic are highly unlikely without social misperception. We also find trade-offs between human health outcomes, the viability of the polluting industry and the survival of the fishery. We conclude that an understanding of human–environment interactions and misperception effects is highly relevant to the resolution of contemporary pollution problems, and merits further study.     

The European perspective on nitrogen emission and deposition

Europe has been successful in reducing the emissions of several nitrogenous pollutants over recent decades. This is reflected in concentrations and deposition rates that have decreased for several components. Emissions of nitrogen containing gases are estimated to have decreased in Europe by 10%, 21% and 14% for N(2)O, NO(x) and NH(3), respectively, between 1990 and 1998. The main reductions are the result of a decrease in industrial and agricultural activities in the east of Europe. The reductions are a result of the economic situation, measures in the transport sector, industry, and the agricultural sector, with only a small part of the reduction due to specific measures designed to reduce emissions. The reduction is significant but far from the end goal for large areas in Europe, in relation to different environmental problems. The Gothenburg Protocol will lead to reductions of 50% and 12% in 2010 relative to 1990 for NO(x) and NH(3), respectively. The N(2)O emissions are expected to grow by 9% between 1998 and 2010. Further reductions are necessary to reach critical limits for ecosystem protection, air quality standards, and climate change. Emissions of nitrogen compounds result from an overload of reactive nitrogen that is produced by combustion processes, by synthesis of ammonia, or by import from other areas as concentrated animal feeds. Some improvements can be made in the efficiency of combustion processes and agricultural systems. However, measures to reduce emissions substantially need to focus on decreasing the production or import of reactive N. Reactive N ceilings for regions, based on critical limits for all N-related effects, can help to focus such measures. An integrated approach might have advantages over the pollutant-specific approach, to combat nitrogen pollution. This could provide the future direction for European policy to reduce the impacts of excess nitrogen.     

经济发展与农业面源污染：分解模型与实证研究

借鉴Islam的研究思路,构建农业面源污染影响因素分解的理论模型。并利用1990～2010年省际面板数据进行实证研究,探讨农业面源污染演变的内在驱动机制,以期为农业面源污染控制和管理提供理论依据。主要研究结论如下：（1）农业面源污染演变受规模效应、结构效应和减污效应的共同影响;（2）规模效应对农业面源污染的影响为正,这说明农业生产规模和农村人口规模的扩大会增大农业面源污染的排放。结构效应的两个重要方面（经济作物比重的提高和畜禽养殖业产值比重的提高）都会导致农业面源污染的加剧。技术进步和经济发展的减污效应开始初步发挥,二者都能有效减少农业面源污染,这为实现农业生产与生态环境的协调发展提供了可能     

Health risk assessment of indoor air pollution in Finnish ice arenas

Poor indoor air quality and epidemic carbon monoxide (CO) and nitrogen dioxide (NO(2)) poisonings due to exhaust emissions from ice resurfacers have been continuously reported from enclosed ice arenas for over 30 years. The health risks in users of Finnish ice arenas were analysed in three ways: (1) evaluation of four cases of epidemic CO poisonings, (2) modelling the association between NO(2) exposure and respiratory symptoms among junior ice hockey players, and (3) estimation of the number of arena users at risk of breathing poor quality air due to non-compliance of ice arenas with recommended abatement measures. The common causes for the CO poisonings involving over 300 subjects were large emissions from propane-fuelled ice resurfacer, small arena volume, negligible ventilation, and very recent opening of the arena. Rhinitis (prevalence 18.3%) and cough (13.7%) during or after training or game were significantly associated with the estimated personal NO(2) exposure of young hockey players (n=793) to average concentrations ranging from 21 to 1176 microg/m(3) in their home arena. During a 6-year follow-up of an intensive information campaign the portion of electric resurfacers increased from 9% to 27%, and that of emission control technology on propane-fuelled resurfacers increased from 13% to 84%. The portion of inadequately ventilated arenas decreased from 34% to 25%. However, 48% of the investigated Finnish ice arenas (n=125) did not fully comply with the non-regulatory recommendations. Consequently, 20000 daily users of ice arenas were estimated to remain in 2001 at risk of breathing poor quality air. Modern small and inadequately ventilated ice arenas pose their users (mostly children and young adults) at risk of breathing poor quality air and suffering from acute adverse health effects. Governmental regulations are needed worldwide to ensure safe sports in enclosed ice arenas.     

资源型城市环境规制的经济增长效应及其传导机制——基于创新补偿与产业结构升级的双重视角

对于中国多数资源型城市来说,改善生态环境与促进经济增长是当前面临的重要任务。一些研究认为治理环境污染可能加重"遵循成本",进而不利于经济增长;也有研究认为环境规制会通过"创新补偿"效应,增进当地产品竞争力,弥补企业成本负担并促进经济增长;此外,还有研究认为环境标准提高有助于区域产业结构升级,进而带动经济增长。为验证中国资源型城市环境规制对经济增长的影响及其传导机制,本文基于2004—2014年资源型城市数据,以样本城市GDP为被解释变量,以工业污染治理设备运行费用为解释变量,进行了面板数据实证分析,并观察了科技行业人员比重和第三产业比重的中介效应。结果显示:(1)资源型城市工业污染物治理对GDP总量和人均GDP的影响均显著为正;(2)在环境规制与GDP(或人均GDP)的正向关系中,科技行业人员比重的提升起到了部分中介作用,即存在显著的创新补偿效应;(3)除了传统观点看到的创新补偿效应,污染治理对产业结构的积极影响也在二者正向关系中有重要的中介作用,而且比创新补偿效应的作用更显著。本文的结论是,资源型城市环境规制未对经济增长造成不利影响,主要是由于经济资源从效益不佳的工业企业流向了第三产业,同时工业部门自身的创新潜力也已逐步凸显。因此,面对经济社会持续发展的压力,资源型城市要取得经济增长与生态环境的双赢,应当强化污染治理成本对企业技术进步的倒逼机制,进一步实现创新驱动发展,同时要构建多元产业体系,促进资源型行业与现代服务业的有效对接和深度融合。     

税收竞争对环境污染的影响及传导机制分析

在中国经济高增长的背后,环境污染问题愈发凸显,不利于经济的可持续增长。税收竞争是影响环境污染的主要因素之一,但是学术界研究税收竞争对环境污染的影响及其作用机制的较少。本文按照污染物属性将其划分为外溢性污染物和非外溢性污染物,通过构建一个包含生产者、消费者、地方政府及中央政府的一般均衡模型,刻画了在税收竞争的背景下,地方政府的税收征管效率对不同属性污染物的影响及其传导机制。结果发现当污染物具有外溢性属性时,税收征管效率对该地环境污染的影响通过改变本地及周边地区资本存量渠道实现;当污染物具有非外溢性属性时,降低税收征管效率通过增加该地区资本存量而提高了环境污染。文章首先使用随机前沿模型测算了2007—2014年中国28个省份企业所得税的税收征管效率,并将其作为税收竞争的衡量指标,然后运用系统GMM法证实了所提的假说。研究显示:地方政府的税收竞争增加了本地区的资本存量;税收竞争是将本地资本存量作为其推高外溢性污染物(二氧化硫)及非外溢性污染物(固体废弃物)排放量的一个主要渠道,邻近地区资本存量则是推高外溢性污染物(二氧化硫)的次要渠道。这意味着,要想改善环境质量,中央政府应规范地方政府的税收竞争行为,尽快建立一套科学、有效的绿色GDP评价体系;完善地方转移支付制度;应针对各个地区的污染及经济发展情况利用财政激励手段引入环保、绿色的资本项目;地方政府应减少不利于环境改善的地方财政支出,增加环保投入比重。     

On-site radioactive soil contamination at the Andreeva Bay shore technical base, Northwest Russia

The radioactive waste (RAW) storage site at Andreeva Bay in the Russian Northwest has experienced radioactive contamination both as a result of activities carried out at the site and due to incidents that have occurred there in the past such as accidental releases of radioactive materials. The site is an interesting case study for decommissioning due to the extremely large amounts of radioactivity present at the site and the conditions under which it is stored; very little has been previously published in the scientific literature about this site. This paper complements the paper describing dose rates at Andreeva Bay which is published in this issue of Journal of Environmental Radioactivity by the same authors. This study presents new data related to the activity concentrations of (137)Cs and (90)Sr in surface soils and measurements of alpha- and beta-particle fluxes taken at different areas around the site. Limited data on 60Co is also presented. The results of the study indicate that the main areas of site contamination are associated with the former spent nuclear fuel storage facility at Building 5, due to accidental discharges which began in 1982. Substantial contamination is also observed at the solid radioactive waste storage facilities, probably due to the ingress of water into these facilities. More than 240 samples were measured: maximum contamination levels were 1 x 10(6)Bq/kg (137)Cs (mean value 4.1 x 10(5)Bq/kg) and 4 x 10(6)Bq/kg (90)Sr (mean value 1.2 x1 0(5)Bq/kg). Localised patches of alpha and beta contamination were also observed throughout the site.     

雾霾污染的城市间动态关联及其成因研究

面对严重的雾霾天气以及雾霾污染边界不断扩张的严峻挑战,加快创新大气污染联防联控体系以形成跨区域协同治污合力势在必行。本文基于京津冀、长三角、珠三角、成渝、长中游等五大地区96个城市2015年的空气质量指数(AQI)以及PM_(2.5)、PM_(10)、SO_2、CO、NO_2、O~3等6种分项污染物的逐日数据,从时间序列数据"预测能力"的视角,在向量自回归模型框架下识别雾霾污染的城市间动态交互影响效应,运用社会网络分析方法刻画雾霾污染空间关联的网络结构特征。在此基础上,运用二次指派程序从分项污染物视角考察雾霾污染空间关联的关键诱因,并利用双变量Moran指数揭示雾霾污染与其影响因素之间的空间相关性。研究发现,城市雾霾污染之间存在普遍的动态关联关系且呈现出联系紧密、稳定性强、带有明显特征的多线程复杂网络结构形态。不论在地区内部还是在全部样本城市当中,均不存在孤立的城市节点,这意味着面对雾霾污染的空间关联网络,任何一个城市都不能独善其身,均受到来自地区内部和地区以外其他城市以及它们构成的空间关联网络的影响。在六种分项污染物中,PM_(2.5)的空间关联是导致雾霾污染空间关联的最主要诱因。城市雾霾污染与其影响因素尤其是城市人口密度、投资强度、工业污染排放之间存在显著的空间相关性。基于上述结论,中国应当加快构建以防控PM_(2.5)为重点的跨区域雾霾污染协同治理机制,并将其融入城市群发展战略以及区域发展战略之中,最终实现包含雾霾污染协同治理在内的全方位的区域协同发展。     

中国若干典型城市对流层NO2时空分布特征

随着经济的发展,NO2污染日趋严重。利用OMI（Ozone Monitoring Instrument,臭氧监测仪）数据得到北京、上海、广州、武汉、西安5个城市2004年10月~2009年7月的NO2浓度月均值变化的时间序列,分析5个城市的NO2浓度变化特征。并根据2007年1月~2008年12月5个城市环境监测中心发布的NO2污染API指数,推算出近地面NO2浓度月均值,与OMI遥感数据反演的对流层柱浓度进行比较,两组数据有较一致的变化趋势。根据OMI数据得到的该5个城市2005～2008年的NO2浓度年均空间分布,发现中心城区NO2浓度值远高于郊区,形成了城市气候的“混浊岛效应”,这与发达的城市交通,高强度的人口活动以及城市局地流场特征有着密切的关系。通过GOME(Global Ozone Monitoring Experiment,全球臭氧监测实验)NO2浓度年均变化值和1999～2008年5城市机动车保有量的相关分析,认为机动车尾气排放量的增加是我国发达城市NO2污染的主要原因。〖