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1.
The presence of toxic heavy metals in the environment is considered as a risk factor for adverse human and environmental health effects. Farahabad Region is a tourist center in the southern coast of Caspian Sea in Mazandaran Province of Iran. Environmental monitoring of this site is important for public health for individuals visiting and residing in this region. Although numerous biomonitoring data are available globally, very few if any apparent investigations have been conducted in this region. In this study, concentration of three heavy metals chromium (Cr), lead (Pb), and cadmium (Cd) was determined for one year in Cladophora glomerata, the predominant macroalga species present in this region. Detection of heavy metals was performed with atomic absorption spectrophotometer using standard methods. Results showed that the range of Cr metal in various algal samples was 29–55 ppm/g dry weight. The levels of Pb in algal samples (Cladophora) ranged from 2 to 8 ppm/g dry weight. The Cd concentrations in C. glomerata biomass ranged from 1.5 to 8.2 ppm/g dry biomass. In view of potential threats of such high metal concentrations in coastal waters and in algal tissues, it is necessary to adopt conservation measures to ensure public health safety.  相似文献   

2.
The present study was conducted to determine the heavy metal contamination in soil with accumulation in plants in waste water irrigated areas. Results revealed that waste water contained lower concentrations of Cr, Zn, Cu, and Pb except Cd (0.03) than the permissible limits prescribed by the World Health Organization. The maximum metal concentrations occurred in Brassica oleracea (Zn 63.80, Cu 12.25, Cr 10.65, Pb 3.63, and Cd 0.56 mg Kg?1).The metal enrichment (EF of Cd 1.9, Cr2.9, Zn 4.8, Cu 6.5, and Pb 15.5) and degree of contamination (CF of Cd 2.9, Cr 2.0, Zn 2.3, Cu 2.7, and Pb 2.2) showed that accumulation of the five toxic metals increased during sewage irrigation as compared with the reference values, other Indian regions and globally. However, based on WHO standards for heavy metal contamination of soil and irrigation water, our data does not ensure safe levels for food.  相似文献   

3.
几种植物处理含重金属废水的适应性研究   总被引:18,自引:2,他引:18  
试验采用蕹菜、油菜、美人蕉、水葫芦、水花生、水浮莲6种适应人工湿地的植物,在水培情况下研究了它们对Hg、Cd、Pb、Cr、Cu、Zn6种重金属的适应性,以综合考虑了植物的适水性与对重金属耐性的生物量为指标,得出了植物对6种重金属模拟废水综合耐性由强到弱的排序为美人蕉→水葫芦→油菜→水浮莲→蕹菜→水花生。不同植物对于其中一种重金属的单一耐性也有差异,美人蕉对Cr、Hg、Zn耐性较强,水浮莲对Pb、Cu、Cd耐性较强。植物对重金属的综合耐性和单一耐性的试验结果可为湿地处理含重金属废水提供参考。  相似文献   

4.
The present investigation deals with the accumulation of heavy metals in fields contaminated with fly ash from a thermal power plant and subsequent uptake in different parts of naturally grown plants. Results revealed that in the contaminated site, the mean level of all the metals (Cd, Zn, Cr, Pb, Cu, Ni, Mn and Fe) in soil and different parts (root and shoots) of plant species were found to be significantly (p<0.01) higher than the uncontaminated site. The enrichment factor (EF) of these metals in contaminated soil was found to be in the sequence of Cd (2.33) > Fe (1.88) > Ni (1.58) > Pb (1.42) > Zn (1.31) > Mn (1.27) > Cr (1.11) > Cu (1.10). Whereas, enrichment factor of metals in root and shoot parts, were found to be in the order of Cd (7.56) > Fe (4.75) > Zn (2.79) > Ni (2.22) > Cu (1.69) > Mn (1.53) > Pb (1.31) > Cr (1.02) and Cd (6.06) approximately equal Fe (6.06) > Zn (2.65) > Ni (2.57) > Mn (2.19) > Cu (1.58) > Pb (1.37) > Cr (1.01) respectively. In contaminated site, translocation factor (TF) of metals from root to shoot was found to be in the order of Mn (1.38) > Fe (1.27) > Pb (1.03) > Ni (0.94) > Zn (0.85) > Cd (0.82) > Cr (0.73) and that of the metals Cd with Cr, Cu, Mn, Fe; Cr with Pb, Mn, Fe and Pb with Fe were found to be significantly correlated. The present findings provide us a clue for the selection of plant species, which show natural resistance against toxic metals and are efficient metal accumulators.  相似文献   

5.
The river Kali has been one of the major recipients of industrial effluents in the Muzaffarnagar district of western Uttar Pradesh. The present studies revealed the occurrence and bioaccumulation of heavy metals (Cd, Cr, Pb, Zn, Mn) in riverine water, sediment, and muscles of two fish species, Heteropneustis fossilis and Puntius ticto. Data showed that the order of occurrence of heavy metals was Pb > Zn > Mn > Cr > Cd in river water, Mn > Zn > Pb > Cr > Cd in sediment, Zn > Mn > Cr > Cd > Pb in Puntius ticto and Cr > Zn > Mn > Cd > Pb in Heteropneustis fossilis. Results indicate that the concentrations of Cd, Pb, and Zn in river water, Pb, Zn, and Mn in sediment, Cd, Cr, Pb, and Zn concentration in muscles of Puntius ticto and Cr, Pb, and Zn concentration in in muscles of Heteropneustis fossilis are higher than the permissible standard limits. The presence of heavy metals contributed to toxicity in different organs of fish in River Kali. The bioaccumulation of heavy metals in different biotic organisms in river ecosystem may have adverse consequences on humans and livestock.  相似文献   

6.
In the present study, impact of tannery and other industrial effluents on the physico-chemical characteristics of loamy drain water and their consequent impact on soil and plants irrigated with effluent have been studied. The study reveals most of the parameter pH, BOD5 and COD at sampling station I was higher than station II. Waste water quality at both Stations I and II exceeded prescribed limits (BIS) for safe disposal of effluents into the surface water Samples of soil and vegetables from the land irrigated with loamy drain water has been collected and analyzed for Cu, Zn, Ni, Cr Pb and Cd. The different metals showed different enrichment factor for loamy drain water irrigated soil and are as follows: Cd 30% (max), Pb 26%, Zn 18%, Cr 5%, Cu 5%, Ni 2% (min). For plant samples collected at polluted sites are Ni 46% spinach (whole plant) (max), Zn 42% spinach (whole plant), Cr 39% spinach (whole plant), Cu 33% spinach (whole plant), Pb 20% potato tuber, Cd 20% potato tuber (min). The levels of Zn 145, Cu 5.25, and Ni 39.25 microg/ g in spinach, Pb 29.25, Cr 38. 25 and Cd 3.2 microg/g in potato tuber grown on polluted soil irrigated with contaminated drain water were found more than the reference value, which may create chronic health hazard problem to human and cattle through food chain in long run. Accumulation of toxic heavy metals may be build up in the agriculturally productive land where it is treated with contaminated effluent enrich with metals in turn bio-concentrated in the edible fodder/plants.  相似文献   

7.
Heavy metals, a highly polluting group of constituents known to exert adverse effects, tend to accumulate in living organisms. The objective of this study was to determine the accumulation and translocation of heavy metals in soil and in paddy crop irrigated with lake water compared to soil and paddy crop irrigated with bore-well water. The quantities of heavy metals (Cd, Cr, Cu, Pb, Zn, As, Mn, and Hg) were determined in different parts of rice plants (Oryza sativa). Results revealed that the mean levels of soil Cd, Cr, Pb, Zn, As, Mn, and Hg in experimental soil and in different parts of rice plant (root, straw, and grain) were higher than the control except for Cu. The content of eight toxic metals was significantly higher in root than in aerial parts of the rice (straw and grains). Rice roots were enriched in Cd, As, Hg, and Pb from the soil, while Cr, Cu, Zn, and Mn were hardly taken by the roots. Bioaccumulation factor for Hg was significantly higher than other heavy metals. Metal transfer factors from soil to rice plants were significant for Cd, Cr, Cu, Pb, Zn, As, Mn, and Hg. The concentrations of metals in lake water were found to be within the permissible limit of Indian standard prescribed by Central Pollution Control Board (2000), except for Hg and As, which were higher than the limit of Indian standard. However, the concentrations of heavy metals in soil and rice grains were still below the maximal levels, as stipulated by Indian Prevention of Food Adulteration Act (PFA, 1954) and World Health Organization (WHO, 1993) guidelines.  相似文献   

8.
Total concentrations of Cr, Ni, Cu, Zn, Cd and Pb in surface sediments were determined to investigate the regional trends of heavy metal contamination in 11 coastal areas in Korea. Enrichment factor (EF) of heavy metals was calculated by comparing the level of their regional background. The averages of EF values in study areas were 0.99 for Cr, 1.05 for Ni, 4.23 for Cu, 1.80 for Zn, 3.92 for Cd and 1.54 for Pb, respectively. Dilute HCl extractions were useful to deduce the anthropogenic sources of heavy metals and the 1 M HCl extractable fractions of each metal varied from 0.3 to 37.3% for Cr, 1.9 to 66.3% for Ni, 4.2 to 92.9% for Cu, 7.1 to 99.7% for Zn, 10.9 to 98.9% for Cd and 15.0 to 99.1% for Pb. Comparing 1 M HCl extractable fraction to total concentration, large portions of Cu, Zn, Cd and Pb were present as potentially bioavailable fractions from anthropogenic input and were significantly correlated with their EF values showing r > 0.68.  相似文献   

9.
Heavy metal concentrations (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn) were determined in various tissues (hepatopancreas, branchial hearts, salivary gland, gills, genital tract, mantle, arms and skin) of Octopus vulgaris collected from three different contaminated sites in front of Alexandria (Egypt) during 2000. All collected tissues displayed high enrichment factors when compared to ambient levels. Heavy metal concentrations in most tissues displayed significant differences among sites, sizes and sex. This study suggests that hepatopancreas, and to a lesser extent branchial hearts, are better indicators of chronic Cu, Fe, Zn and Cd contamination than edible tissues. The enrichment factor (EF) for heavy metals in the hepatopancreas and in edible tissues allowed discriminating our samples into three main groups; (1) EF?>?55 (Cu), (2) EF ranging from 15 to 7.5 (Fe, Cd and Zn) and (3) EF?相似文献   

10.
The accumulations of Al, Cd, Cr, Cu, Fe, Ni, Pb and Zn in the exoskeleton, gills, hepatopancreas and abdominal muscles of crayfish Astacus leptodactylus (Eschscholtz, 1823) were determined. The strongest correlation observed was between Cr and Ni in the gills (r?=?0.904); moderate to strong correlations between Al, Cr, Fe, Ni and Cu were also observed in gill tissue. Disregarding the gills, the strongest correlation was found between Cu and Zn in the hepatopancreas (r?=?0.808); the correlation between these two metals might have been a result of metallothionein activity. The accumulation of Pb was found to correlate with that of Cd in the exoskeleton, Cd and Zn in the gills, Zn and Cu in the hepatopancreas and Cu in the abdominal muscle. None of these correlations were present in lakewater and sediment samples, suggesting that the crayfish metabolism may be responsible for the co-accumulation of metal–metal pairs. As all correlations in non-gill tissues are observed between divalent metals, a shared transporter such as divalent metal transporter 1 might be involved in the accumulation of these metals.  相似文献   

11.
The concentrations of four metals (Cd, Ni, Pb, and Cr) were determined in the muscles, gills, and livers of two edible fish species (Liza klunzingeri and Sillago sihama) caught from the Hara biosphere of Southern Iran. In both fish species, metal concentrations and bioaccumulation factors were in the sequence liver?>?gill?>?muscle. Bioaccumulation factors were found to be highest in S. sihama. The metal concentrations were descending in the order of Ni?>?Cr?>?Pb?>?Cd, except for muscle samples from S. sihama showing an inversion of Pb and Cr. There is a significant negative correlation between the concentrations of the metals in each tissue with length, weight, and age, except for muscle in L. klunzingeri. Some metal levels in the muscle exceeded the limits recommended by FAO, WHO, and FEPA.  相似文献   

12.
Some vascular plants are known to concentrate trace metals and are regarded to be suitable indicators of atmospheric metal deposition. Among plant species used for biogeochemical studies dandelion (Taraxacum officinale.) is convenient for monitoring air/soil pollution. The plant commonly occurs in different ecosystems with relatively parallel stages of ontogenesis over a broad area of geographical regions. Its leaves and roots are easily accessible for sampling. Leaf to root ratios of metal concentrations in dandelion may indicate the source of metals during the growing season. Trace metals in leaves and roots of dandelion from 132 sites in Poland showed higher concentrations in the plants from the SW region compared to those from the NE region of the country. However, the differences were only statistically significant ( = 0.05) for Cd, Ni, and Pb. Geometric means of metal concentrations (mg kg–1, air dried weight) in dandelion leaves of the SW and NE regions were: Cd 0.85, 0.52; Cr 0.99, 0.81; Cu 11.2, 11.1; Fe 184.4, 100.0; Mn 59.7, 51.4; Ni 2.1, 1.5; Pb 4.4, 3.0; and Zn 49.6, 41.3, respectively. Markedly higher concentrations of Cd, Pb, and Zn were found in the leaves of the dandelion over roots in the SW region. These metals are the most serious aerial pollutants in that part of the country.  相似文献   

13.
The levels of heavy metals (Cd, Cr, Ni, Pb, Sb and V) in Sporobulus pyramidalis plant species from an abandoned battery industry environment were determined during the wet and dry seasons as follows: The ranges in metal concentrations during the wet and dry seasons were 0.002, 0.420, 0.036 and 36.10?µg?g?1, respectively. The coefficients of variation for the metals during wet and dry seasons ranged between none to 151.724% and 13.838–214.935%, respectively. The results showed higher levels of the metals in S. pyramidalis during the dry than wet season. Results obtained from both wet and dry season when compared with background values, Federal Environmental Protection Agency and other international standards revealed that the plant species accumulated high levels of these heavy metals which was evident in concentrations exceeding maximum tolerable limits. The health implications of consuming this plant and any other plant or crop within this environment are discussed.  相似文献   

14.
Twenty trace elements in fine particulate matters (i.e., PM2.5) at urban Chengdu, a southwest megacity of China, were determined to study the characteristics, sources and human health risk of particulate toxic heavy metals. This work mainly focused on eight toxic heavy metal elements (As, Cd, Cr, Cu, Mn, Ni, Pb and Zn). The average concentration of PM2.5 was 165.1 ± 84.7 µg m?3 during the study period, significantly exceeding the National Ambient Air Quality Standard (35 µg m?3 in annual average). The particulate heavy metal pollution was very serious in which Cd and As concentrations in PM2.5 significantly surpassed the WHO standard. The enrichment factor values of heavy metals were typically higher than 10, suggesting that they were mainly influenced by anthropogenic sources. More specifically, the Cr, Mn and Ni were slightly enriched, Cu was highly enriched, while As, Cd, Pb and Zn were severely enriched. The results of correlation analysis showed that Cd may come from metallurgy and mechanical manufacturing emissions, and the other metals were predominately influenced by traffic emissions and coal combustion. The results of health risk assessment indicated that As, Mn and Cd would pose a significant non-carcinogenic health risk to both children and adults, while Cr would cause carcinogenic risk. Other toxic heavy metals were within a safe level.  相似文献   

15.
The level of accumulation of selected essential and non-essential metals, namely; Ca, Cu, Fe, Zn, Mn, Cd, Pb, and Cr have been investigated in the seeds, fruits, and flowers of some medicinal plants utilized for tapeworm treatment in Ethiopia and their respective soil samples. These include seed of Cucurbita maxima (Duba), fruit of Embelia abyssinica (Ankoko), flowers of Hagenia abyssinica (Kosso), and fruits of Rosa abyssinica (Kega) and their respective soil samples. A wet digestion procedure with a mixture of conc. HNO3 and HClO4 for the plant samples and a mixture of conc. HNO3, HCl, and H2O2 for soil samples were used to solubilize the metals. Ca (1280–12,670?mg?kg?1) was the predominant metal followed by Fe (104–420?mg?kg?1), and Zn (18–185?mg?kg?1) in all the plant materials except for Hagenia abyssinica flower from Hirna in which Mn (16–42?mg?kg?1) followed by Fe. Among the non-essential toxic metals, Pb was not detected in Cucurbita maxima of Boji, Gedo and Hirna origins and in Rosa abyssinica of Hirna site. Similarly, Cr was not detected in Rosa abyssinica fruits of Boji and Gedo sites. The sampled soils were found to be between strongly acidic to weakly basic (pH: 4.7–7.1). In the soil samples, Ca (8528–18,900?mg?kg?1) was the most abundant metal followed by Fe (417–912?mg?kg?1), Zn (155–588?mg?kg?1), Mn (54–220?mg?kg?1), Cr (21–105. mg?kg?1), Cu (11–58?mg?kg?1), Pb (13–32?mg?kg?1) and Cd (2.8–4.8?mg?kg?1). The levels of most of the metals determined in the medicinal plants and the respective soil samples are in good agreement with those reported in the literature and the standards set for the soil by various legislative authorities.  相似文献   

16.
The quality of cultivated consumed vegetables in relation to environmental pollution is a crucial issue for urban and peri-urban areas, which host the majority of people at the global scale. In order to evaluate the fate of metals in urban soil–plant–atmosphere systems and their consequences on human exposure, a field study was conducted at two different sites near a waste incinerator (site A) and a highway (site B). Metal concentrations were measured in the soil, settled atmospheric particulate matter (PM) and vegetables. A risk assessment was performed using both total and bioaccessible metal concentrations in vegetables. Total metal concentrations in PM were (mg kg?1): (site A) 417 Cr, 354 Cu, 931 Zn, 6.3 Cd and 168 Pb; (site B) 145 Cr, 444 Cu, 3289 Zn, 2.9 Cd and 396 Pb. Several total soil Cd and Pb concentrations exceeded China’s Environmental Quality Standards. At both sites, there was significant metal enrichment from the atmosphere to the leafy vegetables (correlation between Pb concentrations in PM and leaves: r = 0.52, p < 0.05) which depended on the plant species. Total Cr, Cd and Pb concentrations in vegetables were therefore above or just under the maximum limit levels for foodstuffs according to Chinese and European Commission regulations. High metal bioaccessibility in the vegetables (60–79 %, with maximum value for Cd) was also observed. The bioaccessible hazard index was only above 1 for site B, due to moderate Pb and Cd pollution from the highway. In contrast, site A was considered as relatively safe for urban agriculture.  相似文献   

17.
为了解我国华东地区鳜肌肉重金属含量现状,采集华东地区(江西南昌,安徽池州、滁州,江苏南京、扬州,浙江建德等)10个采样点野生鳜和池塘主养、池塘套养鳜样本共60份,采用原子荧光光谱分析法(AFS)、石墨炉原子吸收法(GFAAS)测定鳜背部肌肉中铬(Cr)、镉(Cd)、无机砷(As)、汞(Hg)和铅(Pb)等5种重金属的含量,评估其食用安全性与健康风险。结果表明,肌肉中Cd、Cr、Pb、As和Hg的总检出率为98.67%,总超标率为11.67%;其中,Pb、Cd和As超标样,分别占总样本量的28.33%、15%和15%,超标浓度为(0.612±0.111)、(0.181±0.031)和(0.474±0.035) mg·kg~(-1),71.43%的超标样分布于野生鳜群体;Cr、Hg的检出含量均低于我国鱼类水产品重金属的最高限量标准(GB 2762—2017)。3种养殖方式的鳜肌肉中重金属含量分布具有相似的规律(Pb>As>Cr=Cd>Hg),野生鳜肌肉中重金属含量高于人工养殖鳜,池塘主养鳜与池塘套养鳜之间无明显差异。食用安全性评价结果显示,目前,华东地区鳜达到国家标准的限量要求,仅Pb、As含量稍高,分别占周可耐受摄入量(PTWI)的14.42%和21.54%。健康风险评价结果显示,所有鳜样均未超过国际辐射防护委员会(ICRP)推荐的最大可接受水平(5×10~(-5)a~(-1))。野生鳜食用安全性低于人工养殖鳜,健康风险高于人工养殖鳜。上述研究结果为鳜水产品安全性评价与健康养殖提供了基础数据。  相似文献   

18.
The ability of surface flow and subsurface flow simulated wetlands to remove heavy metals from a NaCI-enriched wastewater was examined, employing bulrush (Scirpus validus) and cattail (Typha angustifolia) plants, and two organically amended substrates (mixtures of mushroom compost and leaf litter,with topsoil) with a limestone liner. A simulated wastewater solution containing Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn as chloride salts was added to the wetlands at a rate of 0.3 l h–1. During 12 weeks of surface flow, Fe was retained most efficiently (74%), and Mn the least (24%). Most metal retention occurred in residual forms, primarily in the upper 5 cm of the substrate. A subsequent 10 week subsurface flow treatment exhibited greater removal efficiencies for all metals, probably due to increased contact with the highly buffered lower substrate. During both treatments, bioaccumulation occurred in plants, but accounted for a very small portion of the total metal removal. Plant species did not significantly influence wetland performance with respect to metal retention. Substrate type did not affect removal efficiency for most metals, but did influence the forms of the metals retained in the wetland.To whom correspondence should be addressed.  相似文献   

19.
为探讨重金属Cr(VI)、Pb以及Cu对沙蚕体腔细胞DNA的毒性效应,以双齿围沙蚕为受试动物,重金属按不同剂量水平,Cr(VI):10、100和200 mg·L~(-1),Pb:5、50和100 mg·L~(-1),Cu:1、10和20 mg·L~(-1),分别胁迫沙蚕24 h,以不加任何重金属离子的海水为对照,采用单细胞凝胶电泳技术,检测其体腔细胞DNA损伤程度。结果表明,与空白对照组相比,3种重金属离子的各浓度组都能引起沙蚕体腔细胞DNA损伤,且3种重金属胁迫浓度与细胞DNA损伤程度之间存在显著的剂量-效应关系。双齿围沙蚕可以作为单细胞凝胶电泳的实验材料用于重金属所致环境污染的生物监测指示生物。  相似文献   

20.
Concentrations of nine heavy metals (Cr, Cd, Pb, Ni, Cu, Zn, Mn, As, and Fe) in the muscles of four fish species (O. niloticus, C. gariepinus, P. latipinna, and A. d. dispar) collected from the Riyadh River were detected using atomic absorption spectrophotometry in two different seasons in 2012. The concentrations of the studied heavy metals except Cd, Pb, Ni, and Cu in Aphanius d. dispar and Poecilia latipinna were found to be below the safe limits suggested by various authorities. This study also showed that Zn was predominant, while Cr was least accumulated metal in the studied fish muscles. Data demonstrated that there was a significant variation in the heavy-metal concentrations in different fish species in the Riyadh River. Significant positive correlations between heavy-metal concentrations in fish muscles were also found both in pre- and post-monsoon seasons. Metal pollution index was calculated to distinguish polluted from unpolluted ecosystems based upon current knowledge of metal bioavailability, bioconcentration, and bioaccumulation patterns. From the human health point of view, this study showed that there was a possible health risk to consumers due to the intake of Aphanius d. dispar and Poecilia latipinna under the current consumption rate in the country.  相似文献   

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