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1.
A method for quality screening is suggested to detect volatile impurities in inorganic coagulants that are used for drinking water treatment. Static headspace gas chromatography with mass spectrometry detection (HS–GCMS) is sensitive and selective to detect volatiles in low concentrations. This study has discovered that volatile organic impurities are detectable in ferric and aluminium-based coagulants which are used for drinking water treatment. For ferric chloride, 2-propanol was detected at a level of 17–24 μg ml−1, acetone at 0.7–1.7 μg ml−1, 1,1,1-trichloroacetone at 0.02–0.04 μg ml−1, trichloromethane at 0.01–0.02 μg ml−1 and toluene at 0.01–0.12 μg ml−1. For ferric chloride sulfate, acetone was detected at a level of 0.12 μg ml−1, 1,1,1-trichloroacetone at 0.06–0.08 μg ml−1, trichloromethane at 0.13–0.23 μg ml−1, bromodichloromethane at 0.04–0.06 μg ml−1 and dibromochloromethane at 0.04–0.05 μg ml−1. For aluminium hydroxide chloride, only trichloromethane was detectable, but below the method detection limits (MDL). Although the concentrations of these impurities in commercial coagulants are low, this observation is important and should have impact on water industries for them to pay attention to the chemicals they are using for drinking water production.  相似文献   

2.
Age dependency of [3H]-ouabain binding, 45Ca2+ eflux and its magnetosensitivity in rats’ brain cortex and heart muscle tissues were studied. Curves of dose-dependent [3H]-ouabain binding consisted of three components with different affinities (10−7–10−4 M (α1); 10−9–10−7 M (α2); and 10−11–10−9 M (α3)). These curves were also characterized by different dose-dependent kinetics. [3H]-ouabain binding with α3 receptors in brain cortex and heart muscle tissues of young and adult animals had a dose-dependent character, while that in old ones had a dose-independent character. A 0.2 T static magnetic field (SMF) exposure had modulation effect on ouabain binding with α1, α2 and α3 receptors in young rats, while in adult ones, only α3 receptors were magnetosensitive. In old animals, SMF exposure had no significant effect on ouabain binding with α3 receptors in brain cortex, while in heart muscle, it had inhibitory effect on it. Age-dependent effect of ouabain impact on 45Ca2+ efflux showed that all concentrations of ouabain lead to inhibitory effect in young animals’ brain cortex and heart muscle (with the exception of 10−10 and 10−6 M), while in old ones, it had activation effect as compared with data received without ouabain. SMF exposure in young animals had activation effect on 45Ca2+ efflux from brain cortex and heart muscle in data without ouabain, and in old rats, 45Ca2+ efflux from brain cortex was magnetic insensitive. In old animals, SMF increased 45Ca2+ efflux even after extra low concentration of ouabain. It is suggested that α3 receptors having a crucial role in the regulation of Na+/Ca2+ exchange serve as age-dependent magnetosensors of excitable cells.  相似文献   

3.
The effects of turbulence intensity (velocity gradient, G (s−1)), Henry's law constant (H), and molecular weight (M) on the volatilization rates of organic compounds are examined using changes in the mass transfer coefficients (KOL (cm/min)) under specific liquid-mixing intensities. The selected compounds were divided into three groups according to their H values (mole in gas/mole in liquid, dimensionless), which ranged from 102 to 10−5. The relationship of the KOL relative to G, H and M was obtained via multiple regression. The obtained values of these parameters indicate that the primary factor affecting the KOL values of the high H compounds is their M values. The effects of the H values on the KOL values of the high H compounds can be neglected. On the other hand, the H value is the major factor determining the KOL values of the low H compounds. The changes in the KOL values of the different H compounds exhibit different profiles as the liquid-mixing intensity increases. The M and H values of middle H compounds possibly affect their KOL values. The effects of the liquid-mixing intensity on the KOL values of the organic compounds increase with increasing H values. The variation in the KOL values might be a result of the concentration of the organic compounds at the interface between the liquid and gas films. The empirical relationship between KOL and some selected parameters, G, H and M, is examined in this study. The obtained results can help to estimate volatilization loss of organic solutes in wastewater treatment facilities.  相似文献   

4.
The concentrations of heavy metals (mg/g) Pb, Ni, Cu, Cr, Fe, Co, Cd, and Hg in the tissues of young and adult toads exposed to petroleum-polluted environment were determined in order to assess the impact of petroleum-processing activities in Ekpan. The data showed that the levels of these Metals ranged between 0.15–1.18 and 0.10–0.48 in young and adult toads respectively. The heavy metals concentrations reported for the young toads have an abundance trend in the order of Pb > Fe > Ni > Cr > Cu > Co > Cd > Hg, while those of the adult toads are in the order of Pb > Fe > Cr > Ni > Cu > Cd > Hg > Co. The control analysis was carried out in a non-oil polluted area (Obiaruku) and the values served as base line values for the study.  相似文献   

5.
Book reviews     

RECORDING OLD HOUSES: A GUIDE

R. W. McDowall, 1980.

Council for British Archaeology.

33 pp. Illustrated Booklet.

THE GOOD LOOKING HOUSE

Beverley Pyke, 1980

The Redcliffe Press, Bristol.

64 pp. Illustrated Paperback, £2.25.

DEPENDENT DEVELOPMENT IN U.K. REGIONS WITH PARTICULAR REFERENCE TO WALES

P. Cooke

Progress in Planning, Vol. 15, pp. 1–62,1980

THE ECONOMICS OF IRRIGATION

I. Carruthers and Colin Clark, 1981

Liverpool University Press

LANDSCAPE BY DESIGN

Tony Aldous with Brian Clouston

Heinemann, London, £12.50

EVALUATION IN THE TPP PROCESS

A. G. Boviard, Editor, J.U.R.V.E.,

University of Aston in Birmingham. £6.50

PUBLIC TRANSPORT PLANNING IN SHIRE COUNTIES: An Evaluation of the Public Transport Plan as an aid to Transport Policy Making

J. P. Rigby

Oxford Polytechnic, Dept. of Town Planning  相似文献   

6.
Book reviews     

Geography and the Urban Environment Volume 3

Edited by D. T. Herbert, R. J. Johnston Wiley, 1980

428 pp

Les Villes Francaises

P. Barrere and M. Casson‐Monnat.

Masson, Paris, 1980.

Planning in the Soviet Union

Pallot, J., and Shaw, D.J.B.

Crook Helm, London, £6.95.

The Study of Urban Geography — Third Edition

Harold Carter

Edward Arnold (Publishers) Ltd., London

£6.95 paperback.

Land Use

David Rhind and Ray Hudson

Methuen and Co. Ltd., London.

£4.95 paperback.  相似文献   

7.
Efforts were made to assess the earthworm’s density and their casting activity under different surface plant stands (Citrus reticulata, Rosa indica, Citrus + Rosa, Tabernaemontana divaricata, Dalbergia sissoo, and Cynodon dactylon) at few natural and planted sites of a semiarid part of Rajasthan, India. The role of earthworm community in nutrient dynamics of different layers of canopy soils was also measured during this study. Results suggested a direct impact of aboveground vegetation cover on soil microclimatic conditions and earthworm density. The maximum earthworm population density and casts production was under mixed plantation, i.e., Citrus + Rosa (119.2 ind. m−2 and 2,127.27 gm m2, respectively), while T. divaricata supported the minimum earthworm density and casting activities. The population density and total casts production was in the order: C. reticulata + R. indica > R. indica > D. sissoo > C. dactylon > C. reticulata > T. divaricata. Earthworm casts and canopy soils (0–10 and 10–20 cm depth) under different plant stand were analyzed for organic C, total N, available P, and exchangeable cations (K+, Ca2+ and Mg2+). Earthworm casts collected under Citrus + Rosa showed the maximum level of organic C, total N, available P, and exchangeable cations (K+ and Mg2+). It is concluded that resource input by standing plant community directly affects the canopy soil quality and, thereby nutrient level in earthworm casts. This study suggested that aboveground vegetation pattern plays an important role to improve the nutrient level of canopy soils and belowground earthworm activities.  相似文献   

8.
The degradation of polyacrylamide (PAM) in simulate wastewater was studied in UV/Fenton/C4H4O62? system. The factors such as molecular ratio of H2O2/Fe2+/C4H4O62?, pH, and the dosage of Fenton reagent that could affect the PAM degradation in the UV/Fenton/C4H4O62? system were investigated. The experimental results showed that adding C4H4O62? to UV/Fenton system could form photosensitive ferrous complexes, which led to higher degradation efficiency of PAM. The degradation rate of PAM could be up to 95.2% under the following conditions: the concentration of H2O2, Fe2+, and C4H4O62? were 22.5, 2.25, and 2.25 mmol/L, respectively (i.e., molecular ratio of H2O2/Fe2+/C4H4O62? was 10:1:1), the pH value was 3.0.  相似文献   

9.
Epigeic earthworms (Oligochaeta) have been appeared as key organisms to convert organic waste resources into value-added products, i.e., vermicompost and worm biomass. The assessment of reproduction potential of composting earthworm may be beneficial for large-scale earthworm production. Although, the waste minimizing potential of Perionyx excavatus and Perionyx sansibaricus is well proved, but little information is available about their fecundity rate. In this study, the efforts have been made to explore the growth and reproduction biology of P. excavatus and P. sansibaricus, using cattle waste solid as culture substrate, under laboratory conditions. Earthworms were weighed weekly and number of cocoons produced per week assessed. Biomass productions, fecundity, maturation, natality all were significantly different between P. excavatus and P. sansibaricus. The highest mean individual biomass was 767.7 ± 18.4 mg and 612.6 ± 20.6 mg, respectively in P. sansibaricus and P. excavatus. However, the highest cocoon numbers occurred in P. excavatus (492.3 ± 13.6), significantly higher than P. sansibaricus (269.6 ± 17.1). Fecundity was slightly different in both species: 1.38 ± 0.77 cocoons adult worm−1 week−1 (P. excavatus) and 1.58 ± 0.74 cocoons adult worm−1 week−1 (P. sansibaricus). The hatchling success rate (%) was highest in P. excavatus. Overall natality (juveniles adult−1 week−1) was highest in P. sansibaricus (1.52) than P. excavatus (1.26), which suggests that P. sansibaricus may be a better candidate for rapid propagation of earthworms in cattle waste solid.  相似文献   

10.
Exergo-economic analysis of the pinch point temperature difference (PPTD) in both evaporator and condenser of sub-critical organic Rankine cycle system (ORCs) are performed based on the first and second laws of thermodynamics. Taking mixture R13I1/R601a as a working fluid and the annual total cost per net output power Z as exergo-economic performance evaluation criterion, the effects of PPTD in evaporator ΔTe, and the PPTD ratio of condenser to evaporator y, on the exergo-economic performance of ORCs are analyzed. Moreover, how some other parameters influence the optimal PPTD in evaporator ΔTe,opt and the optimal PPTD ratio of condenser to evaporator yopt are also discussed. It has been found that the exergo-economic performance of ORCs is remarkably influenced by ΔTe and y, and there exists ΔTe,opt and yopt. In addition, ΔTe,opt and yopt are affected by heat transfer coefficient ratio of condenser to evaporator ß, the temperature of working fluid at dew point in condenser T1a, and composition of R13I1/R601a: larger ß and T1a lead to lower ΔTe,opt and yopt; by contraries, larger mass fraction of R13I1 makes ΔTe,opt and yopt increase, and yopt increases linearly. The effects of the temperature of working fluid at bubble point in evaporator T3a, mass flow rate of exhaust flue gas mg, and inlet temperature of exhaust flue gas Tgi on ΔTe,opt and yopt are very slight. For comparison, three additional working fluids, namely R601a, R245fa, and 0.32R245fa/0.68R601a, are also taken into account.  相似文献   

11.
This paper examines the economic value of selected ecosystem services of Corbett Tiger Reserve, India. The direct cost was derived from secondary sources, and indirect and opportunity costs through socioeconomic surveys. For recreational value the individual approach to travel cost method was used, and to assess carbon sequestration the replacement cost method was used. The maintenance cost of the reserve was estimated as US $2,153,174.3 year−1. The indirect costs in terms of crop and livestock depredation by wild animals ranged from US $2,153,174.3 year−1. The indirect costs in terms of crop and livestock depredation by wild animals ranged from US 2,408 to US $37,958 village−1 over a period of 5 years. The dependence of local communities was for fuel wood (US $37,958 village−1 over a period of 5 years. The dependence of local communities was for fuel wood (US 7,346 day−1), fodder (US $5,290 day−1), small timber, and other nontimber forest products. The recreational value of the reserve was estimated as US $5,290 day−1), small timber, and other nontimber forest products. The recreational value of the reserve was estimated as US 167,619 year−1. With the cost per visitor being US $2.5, the consumers’ surplus was large, showing the willingness of visitors to pay for wildlife recreation. The forests of the reserve mitigate carbon worth US $2.5, the consumers’ surplus was large, showing the willingness of visitors to pay for wildlife recreation. The forests of the reserve mitigate carbon worth US 63.6 million, with an annual flow of US $65.0 ha−1 year−1. The other benefits of the reserve include US $65.0 ha−1 year−1. The other benefits of the reserve include US 41 million through generation of electricity since 1972. The analysis reveals that, though the benefits outweigh costs, they need to be accrued to local communities so as to balance the distribution of benefits and costs.  相似文献   

12.
13.
Textile mill waste can be vermicomposted if it is mixed in the range of 20–30% with cow dung. This article reports the effect of inoculation, of nitrogen fixing Azotobacter chroococcum strain; Azospirillum brasilense strain and phosphate solubilizing Pseudomonas maltophila, on nitrogen and phosphorus content of vermicomposts prepared from cow dung (CD) and cow dung spiked textile mill sludge (CD + STMS). The CD vermicompost was more supportive to the growth and multiplication of all the three bacteria than CD + STMS vermicompost. In Azotobacter chroococcum treated vermicomposts maximum nitrogen content was recorded between 45 and 60 days [CD␣vermicompost (25.9 ± 0.45 g kg−1) and CD + STMS vermicompost (20.6 ± 0.62 g kg−1)] followed by Azospirillum brasilense inoculation [CD vermicompost (19.4 ± 0.60 g kg−1) and CD + STMS vermicompost (18.6 ± 0.17 g kg−1)]. Phosphorus content in Pseudomonas maltophila inoculated CD vermicompost was 20.8 ± 0.20 g kg−1 and CD + STMS vermicompost was 13.4 ± 0.45 g kg−1 after 75th day of inoculation.  相似文献   

14.
15.
The study investigated vegetative and soil properties in four created mitigation wetlands, ranging in age from three to ten years, all created in the Virginia Piedmont. Vegetation attributes included percent cover, richness (S), diversity (H′), floristic quality assessment index (FQAI), prevalence index (PI), and productivity [i.e., peak above-ground biomass (AGB) and below-ground biomass]. Soil attributes included soil organic matter (SOM), gravimetric soil moisture (GSM), pH, and bulk density (Db) for the top 10 cm. Species dominance (e.g., Juncus effusus, Scirpus cyperinus, Arthraxon hispidus) led to a lack of differences in vegetative attributes between sites. However, site-based differences were found for GSM, pH, and SOM (P < 0.001). Soil attributes were analyzed using Euclidean cluster analysis, resulting in four soil condition (SC) categories where plots were grouped based on common attribute levels (i.e., SC1 > SC2 > SC3 > SC4, trended more to less developed). When vegetation attributes were compared between SC groups, greater SOM, lower Db, more circumneutral pH, and higher GSM, all indicative of maturation, were associated with higher H′ (P < 0.05), FQAI (P < 0.05), and total and volunteer percent cover (P < 0.05), and lower AGB (P < 0.001), PI (P < 0.05), and seeded percent cover (P < 0.05). The outcome of the study shows that site age does not necessarily equate with site development with soil and vegetation developmental rates varying both within and among sites. The inclusion of soil attributes in post-construction monitoring should be required to enhance our understanding and prediction of developmental trajectory of created mitigation wetlands.  相似文献   

16.
The rice fields, depleted of O2, contain large amount of moisture and organic substrates to provide an ideal anaerobic environment for methanogenesis and are one of the principal anthropogenic sources of methane. In order to mitigate this emission Alternative Electron Acceptors (AEA) were altered in the soil. The experiments were carried out in four seasons at the site of Balarampur, near Baruipur, South 24 Parganas, West Bengal, namely September–December, 2005 (Cultivar: Sundari), February–May, 2006 (Cultivar: Sundari), September–December, 2006 and February–May, 2007 (Cultivar: Swarna-Pankaj). The seasonal average methane flux (Fe treated), for the cultivar type “Sundari” (season: September–December, 2005), is 4.41 t ha−1, as compared to the value of 6.40 t ha−1 for the untreated soil. Similarly for February–May, 2006, the seasonal average methane flux (Fe treated) is 5.52 t ha−1, whereas the untreated flux is 5.69 t ha−1. In the third and fourth seasons we had two treatments with Ammonium Thiosulphate and Ferric Hydroxide. The seasonal average methane flux (treatment: Ammonium Thiosulphate) is 4.35 t ha−1 and 5.41 t ha−1 respectively, whereas for the ferric hydroxide treated soil it is 4.35 t ha−1 and 6.14 t ha−1 respectively. The properties related to the nutrient quality of the harvested paddy seeds supplement these results.  相似文献   

17.
ABSTRACT: This paper explores the use of nonlinear programming in river basin water quality modelling. Applications recently reported in the literature, along with the author's experience with nonlinear programming, are reviewed. Results obtained using nonlinear programming are compared with the results obtained by other researchers using linear and dynamic programming to solve river basin water quality optimization problems. These water quality models have objective functions with continuous first partial derivatives, several inequality and variable bound constraints, and are of the form: minizie Σj=nj=1Yj(Xj) subject to Σj=nj=1aijXjbi, i=1,2, …, m cjXjdj, j= 1,2, …, n The variable Xi is the maximum allowable ratio of the BOD (biochemical oxygen demand) of the effluent outflow to the BOD of the wastewater inflow for treatment plant j, in the range cj to dj. The aijd and bi are constants in the DO (dissolved oxygen) and BOD constraints. The resuks show, given certain assumptions about the data, that nonlinear programming is a better solution method for these problems than is either linear programming or dynamic programming.  相似文献   

18.
This study uses rate parameters in pseudo-first-order (PFO) and pseudo-second-order (PSO) equations (k1 and k2qe, respectively) to judge the extent for approaching equilibrium in an adsorption process. Out of fifty-six systems collected from the literature, the adsorption processes with a k2qe value between 0.1 and 0.8 min?1 account for as much as 70% of the total. These are classified as fast processes. This work compares the validity of PFO and PSO equations for the adsorption of phenol, 4-chlorophenol (4-CP), and 2,4-dichlorophenol (2,4-DCP) on activated carbons prepared from pistachio shells at different NaOH/char ratios. The activated carbons, recognized as microporous materials, had a surface area ranging from 939 to 1936 m2/g. Findings show that the adsorption of phenol, 4-CP, and 2,4-DCP on activated carbons had a k2qe value of 0.15–0.58 min?1, reflecting the fast process. Evaluating the operating time by rate parameters revealed that k2qe was 1.6–1.8 times larger than k1. These findings demonstrate the significance of using an appropriate kinetic equation for adsorption process design.  相似文献   

19.
The performance of polyurethane rotating discs (RBC-1) versus polystyrene rotating discs (RBC-2) for the treatment of an up-flow anaerobic sludge blanket (UASB) reactor effluent fed with domestic wastewater was investigated. Both RBC units were operated at the same organic loading rate (OLR) of 10.5 gCOD/m2 d. and a hydraulic retention time (HRT) of 2.5 h. The residual values of COD fractions (CODsuspended, CODcolloidal and CODsoluble) in the treated effluent of RBC-1 and RBC-2 were similar. However, the removal efficiency of ammonia in the RBC-1 (87 ± 4%) was significantly higher than that found for RBC-2 i.e. 24 ± 6%. Moreover, RBC-1 achieved a substantial removal efficiency of 99.0 ± 1% for Escherichia coli (E. coli), while RBC-2 removed 91.2 ± 0.3%. Based on these results, optimization of RBC-1 treating UASB reactor effluent was extensively performed. The RBC-1 was operated at an OLR's of 4.0, 11 and 23 gCOD/m2 d. The results obtained showed that increasing the OLR from 11.0 to 23.0 gCOD/m2 d and decreasing the HRT from 2.5 to 1.25 h significantly declined the effluent quality of CODtotal and ammonia. However, the residual values of CODtotal and ammonia remained unaffected when increasing the OLR from 4.0 to 11.0 gCOD/m2 d and by decreasing the HRT from 5 to 2.5 h. Bacteriological examination showed that the mean residual count of E. coli remained at a level of 104/100 ml, in the effluent of RBC-1 independent on the imposed HRT. Accordingly, it is recommended to operate RBC-1 for treatment of anaerobically pre-treated sewage at an OLR of 11 gCOD/m2 d and an HRT of 2.5 h.A feed-less (ammonia limitation) period of 9.0 days followed by 9.0 days feeding with high OLR of 26 gCOD/m2 d. (raw sewage) was investigated to elaborate, if the nitrifiers of the RBC-1 are capable to convert ammonia to nitrate after totally 18 days when retuning back to the normal operating conditions. The results of the experiment clearly show a strong and immediate detrimental effect of imposing high OLR of 26 gCOD/m2 d on the nitrification process in the nitrifying RBC unit. However, after returning back to the original OLR of 10.6 gCOD/m2 d, the nitrification efficiency in the RBC unit was recovered within 2–3 days.  相似文献   

20.
In the Upper Colorado River Basin (UCRB), there is a deep reliance on seasonal snowpack for maintenance of water resources. The term “snow drought” has recently emerged to describe periods of anomalously low snowpack. Unique seasonal patterns in precipitation and temperature that drive snow drought can have distinct hydrologic signatures, and these relationships have not been carefully studied in the UCRB. Here we examine snow drought with a new classification scheme using peak snow water equivalent (SWE) and the ratio of basin-wide modeled peak SWE to accumulated (onset to peak) precipitation (SWE/P) that clusters snow drought years into three distinct groups—“warm,” “dry,” and “warm & dry”—that minimize within-group variance. Over the period 1916–2018, we identify 14 warm years ( P ¯  = 160 mm; SWE / P ¯  = 0.24), 24 dry years ( P ¯  = 117 mm; SWE / P ¯  = 0.35), and 21 warm & dry years ( P ¯  = 94 mm; SWE / P ¯  = 0.23). An elevation-based analysis reveals two distinct patterns: warm snow droughts see severe SWE reductions primarily at lower (<2600 m) elevations (65% at lower elevations, 37% overall), whereas “dry” scenarios exhibit a consistent reduction across all elevations (39% overall). Using naturalized streamflow data, we also differentiate snow droughts by their earlier streamflow timing and decreased peakedness (warm: 7 days, 2%; dry: 7 days, 2%; warm & dry: 13 days, 5%). This research provides new insights into snow drought patterns relevant for regional water management.  相似文献   

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