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1.
用甲醛法测定SO2的影响因素及质量保证措施 总被引:1,自引:0,他引:1
何平 《环境监测管理与技术》1994,6(3):52-54
探讨了甲醛法测定SO_2浓度时PRA浓度和实验温度对SO_2曲线斜率的影响。根据实验结果,提出测定SO_2方法1的实验室质量保证措施,得出不同显色温度的显色时间;RSD小于4%,系统误差小、精密度好、准确度高。 相似文献
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甲醛法测定SO2灵敏度初探周秀华(浙江省平湖市环境监测站,平湖314200)试验表明,NaOH摩尔浓度对方法灵敏度有较大影响,其适宜浓度应为2.50mol/L,此时灵敏度可提高(14%),而且相对标准偏差为3%(n=5),表明方法的精密度和准确度也相... 相似文献
3.
用扩散法被动式个体采样器同时测定空气中二氧化硫和二氧化氮 总被引:3,自引:0,他引:3
本文介绍了用被动式个体采样器同时测定空气中SO2和NO2的方法,吸收层用三乙醇胺(20%)+碳酸钠(5%)溶液浸渍的滤纸,采样后分成两等分,分别测定SO2和NO2浓度。与有动力的溶液吸收管现场对比验证,表明两者结果是一致的。在外环境监测时,为了克服风速的影响,可将被动式个体采样器放在TSP流量采样器的帽形采样头中,这样可同时测定环境空气中TSP、SO2和NO2。 相似文献
4.
利用历年兰州市环境质量报告书和有关该市大气环境研究课题、厂矿评价资料和结论,对兰州市区各网格点内SO2年排放量和采暖期排放量分担率分别进行了绘图分析。依据分担率分布特征和盛行风向,定性验证了兰州市区各采样点SO2监测值的分布特征。 相似文献
5.
我国SO2总量控制监测技术的进展 总被引:1,自引:0,他引:1
黄维 《甘肃环境研究与监测》1999,12(3):166-168
我国在实施SO2排放总量控制的同时,SO2排放总量监测技术也得到了发展,体现在手工采样监测方法,特别是碘量法得到了进一步完善,拥有了我国自己设计生产的基于多种测定原理的便携式SO2自动测定仪,基本适应了当前SO2总量控制监测的需要。 相似文献
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以赤市2种采样方法获得的数据为基础,运用数据统计中的双因素方差法及一元线性回归法对2种采样方法的相关性进行了验证。结果表明,连续采样法代替五日手工采样法后,对于SO2、NOx2种方法之间无显著差异,对于TSP两方法的延续性很差。 相似文献
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对甲醛缓冲溶液吸收-盐酸副玫瑰胺测定大气中SO2的两种分析方法进行了对比实验表明,由于实验条件和试剂浓度不同,造成测定结果有一定差异,(空气和废气监测分析方法)法略高于(环境监测技术规范)法。 相似文献
9.
用数理统计的原理,当样本容量满足检验方法要求时,用柯尔莫哥洛夫--斯米尔诺夫、皮尔逊、概率纸等法对绵阳市城区SO2监测值进行分布类型的统计检验。其结果SO2的时空分布类型为近似对数正态。用几何均数代表样本的平均值,例行监测时段的SO2测值与增加采样频率后的测值基本无差异。而用算术均数表示平均值时,均值则落在总体均值的置信区间外。故当样本分布类型确定后,样本的主要特征数应由分布类型确定。 相似文献
10.
丁美兰 《环境监测管理与技术》1994,6(2):61-61
大气采样器气路故障的快速检查方法丁美兰(山东省东营市环保研究所257091)大气中SO2与NOx的采样过程中气路经常出现阻塞或漏气的故障,必须迅速排除,才能保质保量的完成预定的采样任务。1采样气路采样系统依次由吸收瓶,干燥筒、微孔滤膜,转子流量计、临... 相似文献
11.
Personal monitoring methods for the determination of hourly integrated concentrations of NO2 and SO2 in ambient air have been developed. Triethanolamine (TEA)-impregnated C18 Sep-Pak cartridges were used to collect NO2 and SO2 simultaneously. After sampling, NO2 and SO2 as their nitrite, nitrate, sulfite and sulfate analogues were stripped from the cartridges with a solution of 5% methanol in distilled, deionized water (DDW) and then determined by ion chromatography. Laboratory tests were conducted to evaluate the sampling rate, collection and recovery efficiencies, breakthrough volumes, absorption capacity, interference and sample stability on the cartridge during storage. NO2 and SO2 detection limits of 0.3 and 0.4 ppb respectively for 1 h samples were obtained. Recoveries for both NO2 and SO2 exceeded 85%. 相似文献
12.
将每天TSP、SO_2两种污染物各采四次样并分别进行测定,简化为每天各采一个“日混合样”进行测定,对测定结果进行数理统计检验结果表明:测定值之间不存在显著性差异、两种方法的测值波动是由偶然因素造成的,因此,简化方法即采日混合样进行分析是一种可靠的监测方法,它适用于煤质中含硫份较低的地区。 相似文献
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大气中SO_2、NO_x、TSP和CO平行采样监测结果的统计分析表明,地面与楼顶采样的差异不显著,其浓度变化有随高度呈规律性的变化趋向,降雪具有明显的洗脱清除作用。 相似文献
15.
平行双样对大气二氧化硫采样样品进行质量控制的应用研究 总被引:3,自引:0,他引:3
通过对大气二氧化硫采样平行双样相对偏差变化规律的分析,证明了用平行双样控制大气二氧化硫采样样品的质量是可行的,并确定了平行双样相对偏差的控制指标,为大气二氧化硫采样的质量控制提供了可靠的依据 相似文献
16.
对1992年连续十二个月的二氧化硫监测数据的分析,掌握了二氧化硫随时间的变化规律。对间断采样频率的代表性作出结论。 相似文献
17.
In this work we present the results of extensive characterization and optimization of the Ambient Ion Monitor-Ion Chromatograph (AIM-IC) system, an instrument developed by URG Corp. and Dionex Inc. for simultaneous hourly measurements of the water-soluble chemical composition of atmospheric fine particulate matter (PM(2.5)) and associated precursor gases. The sampling assembly of the AIM-IC consists of an inertial particle size-selection assembly, a parallel-plate wet denuder (PPWD) for the collection of soluble gases, and a particle supersaturation chamber (PSSC) for collection of particles, in series. The analytical assembly of the AIM-IC consists of anion and cation IC units. The system detection limits were determined to be 41 ppt, 5 ppt, and 65 ppt for gas phase NH(3(g)), SO(2(g)), and HNO(3(g)) and 29 ng m(-3), 3 ng m(-3), and 45 ng m(-3) for particle phase NH(4)(+), SO(4)(2-), and NO(3)(-) respectively. From external trace gas calibrations with permeation sources, we determined that the AIM-IC is biased low for NH(3(g)) (11%), SO(2(g)) (19%), and HNO(3(g)) (12%). The collection efficiency of SO(2(g)) was found to strongly depend on the composition of the denuder solution and was found to be the most quantitative with 5 mM H(2)O(2) solution for mixing ratios as high as 107 ppb. Using a cellulose membrane in the PPWD, the system responded to changes in SO(2(g)) and HNO(3(g)) within an hour, however for NH(3(g)), the timescale can be closer to 20 h. With a nylon membrane, the instrument response time for NH(3(g)) was significantly improved, becoming comparable to the responses for SO(2(g)) and HNO(3(g)). Performance of the AIM-IC for collection and analysis of PM(2.5) was evaluated by generating known number concentrations of ammonium sulfate and ammonium nitrate particles (with an aerodynamic diameter of 300 nm) under laboratory conditions and by comparing AIM-IC measurements to measurements from a collocated Aerosol Mass Spectrometer (AMS) during a field-sampling campaign. On average, the AIM-IC and AMS measurements agreed well and captured rapid ambient concentration changes at the same time. In this work we also present a novel inlet configuration and plumbing for the AIM-IC which minimizes sampling inlet losses, reduces peak smearing due to sample carryover, and allows for tower-height sampling from the base of a research tower. 相似文献
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针对1990年和1991年绵阳市SO_2浓度升高,尤其是1990年和1991年元月监测的SO_2浓度值更高。经研究发现监测采样时的气象条件对污染物测定值产生重要影响。 相似文献
19.
Carter SR Seixas NS Thompson ML Yost MG 《Journal of environmental monitoring : JEM》2004,6(11):932-937
Aluminium smelter potrooms are unique in that workplace exposures to hydrogen fluoride (HF), sulfur dioxide (SO2), and particulate matter occur simultaneously for some tasks. The peak exposures to these contaminants are of increasing interest in discovering the etiology of respiratory health effects. While a variety of direct-reading instruments are available for sulfur dioxide and particulate matter, only a few exist for hydrogen fluoride. The sensors in these HF instruments have a cross-sensitivity to sulfur dioxide making it difficult to monitor HF in an environment that also contains SO2. To overcome this problem, we assessed the simultaneous use of two electrochemical instruments: one with a SO2 sensor that does not respond to HF and the second with a hydrogen fluoride sensor that responds to both HF and SO2 in a 1 : 1 ratio, termed 'total acid gas'. The difference in the response between the two instruments should indicate the HF concentration: [HF + SO2] minus SO2 equals HF. The performance characteristics of this sampling train were evaluated in the laboratory through the generation of both HF and SO2 with permeation tubes. The response and recovery times for the SO2 only instrument were acceptable (6 and 15 s, respectively), but the "total acid gas" instrument exhibited both slow response and slow recovery approaching three and six min. The association between the traditional integrated filter sampling method and the direct-reading instrument for SO2 is 0.80 (Spearman's rho). The use of the digital filter strengthens the association between the HF direct-reading instrument and the integrated samples from 0.41 to 0.68. 相似文献
20.
利用三氧化硫(SO3)发生装置以及模拟烟气湿法脱硫系统,研究了烟气再热温度、恒温水浴温度、采样速率、冷凝管类型规格及吸收瓶个数等不同采样参数对SO3酸雾采集率的影响。结果表明,当烟气再热温度低于烟气酸露点时会导致SO3酸雾收集率下降,采用控制冷凝法采样时应使用大流量(10L/min)采样,冷凝管应选择外套长度为400 mm的蛇形螺旋冷凝管,并将冷凝管置于温度为65℃左右的恒温水浴中;用碱液吸收法采样时应串联3个吸收瓶后,使用小流量(1L/min)采样。烟气温湿度、二氧化硫(SO2)浓度以及烟气中共存组分等对碱性吸收法的采集影响较大,而对控制冷凝法几乎没有影响。因此确立了针对湿法脱硫后高湿烟气环境下SO3酸雾的监测方法为控制冷凝法更为适宜。 相似文献