Potential release scenarios for carbon nanotubes used in composites

The expected widespread use of carbon nanotube (CNT)-composites in consumer products calls for an assessment of the possible release and exposure to workers, consumers and the environment. Release of CNTs may occur at all steps in the life cycle of products, but to date only limited information is available about release of CNTs from actual products and articles. As a starting point for exposure assessment, exploring sources and pathways of release helps to identify relevant applications and situations where the environment and especially humans may encounter releases of CNTs. It is the aim of this review to identify various potential release scenarios for CNTs used in polymers and identify the greatest likelihood of release at the various stages throughout the life-cycle of the product. The available information on release of CNTs from products and articles is reviewed in a first part. In a second part nine relevant release scenarios are described in detail: injection molding, manufacturing, sports equipment, electronics, windmill blades, fuel system components, tires, textiles, incineration, and landfills. Release from products can potentially occur by two pathways; (a) where free CNTs are released directly, or more frequently (b) where the initial release is a particle with CNTs embedded in the matrix, potentially followed by the subsequent release of CNTs from the matrix.The potential for release during manufacturing exists for all scenarios, however, this is also the situation when exposure can be best controlled. For most of the other life cycle stages and their corresponding release scenarios, potential release of CNTs can be considered to be low, but it cannot be excluded totally. Direct release to the environment is also considered to be very low for most scenarios except for the use of CNTs in tires where significant abrasion during use and release into the environment would occur. Also the possible future use of CNTs in textiles could result in consumer exposure. A possibility for significant release also exists during recycling operations when the polymers containing CNTs are handled together with other polymers and mainly occupational users would be exposed.It can be concluded that in general, significant release of CNTs from products and articles is unlikely except in manufacturing and subsequent processing, tires, recycling, and potentially in textiles. However except for high energy machining processes, most likely the resulting exposure for these scenarios will be low and to a non-pristine form of CNTs. Actual exposure studies, which quantify the amount of material released should be conducted to provide further evidence for this conclusion.     

An approach for environmental risk assessment of engineered nanomaterials using Analytical Hierarchy Process (AHP) and fuzzy inference rules

The usage of Engineered Nanoparticles (ENPs) in consumer products is relatively new and there is a need to conduct environmental risk assessment (ERA) to evaluate their impacts on the environment. However, alternative approaches are required for ERA of ENPs because of the huge gap in data and knowledge compared to conventional pollutants and their unique properties that make it difficult to apply existing approaches. This study aims to propose an ERA approach for ENPs by integrating Analytical Hierarchy Process (AHP) and fuzzy inference models which provide a systematic evaluation of risk factors and reducing uncertainty about the data and information, respectively. Risk is assumed to be the combination of occurrence likelihood, exposure potential and toxic effects in the environment. A hierarchy was established to evaluate the sub factors of these components. Evaluation was made with fuzzy numbers to reduce uncertainty and incorporate the expert judgements. Overall score of each component was combined with fuzzy inference rules by using expert judgements. Proposed approach reports the risk class and its membership degree such as Minor (0.7). Therefore, results are precise and helpful to determine the risk management strategies. Moreover, priority weights calculated by comparing the risk factors based on their importance for the risk enable users to understand which factor is effective on the risk. Proposed approach was applied for Ag (two nanoparticles with different coating) and TiO₂ nanoparticles for different case studies. Results verified the proposed benefits of the approach.     

Life cycle assessment part 1: framework, goal and scope definition, inventory analysis, and applications

Sustainable development requires methods and tools to measure and compare the environmental impacts of human activities for the provision of goods and services (both of which are summarized under the term "products"). Environmental impacts include those from emissions into the environment and through the consumption of resources, as well as other interventions (e.g., land use) associated with providing products that occur when extracting resources, producing materials, manufacturing the products, during consumption/use, and at the products' end-of-life (collection/sorting, reuse, recycling, waste disposal). These emissions and consumptions contribute to a wide range of impacts, such as climate change, stratospheric ozone depletion, tropospheric ozone (smog) creation, eutrophication, acidification, toxicological stress on human health and ecosystems, the depletion of resources, water use, land use, and noise-among others. A clear need, therefore, exists to be proactive and to provide complimentary insights, apart from current regulatory practices, to help reduce such impacts. Practitioners and researchers from many domains come together in life cycle assessment (LCA) to calculate indicators of the aforementioned potential environmental impacts that are linked to products-supporting the identification of opportunities for pollution prevention and reductions in resource consumption while taking the entire product life cycle into consideration. This paper, part 1 in a series of two, introduces the LCA framework and procedure, outlines how to define and model a product's life cycle, and provides an overview of available methods and tools for tabulating and compiling associated emissions and resource consumption data in a life cycle inventory (LCI). It also discusses the application of LCA in industry and policy making. The second paper, by Pennington et al. (Environ. Int. 2003, in press), highlights the key features, summarises available approaches, and outlines the key challenges of assessing the aforementioned inventory data in terms of contributions to environmental impacts (life cycle impact assessment, LCIA).     

Sustainability risk identification in product development

Sustainability-related issues present significant financial, strategic, compliance and operational risks to manufacturers. Many of these risks directly or indirectly result from the way a product is designed and managed across its life cycle. Assessing sustainability risk (S _R) at the product design stage is crucial for the development of products that both minimise sustainability risk exposure and are environmentally sustainable. Managing the costs associated with these risks requires risk management intervention at the design stage before these costs are committed throughout the life cycle (production, use, end-of-life). The goal of the sustainability risk assessment (SRA) methodology is to provide an approach to comparing the financial cost of a ‘sustainable product’ vs. an ‘unsustainable product’, by factoring in the effects of S _R on life-cycle cost. The SRA methodology demonstrates that, in some cases, sustainable products cost less than unsustainable products when sustainability risk is considered in the costing analysis. This paper outlines the first step of the SRA methodology, which is a process for identifying S _R inherent in the product life cycle. Once key risks are identified, the subsequent steps of the SRA assess and prioritise these risks for treatment through changes to product design and materials composition.     

林产品生物碳通量的动态生命周期评估

将时间因素和生物碳通量纳入林产品生命周期碳足迹评估,通过动态生命周期分析法(Dynamic Life Cycle Assessment,DLCA),确定林产品生产、使用和废弃阶段替代化石能源的净温室气体减排和对森林碳损失的净弥补时间。首先,建立温室气体排放和封存的动态生命周期清单,评估刨花板全生命周期的碳动态和碳足迹;其次,根据ISO 14040和PAS 2050标准提供的静态生命周期分析法分别核算包含与不包含碳储计算的碳足迹,量化时间因素和生物碳通量对于碳足迹结果差异的影响程度;最后,对比自然生长状态的森林碳汇情境,评估刨花板使用和废弃阶段替代化石燃料实现净气候减排所需的时间。研究表明:①时间因素和生物碳通量核算对碳足迹结果影响较大(223.34%),忽视时间因素会低估刨花板的减排贡献(18.98%)。②动态生命周期分析法可准确评估生物碳和温室气体排放的时间问题,但对时间范围非常敏感(75.19%和113.25%)。③生产、使用林产品以及林产品对化石能源的替代是实现长期气候减排的有效方式,在100a的时间范围能够弥补因森林砍伐造成的碳损失,从而实现碳中性。     

Life cycle assessment part 2: current impact assessment practice

Providing our society with goods and services contributes to a wide range of environmental impacts. Waste generation, emissions and the consumption of resources occur at many stages in a product's life cycle-from raw material extraction, energy acquisition, production and manufacturing, use, reuse, recycling, through to ultimate disposal. These all contribute to impacts such as climate change, stratospheric ozone depletion, photooxidant formation (smog), eutrophication, acidification, toxicological stress on human health and ecosystems, the depletion of resources and noise-among others. The need exists to address these product-related contributions more holistically and in an integrated manner, providing complimentary insights to those of regulatory/process-oriented methodologies. A previous article (Part 1, Rebitzer et al., 2004) outlined how to define and model a product's life cycle in current practice, as well as the methods and tools that are available for compiling the associated waste, emissions and resource consumption data into a life cycle inventory. This article highlights how practitioners and researchers from many domains have come together to provide indicators for the different impacts attributable to products in the life cycle impact assessment (LCIA) phase of life cycle assessment (LCA).     

Ecotoxicity of engineered TiO2 nanoparticles to saltwater organisms: An overview

The innovative properties of nanomaterials make them suitable for various applications in many fields. In particular, TiO₂ nanoparticles (nTiO₂) are widely used in paints, in cosmetics and in sunscreens that are products accessible to the mass market. Despite the great increase in the use of such nanomaterials, there is a paucity of general information about their potential effects to the aquatic species, especially to saltwater ones. Moreover, the difficulties of determining the effective exposure scenario make the acquired information low comparable. In this work, questions about the complexity of the real exposure scenario determination are discussed. The state of the art, concerning the experimental activities with nTiO₂ toward the saltwater organisms is firstly illustrated, providing statistical information about the different matrices, organisms and nanoparticles employed. A comparison of the nTiO₂ ecotoxicity effects, grouped by taxonomic classes, is provided illustrating their relative experimental conditions. Findings show the need to develop specific protocols for toxicity tests with ENPs to control the variability of experimental conditions. Some advices are finally proposed for the future experimental activities.     

Life cycle sustainability assessments (LCSA) of four disposal scenarios for used polyethylene terephthalate (PET) bottles in Mauritius

Improper disposal of post-consumer Polythylene Terephthalate (PET) bottles constitutes an eyesore to the environmental landscape and gives rise to numerous environmental and health-related nuisances. These problems impact negatively on the flourishing tourism industry in Mauritius. The present study was therefore undertaken to determine a sustainable disposal method among four selected disposal alternatives of post-consumer PET bottles in Mauritius. The disposal scenarios investigated were: 100 % landfilling (scenario 1); 75 % incineration with energy recovery and 25 % landfilling (scenario 2); 40 % flake production (partial recycling) and 60 % landfilling (scenario 3); and 75 % flake production and 25 % landfilling (scenario 4). Environmental impacts of the disposal alternatives were determined using ISO standardized life cycle assessment (LCA) and the SimaPro 7.1 software. Cost-effectiveness was determined using Life cycle costing (LCC) as described by the recent Code of Practice on LCC. An excel-based model was constructed to calculate the various costs. Social impacts were evaluated using Social Life Cycle Assessment (S-LCA) based on the UNEP/SETAC Guidelines for Social Life Cycle Assessment. For this purpose, a new and simple social life cycle impact assessment method was developed for aggregating inventory results. Finally, Life Cycle Sustainability Assessment (LCSA) was conducted to conclude the sustainable disposal route of post-consumer PET bottles in Mauritius. The methodology proposed to work out LCSA was to combine the three assessment tools: LCA, LCC and S-LCA using the Analytical Hierarchy Process. The results indicated that scenario 4 was the sustainable disposal method of post-consumer PET bottles. Scenario 1 was found to be the worst scenario.     

Relative Assessment of Indicators in Sustainability Enhancement (RAISE): a first approach in the manufacturing stage of products

The estimation of the sustainability performance of products requires tools to provide systematic approaches to the definition of impacts, indicators and comparative scenarios from early design stages. This paper illustrates the Relative Assessment of Indicators in Sustainability Enhancement (RAISE) methodology that is based on the measure of negative impacts generated during any product life cycle stage. This approach includes a systematic process for the definition and evaluation of indicators to compare the sustainability performance of products considering each indicator individually and using a holistic index of sustainability to entail an overall comparison between products from manufacturing scenarios. The RAISE method is developed with the aim of assessing sustainability performance of product life cycle stages and incorporating this assessment into the decision-making process when comparing different manufacturing scenarios. A guitar capo manufactured in polymeric material is used as case study to demonstrate the use of the method. In this paper, only the manufacturing stage is considered; however, the method can also be employed in other stages of the life cycle.     

Dynamic life cycle costing based on lifetime prediction

Reliable prediction of total product life cycle costs is crucial for the life cycle management of products. These costs are predominantly dictated by the actual operational behaviour of the product's lifetime, and cannot be sufficiently determined through deterministic calculations due to the stochastic and the dynamic nature of the problem. This is specifically true when considering running systems with unknown lifetime and operation parameters. Against this background, the paper presents a dynamic methodology for predicting life cycle costs based on product failure mechanisms, their associated critical lifetime prediction parameters and optional maintenance strategies to enable decision support for product design and use phase strategies.     

Environmental and health effects of nanomaterials in nanotextiles and façade coatings

Engineered nanomaterials (ENM) are expected to hold considerable potential for products that offer improved or novel functionalities. For example, nanotechnologies could open the way for the use of textile products outside their traditional fields of applications, for example, in the construction, medical, automobile, environmental and safety technology sectors. Consequently, nanotextiles could become ubiquitous in industrial and consumer products in future. Another ubiquitous field of application for ENM is fa?ade coatings. The environment and human health could be affected by unintended release of ENM from these products. The product life cycle and the product design determine the various environmental and health exposure situations. For example, ENM unintentionally released from geotextiles will probably end up in soils, whereas ENM unintentionally released from T-shirts may come into direct contact with humans and end up in wastewater. In this paper we have assessed the state of the art of ENM effects on the environment and human health on the basis of selected environmental and nanotoxicological studies and on our own environmental exposure modeling studies. Here, we focused on ENM that are already applied or may be applied in future to textile products and fa?ade coatings. These ENM's are mainly nanosilver (nano-Ag), nano titanium dioxide (nano-TiO(2)), nano silica (nano-SiO(2)), nano zinc oxide (nano-ZnO), nano alumina (nano-Al(2)O(3)), layered silica (e.g. montmorillonite, Al(2)[(OH)(2)/Si(4)O(10)]nH(2)O), carbon black, and carbon nanotubes (CNT). Knowing full well that innovators have to take decisions today, we have presented some criteria that should be useful in systematically analyzing and interpreting the state of the art on the effects of ENM. For the environment we established the following criteria: (1) the indication for hazardous effects, (2) dissolution in water increases/decreases toxic effects, (3) tendency for agglomeration or sedimentation, (4) fate during waste water treatment, and (5) stability during incineration. For human health the following criteria were defined: (1) acute toxicity, (2) chronic toxicity, (3) impairment of DNA, (4) crossing and damaging of tissue barriers, (5) brain damage and translocation and effects of ENM in the (6) skin, (7) gastrointestinal or (8) respiratory tract. Interestingly, some ENM might affect the environment less severely than they might affect human health, whereas the case for others is vice versa. This is especially true for CNT. The assessment of the environmental risks is highly dependent on the respective product life cycles and on the amounts of ENM produced globally.     

Tracking chemicals in products around the world: introduction of a dynamic substance flow analysis model and application to PCBs

Dynamically tracking flows and stocks of problematic chemicals in products (CiPs) in the global anthroposphere is essential to understanding their environmental fates and risks. The complex behavior of CiPs during production, use and waste disposal makes this a challenging task. Here we introduce and describe a dynamic substance flow model, named Chemicals in Products - Comprehensive Anthropospheric Fate Estimation (CiP-CAFE), which facilitates the quantification of time-variant flows and stocks of CiPs within and between seven interconnected world regions and the generation of global scale emission estimates. We applied CiP-CAFE to polychlorinated biphenyls (PCBs), first to evaluate its ability to reproduce previously reported global-scale atmospheric emission inventories and second to illustrate its potential applications and merits. CiP-CAFE quantifies the pathways of PCBs during production, use and waste disposal stages, thereby deducing the temporal evolution of in-use and waste stocks and identifying their long-term final sinks. Time-variant estimates of PCB emissions into air, water and soil can be attributed to different processes and be fed directly into a global fate and transport model. By capturing the international movement of PCBs as technical chemicals, and in products and waste, CiP-CAFE reveals that the extent of global dispersal caused by humans is larger than that occurring in the natural environment. Sensitivity analysis indicates that the model output is most sensitive to the PCB production volume and the lifetime of PCB-containing products, suggesting that a shortening of that lifetime is key to reducing future PCB emissions.     

Research on whole life cycle carbon emission model of typical buildings

Based on the theory of life cycle assessment (LCA), this article analyzes the influence factors on carbon emissions from residential buildings. In the article, the life cycle of residential buildings has been divided into five stages: building materials production period, construction period, operation and maintenance period, demolition period, and solid waste recycle and disposal period. Based on this definition, the authors provide a theoretical model to calculate carbon emissions of residential building life cycle. In particular, the factor of human activities was introduced in the calculation of carbon emissions from the buildings. Furthermore, the authors put forward a model for calculation with the unit of carbon emissions for per-capita living space.     

Green Composites as Panacea? Socio-Economic Aspects of Green Materials

Much academic research and industrial development explores new ways to create greener and environmentally friendlier chemicals and materials for a variety of applications. A significant part of this work focuses on the development, processing and manufacturing, recycling and disposal of green plastics, adhesives, polymer composites, blends and many other industrial products from renewable resources. Natural fibres offer the potential to deliver greater added value, sustainability, renewability and lower costs especially in the automotive industry. Further research involves the fibre crop production. The ever-increasing volume of scientific literature refers with enthusiasm to the potential of natural fibres in technological, economic and ecological terms. This enthusiasm tends to also expand to the areas of human life and socio-economic development for the fibre crop growers and their communities. However, there is very little debate or evidence to support statements about the assumed advantages for the affected population in rural areas. We argue that despite the predicted new boom in the demand of natural fibres, it is unlikely that this will represent a real improvement in the quality of life of crop fibre growers and their communities. This paper examines the experience of Mexico as a case study and argues that only through consistent political will and co-operation between governments, industry, scientists, consumer groups and local communities, as well as a suitable economic strategy such as local subsidies, a truly sustainable economic development, social equity and improved environmental quality will be achieved for tens of thousands of natural fibre growers.     

Measurement of Fruit and Vegetable Losses in Brazil: A Case Study

This research conducted on municipal solid waste management for the first time quantified food spoilage as being 8.8% weight of all officially collected household garbage in the Brazilian city under study. The unexpected size of this waste fraction gave rise to work on the causes of waste and on its distribution over the product life cycle specific to fruit and vegetables. Waste was defined as being the combination of losses and scraps. Administrative shortcomings were identified as basic reasons for waste. At the producer and consumer ends of the cycle, negligence was shown to be the single most important problem. Fruit and vegetables deteriorate during the operations of handling, transport, packaging, storage, selling and consumption. The study detailed the occurrence of waste at all of these stages. In the medium-size Brazilian city, the total waste of fruit and vegetables was shown to amount to 16.6% weight in the marketing stage of the life cycle. At the consumer level, it was measured as 3.4% weight of all household garbage. Specific reasons for this waste were identified at the levels of producer, wholesaler and retailer. Short-term remedies were pointed out that invariably corrected deficient management procedures. It was shown that very simple administrative measures can significantly reduce the spoilage of fruit and vegetables. Long-term strategies involve the creation of sample cases for administration of the fruit and vegetables life cycle at all stages.     

Evaluation of the strength characteristics of cement-stabilized clay–crumb rubber mixtures for its sustainable use in geotechnical applications

The proper disposal of discarded waste tires is becoming a serious matter of concern worldwide as huge proportion of this waste is being generated which makes the proper disposal virtually infeasible. About 1000 million of waste tires are discarded every year, and by the year 2030, it will turn up to 1200 million per year. If this enormous quantum of waste remains unattended, it would led to serious health and environmental problems. The investigation aims at appraising the compaction and strength characteristics of clayey soil incorporated with waste crumb rubber and cement for its sustainable use in geotechnical application. A series of unconfined compression strength and split tensile strength tests were carried out on clayey soil incorporated with two percentages of cement (3 and 6%) by weight and four percentages of crumb rubber (2.5, 5.0, 7.5, and 10.0%) by weight. Moreover, scanning electron microscope analysis was also carried out to get better intuition about the behaviour of the composite. Test results suggested that crumb rubber (up to 5%) could be mixed with uncemented/cemented clay soil with the congruent impression. The inclusion of discarded waste tires in cemented clay would be one of the congenial methods for the disposal of this waste as it substantially reduces the deleterious influence of waste tire disposal on human health and ecology.     

Evaluation of Brasilia wastewater sludge as a biomass resource for the production of energy by gasification simulation

This work evaluated the sludge potential of the Wastewater Treatment Plant (ETA) in the city of Brasília to be used as a fuel by gasification. It is known that ETA sludge is a significant environmental liability, since current legislation restricts its final disposal. For this, the chemical characterisation of ETA sludge was performed by immediate and elemental analysis. No traces of heavy metals were observed, and the moisture (ω) and ash contents were 31.17 and 51.77%, respectively, different from those already reported in the literature because the composition depends on the water treatment technology employed. The gasification process was numerically simulated; once dry, it constitutes a residue with an energy content (HHV) of 22.4498 MJ kg^?1, comparable with other types of biomass currently used for large-scale energy generation by thermochemical processes (e.g. agricultural residues, wood and sugar cane bagasse). For the numerical simulation with an equivalence ratio (Φ) near 3, higher concentrations of CO and H₂ can only be achieved with ω lower than 15%. The results showed that gasification can be an attractive option for the disposal and use of a renewable waste resource, such as ETA sludge, in an environmentally safe way, and it is allowed by local legislation.     

Improving the thermal performance of single-glazed windows using translucent granular aerogel

Cost-effective materials, products and installation methods are required to improve the energy efficiency of the UK's existing building stock. The aim of this paper is to assess the potential for high-performance translucent granular aerogel insulation to be retrofitted over single glazing to reduce heat loss without blocking out all of the useful natural light. In situ testing of a 10-mm-thick prototype panel, consisting of a clear twin-wall polycarbonate sheet filled with granular aerogel, was carried out and validated with steady-state calculations. Results demonstrate that an 80% reduction in heat loss can be achieved without detrimental reductions in light transmission. Payback calculations accounting for the inevitable thermal bridging from openable solutions such as roller shutters or pop-in secondary glazing suggest that a return on investment between 3.5 and 9.5 years is possible if products are consistently used over the heating season. Granular aerogel is a promising material for improving the thermal performance of existing windows. Future research will seek to map out different ways in which the material can be applied to the existing UK housing stock, identifying which systems offer the greatest potential for widespread CO₂ savings over their life cycle.     

Carbon footprint of recycled biogenic products: the challenge of modelling CO2 removal credits

Current carbon footprinting (CF) and life cycle assessment (LCA) methods do not treat recycled biogenic carbon adequately, because the calculation rules for recycled products and biogenic carbon stored in products are defined independently from each other. Therefore, an improved and consistent calculation rule for the CF of product systems containing both recycling processes and carbon stored in products is proposed. The methodological approach consists of the application of the same allocation principles for both greenhouse gas (GHG) releases and GHG removals: (1) explicit accounting of inputs (GHG removals) and outputs (GHG releases) of biogenic carbon flows instead of assuming carbon neutrality per se; (2) consistent application of allocation rules for environmental benefits and environmental burdens. It is shown that the different modelling approaches (e.g. polluter pays, conservative or partitioning) lead to different results in LCA and CF calculations, e.g. the GHG emissions of first life cycle of the product system calculated here range between ? 1.6 units in the polluter pays approach and 4 units in the conservative approach. It is shown that the currently common modelling is an average approach for primary biogenic material, a worst-case approach for recycled biogenic material and a best-case approach for disposed biogenic material. This paper proposes to improve the currently developed standards for CF by adding a requirement to the goal and scope definition phase that ensures the consistent and transparent documentation, how biogenic carbon removal credits are allocated between life cycles.     

城市产业部门CO2排放三层次核算研究

城市是人类生产和生活的中心,超过75%的温室气体从城市产生,其中又以城市产业部门能源消费和工业过程非能源产生的CO2为主。本文基于投入产出模型,评价城市产业部门3个不同层次的CO2排放。以重庆为案例,核算其2002-2008年产业部门三个层次的CO2排放,包括能源消费直接排放、购买电力间接排放和全生命周期排放,并进行多层次对比。结果显示传统能源消耗和购买电力为对象的核算方法低估了产业部门CO2排放水平。2002-2008年,重庆各产业部门排放量逐年增加,碳排放强度整体呈现下降趋势。煤炭开采和洗选业、非金属矿采选业、非金属矿物制品业、电力、热力的生产和供应业,化学工业、金属冶炼及压延加工业、交通运输、仓储及邮电通讯业部门共7大行业是重庆碳排放的重点行业。部门交通设备制造业是重庆的优势产业,排放总量大,但是排放强度却相对较小,因此应大力发展该产业以促进重庆市低碳经济的发展。